Safety Data Sheet Wizard 31 Epoxy Ball Plug Hardener. 1. Identification

Transcription

1 1. Identification 1.1. Product identifier Product Identity Alternate Names Part Numbers: / , 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method See Technical Data Sheet. See Technical Data Sheet Details of the supplier of the safety data sheet Company Name Brunswick Bowling & Billiards 525 W. Laketon Ave. Emergency Muskegon, MI USA CHEMTREC (USA) (800) hour Emergency Telephone No. CHEMTEL Customer Service: Brunswick Bowling & Billiards Hazard(s) identification 2.1. Classification of the substance or mixture Acute Tox. 5;H313 May be harmful in contact with skin. (Not adopted by US OSHA) Skin Corr. 1;H314 Causes severe skin burns and eye damage. Eye Dam. 1;H318 Causes serious eye damage. Skin Sens. 1;H317 May cause an allergic skin reaction. Repr. 1B;H360Df May damage the unborn child. Suspected of damaging fertility. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects. Page 1 of 11

2 2.2. Label elements Danger H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H360Df May damage the unborn child. Suspected of damaging fertility. H412 Harmful to aquatic life with long lasting effects. [Prevention]: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. [Response]: P IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician. P IF ON SKIN: Wash with plenty of soap and water. P IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower. P IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P IF exposed or concerned: Get medical advice / attention. P310 Immediately call a POISON CENTER or doctor / physician. P321 Specific treatment (see information on this label). Page 2 of 11

3 P IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P If skin irritation or a rash occurs: Get medical advice / attention. P363 Wash contaminated clothing before reuse. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. 3. Composition/information on ingredients This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes 1,2-Ethanediamine, N-(2-aminoethyl)-, reaction products with glycidyl p-tolyl ether CAS Number: Polyoxypropylenediamine CAS Number: Not Provided [1] Skin Corr. 1;H314 [1] Triethylene tetramine CAS Number: Benzenedicarboxylic acid, dibutyl ester CAS Number: Acute Tox. 3;H311 Skin Corr. 1B;H314 Skin Sens. 1;H317 Aquatic Chronic 3;H Repr. 1B;H360Df Aquatic Acute 1;H400 [1] [1][2] In accordance with paragraph (i) of , the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vpvb-substance. *The full texts of the phrases are shown in Section 16. Section 4. First aid measures 4.1. Description of first aid measures General Inhalation In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious, place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Page 3 of 11

4 Eyes Skin Ingestion Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser. If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed Overview Eyes Skin No specific symptom data. Treat symptomatically. See section 2 for further details. Causes serious eye damage. May be harmful in contact with skin. May cause an allergic skin reaction. Causes severe skin burns and eye damage. Section 5. Fire-fighting measures 5.1. Extinguishing media Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Dry sand. Limestone powder. Do Not use water directly on fire. Use water spray to cool down fire-exposed containers. Water spray may cause frothing Special hazards arising from the substance or mixture Hazardous decomposition: Incomplete combustion may form carbon monoxide. May generate ammonia Avoid breathing dust / fume / gas / mist / vapors / spray Advice for fire-fighters None ERG Guide No. 153 Section 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8) Environmental precautions Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Page 4 of 11

5 6.3. Methods and material for containment and cleaning up SMALL SPILL: Remove spillage by absorbing in absorbent material. LARGE SPILL: If possible, stop flow of product. Construct dike to prevent spreading. Place in appropriate chemical waste container and dispose of in accordance with all local, state and federal regulations. Section 7. Handling and storage 7.1. Precautions for safe handling Handle containers carefully to prevent damage and spillage. Do not use sodium nitrite or other nitrosating agents. Suspected cancer causing nitrosamines could be formed. Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Avoid breathing vapors and/or aerosols. Avoid contact with eyes. Use only in well-ventilated areas. Use personal protective equipment. When using, do not eat, drink or smoke. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. STORAGE TEMPERATURE: 16 C (60 F) Minimum to 27 C (80 F) Maximum Incompatible materials: Mineral or organic acids, oxidizing agents, aldehydes, ketones and organic halides. See section 2 for further details. - [Storage]: 7.3. Specific end use(s). Section 8. Exposure controls and personal protection 8.1. Control parameters Exposure CAS No. Ingredient Source Value Benzenedicarboxylic acid, dibutyl ester OSHA ACGIH NIOSH Supplier TWA 5 mg/m3 TWA: 5 mg/m3 TWA 5 mg/m Triethylene tetramine OSHA ACGIH NIOSH Supplier AIHA WEEL 8 h TWA 1ppm Page 5 of 11

6 Polyoxypropylenediamine OSHA ,2-Ethanediamine, N-(2- aminoethyl)-, reaction products with glycidyl p-tolyl ether ACGIH NIOSH Supplier OSHA ACGIH NIOSH Supplier 8.2. Exposure controls Respiratory Eyes Skin Engineering Controls Other Work Practices See section 2 for further details. If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. Wear safety glasses with side shields to protect the eyes. An eye wash station is suggested as a good workplace practice. Wear PVC or rubber gloves to keep skin contact to a minimum. Refer to the manufacturer's recommendations regarding the suitability of any gloves used. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Section 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odor Odor threshold ph Melting point / freezing point Amber Medium Viscosity Liquid Amine odor Not determined Alkaline Not Applicable Initial boiling point and boiling range 277 C Flash Point 118 C PMCC Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive limits Lower Explosive Limit: Not Measured Upper Explosive Limit: Not Measured Page 6 of 11

7 Vapor pressure (Pa) < 13 mmhg at 21 C (70 F) Vapor Density < 13 Specific Gravity Not Measured Solubility in Water Not Measured Partition coefficient n-octanol/water (Log Kow) Not Measured Auto-ignition temperature 294 C Decomposition temperature Not Applicable Viscosity (cst) Not Applicable VOC Content Other information No other relevant information. Section 10. Stability and reactivity Reactivity Hazardous Polymerization will not occur Chemical stability Stable under normal circumstances Possibility of hazardous reactions Conditions to avoid Incompatible materials Mineral or organic acids, oxidizing agents, aldehydes, ketones and organic halides Hazardous decomposition products Incomplete combustion may form carbon monoxide. May generate ammonia Section 11. Toxicological information Acute toxicity Note: When no route specific LD50 data is for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor LC50, mg/l/4hr Inhalation Dust/Mist LC50, mg/l/4hr Inhalation Gas LC50, ppm 1,2-Ethanediamine, N-(2-aminoethyl)-, reaction products with glycidyl p-tolyl ether - ( ) Page 7 of 11

8 Polyoxypropylenediamine - ( ) Triethylene tetramine - ( ) Benzenedicarboxylic acid, dibutyl ester - ( ) Carcinogen Data 2,885.00, Rat - Category: 5 2,780.00, Rat - Category: 5 8,000.00, Rat - Category: NA 2,980.00, Rabbit - Category: , Rabbit - Category: 3 20,860.00, Rabbit - Category: NA CAS No. Ingredient Source Value Benzenedicarboxylic acid, dibutyl ester OSHA NTP IARC Regulated Carcinogen: No Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Triethylene tetramine OSHA Regulated Carcinogen: No NTP IARC Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Polyoxypropylenediamine OSHA Regulated Carcinogen: No ,2-Ethanediamine, N-(2- aminoethyl)-, reaction products with glycidyl p-tolyl ether NTP IARC OSHA NTP IARC Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Regulated Carcinogen: No Known: No; Suspected: No Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Classification Category Hazard Description Acute toxicity (oral) --- Not Applicable Acute toxicity (dermal) 5 May be harmful in contact with skin. (Not adopted by US OSHA) Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation 1 Causes severe skin burns and eye damage. Serious eye damage/irritation 1 Causes serious eye damage. Respiratory sensitization --- Not Applicable Skin sensitization 1 May cause an allergic skin reaction. Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity 1B May damage the unborn child. Suspected of damaging fertility. Page 8 of 11

9 STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable Section 12. Ecological information Toxicity Harmful to aquatic life with long lasting effects. Toxic to aquatic life Aquatic Ecotoxicity Ingredient 1,2-Ethanediamine, N-(2-aminoethyl)-, reaction products with glycidyl p-tolyl ether - ( ) Polyoxypropylenediamine - ( ) Triethylene tetramine - ( ) Benzenedicarboxylic acid, dibutyl ester - ( ) 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l Not Available Not Available Not Available 15.00, Oncorhynchus mykiss , Pimephales promelas 0.48, Lepomis macrochirus 80.00, Daphnia magna 33.90, Daphnia magna 2.10 (72 hr), Pseudokirchneriella subcapitata (72 hr), Selenastrum capricornutum 2.99, Daphnia magna 0.21 (96 hr), Scenedesmus acutus Persistence and degradability There is no data on the preparation itself Bioaccumulative potential Not Measured Mobility in soil Results of PBT and vpvb assessment This product contains no PBT/vPvB chemicals Other adverse effects. Section 13. Disposal considerations Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. Page 9 of 11

10 Section 14. Transport information UN number UN proper shipping name Transport hazard class(es) Packing group DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) ICAO/IATA UN2735 UN2735 UN2735 UN2735, Amines, liquid, corrosive, n.o.s, (Triethylene Tetramine, Epoxy-polyamine Adduct, Polyetheramine), 8, II Amines, liquid, corrosive, n.o.s (Triethylene Tetramine, Epoxypolyamine Adduct, Polyetheramine) DOT Hazard Class: 8 IMDG: 8 Sub Class: 9 II II II Environmental hazards IMDG Marine Pollutant: No; Special precautions for user No further information Amines, liquid, corrosive, n.o.s, (Triethylene Tetramine, Epoxypolyamine Adduct, Polyetheramine) Air Class: 8 Section 15. Regulatory information Regulatory Overview Toxic Substance Control Act ( TSCA) WHMIS 1988 Classification US EPA Tier II Hazards The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All components of this material are either listed or exempt from listing on the TSCA Inventory. D2A E Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Page 10 of 11

11 EPCRA 313 Toxic Chemicals: Benzenedicarboxylic acid, dibutyl ester Proposition 65 - Carcinogens (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Developmental Toxins (>0.0%): Benzenedicarboxylic acid, dibutyl ester Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): Benzenedicarboxylic acid, dibutyl ester Section 16. Other information SDS Revision Date 12/19/2017 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H360Df May damage the unborn child. Suspected of damaging fertility. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects. The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material in any process, unless specified in the text. End of Document Page 11 of 11