Bioguard Spa Swirl Away

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1 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name: Company: Chemtura New Zealand Ltd Level 7, 435 King William St Adelaide SA 5000 Australia Telephone : or Telefax : or Distributor The Storage and Distribution Centre NZ 3 Goodman Place Penrose, Auckland 1026 New Zealand Telephone : Telefax : Emergency telephone number: Customer Service: or For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by: Product Safety Department (US) Further information for the safety data sheet : MSDSRequest@chemtura.com 2. HAZARDS IDENTIFICATION Hazardous substance, Non-dangerous goods ERMA Register Approval Number : HSR HSNO Hazard Classification 6.3A (Skin irritation) 8.3A (Serious eye damage) Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. Precautionary statements SAP / 9 SDS Number:

2 Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration >= 1 - < 5% pentasodium triphosphate >= 1 - < 5% 4. FIRST AID MEASURES General advice General advice Inhalation Skin contact Eye contact Ingestion : For advice, contact a Poisons Information Centre (Phone: Australia or New Zealand ) or a doctor at once. : No hazards which require special first aid measures. : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. SAP / 9 SDS Number:

3 If symptoms persist, call a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Special protective equipment for fire-fighters Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : In the event of fire, wear self-contained breathing apparatus. : Standard procedure for chemical fires. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion Storage Requirements for storage areas and containers Other data : Avoid contact with skin and eyes. For personal protection see section 8. : Normal measures for preventive fire protection. : Keep container tightly closed in a dry and well-ventilated place. : No decomposition if stored and applied as directed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters We are not aware of any national exposure limit. Personal protective equipment Hand protection : Polyvinyl alcohol or nitrile- butyl-rubber gloves Before removing gloves clean them with soap and water. Eye/face protection : Eye wash bottle with pure water Tightly fitting safety goggles SAP / 9 SDS Number:

4 Skin and body protection Hygiene measures : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid : clear blue : pleasant Safety data Flash point : Note: not applicable Freezing point : -5 C Boiling point/boiling range : 105 C Vapour pressure : hpa Water solubility : Note: completely miscible 10. STABILITY AND REACTIVITY Conditions to avoid Hazardous decomposition products Hazardous reactions : Remarks: no data available : Note: Sodium oxides Sulphur oxides Carbon oxides Hydrogen halides : Note: No decomposition if used as directed. 11. TOXICOLOGICAL INFORMATION Acute toxicity SAP / 9 SDS Number:

5 Acute oral toxicity : LD50 rat Dose: 500-2,000 mg/kg Method: OECD Test Guideline 401 pentasodium triphosphate : LD50 rat Dose: 3,100 mg/kg Acute dermal toxicity pentasodium triphosphate : LD50 rabbit Dose: > 7,940 mg/kg Skin corrosion/irritation Skin irritation : Remarks: May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Eye irritation : Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Respiratory or skin sensitization Sensitisation : Remarks: no data available Germ cell mutagenicity : Ames test Result: negative Genotoxicity in vivo : Species: mouse Result: negative Species: rat Result: negative Target Organ Systemic Toxicant - Single exposure pentasodium triphosphate : Exposure routes: Inhalation Remarks: May cause respiratory irritation. Repeated dose toxicity : Oral rat Exposure time: 90 days () SAP / 9 SDS Number:

6 Oral rat male and female pentasodium triphosphate : Exposure routes: Inhalation Remarks: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Further information : no data available 12. ECOLOGICAL INFORMATION Biodegradability : aerobic Result: Readily biodegradable. 69 % Method: Modified Sturm Test Bioaccumulation : Species: Leuciscus idus (Golden orfe) Exposure time: 3 d Bioconcentration factor (BCF): 130 Toxicity to fish : static test LC50 Species: Danio rerio (zebra fish) Dose: mg/l Exposure time: 96 h Method: OECD Test Guideline 203 static test LC50 Species: Salmo gairdneri Dose: mg/l Exposure time: 96 h Analytical monitoring: no Method: OECD Test Guideline 203 pentasodium triphosphate : static test LC50 Species: Leuciscus idus (Golden orfe) Dose: > 1, mg/l Exposure time: 48 h Toxicity to daphnia and other aquatic invertebrates. : EC50 Species: Daphnia magna (Water flea) Dose: 5.88 mg/l Exposure time: 48 h SAP / 9 SDS Number:

7 Analytical monitoring: yes EC50 Species: Daphnia magna (Water flea) Dose: mg/l Exposure time: 24 h Analytical monitoring: no Toxicity to algae : Growth inhibition Species: Freshwater algae Dose: mg/l Exposure time: 96 h Analytical monitoring: yes Further information on ecology Additional ecological information : There is no data available for this product. 13. DISPOSAL CONSIDERATIONS Product Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Offer surplus and non-recyclable solutions to a licensed disposal company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. 14. TRANSPORT INFORMATION ADG ADR IATA IMDG SAP / 9 SDS Number:

8 RID 15. REGULATORY INFORMATION ERMA Register Approval Number HSNO Hazard Classification : HSR : 6.3A (Skin irritation) 8.3A (Serious eye damage) Other international regulations Notification status US.TSCA : On TSCA Inventory DSL AICS NZIoC ENCS KECI PICCS IECSC : All components of this product are on the Canadian DSL list. 16. OTHER INFORMATION Further information Carechem24 International Worldwide Coverage - Chemtura Corporation Emergency Telephone Numbers Europe: Asia Pacific: All European Countries +44 (0) Australia New Zealand China Japan Indonesia Malaysia Thailand SAP / 9 SDS Number:

9 Hong Kong, Singapore, Sri Lanka, Taiwan, Philippines Korea Vietnam India Pakistan Bangladesh Middle East: Africa: Latin America: Arabic speaking countries All other countries Arabic speaking countries All other countries All (0) (0) (0) The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP / 9 SDS Number:

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