SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 907/2006/EC, Article 3 SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier Product name.2. Relevant identified uses of the substance or mixture and uses advised against Description Thermochromic pigment..3. Details of the supplier of the safety data sheet Company Address Web Thermographic Measurements Ltd Riverside Buildings Dock Road Connah s Quay Flintshire CH5 4DS United Kingdom Telephone +44 (0) Fax +44 (0) address of the competent person.4. Emergency telephone number Emergency telephone number Intended use SECTION 2: Hazards identification sales@t-m-c.com chrisc@t-m-com +44 (0) Hours to Classification of the substance or mixture 2... Classification - 67/548/EEC Main hazards Classification - EC 272/ Label elements Hazard pictograms date Thermochromic powder for use in colour change inks. May be used to prepare colour change plastic masterbatch. Xn; R62 Xi; R4-43 Symbols: Xn: Harmful. / Risk of serious damage to eyes. May cause sensitisation by skin contact. Possible risk of impaired fertility. Skin Sens. : H37; Eye Dam. : H38; Repr. 2: H36f; Signal Word Danger Copyright 205 ChemSoft Limited. All rights reserved

2 2.2. Label elements Hazard Statement Prevention Response Storage Disposal 2.3. Other hazards Other hazards Skin Sens. : H37 - May cause an allergic skin reaction. Eye Dam. : H38 - Causes serious eye damage. Repr. 2: H36f - Suspected of damaging fertility. P20 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P26 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P28 - Use personal protective equipment as required. date 2/ P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P305+P35+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P33 - IF exposed or concerned: Get medical advice/attention. P30 - Immediately call a POISON CENTER or doctor/physician. P32 - Specific treatment (see on this label). P333+P33 - If skin irritation or rash occurs: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. P405 - Store locked up. P50 - Dispose of contents/container to No data available. SECTION 3: Composition/information on ingredients 3.. Substances 67/548/EEC / 999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification 4,4'-Isopropylidenediphenol % Repr. Cat. 3; R62 Xi; R37-4 R43 R52 EC 272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification 4,4'-Isopropylidenediphenol % Repr. 2: H36f; STOT SE 3: H335; Eye Dam. : H38; Skin Sens. : H37; 3.2. Mixtures SECTION 4: First aid measures 4.. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Refer to section Section 3.. Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Irritating to eyes. Rinse immediately with plenty of water for 5 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING Most important symptoms and effects, both acute and delayed Inhalation May cause irritation to respiratory system. Copyright 205 ChemSoft Limited. All rights reserved

3 4.2. Most important symptoms and effects, both acute and delayed Eye contact Skin contact Ingestion May cause irritation to eyes. May cause irritation to skin. Ingestion may cause nausea and vomiting Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion SECTION 5: Firefighting measures 5.. Extinguishing media If you feel unwell, seek medical advice (show the label where possible). If breathing is difficult give oxygen. Seek medical attention. date Rinse immediately with plenty of water for 5 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. 3/ Skin irritation and dermatitis. Wash off immediately with plenty of soap and water. Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. Carbon oxides Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. 6.. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.. Precautions for safe handling Avoid raising dust. Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. For disposal see section Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers. Apart from the uses mentioned in section.2 no other specific uses are stipulated. SECTION 8: Exposure controls/personal protection 8.2. Exposure controls Appropriate engineering controls Individual protection measures Eye / face protection Copyright 205 ChemSoft Limited. All rights reserved. Ensure adequate ventilation of the working area. Wear chemical protective clothing. Approved safety goggles

4 4/6 date Exposure controls Skin protection - Handprotection Chemical resistant gloves (PVC). Respiratory protection Wear:. Suitable respiratory equipment. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties State Powder Colour Various colours according to type. Odour Mild ph Not applicable. Flash point Not applicable. Flammability limits Not applicable. Vapour Flammability Not applicable. Upper Explosive Limit No data available Lower Explosive Limit No data available Relative density No data available Partition coefficient No data available (n-octanol/water) Autoignition temperature No data available 9.2. Other information Viscosity Not applicable. Explosive No data available Solubility Insoluble in water Surface tension Not applicable. SECTION 0: Stability and reactivity 0.. Reactivity 0.2. Chemical stability 0.3. Possibility of hazardous reactions 0.4. Conditions to avoid 0.5. Incompatible materials Heating during moulding will generate high levels of formaldehyde vapours which should be vented. Heating produces hazardous fumes. Stable under normal conditions. Heating during moulding will generate high levels of formaldehyde vapours which should be vented. Avoid formation of dust. Avoid sparks, flames, heat and sources of ignition. Burning produces irritating, toxic and obnoxious fumes. Alkalis Hazardous decomposition products SECTION : Toxicological information.. Information on toxicological effects Acute toxicity..4. Toxicological Information Burning produces irritating, toxic and obnoxious fumes. May cause sensitisation by skin contact. 4,4'-Isopropylidenediphenol Oral Rat LD50: 4240 mg/kg Oral Mouse LD50: 2500 mg/kg Dermal Rabbit LD50: 3 ml/kg Copyright 205 ChemSoft Limited. All rights reserved

5 SECTION 2: Ecological information 2.. Toxicity date 5/ ,4'-Isopropylidenediphenol Green algae EC50/96h: 3. Daphnia LC50/48h: 0.2 SECTION 3: Disposal considerations 3.. Waste treatment methods General information Disposal methods Fathead minnows LC50/96h: 4.6 Sweep up. SECTION 4: Transport information Further information SECTION 5: Regulatory information Dispose of in compliance with all local and national regulations. Dispose of this material and its container to hazardous or special waste collection point. Do not allow product to enter drains. The product is not classified as dangerous for carriage. 5.. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations SECTION 6: Other information Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 Further information Copyright 205 ChemSoft Limited. All rights reserved. This safety datasheet complies with the requirements of Regulation (EC) No. 907/2006. COMMISSION REGULATION (EU) No 453/200 of 20 May 200 amending Regulation (EC) No 907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 488/94 as well as Council Directive 76/769/EEC and Commission Directives 9/55/EEC, 93/67/EEC, 93/05/EC and 2000/2/EC. REGULATION (EC) No 907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 8 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 488/94 as well as Council Directive 76/769/EEC and Commission Directives 9/55/EEC, 93/67/EEC, 93/05/EC and 2000/2/EC. This document differs from the previous version in the following areas: Classification - EC 272/ Hazard pictograms. 2 - Prevention. 2 - Response. 2 - Storage. R37 - Irritating to respiratory system. R4 - Risk of serious damage to eyes. R43 - May cause sensitisation by skin contact. R52 - Harmful to aquatic organisms. R62 - Possible risk of impaired fertility. Skin Sens. : H37 - May cause an allergic skin reaction. Eye Dam. : H38 - Causes serious eye damage. STOT SE 3: H335 - May cause respiratory irritation. Repr. 2: H36f - Suspected of damaging fertility. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use,

6 Further information date 6/ storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. Copyright 205 ChemSoft Limited. All rights reserved