MSDS Material Safety Data Sheet
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1 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER PRODUCT NAME MANUFACTURER PERMABOND LLC 14 Robinson Street Pottstown, PA EMERGENCY PHONES: MEDICAL TRANSPORT (CHEMTREC) MSDS REQUESTS: HELP LINE: SYNONYMS None 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL FAMILY Epoxy Resin COMPONENT CAS NUMBER CONCENTRATION (%) Bisphenol A epichlorohydrin polymer HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING: MAY CAUSE EYE IRRITANTION MAY CAUSE SKIN IRRITANTION MAY CAUSE ALERGIC SKIN REACTION MAY CAUSE RESPIRATORY TRACT IRRITATION Physical State: Odor: Color: Viscous liquid Slight epoxy Colorless EYE SKIN CONTACT INHALATION INGESTION May cause eye irritation. Irritating to skin. Repeated and/or prolonged contact may cause skin sensitization. May cause irritation to the respiratory system. May cause irritation to the gastrointestinal tract 4. FIRST AID MEASURES EYE Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 15 minutes. Obtain medical attention. SKIN CONTACT INHALATION INGESTION Clean exposed areas thoroughly with soap and water until all chemical is removed. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Remove to fresh air. If symptoms develop or persist, get medical attention. DO NOT induce vomiting. Keep warm and calm. Get prompt medical attention. PAGE 1 OF 5
2 5. FIREFIGHTING MEASURES AUTOIGNITION FLASH POINT EXTINGUISHING MEDIA SPECIAL FIREFIGHTING PROCEDURES FIRE & EXPLOSION HAZARDS HAZARDOUS COMBUSTION PRODUCTS LOWER EXPLOSION LIMIT (%) UPPER EXPLOSION LIMIT (%) FLAMMABILITY HAZARD CLASS >200 F (Pensky Martens closed cup) CO2; Dry Chemical; Foam; Water Fog Fire fighters should be equipped with self contained breathing apparatus to protect against potentially toxic and irritating fumes. Cool exposed equipment with water spray. Polymerization may take place at elevated temperatures. Thermal decomposition could produce carbon monoxide, carbon dioxide and unidentified organic compounds 1 = Slight. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES Ensure adequate ventilation and soak up inert absorbent material. Place in containers until disposal Prevent material from entering into drains. 7. HANDLING AND STORAGE HANDLING/STORAGE Keep in a cool dry place. Store in a well ventilated area away from heat, spark and open flame. Do not breath vapors or mist. Keep container closed. Avoid contact with shin, eyes and clothing. Maximum storage temperature is 100 F 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Hazardous components ACGIH TLV OSHA ACGIH PEL TLV OTHER Biphenol A epichlorohydrin None None None Polymer VENTILATION REQUIREMENTS Local exhaust ventilation to maintain airborne concentrations below established. EYE PROTECTION REQUIREMENTS Safety glasses with side shields, goggles or face shield to protect against splashing. GLOVE REQUIREMENTS Employee must wear chemical resistant, impermeable protective gloves to prevent contact with this product. CLOTHING REQUIREMENTS No special clothing required for low volume activity. CHANGE/REMOVAL OF CLOTHING Remove contaminated clothing and launder before reuse. WASH REQUIREMENTS RESPIRATOR REQUIREMENTS Wash before eating, drinking, or using toilet facilities. None required under normal handling conditions. Use NIOSH approved respirator if vapor or mist levels are irritating. PAGE 2 OF 5
3 9. PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR MIXTURE Mixture PHYSICAL FORM Liquid COLOR Colorless ODOR Slight epoxy odor ODOR THRESHOLD PH AS IS ph IN (1%) SOLUTION OXIDIZING PROPERTIES BOILING POINT >200 C MELTING/FREEZING POINT SOLUBILITY IN WATER Slightly VISCOSITY 15,000 cp SPECIFIC GRAVITY (WATER=1) 1.17 VAPOR PRESSURE 77C) 0.03 VAPOR DENSITY (air = 1) VOLATILE ORGANIC COMPOUNDS Nil AUTOIGNITION FLASH POINT >200 F (Pensky Martens closed cup) 10. STABILITY AND REACTIVITY STABILITY Stable MATERIALS TO AVOID Strong acids, strong bases, strong oxidizers. REACTIVITY HAZARD CLASS 1 = Slightly reactive material. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. CONDITIONS TO AVOID Excessive heat, temperatures above 100 F, storage with incompatible materials. Avoid mixing part A with part B in large quantities (1 Kg) unless you plan to use it immediately. 11. TOXICOLOGICAL INFORMATION ROUTE OF ENTRY Skin Contact; Eye Contact; Ingestion CHRONIC (LONG TERM) EFFECTS OF EXPOSURE EFFECTS OF CHRONIC EXPOSURE The toxicological effects of this material have not been fully evaluated. The use of good industrial hygiene is required. Avoid contact with skin and eyes. Do not ingest or inhale TARGET ORGANS SKIN SENSITIZATION CARCINOGEN Skin; Eyes Sensitizer. May cause allergic reaction. No. PAGE 3 OF 5
4 11. TOXICOLOGICAL INFORMATION CONT D COMPONENT ORAL TOXICITY NOTES ON ORAL TOXICITY Bisphenol A epichlorohydrin Polymer Oral LD50: Rat mg/kg Oral LD50: Mouse mg/kg Ingestion may cause irritation of the gastrointestinal tract COMPONENT DERMAL TOXICITY NOTES ON DERMAL TOXICITY Bisphenol A epichlorohydrin Polymer Dermal LD50: Rabbit > mg/kg Irritating to skin. Repeated and/or prolonged contact may cause skin sensitization COMPONENT INHALATION TOXICITY NOTES ON INHALATION TOXICITY Bisphenol A epichlorohydrin Polymer Vapors and/or aerosols which may be formed at elevated temperatures may be irritating to eyes and respiratory tract. COMPONENT Bisphenol A epichlorohydrin Polymer NOTES ON EYE IRRITATION May cause temporary discomfort or irritation. 12. ECOLOGICAL INFORMATION POTENTIAL TO BIOACCUMULATE AQUATIC TOXICITY Unknown. None Established 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS Disposal should be in accordance with local, state or national legislation. EMPTY CONTAINER WARNINGS Empty containers may contain product residue; follow MSDS and label warnings even after they have been emptied. PAGE 4 OF 5
5 14. TRANSPORTATION INFORMATION This section provided for general information only. FOR NON BULK SHIPMENTS. FOR MORE COMPLETE TRANSPORTATION REGULATORY INFORMATION PLEASE REFER TO THE SHIPPING DOCUMENTS ACCOMPANYING THE SHIPMENT OF THIS PRODUCT. DOT CLASSIFICATION PROPER SHIPPING NAME Not regulated The information provided herein may not include the impact of additional regulatory requirements (e.g., for materials meeting the definition of a hazardous waste under RCRA, hazardous substances under CERCLA, and/of marine pollutants under CWA or other similar federal, state or local laws) or any associated exceptions or exemptions under regulations applicable to the transport of this material. 15. REGULATORY INFORMATION USA TSCA CERCLA/SARA All components are listed or exempt from listing on the Toxic Substances Control Act Inventory. Contains no substances at or above the reporting limit under section 313. CALIFORNIA PROPOSITION 65 This product contains a product known to the state of California to cause cancer and birth defects or other reproductive harm. 16. OTHER INFORMATION MSDS DATE 02/27/09 This MSDS contains change from the previous one in section 1; Update on Manufacturer Address. FOR INFORMATION CONTACT: Permabond LLC HELP Line: ADDITIONAL INFORMATION: The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are based on our research and on data from other reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their purposes. PAGE 5 OF 5
6 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER PRODUCT NAME MANUFACTURER PERMABOND LLC 14 Robinson Street Pottstown, PA EMERGENCY PHONES: MEDICAL TRANSPORT (CHEMTREC) MSDS REQUESTS: HELP LINE: SYNONYMS None 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL FAMILY Catalyst for Epoxy Resin COMPONENT CAS NUMBER CONCENTRATION (%) Mercaptan terminated polymer Proprietary Triethylenetetramine HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER: CAUSES EYE BURNS CAUSES SKIN BURNS MAY CAUSE ALERGIC SKIN REACTION MAY CAUSE ALERGIC RESPIRATORY REACTION MAY CAUSE RESPIRATORY TRACT IRRITATION MAY BE HARMFUL IF SWALLOWED Physical State: Odor: Color: Viscous liquid Sulfur Slightly yellow EYE SKIN CONTACT INHALATION INGESTION Causes burns. Severe eye irritation. Redness. May cause tissue damage. May cause skin burns. Severely irritating to skin. May cause skin sensitization. Rash. Redness Severely irritating. May cause allergic respiratory reaction. May cause respiratory tract irritation May be harmful if swallowed. May cause burns of mouth and throat. PAGE 1 OF 6
7 4. FIRST AID MEASURES EYE Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 15 minutes. Obtain immediate medical attention. SKIN CONTACT INHALATION INGESTION Immediately flush skin with plenty of water and soap. Remove contaminated clothing and launder before reuse. Remove shoes and thoroughly clean them before reuse. Get medical attention if symptoms (blistering or irritation) occur. Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get medical attention. DO NOT induce vomiting unless directed by medical personnel. Keep warm and calm. Get immediate medical attention. 5. FIREFIGHTING MEASURES AUTOIGNITION FLASH POINT EXTINGUISHING MEDIA SPECIAL FIREFIGHTING PROCEDURES FIRE & EXPLOSION HAZARDS HAZARDOUS COMBUSTION PRODUCTS LOWER EXPLOSION LIMIT (%) UPPER EXPLOSION LIMIT (%) FLAMMABILITY HAZARD CLASS >200 F (estimated) CO2; Dry Chemical; Foam; Water Fog Fire fighters should be equipped with self contained breathing apparatus to protect against potentially toxic and irritating fumes. Cool exposed equipment with water spray. Low fire hazard. Combustion will evolve toxic and irritating vapors. Thermal decomposition could produce carbon monoxide, carbon dioxide, oxides of nitrogen and unidentified organic compounds 1 = Slight. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES Ensure adequate ventilation. Absorb spillages with inert absorbent material. Place in containers until disposal. Prevent material from entering into drains. 7. HANDLING AND STORAGE HANDLING/STORAGE Keep in a cool dry place. Store in a well ventilated area away from heat, spark and open flame. Do not breath vapors or mist. Keep container closed. Avoid contact with shin, eyes and clothing. Maximum storage temperature is 100 F. PAGE 2 OF 6
8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Hazards components ACGIH TLV OSHA PEL Other Mercaptan terminated polymer None None None Triethylenetetramine None None None VENTILATION REQUIREMENTS Local exhaust ventilation to maintain airborne concentrations below established exposure limits. EYE PROTECTION REQUIREMENTS Safety glasses with side shields, goggles or face shield to protect against splashing. GLOVE REQUIREMENTS Employee must wear chemical resistant, impermeable protective gloves to prevent contact with this product. CLOTHING REQUIREMENTS No special clothing required for low volume activity. CHANGE/REMOVAL OF CLOTHING Remove contaminated clothing and launder before reuse. WASH REQUIREMENTS RESPIRATOR REQUIREMENTS Wash before eating, drinking, or using toilet facilities. Use NIOSH approved respirator if the potential for exceeding established exposure limits exists. 9. PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR MIXTURE Mixture PHYSICAL FORM Viscous liquid COLOR Slightly yellow ODOR Sulfur PH AS IS ph IN (1%) SOLUTION OXIDIZING PROPERTIES BOILING POINT >260 C MELTING/FREEZING POINT SOLUBILITY IN WATER Slightly VISCOSITY 30,000 cp SPECIFIC GRAVITY (WATER=1) 0.98 EVAPORATION RATE VAPOR PRESSURE C) <0.01 VAPOR DENSITY (air = 1) VOLATILE ORGANIC COMPOUNDS AUTOIGNITION FLASH POINT Nil 300 F (Cleveland Open Cup) PAGE 3 OF 6
9 10. STABILITY AND REACTIVITY STABILITY Stable MATERIALS TO AVOID Strong acids, strong bases strong oxidizers, amines and water. REACTIVITY HAZARD CLASS 1 = Slightly reactive material. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. CONDITIONS TO AVOID Excessive heat, storage with incompatible materials. Avoid mixing part A with part B in large quantities (1 Kg) unless you plan to use it immediately. 11. TOXICOLOGICAL INFORMATION ROUTE OF ENTRY Skin Contact; Eye Contact; Ingestion; Inhalation CHRONIC (LONG TERM) EFFECTS OF EXPOSURE EFFECTS OF CHRONIC EXPOSURE The toxicological effects of this material have not been fully evaluated. The use of good industrial hygiene is required. Avoid contact with skin and eyes. Do not ingest or inhale ROUTES OF ENTRY CARCINOGEN Skin contact; Eye contact, Ingestion, Inhalation No. COMPONENT ORAL TOXICITY NOTES ON ORAL TOXICITY Mercaptan terminated polymer Triethylenetetramine Not established Oral LD50: Rat 2500 mg/kg Irritant Corrosive to mouth, throat and stomach COMPONENT DERMAL TOXICITY NOTES ON DERMAL TOXICITY Mercaptan terminated polymer Not established Repeated or prolonged skin contact may result in moderate irritation. Repeated and/or prolonged contact may cause skin sensitization. Triethylenetetramine Dermal LD50: Rabbit 805 mg/kg Corrosive to skin. May cause allergic skin reaction. May be absorbed through the skin. PAGE 4 OF 6
10 11. TOXICOLOGICAL INFORMATION CONT D COMPONENT INHALATION TOXICITY NOTES ON INHALATION TOXICITY Mercaptan terminated polymer No data available Irritating. Vapors and/or aerosols which may be formed at elevated temperatures may be irritating to eyes and respiratory tract. Avoid breathing vapors or mists. Triethylenetetramine No data available Respiratory tract irritant. May cause allergic respiratory reaction. COMPONENT Mercaptan terminated polymer Triethylenetetramine 12. ECOLOGICAL INFORMATION POTENTIAL TO BIOACCUMULATE AQUATIC TOXICITY Unknown. None Established NOTES ON EYE IRRITATION May cause eye irritation. Corrosive to eyes. Severe eye irritant. May cause severe burns that could lead to tissue damage. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS Disposal should be in accordance with local, state or national legislation. EMPTY CONTAINER WARNINGS Empty containers may contain product residue; follow MSDS and label warnings even after they have been emptied. 14. TRANSPORTATION INFORMATION This section provided for general information only. FOR NON BULK SHIPMENTS. FOR MORE COMPLETE TRANSPORTATION REGULATORY INFORMATION PLEASE REFER TO THE SHIPPING DOCUMENTS ACCOMPANYING THE SHIPMENT OF THIS PRODUCT. DOT CLASSIFICATION PROPER SHIPPING NAME HAZARDS CLASS IDENTIFICATION NUMBER PACKING GROUP Triethylenetetramine mixture 8 UN2259 II The information provided herein may not include the impact of additional regulatory requirements (e.g., for materials meeting the definition of a hazardous waste under RCRA, hazardous substances under CERCLA, and/of marine pollutants under CWA or other similar federal, state or local laws) or any associated exceptions or exemptions under regulations applicable to the transport of this material. PAGE 5 OF 6
11 15. REGULATORY INFORMATION USA TSCA CERCLA/SARA All components are listed or exempt from listing on the Toxic Substances Control Act Inventory. Contains no substances at or above the reporting limit under section 313. CALIFORNIA PROPOSITION 65 No chemicals listed on proposition 65 are known to be present. 16. OTHER INFORMATION MSDS DATE 02/27/09 This MSDS contains change from the previous one in section 1; Update on Manufacturer Address. FOR INFORMATION CONTACT: Permabond LLC HELP Line: ADDITIONAL INFORMATION: The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are based on our research and on data from other reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their purposes. PAGE 6 OF 6
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