Safety Data Sheet according to Regulation (EC) No. 453/2010
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- Timothy Jeffry Parsons
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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : RAPICIDE OPA/28 Product code : ML /ML Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : High-level disinfectant for professional medical use Uses advised against 1.3. Details of the supplier of the safety data sheet MEDIVATORS BV Sourethweg 11 Heerlen, 6422PC - Netherlands T (31) ; (UK) - F (31) info@medivatorsbv.com 1.4. Emergency telephone number Emergency number : CHEMTREC (800) CHEMTREC International +1 (703) hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1 Eye Irrit. 2 H319 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified. Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS07 Signal word (CLP) : Warning Hazard statements (CLP) : H319 - Causes serious eye irritation. Precautionary statements (CLP) : P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. EUH phrases : EUH208 - Contains ortho-phthalaldehyde. May produce an allergic reaction. Unknown hazards to the aquatic environment (CLP) : Contains 3 % of components with unknown hazards to the aquatic environment Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture EN Rev B Page 1 of 6
2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 1,2-Propylene glycol substance with national workplace exposure limit(s) (GB) (CAS No) (EC no) Alcohols, C9-11, ethoxylated (CAS No) (EC no) ortho-phthalaldehyde (CAS No) (EC no) Not classified. 2.1 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 Skin Sens. 1, H317 Aquatic Acute 1, H400 Name Product identifier % Classification according to Directive 67/548/EEC 1,2-Propylene glycol substance with national workplace exposure limit(s) (GB) (CAS No) (EC no) Alcohols, C9-11, ethoxylated (CAS No) (EC no) ortho-phthalaldehyde (CAS No) (EC no) Full text of R- and H-phrases: see section Not classified. 2.1 Xn; R22 Xi; R T; R25 C; R34 R43 N; R50 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May produce an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : None known Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel Environmental precautions 6.3. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container EN Rev B Page 2 of 6
3 6.4. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters United Kingdom WEL TWA (mg/m³) 474 mg/m³ (total particulates and vapour) 10 mg/m³ (particulates) United Kingdom WEL TWA (ppm) 150 ppm (total particulates and vapour) United Kingdom WEL STEL (mg/m³) 1422 mg/m³ (calculated-total particulate and vapour) 30 mg/m³ (calculated-particulate) United Kingdom WEL STEL (ppm) 450 ppm (calculated-total particulate and vapour) 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls Other information : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. : Wear chemically resistant protective gloves. : Wear eye protection. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Maintain levels below Community environmental protection thresholds. : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Colour : Colourless Odour : Mild but distinctive Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : > 100 C (> 212 F) Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Not flammable Vapour pressure Relative vapour density at 20 C Relative density : Solubility Log Pow Viscosity, kinematic Viscosity, dynamic EN Rev B Page 3 of 6
4 Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity No dangerous reaction known under conditions of normal use Chemical stability Stable under normal storage conditions Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Heat Incompatible materials None known Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified. RAPICIDE OPA/28 LD50 dermal rabbit LC50 inhalation rat LD50 dermal rabbit Alcohols, C9-11, ethoxylated ( ) LD50 dermal rabbit ortho-phthalaldehyde ( ) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) > 2000 mg/kg > 2000 mg/kg > 20 mg/l/4h mg/kg mg/kg 1378 mg/kg >2 g/kg 120 mg/kg : Causes serious eye irritation. : Contains ortho-phthalaldehyde. May produce an allergic reaction. Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 : May cause long-term adverse effects in the aquatic environment mg/l (96 h - Oncorhynchus mykiss [static]) > 1000 mg/l (48 h - Daphnia magna [Static]) ml/l (96 h - Oncorhynchus mykiss [static]) EN Rev B Page 4 of 6
5 12.2. Persistence and degradability RAPICIDE OPA/28 Persistence and degradability Not established Bioaccumulative potential RAPICIDE OPA/28 Bioaccumulative potential BCF fish 1 < Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR UN number Not regulated for transport UN proper shipping name Transport hazard class(es) Packing group Not established. : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible Environmental hazards Dangerous for the environment Marine pollutant Other information Special precautions for user Special transport precautions : No. : No. : No supplementary information available. : Do not handle until all safety precautions have been read and understood Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions. Contains no REACH candidate substance National regulations Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Indication of changes: None. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: EN Rev B Page 5 of 6
6 Classification Eye Irrit. 2 EUH208 Classification Procedure Concentration limits Concentration limits Other information : None. Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Sensitisation Skin, category 1 H301 H302 H314 H317 H318 H319 H400 R22 R25 R34 R41 R43 R50 C N T Xi Xn Toxic if swallowed Harmful if swallowed Causes severe skin burns and eye damage May cause an allergic skin reaction Causes serious eye damage Causes serious eye irritation Very toxic to aquatic life Harmful if swallowed Toxic if swallowed Causes burns Risk of serious damage to eyes May cause sensitisation by skin contact Very toxic to aquatic organisms Corrosive Dangerous for the environment Toxic Irritant Harmful Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use EN Rev B Page 6 of 6
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