: Core-Flo DC/Core-Flo DC Lite Base

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Core-Flo DC/Core-Flo DC Lite Base Date of issue: 01/27/2017 Version: 2 : Mixture 1.2. Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier Manufacturer Bisco, Inc W. Irving Park Rd. Schaumburg, IL T F sales@bisco.com Emergency telephone number : Core-Flo DC/Core-Flo DC Lite Base : For Rx Only Emergency number : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Respiratory sensitisation Category 1 Skin sensitization Category 1 H315 H319 H334 H317 Full text of H statements : see section 16 Causes skin irritation Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled : P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P403+P235 - Store in a well-ventilated place. Keep cool P264 - Wash hands thoroughly after handling P304+P341 - If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose in a safe manner in accordance with local/national regulations. 01/25/2017 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification Glass Filler (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Resp. Sens. 1, H334 Amorphous Silica (CAS No) Eye Irrit. 2A, H319 Resp. Sens. 1, H334 Ethoxylated Bis A Dimethacrylate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Bisphenol A Diglycidylmethacrylate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Triethylene Glycol Dimethacrylate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Causes skin irritation. : Causes serious eye irritation Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 01/25/2017 EN (English US) 2/8

3 For emergency responders Protective equipment Emergency procedures : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Use only outdoors or in a well-ventilated area. Avoid breathing mist, vapors. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep container tightly closed. : Strong bases. strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Appropriate engineering controls 8.3. Individual protection measures/personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses. Skin and body protection: Wear suitable protective clothing Respiratory protection: 01/25/2017 EN (English US) 3/8

4 In case of inadequate ventilation wear respiratory protection Other information: When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste. Color : Brown / Blue / White Odor : Acrylic Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects 01/25/2017 EN (English US) 4/8

5 Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LD50 oral rat LD50 dermal rabbit ATE US (oral) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) 3160 mg/kg (Rat) > 5000 mg/kg (Rabbit) mg/kg body weight LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group mg/kg (Rat) mg/kg body weight : Causes skin irritation. : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Based on available data, the classification criteria are not met 4 - Probably Not Carcinogenic IARC group Reproductive toxicity Specific target organ toxicity (single exposure) 3 - Not Classifiable Based on available data, the classification criteria are not met LOAEL (oral,rat) mg/kg body weight LOAEL (dermal,rat/rabbit) mg/kg body weight LOAEL (inhalation,rat,gas) ppmv/4h LOAEL (inhalation,rat,vapour ) mg/l/4h LOAEL (inhalation,rat,dust/mist/fume) mg/l/4h LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEL (inhalation,rat,gas) LOAEL (inhalation,rat,vapour ) LOAEL (inhalation,rat,dust/mist/fume) Specific target organ toxicity (repeated exposure) mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day 01/25/2017 EN (English US) 5/8

6 LOAEL (inhalation,rat,dust/mist/fume,90 days) mg/l/6h/day LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) LOAEL (inhalation,rat,dust/mist/fume,90 days) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day : Based on available data, the classification criteria are not met. : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Causes skin irritation. : Causes serious eye irritation. SECTION 12: Ecological information Toxicity Persistence and degradability Core-Flo DC/Core-Flo DC Lite Base Persistence and degradability Not established. Persistence and degradability Biodegradability in water: no data available. Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Persistence and degradability Biodegradability: not applicable. Biodegradability in water: no data available. Forming sediments in water Bioaccumulative potential Core-Flo DC/Core-Flo DC Lite Base Bioaccumulative potential Not established. Log Pow 4.94 (Estimated value) Bioaccumulative potential No bioaccumulation data available. Bioaccumulative potential Not bioaccumulative. Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. 01/25/2017 EN (English US) 6/8

7 Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Product/Packaging disposal recommendations Ecology - waste materials SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT TDG : Dispose in a safe manner in accordance with local/national regulations. Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. Transport by sea Not regulated Air transport Not regulated SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) inventory. EU-Regulations National regulations US State regulations SECTION 16: Other information Revision date : 01/05/2017 Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. 01/25/2017 EN (English US) 7/8

8 Revision date: 01/25/2017 Full text of H-phrases: H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H320 Causes eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/25/2017 EN (English US) 8/8