1. PRODUCT AND COMPANY. Super Tough Thin Set mortar (White) Adhesive mortar for ceramic.

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1 Product name: Product code: Common or Generic Name: Manufacturer / Address: 1. PRODUCT AND COMPANY Not available Adhesive mortar for ceramic. Atria Industries Corp NW 82 Ave, Doral, Florida, Phone Number: Web page: Emergency +1 (786) Phone Number: atriaindustries1@gmail.com 2. COMPOSITION / INFORMATION ON COMPONENTS MIXTURE Chemical Name Chemical composition Nº CAS %Weight Silica quartz SiO % Portland cement N/D % (gray) Calcium carbonate CaCO % Resin 2-hidroxietil-metiléter % 3. HAZARDS IDENTIFICATION Skin corrosion serious eye injury Skin irritation and other Aspiration hazard Product classification Skin Irrit. 2 It causes skin irritation. Eye Dam. 1 It causes serious eye damage. Skin Sens. May cause allergic skin reaction 1 It can cause cancer. <State route of exposure if it is conclusively Carc. 1A proven that no other routes are dangerous> It can irritate the respiratory tract. 1

2 It can irritate the respiratory tract. STOT SE 3 It causes damage to organs through prolonged or repeated STOT RE 1 exposure if inhaled. Potential health effects: Exposure routes to consider: Eye contact, skin contact, inhalation and ingestion. Routes of exposure DESCRIPTION Eye contact: Dust exposure can cause severe irritation, redness, tearing and blurred vision. Repeated or prolonged contact may cause chemical burns, corneal injuries and even blindness. Such exposures require immediate first aid (see Section 4) and medical attention to prevent significant damage to eyes. Skin Contact: Cause skin irritation due to corrosion. Handling can cause dry skin, discomfort, irritation, thickening, cracks or fissures of the skin and dermatitis. The answer may appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons already sensitized may react to their first contact with the product. Other people may experience for the first time this effect after years of contact with the ATRIA Mortar. Inhalation: Inhalation of dust can cause coughing and labored breathing and possible irritation, causing damage to organs through prolonged or repeated exposure. Ingestion: Carcinogenic Potential: The ATRIA Mortar contains considerable amounts of silica quartz and prolonged exposure thereof can aggravate other lung conditions and cause silicosis, a disabling and potentially fatal lung disease. Irritating to mouth, throat and stomach. Do not induce vomiting without medical care. Silica Quartz is a potential contaminant in trace levels, as it is now classified by the International Bank for Research on Cancer (IARC) as a known human carcinogen (Group I). The National Toxicology Program (NTP) assigned to breathable silica feature "reasonably anticipated to be [one] carcinogen". 4. FIRST AID MEASURES Inhalation: Skin Contact: Eye contact: Remove victim from exposure, where can breathe fresh air and keep comfortable; and if symptoms persist or cough does not calm, seek medical assistance. Wash skin with soap and water. Remove contaminated clothing and shoes and wash them before using it again. If irritation or rash seek medical assistance. Wash eyes immediately and thoroughly with water. Continue rinsing eyes for at least 15 minutes, including under lids, to remove all particles. Remove contact lenses in the case of carry. If irritation 2

3 persists, repeat flushing. Seek medical attention (ophthalmological) immediately. Ingestion: Special Information to physician: Do not induce vomiting without medical advice. If conscious, drink plenty of water. Consult doctor immediately. Never give anything by mouth to an unconscious person. If a person vomits and is positioned face up, you should turn aside. No specific treatment. Treat symptomatically. 5. PREVENTION AND FIREFIGHTING Flash Point ( C): non Combustible Auto Ignition Temperature ( C): non Combustible Flammability Limits (% v / v): N / A Fire extinguishers media: non Combustible Risk of combustion product: None Special Firefighting Procedures: None Unusual Fire and Explosion Hazards: None Protective Equipment for Fire Fighting As in any fire, wear self-contained apparatus in positive pressure, approved (MSHA / NIOSH) full protective clothing and breathing. During a fire, irritating and toxic gases may be generated by thermal decomposition or combustion. Mechanical sensitivity Contact: None Mechanical sensitivity Contact: None Personal precautions: Environmental precautions: Cleaning Methods: 6. SPILL CONTROL MEASURES Avoid dust formation. Avoid breathing dust and contact with skin. In the case of exposure to dust over regulatory limits (see section 8); use Individual Personal Protective Equipment Respiratory recommended (see section 8). Collect immediately and thoroughly sweeping or preferably vacuumed. After cleaning, flush away traces with wet towel. Keep in suitable, closed containers for disposal. Do not pour into drains or allow to enter waterways. If small leaks occur during handling of the packaging, pick immediately and thoroughly sweeping or preferably vacuumed. Dispose of material in appropriate containers. Handling: 7. HANDLING AND STORAGE Use only in area provided with appropriate exhaust ventilation. Avoid 3

4 Storage: formation of breathable particles. In the event of insufficient ventilation, wear suitable respiratory equipment individual protection. Avoid contact with eyes, on skin and clothing. Do not breathe fumes. Do not ingest. Good cleaning is important to prevent dust accumulation. Do not mix with other chemicals, except for the indicated by the manufacturer. Use chemical resistant gloves and eye protection. Wash contaminated clothing before reuse and wash hands before eating and drinking. Keep tightly closed in a dry, well-ventilated container at room temperature. Keep out of the reach of children. 8. CONTROL OF PERSOL PROTECTION Control Standards: OCCUPATIOL EXPOSURE LIMITS Chemical Name OSHA-PEL ACGIH-TLV CAP Silica quartz 0.1 mg/m³ mg/m³ 0,05 mg/m 3 A2 Portland cement (gray) 5 mg/m³ (Breathable) 10 mg/m³ (Breathable) 10 mg/m 3 (1) 15 mg/m³ (Total) Calcium carbonate 5 mg/m³ (Breathable) 5 mg/m³ (Breathable) 10 mg/m 3 (1) 15 mg/m³ (Total) Resin NE NE NE (1): The value is particulate inhalable (total) containing no asbestos and less than 1% crystalline silica Engineering Controls: P er s o n al p r ot e ct iv e Eye and Face Protection: Skin Protection: Respiratory Protection: Use adequate ventilation especially in confined areas, to maintain exposure (levels of dust, smoke, vapor, etc.) below recommended exposure limits. If engineering measures are not sufficient to maintain the concentration of dust particles below the OEL (occupational exposure limit) appropriate respiratory protection shall be used. Wear safety glasses with side shields or goggles in situations where there is a risk of exposure to splashes or products puffs. Wear goggles without ventilation or with indirect ventilation in extremely dusty or unpredictable environments. No contact lenses must be used when working with the product. Hand Protection: Use gloves (neoprene) chemically resistant to this material when its frequency is prolonged or repeated contact may occur. Skin Protection: Use proper and clean clothes covering the entire body. Avoid activities that cause dust to disperse in the air. Use local or general ventilation to ensure that exposure 4

5 e q ui p m e nt : Personal hygiene measures: remains below the applicable exposure limits. Use NIOSH (29 CFR ) and approved ANSI standard for respiratory protection (Z88.2) in areas with poor ventilation, or when exposure limits are exceeded, or when dust causes irritation or discomfort. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practices respect. Wash hands before breaks and after end of workday. When using, do not eat, drink or smoke. 9. PHYSICAL PROPERTIES CHEMICAL Physical State: Dust Color: White Odor: Characteristic Ph.: > 11 Initial Boiling Point: Final Boiling Point: Flashpoint: no Fuel Limit - Minor: Limit - Mayor: Auto Ignition Temperature: no Fuel Explosive properties: Vapor pressure: Vapor Density: Density: 1.60 g / ml (apparent) Solubility: Slightly soluble in water Coefficient octanol / water: 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions of use, storage and transport. Store dry. No dangerous reaction known under normal use conditions. Conditions to be Avoided: Incompatible materials. Materials to be avoided: Strong acids and bases, strong oxidizing agents. Hazardous Decomposition Products: No data available. 11. POISON INFORMATION SYMPTOMS RELATED TO THE PHYSICAL / CHEMICAL / TOXICOLOGICAL FEATURES: 5

6 Eye contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with redness and swelling in the cornea. Skin contact: Causes skin irritation. Handling can cause dry skin, discomfort, irritation and dermatitis. May cause sensitization by skin contact. Inhalation: May cause respiratory tract irritation. It causes damage to organs through prolonged or repeated exposure. The product contains breathable silica (quartz) can cause silicosis (a serious disabling and fatal lung disease), pulmonary fibrosis (scarring). Some studies have shown a high incidence of cases of scleroderma, connective tissue disorders, lupus, rheumatoid arthritis, chronic kidney disease and end in workers exposed to breathable silica. Occupational exposure to breathable dust and breathable crystalline silica should be monitored and controlled. Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and / or discomfort, nausea or vomiting. ACUTE TOXICITY Chemical Name LC50 LD50 Silica quartz Portland cement (gray) Calcium carbonate Oral: 6450 mg/kg, rat. Resin Oral: > mg/kg, rat. Chemical Name Silica quartz Portland cement (gray) Calcium carbonate Resin CARCINOGENICITY List of Chemicals as Carcinogens or Potential Carcinogens (NTP,IARC,OSHA,ACGIH,CP65) N-A2, I-1, O-1, ACGIH-A2, CP65 ACGIH-A4 EFFECTS OF SHORT AND LONG TERM EXPOSURE SHORT TERM: Skin: Eye: Respiratory Sensitization: Skin Sensitization: Single Exposure: Aspiration Hazard: Cause skin irritation It causes severe eye injury May produce an allergic reaction on the skin it can irritate the respiratory tract 6

7 LONG TERM: carcinogenicity: Germ cell mutagenicity: Toxic for reproduction: Continuous exposure: Synergistic effects / antagonistic: May cause cancer It causes damage to organs through prolonged or frequent exposure. 12. ECOLOGICAL INFORMATION Eco toxicity: An environmental analysis of the impact of this specific product has not been produced. However, plants and animals may experience longterm harmful or fatal effects if exposed in direct contact with the product. Prevent entry into sewers and waterways. Chemical Name EC50/NOEC-48 hours LC50/NOEC-96 hours Silica quartz Portland cement (gray) Calcium carbonate Resin > mg/l, bacterium > 500mg/l, fishes (OECD 209) (OECD 203) Persistence / degradability: The set material is not biodegradable and is persistent in the environment. Mobility: bioaccumulation: 13. CONSIDERATIONS DISPOSAL AND TREATMENT Waste Disposal: After 2 hours, the product hardens on contact with water (H2O). Once hardened, it can be disposed. Do not dispose of waste into sewer. Ensure that the waste management process complies with government and local regulations. Disposal of Containers / Containers: Remove containers / containers according to the compliance of all government and local regulations. DOT IATA IMDG TDG 14. TRANSPORT INFORMATION It is not regulated as a hazardous material by DOT. It is not classified as hazardous goods. It is not classified as hazardous goods. It is not classified as hazardous goods. 15. REGULATORY INFORMATION 7

8 16. OTRA INFORMACIÓN ABBREVIATIONS : Not applicable NE: Not Established ND: Not Determined IDLH: Limit immediately dangerous to life or health TLV: The threshold limit value PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit TWA: Time Weighted Average OECD Guidelines for testing of chemicals CAS: Chemical Abstracts Service EC: Concentration without effect LC: Lethal Concentration USA: Department of Transportation (DOT). Occupational Safety and Health Administration (OSHA). International Agency for Research on Cancer (IARC). National Toxicology Program (NTP). National Fire Protection Association (NFPA). National Institute for Occupational Safety and Health (NIOSH). American Conference of Governmental Industrial Hygienists (ACGIH). International Air Transport Association (IATA). International Maritime Dangerous Goods (IMDG). Transport of Dangerous Goods (TDG). NFPA RATING NFPA Health Hazard: 2 = Moderate NFPA Flammability: 0 = Not combustible NFPA Reactivity: 0 = Minimal Special Hazard NFPA: None NOTE: "This Safety Data Sheet (MSDS) has been designed according to the 8

9 Date of elaboration: 04/20/2016 Date of update: N/A Version: 1 9