Safety Data Sheet according to (EC) No 1907/2006

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1 Safety Data Sheet according to (EC) No 1907/2006 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 1 of 11 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: adhesive and sealant 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) ua-productsafety.de@henkel.com 1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Skin irritation Category 2 H315 Causes skin irritation. Serious eye irritation Category 2 H319 Causes serious eye irritation. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects Label elements Label elements (CLP):

2 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 2 of 11 Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Warning H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection Other hazards Persons suffering from allergic reactions to epoxides should avoid contact with the product. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Mixtures General chemical description: adhesive and sealant Base substances of preparation: Epoxy resin SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: resin (number average EC Number REACH-Reg No content Classification % Skin Irrit. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H319 Aquatic Chronic 2 H < 5 % Eye Irrit. 2 H319 0,1- < 1 % Aquatic Acute 1 H400 Aquatic Chronic 1 H ,1- < 1 % Eye Irrit. 2 H319 STOT SE 3 H335 Repr. 2 H361d Aquatic Chronic 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

3 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 3 of 11 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: IF ON SKIN: Wash with plenty of soap and water. In case of adverse health effects seek medical advice. Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. SKIN: Redness, inflammation. SKIN: Rash, Urticaria Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: All common extinguishing agents are suitable. SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In case of fire toxic gases can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Avoid contact with skin and eyes. Keep unprotected persons away Environmental precautions Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems s and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8

4 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 4 of Precautions for safe handling Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Take off contaminated clothing and wash before reuse. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Store in a cool, dry place Specific end use(s) adhesive and sealant SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Germany Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit Regulatory list category / Remarks Polyvinyl chloride Short Term Category II: substances with a TRGS Classification: resorptive effect. Polyvinyl chloride 1,25 limit(s): TRGS Polyvinyl chloride 10 limit(s): 2 TRGS Barium sulfate Short Term Category II: substances with a TRGS Classification: resorptive effect. Barium sulfate 10 limit(s): 2 TRGS Barium sulfate 1,25 limit(s): TRGS Talc (Mg3H2(SiO3)4) Short Term Category II: substances with a TRGS Classification: resorptive effect. Talc (Mg3H2(SiO3)4) 1,25 limit(s): TRGS Talc (Mg3H2(SiO3)4) limit(s): 2 TRGS 900 Biological Indices: Ingredient [Regulated substance] Aluminium dihydrogen triphosphate Parameters Biological specimen Sampling Conc. Basis of biol. exposure index Aluminum Urine Sampling : End of 200 µg/l DE BAT shift. Remark Additional Information 8.2. controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: In case of dust formation, we recommend wearing of appropriate respiratory protection equipment with particle filter P (EN 14387). This recommendation should be matched to local conditions.

5 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 5 of 11 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166. Skin protection: Wear protective equipment. Protective clothing that covers arms and legs. Protective clothing should conform to EN for liquid splashes or to EN for dusts. Advices to personal protection equipment: Use only personal protection that's CE-labelled according to Directive 89/686/EEC (Europe) or to Regulation No. 819 of 19 August 1994 (Norway). The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions. Personal protective equipment should conform to the relevant EN standard. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance solid material pasty red Odor characteristic Odour threshold ph (20 C (68 F); Conc.: 200 g/l; Solvent: Deionised water (ph 5,8)) Initial boiling point Flash point Decomposition temperature Vapour pressure Density (20 C (68 F)) Bulk density Viscosity (; 20 C (68 F)) Viscosity (kinematic) Explosive properties Solubility (qualitative) (20,0 C (68 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 5,5 Not applicable 1,55 g/cm mpa.s Insoluble

6 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 6 of Other information SECTION 10: Stability and reactivity Reactivity None if used for intended purpose Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials None if used properly Hazardous decomposition products No decomposition if used according to specifications Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Persons suffering from allergic reactions to epoxides should avoid contact with the product. Skin irritation: Causes skin irritation. Eye irritation: Causes serious eye irritation. Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Value type Value Route of application Species LD50 > mg/kg oral rat LD50 > mg/kg oral rat LD50 > mg/kg oral rat LD mg/kg oral rat Acute inhalative toxicity: Value Value Route of Species type application LC50 > 5,7 mg/l 4 h rat

7 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 7 of 11 Acute dermal toxicity: Value type Value Route of application Species LD mg/kg dermal rabbit LD50 > mg/kg dermal rat Skin corrosion/irritation: Result Species slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating rabbit Serious eye damage/irritation: Result Species not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating rabbit Respiratory or skin sensitization: sensitising not sensitising Result Test type Species Mouse local lymphnod e assay (LLNA) Guinea pig maximisat ion test mouse guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / with and without Species OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay)

8 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 8 of 11 SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water Toxicity Ecotoxicity: Harmful to aquatic life with long lasting effects. bisphenol- A- bisphenol- A- bisphenol- A- Value type Value Acute Toxicity Study Species LC50 1,75 mg/l Fish 96 h Oncorhynchus mykiss (reported as Salmo gairdneri) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 9,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline NOEC 2,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline NOEC 0,3 mg/l chronic Daphnia 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC50 > mg/l Fish 48 h Leuciscus idus DIN EC mg/l Daphnia 50 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline EC mg/l Bacteria 3 h OECD Guideline 209 (Activated Sludge, Respiration LC50 > mg/l Fish Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 0,017 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC50 0,17 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) NOEC 500 mg/l Bacteria OECD Guideline OECD Guideline LC mg/l Fish 48 h Poecilia reticulata OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 1,55 mg/l Algae Ankistrodesmus falcatus OECD Guideline Persistence and degradability Result Route of application Degradability

9 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 9 of 11 bisphenol- A- aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil LogKow Bioconcentration factor (BCF) 0,98 Species Temperature Results of PBT and vpvb assessment (epichlorhydrin); epoxy molecular weight <= 700) PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: In consultation with the responsible local authority, must be subjected to special treatment. Waste code The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you Waste adhesives and sealants containing organic solvents or other dangerous substances

10 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 10 of 11 SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of Marpol and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 0 % (VOCV VOC regulation CH) Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Germany): WGK: 2, water-endangering product. (German VwVwS of July 27, 2005 ) Classification in conformity with the calculation method BG regulations, rules, infos: BG information : Guidance document for the handling of epoxy resins. Storage class according to TRGS 510: 11

11 TEROSON EP 8031 known as TEROKAL 8031 FA 280KG Page 11 of 11 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.

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