Dresinate(TM) TX Rosin Soap

Transcription

1 SECTION 1. IDENTIFICATION Product name : Product code : EAN , P75033J4, P75033JS, P75033DR, P75033J2 Manufacturer or supplier's details Company name of supplier : Eastman Chemical Company Address : 200 South Wilcox Drive Kingsport TN Telephone : (423) Emergency telephone : CHEMTREC: , CCN7321 Recommended use of the chemical and restrictions on use Recommended use : Emulsifier Restrictions on use : None known. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Combustible dust Skin irritation : Category 2 Eye irritation : Category 2A Skin sensitization : Category 1 Specific target organ systemic toxicity - single exposure : Category 3 (Respiratory system) GHS label elements Hazard pictograms : Signal Word Hazard Statements : Warning : May form combustible dust concentrations in air. H315 Causes skin irritation. 1 / 11

2 H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Precautionary Statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance name : J Ingredients Chemical name CAS-No. Concentration (% w/w) sodium salt of tall-oil > 75 rosin and resin acids, sodium salt < 20 Water < 5 additive(s) proprietary < 1 Phenothiazine < 0.5 SECTION 4. FIRST AID MEASURES If inhaled : Remove to fresh air. Treat symptomatically. 2 / 11

3 Get medical attention if symptoms occur. In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention if symptoms occur. : Seek medical advice. : Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. : Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Further information Special protective equipment for fire-fighters : Use water spray to extinguish. Dry chemical Carbon dioxide (CO2) : None known. : Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. : No hazardous combustion products are known : Minimize dust generation and accumulation. : Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions : Wear appropriate personal protective equipment. Local authorities should be advised if significant spillages cannot be contained. : Avoid release to the environment. 3 / 11

4 Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Prevent runoff from entering drains, sewers, or streams. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion Advice on safe handling Conditions for safe storage : Minimize dust generation and accumulation. : Avoid breathing dust. Avoid contact with skin and eyes. Do not get on skin or clothing. Use only with adequate ventilation. Wash thoroughly after handling. Minimize dust generation and accumulation. : Keep container tightly closed and in a well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Phenothiazine TWA 5 mg/m3 ACGIH TWA 5 mg/m3 NIOSH REL TWA 5 mg/m3 OSHA P0 Hazardous components without workplace control parameters Ingredients CAS-No. sodium salt of tall-oil rosin and resin acids, sodium salt Engineering measures : Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Wear respiratory protection when its use is identified for certain contributing scenario. 4 / 11

5 Hand protection Remarks Eye protection Protective measures Hygiene measures : Wear chemical-resistant gloves, boots, and protective clothing appropriate for the risk of exposure. Contact glove manufacturer for specific information. : Safety glasses with side-shields : Ensure that eye flushing systems and safety showers are located close to the working place. : Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Color Odor Odor Threshold : powder : dark brown : rosin : not determined ph : Flash point Evaporation rate Flammability (solid, gas) Vapor pressure Relative density Solubility(ies) Water solubility Decomposition temperature Viscosity Viscosity, kinematic Dust deflagration index (Kst) Dust explosion class : not applicable, combustible solid : not determined : May form combustible dust concentrations in air. : not determined : 0.42 (25 C) : completely soluble : Thermal stability not tested. Low stability hazard expected at normal operating temperatures. : not determined : 124 m.b_/s : St 1 - weak explosion SECTION 10. STABILITY AND REACTIVITY 5 / 11

6 Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : None reasonably foreseeable. : Stable under normal conditions. : None known. Stable : Minimize dust generation and accumulation. : Strong oxidizing agents : Carbon dioxide (CO2) Carbon monoxide SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity rosin and resin acids, sodium salt: Acute oral toxicity : LD50 Oral (Rat, female): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Acute dermal toxicity Phenothiazine: Acute oral toxicity : LD50 Dermal (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity : Assessment: Harmful if swallowed. Skin corrosion/irritation Causes skin irritation. rosin and resin acids, sodium salt: Species: Rabbit Exposure time: 4 h Result: none Serious eye damage/eye irritation Causes serious eye irritation. rosin and resin acids, sodium salt: Species: Rabbit Result: Eye irritation 6 / 11

7 Respiratory or skin sensitization Skin sensitization: May cause an allergic skin reaction. Respiratory sensitization: rosin and resin acids, sodium salt: Species: Mouse Result: non-sensitizing Phenothiazine: Test Type: Skin sensitization Assessment: May cause sensitization by skin contact. Germ cell mutagenicity Carcinogenicity IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity STOT-single exposure May cause respiratory irritation. STOT-repeated exposure Repeated dose toxicity Phenothiazine: Assessment: The substance or mixture is classified as specific target organ toxicant, repeated exposure, category 2. Aspiration toxicity 7 / 11

8 Information on likely routes of exposure Product: Inhalation Skin contact Eye contact Ingestion : Remarks: Irritating to respiratory system. : Remarks: Causes skin irritation. May cause an allergic skin reaction. : Remarks: Causes serious eye irritation. : Remarks: None known. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity rosin and resin acids, sodium salt: Toxicity to fish : LC50 (Danio rerio (zebra fish)): 5.4 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates Phenothiazine: M-Factor (Acute aquatic toxicity) M-Factor (Chronic aquatic toxicity) Ecotoxicology Assessment Acute aquatic toxicity Chronic aquatic toxicity : EC50 (Daphnia): 75.6 mg/l Exposure time: 48 h : 1 : 1 : Very toxic to aquatic life. : Very toxic to aquatic life with long lasting effects. Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available 8 / 11

9 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. Domestic regulation 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know SARA 311/312 Hazards SARA 302 SARA 313 : Fire Hazard Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. The ingredients of this product are reported in the following inventories: CH INV DSL AICS NZIoC ENCS KECI : All components of this product are on the Canadian DSL 9 / 11

10 PICCS IECSC TSCA : On TSCA Inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Full text of other abbreviations AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vpvb - Very Persistent and Very Bioaccumulative 10 / 11

11 Instability SAFETY DATA SHEET Further information NFPA: HMIS IV: Flammability Health HEALTH FLAMMABILITY PHYSICAL HAZARD / Special hazard. HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Revision Date : The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8 11 / 11