SAFETY DATA SHEET EPOXY COATING RESIN

Transcription

1 Easy Composites MSDS Epoxy Coating Resin Revision 5 Revision date 04 Sep 2014 Page 1 of 8 SAFETY DATA SHEET EPOXY COATING RESIN 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Coating Resin Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone HAZARDS IDENTIFICATION Classification (EC1272/2008) Eye Irrit. 2: H319; Skin Irrit. 2: H315; Skin Sens. 1: H317; Aquatic Chronic 2: H411; Classification (1999/45/EEC) Xi; R36/38 R43 N; R51/53 Symbols: Xi: Irritant. N: Dangerous for the environment. Main Hazards Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Label elements Signal Word Hazard Statements Precautionary Statements Danger H315 H317 H319 H411 P261 P264 P272 P273 P280 P302+P352 P P321 P332+P313 P333+P313 P337+P313 P363 P391 P501 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment If skin irritation occurs: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention Wash contaminated clothing before reuse. Collect spillage. Dispose of contents/container to Local Authority

2 Easy Composites MSDS Epoxy Coating Resin Revision 5 Revision date 04 Sep 2014 Page 2 of 8 according to official regulations. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Conc. CAS EINECS CAS Symbols/Risk phrases Bisphenol A (epichlorhydrin) (reaction product) % Xi; R36/38 R43 N; R51/53 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention. Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. 5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment Use as appropriate: Water spray, Dry chemical, Carbon dioxide (CO2), Fire will produce dense black smoke., Alcohol resistant foam. Do NOT use water jet. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Do not allow runoff water to enter sewers or drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 7. HANDLING AND STORAGE Handling Storage Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Do not eat, drink or smoke in areas where this product is used or stored. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Respiratory protection Hand protection Eye protection Protective equipment Ensure adequate ventilation of the working area. Do not breathe gas/fumes/vapour/spray. Wear: Suitable respiratory equipment. Wear Latex rubber gloves. Nitrile rubber gloves. Wash hands after handling the product. Approved safety goggles. Avoid contact with eyes. Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wear suitable protective equipment. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Colour Odour Liquid. Clear. Slight.

3 Relative density Viscosity mpa.s (25 C) 10. STABILITY AND REACTIVITY Easy Composites MSDS Epoxy Coating Resin Revision 5 Revision date 04 Sep 2014 Page 3 of 8 Stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomp. products Stable under normal conditions. Under normal conditions of storage and use, hazardous reactions will not occur. Will not decompose if stored and used as recommended. Avoid contact with: Amines. Keep away from heat. Avoid contact with: Oxidising agents, Acids, Bases, Amines. Will not decompose if stored and used as recommended. 11. TOXICOLOGICAL INFORMATION Toxicological information Bisphenol A (epichlorhydrin) (reaction product) Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Oral Rat LD50 = mg/kg Dermal Rabbit LD50 = > 2000 mg/kg Irritating to eyes, respiratory system and skin. Irritating to skin. Irritating to eyes. May cause sensitisation by skin contact. 12. ECOLOGICAL INFORMATION Ecotoxicity Bisphenol A (epichlorhydrin) (reaction product) Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Green Algae EC50/96h = 220mg/l Rainbow trout LD50/96h = mg/l 13. DISPOSAL CONSIDERATIONS General information Disposal methods Disposal of packaging Dispose of in compliance with all local and national regulations. Incinerate in suitable incineration plant, observing local authority regulations. Dispose of in compliance with all local and national regulations. Containers must be recycled in compliance with national legislation and environmental regulations. 14. TRANSPORT INFORMATION ADR/RID UN 3082 Packing group III Class 9 Hazard ID 90 IMDG Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. UN 3082 Packing group III

4 Easy Composites MSDS Epoxy Coating Resin Revision 5 Revision date 04 Sep 2014 Page 4 of 8 Class 9 Marine pollutant EmS Code F A S F IATA UN 3082 Packing group III Class 9 Subsidiary risk Packing Instruction (Cargo) 964 Maximum quantity 450L Packing Instruction (Passenger) 964 Maximum quantity 450L 15. REGULATORY INFORMATION Regulations WGK 2 Chemical safety assessment A Chemical Safety Assessment has not been carried out for this product. 16. OTHER INFORMATION Text of risk phrases in Section 3. Further information R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.

5 Easy Composites MSDS Epoxy Coating Resin Hardener Revision 6 Revision date 05 Sep 2014 Page 5 of 8 SAFETY DATA SHEET EPOXY COATING RESIN HARDENER 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Coating Resin Hardener Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone HAZARDS IDENTIFICATION Main hazards Symbols Harmful in contact with skin and if swallowed. Causes burns. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. Risk phrases Safety phrases R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Conc. CAS EINECS CAS Symbols/Risk phrases Benzyl alcohol 1 25% Xn; R20/22 Isophoronediamine 1 25% Xn; R21/22 C; R34 R43 R52/53 Tetraethylenepentamine 1 25% Xn; R21/22 C; R34 R43 N; R51/53 3,6 Diazaoctanethylenediamin 1 25% Xn; R21 C; R34 R43 R52/53 2,2' Iminodiethylamine (2,2' Iminodi(ethylamine)) 1 25% Xn; R21/22 C; R34 R43

6 Easy Composites MSDS Epoxy Coating Resin Hardener Revision 6 Revision date 05 Sep 2014 Page 6 of 8 4. FIRST AID MEASURES Skin contact Causes burns. Remove contaminated clothing. Wash off immediately with plenty of soap and water. Seek medical attention if irritation or symptoms persist. Eye contact Causes burns. Causes severe inflammation and may damage the cornea. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention. Inhalation Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Inhalation of vapour may cause shortness of breath. Remove the affected person from the source of contamination immediately. Seek medical attention if irritation or symptoms persist. Ingestion Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. Drink 1 to 2 glasses of water. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment Use as appropriate: carbon dioxide (CO2), dry chemical, foam. Corrosive. Burning produces irritating, toxic and obnoxious fumes. Wear self contained breathing apparatus and protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Do not flush into surface water. Do not let product contaminate subsoil. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 7. HANDLING AND STORAGE Handling Storage Ensure adequate ventilation of the working area. Avoid contact with eyes and skin. Adopt best Manual Handling considerations when handling, carrying and dispensing. Do not eat, drink or smoke in areas where this product is used or stored. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limit Values 2,2' Iminodiethylamine (2,2' Iminodi(ethylamine)) 3,6 WEL 8 hr limit ppm: 1 WEL 8 hr limit mg/m3: 4.3 WEL 15 min limit ppm: WEL 15 min limit mg/m3: WEL 8 hr limit ppm: WEL 8 hr limit mg/m3: 1 WEL 15 min limit ppm: WEL 15 min limit mg/m3: 5380 Diazaoctanethylenediamin Benzyl alcohol WEL 8 hr limit ppm: 10 WEL 8 hr limit mg/m3: 44 WEL 15 min limit ppm: WEL 15 min limit mg/m3: Engineering measures Respiratory protection Hand protection Eye protection Protective equipment Ensure adequate ventilation of the working area. Do not breathe gas/fumes/vapour/spray. Wear suitable respiratory equipment when necessary. Wear:. Nitrile rubber gloves. Wash hands after handling the product. Approved safety goggles. Avoid contact with eyes. Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wear suitable protective equipment. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Colour Liquid. Yellow.

7 Easy Composites MSDS Epoxy Coating Resin Hardener Revision 6 Revision date 05 Sep 2014 Page 7 of 8 Odour Ammoniacal. Relative density Viscosity 150 mpa.s (25 C) 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Incompatible materials Hazardous decomposition products Avoid contact with: Acids, Alkalis, Oxidising agents. Will not decompose if stored and used as recommended Avoid contact with: Acids, Alkalis, Oxidising agents. Contact with strong acids will produce an exothermic reaction. Reducing agents. Strong acids. Strong oxidising agents. Will not decompose if stored and used as recommended. Burning produces irritating, toxic and obnoxious fumes. Ammonia. Carbon oxides. Nitrogen oxides. 11. TOXICOLOGICAL INFORMATION Toxicological information 3,6 Diazaoctanethylenediamin Oral Rat LD50: 300 2,000 mg/kg Dermal Rabbit LD50: 1,000 2,000 mg/kg Benzyl alcohol Inhalation Rat LC50/4 h: > mg/l Oral Rat LD50: 1230 mg/kg Oral Mouse LD50: 1040 mg/kg Dermal Rabbit LD50: 2000 mg/kg Isophoronediamine Dermal Rat LD50: > 2000 mg/kg Oral Rat LD50: 1030 mg/kg Dermal Rabbit LD50: 1840 mg/kg Tetraethylenepentamine Oral Rat LD50: 2,000 5,000 mg/kg Dermal Rabbit LD50: 1,000 2,000 mg/kg Corrosivity Causes burns. 12. ECOLOGICAL INFORMATION Toxicity 3,6 Diazaoctanethylenediamin Benzyl alcohol Isophoronediamine Tetraethylenepentamine Daphnia EC50/48h: 31.1 mg/l Fish LC50/96h: mg/l Daphnia EC50/48h: mg/l Fish LC50/96h: 460 mg/l Algae EC50/72h: 770 mg/l Daphnia EC50/48h: 23 mg/l Fish LC50/96h: mg/l 13. DISPOSAL CONSIDERATIONS General information Disposal methods Disposal of packaging Dispose of in compliance with all local and national regulations. Incinerate in suitable incineration plant, observing local authority regulations. Containers must be recycled in compliance with national legislation and environmental regulations. Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. TRANSPORT INFORMATION Hazard pictograms ADR/RID UN 2735 Packing group III Class 8 Hazard ID 80

8 IMDG Proper Shipping Name Easy Composites MSDS Epoxy Coating Resin Hardener Revision 6 Revision date 05 Sep 2014 Page 8 of 8 AMINES, LIQUID, CORROSIVE, N.O.S. UN 2735 Packing group III Class 8 Marine pollutant EmS Code F A S B IATA UN 2735 Packing group III Maximum quantity 5L Packing Instruction 820 (Passenger) (Passenger) Maximum quantity 60L Class 8 (Cargo) Subsidiary Risk Packing Instruction (Cargo) REGULATORY INFORMATION Regulations WGK 2. Chemical safety A Chemical Safety Assessment has not been carried out for this product. assessment 16. OTHER INFORMATION Text of risk phrases in Section 3. Further information R20/22 Harmful by inhalation and if swallowed. R21/22 Harmful in contact with skin and if swallowed. R21 Harmful in contact with skin. R34 Causes burns. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.