Material Safety Data Sheet

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name: EPA REG. NO Product Use Description: Synonyms: Fungicide Terraguard SC, PROCURE 480SC, Terraguard SC-LS, Viticure Company: Chemtura Corporation 199 Benson Road Middlebury, CT United States of America Telephone: Emergency telephone number: CHEMTREC: (24 hours) : Chemtura Corporation Emergency Response: CHEMTURA : For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by: 06/22/2011 Product Safety Department (US) MSDSRequest@chemtura.com SECTION 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! Form: liquid suspension Colour: off-white to tan Odour: mild Hazard Summary : Harmful if swallowed. Irritating to eyes. May cause allergic skin reaction. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Potential Health Effects Primary Routes of Entry Aggravated Medical Condition : Skin Absorption Eye contact Inhalation : Dermatitis Skin disorders Allergies SAP / 11 SDS Number:

2 Target Organs Inhalation Skin Eyes Ingestion Chronic Exposure : Skin Immune system Liver Kidney : No adverse effects are expected under normal conditions of use. : May cause allergic skin reaction. Prolonged or repeated exposure increases the risk. : Irritating to eyes. : Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. : Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Prolonged exposure can be harmful for certain organs, e.g. liver, kidneys, blood, nervous system and skin. Carcinogenicity: IARC OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. Environmental Effects Environmental Effects : Dangerous for the environment SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Component / CAS-No. Triflumizole A815 Tech propane-1,2-diol Weight percent % 6 % SAP / 11 SDS Number:

3 SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact : If breathed in, move person into fresh air. Give oxygen or artificial respiration if needed. Consult a physician after significant exposure. : If on clothes, remove clothes. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation occurs, seek medical advice/attention. Wash contaminated clothing before re-use. Destroy contaminated shoes. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention if irritation develops and persists. Ingestion : Do NOT induce vomiting. Give small amounts of water to drink. Call a physician or poison control centre immediately. Never give anything by mouth to an unconscious person. SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point Ignition temperature : Remarks: Aqueous system : Remarks: not determined Fire fighting Suitable extinguishing media Unsuitable extinguishing media Further information : Extinguishing media - large fires Alcohol-resistant foam Small fires: Carbon dioxide (CO2) Dry chemical : Water spray jet : Fight fires from a safe distance. Move containers from fire area if possible. Use water spray to cool unopened containers. Prevent fire extinguishing water from contaminating surface water or the ground water system. Protective equipment and precautions for firefighters Specific hazards during fire fighting Special protective equipment for fire-fighters : Burning produces noxious and toxic fumes. Thermal decomposition can lead to release of irritating gases and vapours. : Body covering protective clothing, full "turn-out" gear. Self-contained breathing apparatus. SAP / 11 SDS Number:

4 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up Additional advice : Evacuate personnel to safe areas. Ensure adequate ventilation. Avoid contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection. : Toxic to aquatic life. Do not allow material to contaminate ground water system. Prevent product from entering drains. Avoid release to the environment. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Shovel into suitable container for disposal. Large spills should be collected mechanically (remove by pumping) for disposal. Ventilate the area. : Keep in properly labelled containers. Dispose of rinse water as waste water. SECTION 7. HANDLING AND STORAGE Handling Handling procedures : Handle and open container with care. Protect from contamination. Use only in well-ventilated areas. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid inhalation, ingestion and contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection. Wash thoroughly after handling. Keep container closed when not in use. Storage Requirements for storage areas and containers Other data : Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container. : Stable at normal ambient temperature and pressure. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components / CAS-No. Value / Basis / Update propane-1,2-diol US WEEL Control parameters 10 mg/m3 Further information SAP / 11 SDS Number:

5 ,4-dioxane ethylene oxide methyloxirane ACGIH OSHA P OSHA P ACGIH ACGIH OSHA P OSHA P ppm 100 ppm 360 mg/m3 25 ppm 90 mg/m3 1 ppm 2 ppm 100 ppm 240 mg/m3 20 ppm 50 mg/m3 Engineering measures Personal protective equipment Eye protection : Safety glasses with side-shields or Safety goggles Hand protection : Chemical resistant protective gloves Skin and body protection : Long sleeved clothing Remove and wash contaminated clothing before re-use. Discard contaminated shoes. To protect against splashes from pouring: Rubber or plastic boots Rubber or plastic apron SAP / 11 SDS Number:

6 Respiratory protection Hygiene measures : In case of insufficient ventilation, wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used. : Handle in accordance with good industrial hygiene and safety practice. Wear suitable gloves and eye/face protection. Avoid contact with skin, eyes and clothing. Do not inhale aerosol. Ensure adequate ventilation, especially in confined areas. When using do not eat, drink or smoke. Wash thoroughly after handling. Keep working clothes separately. Remove and wash contaminated clothing before re-use. Contaminated work clothing should not be allowed out of the workplace. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid suspension : off-white to tan : mild Safety data Flash point Ignition temperature : Note: Aqueous system : Remarks: not determined ph : Freezing point Boiling point/boiling range : Note: not determined : Note: not determined Specific Gravity : at 20 C Water solubility Solubility in other solvents : Note: not applicable : Note: not applicable SAP / 11 SDS Number:

7 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Hazardous decomposition products Hazardous reactions : Remarks: None known. : Note: After evaporation of water, combustion will generate: Carbon oxides nitrogen oxides (NOx) Hydrogen halides : Hazardous polymerisation does not occur. SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Triflumizole A815 Tech propane-1,2-diol : LD50: 1,420 mg/kg Species: rat : LD50: 20,000 mg/kg Species: rat LD50: 18,500 mg/kg Species: rabbit Acute dermal toxicity Triflumizole A815 Tech propane-1,2-diol : LD50: > 5,000 mg/kg Species: rabbit : LD50: 20,800 mg/kg Species: rabbit Skin irritation : Species: rabbit Result: slight irritation Eye irritation : Species: rabbit Result: No eye irritation Sensitisation : Species: guinea pig Result: negative Repeated dose toxicity Triflumizole A815 Tech Toxicology Assessment CMR effects : : Mutagenicity: negative SAP / 11 SDS Number:

8 12. ECOLOGICAL INFORMATION Toxicity to fish Triflumizole A815 Tech : LC50: 0.58 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) static test LC50: 0.76 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp) semi-static test Analytical monitoring: yes Method: OECD Test Guideline 203 LC50: 1.2 mg/l Exposure time: 96 h Species: Lepomis machrochirus (Bluegill) static test LC50: 1.4 mg/l Exposure time: 96 h Species: Cyprinodon variegatus (sheepshead minnow) flow-through test Analytical monitoring: yes Toxicity to daphnia and other aquatic invertebrates. Triflumizole A815 Tech : EC50: 1.42 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) semi-static test Analytical monitoring: yes Method: OECD Test Guideline 202 LC50: 0.62 mg/l Exposure time: 96 h Species: Mysid shrimp flow-through test Analytical monitoring: yes Toxicity to algae Triflumizole A815 Tech : EC50: > 4.7 mg/l Exposure time: 72 h Species: Freshwater algae static test Analytical monitoring: yes Method: OECD Test Guideline 201 EC50: 1.91 mg/l Exposure time: 72 h Species: Scenedesmus capricornutum (fresh water algae) Analytical monitoring: yes Method: OECD Test Guideline 201 SAP / 11 SDS Number:

9 Toxicity to fish (Chronic toxicity) Triflumizole A815 Tech : NOEC: 0.12 mg/l Exposure time: 24 d Species: Cyprinodon variegatus (sheepshead minnow) flow-through test Toxicity to daphnia and other aquatic invertebrates. (Chronic toxicity) Triflumizole A815 Tech : NOEC: 0.14 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) flow-through test Analytical monitoring: yes Further information on ecology Additional ecological information Triflumizole : SECTION 13. DISPOSAL CONSIDERATIONS Further information : Dispose of waste material in compliance with all federal, state, and local regulations. Pesticide wastes are toxic. Do not contaminate ponds, waterways or ditches with chemical or used container. SECTION 14. TRANSPORT INFORMATION DOT UN number : 3082 Description of the goods : Environmentally hazardous substances, liquid, n.o.s. : (Triflumizole) Class : 9 Packing group : III Labels : 9 Emergency Response : 171 Guidebook Number Environmentally hazardous : yes Triflumizole IATA UN number : 3082 Description of the goods : Environmentally hazardous substance, liquid, n.o.s. (Triflumizole) Class : 9 Packing group : III Labels : 9 Environmentally hazardous : no IMDG SAP / 11 SDS Number:

10 UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triflumizole) Class : 9 Packing group : III Labels : 9 EmS Number 1 : F-A EmS Number 2 : S-F Marine pollutant Environmentally hazardous : yes Triflumizole : yes Triflumizole Not regulated by DOT and TDG if shipped or transported in packaging less than 450 liters by road and/or rail. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity SARA 302 Reportable Quantity SARA 311/312 Hazards : : : Acute Health Hazard Chronic Health Hazard EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Reportable : Quantity ethylene oxide lbs methyloxirane lbs SARA 304 Components : This material does not contain any components with a section 304 EHS RQ. California Prop. 65 Components : WARNING! This product contains a chemical known to the State of California to cause cancer. SAP / 11 SDS Number:

11 1,4-Dioxane ,4- dioxane Oxirane ethylene oxide Oxirane, methyl methyloxirane WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Oxirane ethylene oxide SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 2 Chronic Health Hazard: * Flammability: 0 Reactivity: 0 PPI:Ask supervisor or safety specialist for handling instructions NFPA Classification 0 : Health hazard: 2 Fire Hazard: 0 Reactivity Hazard: Other Emergency Phone Number Latin America: Brazil All other countries +44 (0) Mexico: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP / 11 SDS Number: