Revision Date: SAFETY DATA SHEET 1. IDENTIFICATION , CXV3948A, CVP8251A. Laundry detergent. Consumer use. No information available

Transcription

1 SAFETY DATA SHEET Product identifier 1. IDENTIFICATION Product name: Other means of identification Product code: Synonyms: , CXV3948A, CVP8251A None Recommended use of the chemical and restrictions on use Recommended use: Uses advised against: Laundry detergent. Consumer use. Statements of hazard nature Classified as a hazardous substance or mixture according to the Globally Harmonized System (GHS). Not classified as a dangerous good according to the ADG Code. Details of the supplier of the safety data sheet Distributor Amway of Australia 7-9 Irvine Place Bella Vista NSW 2153 Tel: (02) Fax: (02) Australian Business Number: address: Distributor Amway of New Zealand 6a Pacific Rise Mt Wellington, Auckland 1060 Tel: (612) sds@amway.com Manufacturer Access Business Group, LLC 7575 Fulton Street East Ada, MI USA Tel: Responsible person(s): Technical Office, Amway of Australia (02) Emergency Telephone Number Emergency telephone number (AUS): Emergency telephone number (NZ): For Transportation Emergencies: (02) (Ask for the Technical Dept.) This is not a 24-hour number (Poisons Information Centre). This is a 24-hour number POISON or This is a 24-hour number. ChemTrec + 1 (703) HAZARDS IDENTIFICATION GHS Classification Page 1 of 9

2 Acute toxicity - Oral Category 4 Acute toxicity - Dermal Category 5 * Serious eye damage/eye irritation Category 1 Acute aquatic toxicity Category 2 * *Hazard classification applies to New Zealand; classification not adopted by Australia. Label elements Signal Word DANGER Hazard statements: H302 - Harmful if swallowed H313 - May be harmful in contact with skin H318 - Causes serious eye damage H401 - Toxic to aquatic life Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Avoid release to the environment Precautionary Statements - Response Call a POISON CENTRE or doctor/physician if you feel unwell Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTRE or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant OTHER INFORMATION Notapplicable 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Common Name CAS # Weight % Carbonic acid disodium salt Sodium carbonate Alcohols, C10-16, ethoxylated Surfactant ,2,3-Propanetricarboxylic acid, Organic acid hydroxy- 2-Butenedioic acid (2E)- Fumaric acid Silica gel, precipitated, crystalline free Amorphous silica Subtilisin Enzyme <1 4. FIRST AID MEASURES Page 2 of 9

3 FIRST AID MEASURES Eye contact: Skin contact: Inhalation: Ingestion: Protection of first-aiders: Remove contact lenses. Rinse with gentle stream of water for 15 minutes, holding eyelids open. Get medical advice by calling a poison control center, doctor or hospital emergency room. Rinse skin thoroughly with water. Move to fresh air. If irritation or breathing difficulty develops, GET MEDICAL ADVICE by calling an anti-poison center, doctor or hospital emergency room. If victim is a child, give millilitres of water. For adults, give millilitres of water. Do not induce vomiting when this product is swallowed. If vomiting occurs spontaneously, keep victim in an upright position. GET MEDICAL ADVICE by calling an anti-poison centre, doctor or hospital emergency room. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms:. Indication of any immediate medical attention and special treatment needed Notes to physician: Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media:. Specific hazards arising from the chemical No specific hazard known. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Wear appropriate personal protection equipment (respirator, gloves, goggles, and/or faceshield, boots, protective clothing). For emergency responders: Use personal protective equipment as required. Environmental Precautions See Section 12 for additional Ecological Information. Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Page 3 of 9

4 Methods for containment: Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods for cleaning up: No special collection methods required. Dispose of in accordance with all national and local regulations. Precautions for safe handling 7. HANDLING AND STORAGE Advice on safe handling: Avoid contact with eyes. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage conditions: Keep in a dry place. No special restrictions on storage with other products. Incompatible materials: Contact with highly reactive chemicals like strong acids, strong bases, oxidizers or reducing agents may cause a dangerous reaction. Control parameters Exposure limits: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name Silica gel, precipitated, crystalline free Australian Exposure Standards - Time Weighted Average Australian Exposure Standards - Short Term Exposure Limit New Zealand Exposure Standards - Time-Weighted Average 10 mg/m 3 10 mg/m 3 New Zealand Exposure Standards - Short Term Exposure Limit Derived No Effect Level (DNEL):. Predicted No Effect Concentration (PNEC):. Appropriate engineering controls Engineering measures: Mechanical ventilation is not normally necessary when this product is used according to label directions. Individual protection measures, such as personal protective equipment Eye/face protection: Follow label directions. No special technical protective measures are necessary. Avoid contact with eyes. Where use conditions and/or extent and duration of exposure differ from typical household consumer use, appropriate protective equipment may be necessary to minimize exposures. Page 4 of 9

5 Hand protection: Skin and body protection: Respiratory protection: Follow label directions. Skin protection is not normally necessary when this product is used according to label directions. Where use conditions and/or extent and duration of exposure differ from typical household consumer use, appropriate protective equipment may be necessary to minimize exposures. Follow label directions. Skin and body protection is not normally necessary when this product is used according to product label directions. Where use conditions and/or extent and duration of exposure differ from typical household consumer use, appropriate protective equipment may be necessary to minimize exposures. Follow label directions. Respiratory protective equipment is not normally necessary when this product is used according to product label directions. Where use conditions and/or extent and duration of exposure differ from typical household consumer use, appropriate protective equipment may be necessary to minimize exposures. General industrial hygiene practice: This product is sold as a consumer product. Where use conditions and/or extent and duration of exposure differ from typical household consumer use, appropriate protective equipment may be necessary to minimize exposures. Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Powder Appearance: Granular Odour: Citrus Colour: White with coloured specks Odour threshold: Property Values Remarks Method ph: Solution (1 %) Melting point/freezing point: Boiling point/boiling range: Flash point: Evaporation rate: Flammability (solid, gas): Flammability limit in air: Upper flammability limit: Lower flammability limit: Vapour pressure: Vapour density: Specific Gravity: Water solubility: Solubility(ies): Partition coefficient Auto-ignition temperature: Decomposition temperature: Kinematic viscosity: Dynamic viscosity: Explosive properties: Oxidising properties: Softening point: Molecular weight: VOC content (%): Density: Bulk density: g/cc 10. STABILITY AND REACTIVITY Page 5 of 9

6 Reactivity No data available. Chemical stability Stability: Stable under normal conditions. Sensitivity to mechanical impact: None. Sensitivity to static discharge: None. Possibility of hazardous reactions Contact with highly reactive chemicals like strong acids, strong bases, oxidizers or reducing agents may cause a dangerous reaction. Conditions to avoid Humidity. Keep out of reach of children. Incompatible materials: Not determined. Hazardous decomposition products Not determined. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Aggravated medical conditions: Principle routes of exposure: Inhalation: Eye contact: Skin contact: Ingestion: Exposure to this product may aggravate pre-existing skin, eye, and respiratory disorders. Eye contact, skin contact, inhalation May cause irritation of respiratory tract. See additional information below. Severely irritating to eyes. Prolonged contact may cause redness and irritation. Patch test on human volunteers did not demonstrate sensitisation properties. Ingestion of this product can cause irritation of the mouth and throat, upset stomach, nausea, vomiting and diarrhea. Further information: Repeated inhalation overexposure to enzyme dust can result in sensitization and allergic response in susceptible individuals. Inhalation overexposure to amorphous silica dust may cause changes in the lung (visible only by x-ray) without disability. Numerical measures of toxicity - Product information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) ATEmix (dermal) 1, mg/kg 3, mg/kg Page 6 of 9

7 Numerical measures of toxicity - Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Carbonic acid disodium salt = 4090 mg/kg ( Rat ) - = 2300 mg/m 3 ( Rat ) 2 h ,2,3-Propanetricarboxylic = 3000 mg/kg ( Rat ) - - acid, 2-hydroxy Butenedioic acid (2E)- = 9300 mg/kg ( Rat ) > mg/kg ( Rabbit ) Subtilisin = 3700 mg/kg ( Rat ) - - Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Serious eye damage/eye irritation Sensitisation: Germ cell mutagenicity: Carcinogenicity: Prolonged contact may cause redness and irritation. Risk of serious damage to eyes. Patch test on human volunteers did not demonstrate sensitisation properties. Stearates. Stearates. Reproductive toxicity: STOT - single exposure: STOT - repeated exposure: Aspiration hazard: Stearates. None under normal use conditions. None under normal use conditions. Not applicable. 12. ECOLOGICAL INFORMATION Ecotoxicity Chemical Name Algae/aquatic plants Fish Crustacea Carbonic acid disodium salt 242: 120 h Nitzschia mg/l EC50 1,2,3-Propanetricarboxylic acid, 2-hydroxy Butenedioic acid (2E) Persistence and degradability Readily biodegradable. Bioaccumulation 300: 96 h Lepomis macrochirus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 static : 96 h Lepomis macrochirus mg/l LC50 static 41: 72 h Desmodesmus subspicatus mg/l EC50 245: 48 h Brachydanio rerio mg/l LC50 static 265: 48 h Daphnia magna mg/l EC50 120: 72 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC : 24 h Daphnia magna mg/l EC50 Chemical Name 1,2,3-Propanetricarboxylic acid, 2-hydroxy Butenedioic acid (2E) Partition coefficient Page 7 of 9

8 Mobility in soil. Other adverse effects Waste treatment methods 13. DISPOSAL CONSIDERATIONS Waste from residues/unused products: Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging: Do not re-use empty containers. Only empty packaging can be recycled. 14. TRANSPORT INFORMATION This product has been tested against the UN protocol used to classify transportation hazards and it does not meet the definition of a dangerous good in transport. DOT: UN/ID No.: Not regulated Proper shipping name: Not regulated Hazard Class: Not regulated Packing group: Not regulated IMDG/ADR: UN/ID No.: Not regulated Proper shipping name: Not regulated Hazard class: Not regulated Packing group: Not regulated Marine pollutant: Not applicable ICAO/IATA: UN/ID No.: Not regulated Proper shipping name: Not regulated Hazard class: Not regulated Packing group: Not regulated Marine pollutant: Not applicable The information contained in this document is subject to change or update due to changing government regulations. The user of this document assumes responsibility for complying with all applicable national and international laws and regulations regarding the shipment of Dangerous Goods 15. REGULATORY INFORMATION Poisons Schedule Number: None allocated HSNO Classification (NZ): 6.1D, 6.1E, 8.3A, 9.1D Group Standard (NZ): Cleaning Products (Subsidiary Hazard) Page 8 of 9

9 16. OTHER INFORMATION The information contained herein is believed to be accurate and represents the best information currently available to us, much of which comes from the manufacturer or supplier of components of this product. Therefore, Amway of Australia and Access Business Group LLC make no warranty, express or implied, regarding the accuracy of the data. Health and safety precautions in this data sheet may not be adequate for all individuals and product uses. It is the user's obligation to make certain that this SDS is the most current SDS for the product; to evaluate the information contained in this sheet in connection with the uses to which the product is to be put in the workplace and to use the product safely in accordance with applicable laws and regulations. If there are any questions concerning the information contained in this sheet or its applicability to a particular use, the user is instructed to telephone the Technical Department on (02) Amway of Australia and Access Business Group LLC assume no responsibility for injury from the use of the product described in this sheet in a way different from that provided in the label directions. Prepared By: Access Business Group LLC, Environmental, Health and Safety Department, Ada, Michigan, U.S.A. This data sheet contains changes from the previous version in section(s): None ***END OF SAFETY DATA SHEET*** Page 9 of 9