Safety Data Sheet according to Regulation (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 15 Ceresit CM 77 Ultraflex SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Ceresit CM 77 Ultraflex 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Tile adhesive 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) ua-productsafety.de@henkel.com 1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases. Further information is available at Poison Control Centers Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Serious eye irritation Category 2 H319 Causes serious eye irritation Label elements Label elements (CLP): Hazard pictogram: Signal word: Hazard statement: Warning H319 Causes serious eye irritation.

2 Ceresit CM 77 Ultraflex Page 2 of 15 Supplemental information Contains N,N'-Ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide). May produce an allergic reaction. Precautionary statement: P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. P280 Wear protective gloves/eye protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Other hazards None if used properly. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Mixtures General chemical description: Tile adhesive Base substances of preparation: Auxiliary Reaction product of : Silane & Polyole Mineral fillers SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: Quartz (SiO2) "respirable particulates (reaches the alveoli)" (RCS) >=1% - <10% EC Number REACH-Reg No. content Classification < 10 % STOT RE 2 H < 5 % Acute Tox. 4; Oral H302 piperidyl) sebacate N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) < 5 % Flam. Liq. 3 H226 Acute Tox. 4; Inhalation H332 STOT RE 2; Inhalation H < 2,5 % Eye Dam. 1 H318 Aquatic Chronic 2 H411 Aquatic Acute 1 H400 0,1-1 % Skin Sens. 1B H317 Aquatic Chronic 4 H413 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures General information: In case of adverse health effects seek medical advice. SECTION 4: First aid measures

3 Ceresit CM 77 Ultraflex Page 3 of 15 Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remain (intensive smarting, sensitivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice Most important symptoms and effects, both acute and delayed Causes serious eye irritation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Danger of slipping on spilled product. Ensure adequate ventilation Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section Precautions for safe handling Ensure that workrooms are adequately ventilated. Avoid skin and eye contact. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage

4 Ceresit CM 77 Ultraflex Page 4 of Conditions for safe storage, including any incompatibilities Store in sealed original container. Keep container tightly sealed. Store in a cool, dry place. Storage at 0 to 25 C is recommended. Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Tile adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Germany Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit Regulatory list category / Remarks Titanium dioxide 1,25 limit(s): TRGS Titanium dioxide 10 limit(s): 2 TRGS Titanium dioxide Short Term Category II: substances with a TRGS Classification: resorptive effect. Methanol Time Weighted Average Indicative ECTLV [METHANOL] (TWA): Methanol Skin designation: Can be absorbed through the skin. TRGS 900 Methanol Methanol limit(s): 4 If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). Short Term Classification: Category II: substances with a resorptive effect. TRGS 900 TRGS 900

5 Ceresit CM 77 Ultraflex Page 5 of 15 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment period mg/l ppm mg/kg others aqua 0,36 mg/l (freshwater) aqua (marine 0,036 mg/l water) aqua 2,4 mg/l (intermittent releases) sewage treatment plant (STP) 6,6 mg/l sediment 1,3 mg/kg (freshwater) sediment 0,13 mg/kg (marine water) soil 0,055 mg/kg aqua 0,018 mg/l (freshwater) aqua (marine 0,0018 water) mg/l aqua 0,007 mg/l (intermittent releases) sediment 29 mg/kg (freshwater) sediment 2,9 mg/kg (marine water) soil 5,9 mg/kg sewage treatment plant (STP) Value 1 mg/l Remarks

6 Ceresit CM 77 Ultraflex Page 6 of 15 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers dermal Long term Workers Inhalation Long term General dermal Acute/short term General General General General Inhalation dermal Inhalation oral Acute/short term Long term Long term Long term Workers dermal Acute/short term Workers Inhalation Acute/short term Workers dermal Long term Workers Inhalation Acute/short term Workers Inhalation Long term General General General Inhalation dermal oral Long term Long term Long term Time Value 0,2 mg/kg 2,6 mg/m3 0,1 mg/kg 0,7 mg/m3 0,1 mg/kg 0,7 mg/m3 0,1 mg/kg 0,2 mg/kg 2,6 mg/m3 1,6 mg/kg 2,82 mg/m3 2,82 mg/m3 0,69 mg/m3 0,8 mg/kg 0,4 mg/kg Remarks Biological Indices: Ingredient [Regulated substance] Methanol Parameters Biological specimen Sampling Conc. Basis of biol. exposure index methanol Urine Sampling : End of 30 mg/l DE BGW shift at end of work week. Remark Additional Information 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Filter : AX (EN 14387) This recommendation should be matched to local conditions.

7 Ceresit CM 77 Ultraflex Page 7 of 15 Hand protection: In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. material thickness > 0.1 mm Perforation > 480 minutes In the case of longer and repeated contact please note that in practice the penetration s may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166. Skin protection: Suitable protective clothing Protective clothing should conform to EN for liquid splashes or to EN for dusts. Advices to personal protection equipment: The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions. Personal protective equipment should conform to the relevant EN standard. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste high viscosity white Odor characteristic Odour threshold ph Melting point Solidification temperature Initial boiling point Flash point Evaporation rate Flammability Explosive limits Vapour pressure Relative vapour density: Density (23 C (73.4 F)) Bulk density Solubility Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity (Brookfield; 40 C (104 F); Spindle No: F) Viscosity (kinematic) Explosive properties Oxidising properties 110,5 C (230.9 F); no method 1,55 g/cm3 Partially soluble mpa.s 9.2. Other information

8 Ceresit CM 77 Ultraflex Page 8 of Reactivity Reaction with acids: production of heat and carbon dioxide Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials See section reactivity Hazardous decomposition products Evolves methanol during cure. SECTION 10: Stability and reactivity Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Eye irritation: Causes serious eye irritation. Sensitizing: An allergic reaction cannot be excluded after repeated skin contact. Acute oral toxicity: N,N'-Ethane-1,2- diylbis(12- hydroxyoctadecan-1- amide) Value type Value Route of application Species Method LD oral rat not specified mg/kg LD mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) LD mg/kg oral rat OECD Guideline 423 (Acute Oral toxicity) LD50 > mg/kg oral Acute inhalative toxicity: Value type Value Route of application Species Method LC50 16,8 mg/l vapour 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity)

9 Ceresit CM 77 Ultraflex Page 9 of 15 Acute dermal toxicity: Value type Value Route of application Species Method LD50 > mg/kg dermal rabbit OECD Guideline 402 (Acute Dermal Toxicity) LD mg/kg dermal rabbit not specified LD50 > mg/kg dermal rat OECD Guideline 402 (Acute Dermal Toxicity) Skin corrosion/irritation: Result Species Method not irritating 24 h rabbit EPA OPPTS (Acute Dermal Irritation) not irritating rabbit other guideline: not irritating 24 h rabbit EPA OPP 81-5 (Acute Dermal Irritation) Serious eye damage/irritation: Result Species Method not irritating rabbit EU Method B.5 (Acute Toxicity: Eye Irritation / Corrosion) not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) corrosive 24 h rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: not sensitising not sensitising not sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) Guinea pig maximisat ion test Guinea pig maximisat ion test mouse guinea pig guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) OECD Guideline 406 (Skin Sensitisation)

10 Ceresit CM 77 Ultraflex Page 10 of 15 Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative negative negative positive negative Ames test) in vitro mammalian chromosome aberration test mammalian cell gene mutation assay bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberration test mammalian cell gene mutation assay Metabolic activation / Species Method with and without OECD Guideline 471 (Bacterial Reverse Mutation with and without with and without Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) with and without with and without OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) negative intraperitoneal mouse other guideline: negative negative negative bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberration test mammalian cell gene mutation assay with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) with and without OECD Guideline 473 (In vitro Mammalian Chromosome with and without Aberration Test) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test)

11 Ceresit CM 77 Ultraflex Page 11 of 15 Reproductive toxicity: Hazardous substances Result / Classification Species Species Method NOAEL P = >= mg/kg screening 4 w rat OECD Guideline 421 NOAEL F1 = >= mg/kg oral: gavage (Reproduction / Developmental Toxicity Screening Test) NOAEL P = 250 mg/kg NOAEL P = mg/kg NOAEL F1 = mg/kg onegeneration study oral: gavage onegeneration study oral: gavage onegeneration study oral: gavage rat rat rat OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) Repeated dose toxicity Result NOAEL=>= mg/kg NOAEL=< 62,5 mg/kg Route of application / Frequency of treatment Species Method oral: gavage 31 ddaily rat OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity in Rodents) oral: gavage daily rat OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) inhalation: 5 days/week for 14 rat vapour weeks6 hours/day LOAEL=29 mg/kg oral: feed 90 dcontinuously rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water.

12 Ceresit CM 77 Ultraflex Page 12 of Toxicity N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) Value type Value Acute Toxicity Study Species Method LC50 > 100 mg/l Fish 96 h Pimephales promelas not specified EC50 > 100 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 100 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) EC 50 > mg/l Bacteria 3 h OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test) LC50 4,4 mg/l Fish 96 h Lepomis macrochirus OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 8,58 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 0,705 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) EC10 0,188 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 > 100 mg/l Bacteria 3 h activated sludge, domestic OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test) NOEC 0,23 mg/l chronic Daphnia 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LL50 > 10 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EL50 > 10 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 100 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method

13 Ceresit CM 77 Ultraflex Page 13 of 15 N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) not readily biodegradable. aerobic 24 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) not readily biodegradable. aerobic 22 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) Bioaccumulative potential / Mobility in soil N,N'-Ethane-1,2-diylbis(12- hydroxyoctadecan-1-amide) LogPow Bioconcentration factor (BCF) Species Temperature Method 0,35 25 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 5,86 OECD Guideline 117 (Partition Coefficient (noctanol / water), HPLC Method) Results of PBT and vpvb assessment Quartz (SiO2) "respirable particulates (reaches the alveoli)" (RCS) >=1% - <10% N,N'-Ethane-1,2-diylbis(12-hydroxyoctadecan- 1-amide) PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code

14 Ceresit CM 77 Ultraflex Page 14 of 15 SECTION 14: Transport information UN number Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR UN proper shipping name Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Transport hazard class(es) Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Packing group Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Environmental hazards Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Special precautions for user Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Transport in bulk according to Annex II of Marpol and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 0,00 % (VOCV VOC regulation CH) Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Germany): WGK: 1, slightly water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method WGK: WGK = 1, slightly water endangering mixture. Classification according to the mixture rules in German AwSV regulation annex 1, number 5.2 from 18. April Storage class according to TRGS 510: 11

15 Ceresit CM 77 Ultraflex Page 15 of 15 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.