SAFETY DATA SHEET PIG WET SURFACE REPAIR PUTTY

Transcription

1 Revision Date SAFETY DATA SHEET PIG WET SURFACE REPAIR PUTTY According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name PIG WET SURFACE REPAIR PUTTY 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Repair putty Details of the supplier of the safety data sheet Supplier New Pig Ltd. Hogs Hill Watt Place Hamilton International Technology Park Blantyre, G72 0AH, UK T: +44 ( 0) E: pigpen@newpig.com Web: Emergency telephone number +44 (0) Monday - Friday 08:00-17:00 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Classification (1999/45/EEC) Physical and Chemical Hazards Not classified. Human health Environment Xi;R36/38. R43. R52/53. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health Skin Irrit. 2 - H315;Eye Irrit. 2 - H319;Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Irritating to eyes and skin. The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals. Environment Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements Contains EPOXY RESIN (Number average MW <= 700 ) Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Warning H315 H317 H319 H412 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. 1 / 10

2 Precautionary Statements P280 PIG WET SURFACE REPAIR PUTTY Wear protective gloves/protective clothing/eye protection/face protection. P IF ON SKIN: Wash with plenty of soap and water. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P IF exposed or concerned: Get medical advice/attention. P501 Supplementary Precautionary Statements Supplemental label information 2.3. Other hazards P272 P273 P261 P264 P321 Dispose of contents/container in accordance with national regulations. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Avoid breathing vapour/spray. Wash contaminated skin thoroughly after handling. Specific treatment (see medical advice on this label). P If skin irritation or rash occurs: Get medical advice/attention. P363 EUH205 This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Wash contaminated clothing before reuse. Contains epoxy constituents. May produce an allergic reaction Mixtures TALC % CAS-No.: EC No.: Substance with a Community workplace exposure limit. Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Not classified. TITANIUM DIOXIDE 10-30% CAS-No.: EC No.: Substance with a Community workplace exposure limit. Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Not classified. EPOXY RESIN (Number average MW <= 700 ) 10-30% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Aquatic Chronic 2 - H411 Classification (67/548/EEC) R43 Xi;R36/38 N;R51/53 QUARTZ 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) STOT RE 2 - H373 Classification (67/548/EEC) Xn;R48/20. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section / 10

3 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move into fresh air and keep at rest. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Get medical attention immediately! Do not induce vomiting unless directed by medical personnel. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention Most important symptoms and effects, both acute and delayed Inhalation Unlikely route of exposure during normal use. Ingestion May cause discomfort if swallowed. Skin contact Prolonged skin contact may cause redness and irritation. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Eye contact Irritation of eyes and mucous membranes Indication of any immediate medical attention and special treatment needed The severity of the symptoms described will vary dependant of the concentration and the length of exposure. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards Dike and collect extinguishing water. Prevent entry into drains. Specific hazards When heated and in case of fire, irritating vapours/gases may be formed Advice for firefighters Special Fire Fighting Procedures Avoid breathing fire vapours. Move container from fire area if it can be done without risk. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For personal protection, see section Environmental precautions Do not allow ANY environmental contamination Methods and material for containment and cleaning up 3 / 10

4 Wear necessary protective equipment. Ventilate well. Collect spillage with shovel, broom or the like and reuse, if possible. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Wash thoroughly after dealing with a spillage. Use appropriate containment to avoid environmental contamination Reference to other sections For personal protection, see section 8. See section 11 for more detailed information on health effects and symptoms. Collect and dispose of spillage as indicated in section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear protective clothing as described in Section 8 of this safety data sheet. Read and follow manufacturer's recommendations. Avoid contact with skin and eyes. Avoid discharge to the aquatic environment Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Store in closed original container at temperatures between 5 C and 30 C Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes QUARTZ WEL 0,1 mg/m3 TALC WEL 1 mg/m3 TITANIUM DIOXIDE WEL 10 mg/m3 WEL = Workplace Exposure Limit Exposure controls Engineering measures Provide adequate ventilation. Respiratory equipment Respiratory protection not required. Hand protection Protective gloves are recommended. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye protection Wear approved safety goggles. Other Protection Wear appropriate clothing to prevent reasonably probable skin contact. Hygiene measures Wash hands after handling. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Coloured paste. Colour Green. White. Odour Sulphur. Solubility Insoluble in water Relative density Bulk Density Vapour density (air=1) 4 / 10

5 Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY PIG WET SURFACE REPAIR PUTTY >93 C Sh CC (Setaflash closed cup) Reactivity Violent reaction with: Organic peroxides/hydroperoxides Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known. Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid exposure to high temperatures or direct sunlight Incompatible materials Materials To Avoid Strong oxidising substances. Strong acids. Strong alkalis. Amines Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Fire creates: Toxic gases/vapours/fumes of: Sulphur. Ammonia or amines. SECTION 11: TOXICOLOGICAL INFORMATION 5 / 10

6 11.1. Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Skin Corrosion/Irritation: Irritating. Serious eye damage/irritation: Irritating. Respiratory or skin sensitisation: May cause sensitisation by skin contact. Germ cell mutagenicity: Genotoxicity - In Vitro Carcinogenicity: Carcinogenicity Limited evidence of a carcinogenic effect. Product contains: Crystalline Silica Reproductive Toxicity: Reproductive Toxicity - Fertility Specific target organ toxicity - repeated exposure: Not classified as a specific target organ toxicant after repeated exposure. Inhalation Not relevant at normal room temperatures. When heated, toxic vapours may be formed. Ingestion Gastrointestinal symptoms, including upset stomach. Skin contact Prolonged and frequent contact may cause redness and irritation. May cause sensitisation by skin contact. Eye contact Irritation of eyes and mucous membranes. Toxicological information on ingredients. 6 / 10

7 QUARTZ (CAS: ) Toxicological information Information for: CAS (EC ). Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 0.69 mg/l (dust/mist) Rat 4 hours 7 / 10

8 TITANIUM DIOXIDE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) 5.09 mg/l (dust/mist) Rat 4 hours Skin Corrosion/Irritation: Not irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Buehler test: Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity NOAEL 5 mg/m3 Inhalation. Rat Reproductive Toxicity: Reproductive Toxicity - Fertility Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEC 50 mg/m3 Inhalation. Rat Not classified as a specific target organ toxicant after repeated exposure. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Harmful to aquatic organisms. 8 / 10

9 Ecological information on ingredients. PIG WET SURFACE REPAIR PUTTY QUARTZ (CAS: ) Acute Toxicity - Fish Aquatic Toxicity is unlikely to occur. Acute Toxicity - Aquatic Invertebrates EL50 24 hours > 1000 mg/l Daphnia magna TITANIUM DIOXIDE (CAS: ) Acute Toxicity - Fish LC50 96 hours > 100 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates LC50 48 hours > 100 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 72 hours 61 mg/l Pseudokirchnerella subcapitata (Raphidocelis subcapitata) Persistence and degradability Degradability There are no data on the degradability of this product. Ecological information on ingredients. Degradability Not Applicable - Inorganic chemical. Degradability Not Applicable - Inorganic chemical. QUARTZ (CAS: ) TITANIUM DIOXIDE (CAS: ) Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: Not considered mobile Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name 9 / 10

10 14.3. Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date Safety Data Sheet Status Risk Phrases In Full R52/53 R48/20 R36/38 R43 NC R51/53 Hazard Statements In Full H319 H315 H412 H317 H373 H411 EN_GB_SDS_S135.pdf Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Irritating to eyes and skin. May cause sensitisation by skin contact. Not classified. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Causes serious eye irritation. Causes skin irritation. Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction. May cause damage to organs <<Organs>> through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. 10 / 10