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1 3M UK PLC 3M CENTRE, CAIN RD, BRACKNELL, BERKSHIRE RG12 8HT Tel: ======================================================================== Kit MSDS ======================================================================== Document id : Issue date : 03/10/2003 Version : 5.01 Supersedes date : 03/10/2003 Document status : Issued Format : 23 1 INFORMATION REGARDING KIT Dear Customer, This is the cover sheet for the KIT MSDS. You will find the document numbers of the MSDS that belong to the kit here on this page. Tradename: 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG 3M Product ID: Kit Components SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) 3M UK PLC 3M CENTRE, CAIN RD, BRACKNELL, BERKSHIRE RG12 8HT Tel: ======================================================================== MATERIAL SAFETY DATA SHEET ======================================================================== Document id : Issue date : 03/10/2003 Version : 6.01 Supersedes date : 03/10/2003 Document status : Issued Format : 1 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION Tradename: SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) 3M Product ID: multimedia.3m.com/ /mediawebserv 1/16

2 2 COMPOSITION/INFORMATION ON INGREDIENTS Ingredient name and classification CAS number Percentage ALIPHATIC POLYMER DIAMINE EU Hazard Symbols and Risk Phrases: EU - 3M Classified (Xi; R: ) SULFONIC ACID SALT BIS(3-AMINOPROPYL) ETHER OF Less Than 3 DIETHYLENE GLYCOL EU Hazard Symbols and Risk Phrases: EU - Vendor Classified (C; R:34-52/53) 3 HAZARDS IDENTIFICATION Critical hazards: Irritant. Risk of serious damage to eyes. Irritating to skin. May cause sensitisation by skin contact. 4 FIRST-AID MEASURES Eye Contact: Get immediate medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) Page 2 of 7 Total Pages Ingestion: Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. 5 FIRE-FIGHTING MEASURES multimedia.3m.com/ /mediawebserv 2/16

3 Suitable Extinguishing Media: Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Hazardous Decomposition: Oxides of Nitrogen, Amine Compounds. Carbon Monoxide, Carbon Dioxide. Fire-Fighting Procedures: Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, tunic and trousers (leggings), bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Special Instructions: Not applicable. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Refer to other sections of this Material Safety Data Sheet for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Methods for Cleaning up: Contain spill. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. 7 HANDLING AND STORAGE Incompatible Materials/Conditions: Store away from acids. Ventilation: Keep container in a well-ventilated area. Precautions for Safe Handling: For industrial or professional use only. SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) Page 3 of 7 Total Pages 8 EXPOSURE CONTROLS/PERSONAL PROTECTION multimedia.3m.com/ /mediawebserv 3/16

4 Eye Protection: Avoid eye contact. The following should be worn alone alone or in combination, as appropriate or in combination, to prevent eye contact: Safety glasses with side shields. Indirect vented goggles. Hand Protection: The following glove material(s) are recommended: Butyl rubber. Polyethylene/ethylene vinyl alcohol. Skin Protection: Avoid skin contact. Respiratory Protection: Avoid inhalation of vapours, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half face piece or full face air-purifying respirator with organic vapour cartridges. Ingestion: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Recommended Ventilation: Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapour, or spray. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Exposure Limits: 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: ph: Boiling point/boiling range: Melting point/melting range: Flash point: Autoflammability: Light amber liquid with slight amine odour. Not applicable Not applicable Greater than 100 C multimedia.3m.com/ /mediawebserv 4/16

5 SCOTCH-WELD (TM) EPOXY ADHESIVE Page 4 of 7 Total Pages DP-190-EG (PART A) Vapour pressure: Water Solubility: Specific gravity: Vapour density: Volatile organic compounds: Evaporation rate: Viscosity: Less Than 0.01 mmhg 20 C Nil Approximately 1.01 Water=1 Approximately centipoise Percent Volatile: 0 % by wt 10 STABILITY AND REACTIVITY Conditions to Avoid: Store away from heat. Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction (exotherm) with production of intense heat and smoke. Materials to Avoid: None known. Hazardous Decomposition: Stable. Hazardous polymerisation will not occur. 11 TOXICOLOGICAL INFORMATION Effects from Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Vapours from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: Severe Skin Irritation: Signs/symptoms may include localised redness, swelling, itching, dryness, cracking, blistering, and pain. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation: multimedia.3m.com/ /mediawebserv 5/16

6 Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) Page 5 of 7 Total Pages hoarseness, and nose and throat pain. Vapours from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache,hoarseness, nose and throat pain. Effects from Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhoea and vomiting. 12 ECOLOGICAL INFORMATION Ecotoxicity Data:. Ecofate Data:. Special statements for 2001/58/EC: One or more components of this product have significant known or predicted environmental hazards, but a conservative assessment indicates a low environmental risk. Intended use and proper disposal are unlikely to cause the environmentally hazardous component(s) to enter the environment in quantities or by routes that could cause the adverse environmental impacts. 13 DISPOSAL CONSIDERATIONS Product after Use: Incinerate uncured product in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Special Instructions: Dispose of completely cured (or polymerised) wastes in a sanitary landfill. Since regulations vary, consult applicable regulations or authorities before disposal. 14 TRANSPORT INFORMATION multimedia.3m.com/ /mediawebserv 6/16

7 UN NUMBER: UN number: Not restricted for transportation. UK ROAD/SEA FREIGHT (IMO) CLASSIFICATION: Substance Identification Number: Class: SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) Page 6 of 7 Total Pages Packing Group: Proper Shipping Name: CDG-ROAD (if applicable) ADR/RID CLASSIFICATION: Class: Item Number: ICAO/IATA CLASSIFICATION: Class: Sub-Risk: Packing Group: Proper Shipping Name: 15 REGULATORY INFORMATION Symbol(s): (Xi) St. Andrew's Cross (Irritant). Risk Phrases: (R41) Risk of serious damage to eyes. (R38) Irritating to skin. (R43) May cause sensitisation by skin contact. Safety Phrases: Use only in well ventilated areas. Do not breathe vapour. Do not breathe dust. Avoid contact with the skin and eyes. Wear suitable gloves and eye protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical multimedia.3m.com/ /mediawebserv 7/16

8 advice. After contact with skin, wash immediately with plenty of soap and water. 16 OTHER INFORMATION Regulatory Information: The following UK Regulations as amended may affect the product as supplied: The Chemicals (Hazard Information and Packaging for supply) Regulations, as amended. The Carriage of Dangerous Goods (Classification, Packaging and Labelling) and use of Transportable Pressure Receptacles Regulations 1996, SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART A) Page 7 of 7 Total Pages as amended. Carriage of Dangerous Goods by Road regulations, 1996, as amended. The Petroleum (Consolidation) Act The Control of Substances Hazardous to Health Regulations 1999 as amended. The Special Waste Regulations 1996, as amended. The Environmental Protection Act, 1990 The Health and Safety at Work Act, Reissue date/reason for reissue. Updated accidental release, toxicological and label information. Intended Use of Product: Bonding various substrates. The information on this Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own multimedia.3m.com/ /mediawebserv 8/16

9 intended applications. 3M UK PLC 3M CENTRE, CAIN RD, BRACKNELL, BERKSHIRE RG12 8HT Tel: ======================================================================== MATERIAL SAFETY DATA SHEET ======================================================================== Document id : Issue date : 03/10/2003 Version : 4.01 Supersedes date : 19/05/2003 Document status : Issued Format : 1 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION Tradename: 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) 3M Product ID: 2 COMPOSITION/INFORMATION ON INGREDIENTS Ingredient name and classification CAS number Percentage EPOXY RESIN EU Hazard Symbols and Risk Phrases: EU - Adaptation 25 (Xi,N; R: ) EPOXY RESIN EU Hazard Symbols and Risk Phrases: EU - Vendor Classified (Xi,N; R:43-51/53) 3 HAZARDS IDENTIFICATION Critical hazards: Irritant. Dangerous to environment. Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4 FIRST-AID MEASURES Eye Contact: Flush eyes with large amounts of water. If signs/symptoms multimedia.3m.com/ /mediawebserv 9/16

10 persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 2 of 7 Total Pages Ingestion: Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. 5 FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Hazardous Decomposition: Aldehydes. Carbon Monoxide, Carbon Dioxide. Fire-Fighting Procedures: Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, tunic and trousers (leggings), bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Water may be used to blanket the fire. Special Instructions: None known. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Refer to other sections of this Material Safety Data Sheet for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Methods for Cleaning up: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Collect multimedia.3m.com/ /mediawebserv 10/16

11 as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. 7 HANDLING AND STORAGE Incompatible Materials/Conditions: Store away from acids. Store away from oxidising agents. Ventilation: Keep container in a well-ventilated area. Precautions for Safe Handling: For industrial or professional use only. Avoid contact with oxidising agents. 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 3 of 7 Total Pages 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection: Avoid eye contact. Avoid eye contact with vapours, mists, or spray. The following should be worn alone alone or in combination, as appropriate or in combination, to prevent eye contact: Safety glasses with side shields. Indirect vented goggles. Hand Protection: The following glove material(s) are recommended: Polyethylene/ethylene vinyl alcohol. Skin Protection: Avoid skin contact. Respiratory Protection: Avoid inhalation of vapours, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half face piece or full face air-purifying respirator with organic vapour cartridges. Ingestion: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Recommended Ventilation: Use in a well-ventilated area. Provide ventilated enclosure multimedia.3m.com/ /mediawebserv 11/16

12 for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Exposure Limits: 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: ph: Boiling point/boiling range: Melting point/melting range: Flash point: Autoflammability: Vapour pressure: Water Solubility: Clear liquid paste. Not applicable Greater than C Less Than 0.02 mmhg 20 C Nil 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 4 of 7 Total Pages Specific gravity: Vapour density: Volatile organic compounds: Evaporation rate: Viscosity: Percent Volatile: 1.14 Water= centipoise Nil 10 STABILITY AND REACTIVITY Conditions to Avoid: Store away from acids. Store away from heat. Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction (exotherm) with production of intense heat and smoke. multimedia.3m.com/ /mediawebserv 12/16

13 Materials to Avoid: Strong acids. Strong oxidising agents. Hazardous Decomposition: Stable. Hazardous polymerisation will not occur. 11 TOXICOLOGICAL INFORMATION Effects from Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Vapours from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: Mild Skin Irritation: signs/symptoms may include localised redness, swelling, and itching. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation: Vapours from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache,hoarseness, nose and throat pain. Effects from Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhoea and vomiting. 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 5 of 7 Total Pages 12 ECOLOGICAL INFORMATION Ecotoxicity Data:. Ecofate Data:. Special statements for 2001/58/EC: One or more components of this product have significant known or predicted environmental hazards, but a conservative assessment indicates a low environmental risk. Intended use and proper disposal are unlikely to cause the environmentally multimedia.3m.com/ /mediawebserv 13/16

14 hazardous component(s) to enter the environment in quantities or by routes that could cause the adverse environmental impacts. Other Effects and Information: A conservative, screening level assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk. Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse environmental impacts. 13 DISPOSAL CONSIDERATIONS Potential for Recycling: Reclaim if feasible. Special Instructions: As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator. Dispose of completely cured (or polymerised) wastes in a sanitary landfill. Since regulations vary, consult applicable regulations or authorities before disposal. 14 TRANSPORT INFORMATION UN NUMBER: UN number: Not restricted for transportation. UK ROAD/SEA FREIGHT (IMO) CLASSIFICATION: Substance Identification Number: Class: Packing Group: 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 6 of 7 Total Pages Proper Shipping Name: CDG-ROAD (if applicable) ADR/RID CLASSIFICATION: multimedia.3m.com/ /mediawebserv 14/16

15 Class: Item Number: ICAO/IATA CLASSIFICATION: Class: Sub-Risk: Packing Group: Proper Shipping Name: 15 REGULATORY INFORMATION Symbol(s): (Xi) St. Andrew's Cross (Irritant). (N) Dangerous to environment. Risk Phrases: (R36/38) Irritating to eyes and skin. (R43) May cause sensitisation by skin contact. (R51/53) Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: Avoid contact with the skin and eyes. Wear suitable gloves and eye and face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Contains Epoxy Resins. See information supplied by manufacturer. Avoid release to the environment. Refer to special instructions/safety data sheets. 16 OTHER INFORMATION Regulatory Information: The following UK Regulations as amended may affect the product as supplied: The Chemicals (Hazard Information and Packaging for supply) Regulations, as amended. The Carriage of Dangerous Goods (Classification, Packaging and Labelling) and use of 3M SCOTCH-WELD (TM) EPOXY ADHESIVE DP-190-EG (PART B) Page 7 of 7 Total Pages multimedia.3m.com/ /mediawebserv 15/16

16 Reissue date/reason for reissue. Checked MSDS history. Intended Use of Product: Bonding various substrates. Transportable Pressure Receptacles Regulations 1996, as amended. Carriage of Dangerous Goods by Road regulations, 1996, as amended. The Petroleum (Consolidation) Act The Control of Substances Hazardous to Health Regulations 1999 as amended. The Special Waste Regulations 1996, as amended. The Environmental Protection Act, 1990 The Health and Safety at Work Act, The information on this Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. multimedia.3m.com/ /mediawebserv 16/16

Document id : Issue date : Version : 1.08 Supersedes date : Document status : : 1

Document id : Issue date : Version : 1.08 Supersedes date : Document status : : 1 Page 1 of 6 3M UK PLC 3M HOUSE, PO BOX 1, MARKET PLACE, BRACKNELL, BERKSHIRE RG12 1JU Tel: 01344 858000 ======================================================================== MATERIAL SAFETY DATA SHEET