: Resinomer Base. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification
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1 Date of issue: 11/25/2014 Revision date: 03/06/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture : 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Bisco, Inc W. Irving Park Rd. Schaumburg, IL T F sales@bisco.com Emergency telephone number : For professional use only. Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 Full text of H-phrases: see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Irritant ; Sensitizer GHS08 : H302 - Harmful if swallowed H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled : P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P403+P235 - Store in a well-ventilated place. Keep cool P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose in a safe manner in accordance with local/national regulations Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 03/06/2015 EN (English US) Page 1
2 Name Product identifier % Classification (GHS-US) Glass filler (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Resp. Sens. 1, H334 bisphenol A glycidylmethacrylate (CAS No) Eye Dam. 1, H318 Skin Sens. 1, H317 2-hydroxyethyl methacrylate, stabilized (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Skin Sens. 1, H317 sodium fluoride (CAS No) Acute Tox. 3 (Oral), H301 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Aquatic Acute 3, H402 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). If skin irritation or rash occurs: : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a POISON CENTER/doctor/physician if you feel unwell. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Causes skin irritation. : Causes serious eye irritation. : Swallowing a small quantity of this material will result in serious health hazard Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 03/06/2015 EN (English US) 2/8
3 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing mist, vapors. : Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition. Direct sunlight Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH Glass filler ( ) ACGIH bisphenol A glycidylmethacrylate ( ) ACGIH ACGIH ACGIH TWA (mg/m³) 2.5 mg/m³ ACGIH 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : In case of inadequate ventilation wear respiratory protection. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste. 03/06/2015 EN (English US) 3/8
4 Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point : tooth : acrylic Flash point : 38 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects : Immiscible Acute toxicity ATE US (oral) Glass filler ( ) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) : Oral: Harmful if swallowed mg/kg body weight N/A N/A N/A N/A 03/06/2015 EN (English US) 4/8
5 LD50 oral rat ATE US (oral) 52 mg/kg (Rat) mg/kg body weight LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity > 5000 mg/kg (Rat) > 3000 mg/kg (Rabbit) : Causes skin irritation. : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Glass filler ( ) LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEL (inhalation,rat,gas) LOAEL (inhalation,rat,vapour ) LOAEL (inhalation,rat,dust/mist/fume) Specific target organ toxicity (repeated exposure) Glass filler ( ) LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) LOAEL (inhalation,rat,dust/mist/fume,90 days) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion 3 - Not Classifiable N/A mg/kg body weight N/A mg/kg body weight N/A ppmv/4h N/A mg/l/4h N/A mg/l/4h N/A mg/kg bodyweight/day N/A mg/kg bodyweight/day N/A ppmv/6h/day N/A mg/l/6h/day N/A mg/l/6h/day : Based on available data, the classification criteria are not met. Harmful if swallowed. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Causes skin irritation. : Causes serious eye irritation. : Swallowing a small quantity of this material will result in serious health hazard. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 Threshold limit algae 1 > 530 mg/l (96 h; Lepomis macrochirus; Lethal) 98 mg/l (48 h; Daphnia magna) 74 mg/l (96 h; Pisces) 338 mg/l (48 h; Daphnia magna) 419 ppm (96 h; Gambusia affinis) 249 mg/l (Scenedesmus quadricauda; Toxicity test) LC50 fish mg/l (96 h; Pimephales promelas; Measured concentration) LC50 fish mg/l (48 h; Leuciscus idus) 03/06/2015 EN (English US) 5/8
6 12.2. Persistence and degradability Persistence and degradability bisphenol A glycidylmethacrylate ( ) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Not established. Biodegradability in water: no data available. Biodegradability: not applicable. Persistence and degradability Bioaccumulative potential Readily biodegradable in water. Biodegradability in soil: no data available. Adsorbs into the soil. Bioaccumulative potential bisphenol A glycidylmethacrylate ( ) Log Pow Bioaccumulative potential BCF fish 1 Bioaccumulative potential Not established (Estimated value) No bioaccumulation data available. 2.3 Salmo gairdneri (Oncorhynchus mykiss) Not bioaccumulative. BCF fish (Pisces; Calculated value) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Ecology - soil Toxic to flora Other adverse effects Effect on ozone layer : Effect on the global warming Other information : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR 03/06/2015 EN (English US) 6/8
7 Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute Tox. 4 (Oral) H302 Skin Irrit. 2 H315 Eye Dam. 1 H318 Resp. Sens. 1 H334 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] National regulations \ \ \ \ US State regulations SECTION 16: Other information Revision date : 03/06/2015 Other information : None. Full text of H-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2A Serious eye damage/eye irritation Category 2A Eye Irrit. 2B Serious eye damage/eye irritation Category 2B Resp. Sens. 1 Respiratory sensitisation Category Skin Irrit. 2 Skin corrosion/irritation Category Skin Sens. 1 Skin sensitization Category H301 Toxic if swallowed H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H320 Causes eye irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H402 Harmful to aquatic life 03/06/2015 EN (English US) 7/8
8 SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 03/06/2015 EN (English US) 8/8
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