: TheraCal LC. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification
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1 Date of issue: 01/29/2016 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : TheraCal LC Product group : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc W Irving Park Road, Schaumburg, IL USA , during normal business hours EC Representative: Bisico France, 120, allée de la Coudoulette, Lançon de Provence, France Telephone: Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Sensitisation Skin, category 1 : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted H315 H319 H317 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning : Polyethylene Glycol Dimethacrylate ; Portland cement; Barium Zirconate Powder : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation : P261 - Avoid breathing mist, vapours P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of water P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 01/29/2016 EN (English) 1/7
2 P312 - Call a POISON CENTER/doctor if you feel unwell P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Portland cement (CAS No) (EC no) Xi; R41 Xi; R37/38 R43 Polyethylene Glycol Dimethacrylate (CAS No) Xi; R36/38 Barium Zirconate Powder (CAS No) (EC no) (EC index no) Xn; R20/22 Xi; R36/37/38 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Portland cement (CAS No) (EC no) Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT SE 3, H335 Polyethylene Glycol Dimethacrylate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1A, H317 Barium Zirconate Powder (CAS No) (EC no) (EC index no) Full text of R- and H-statements: see section Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. : Rinse cautiously with water for several minutes. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes eye irritation. Causes serious eye irritation Indication of any immediate medical attention and special treatment needed 01/29/2016 EN (English) 2/7
3 SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Avoid breathing mist, vapours. Use only outdoors or in a well-ventilated area. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures Storage conditions 7.3. Specific end use(s) : Comply with applicable regulations. : Keep container tightly closed. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Belgium Limit value (mg/m³) 10 mg/m³ (Ciment portland; Belgium; Time-weighted average exposure limit 8 h) United Kingdom WEL TWA (mg/m³) 10 mg/m³ Portland cement inhalable dust; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005); Portland cement respirable dust; 4 mg/m³; United Kingdom; Time-weighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) USA - ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (Portland cement; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Respirable fraction. The value is for particulate matter containing no asbestos and < 1% crystalline silica) 8.2. Exposure controls Eye protection Skin and body protection : Chemical goggles or face shield : Wear suitable protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste. 01/29/2016 EN (English) 3/7
4 Colour Odour Odour threshold : Grey. : acrylic. ph : 10 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 75 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Barium Zirconate Powder ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LC50 inhalation rat (Vapours - mg/l/4h) Skin corrosion/irritation Additional information Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity 1980 mg/kg N/A N/A N/A mg/l/4h N/A mg/l/4h : Causes skin irritation. ph: 10 : Causes skin irritation : Causes serious eye irritation. ph: 10 : May cause an allergic skin reaction. 01/29/2016 EN (English) 4/7
5 Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Additional information Barium Zirconate Powder ( ) LOAEL (oral, rat) Specific target organ toxicity (repeated exposure) Barium Zirconate Powder ( ) LOAEL (oral, rat, 90 days) Aspiration hazard : May cause respiratory irritation. : May cause respiratory irritation N/A mg/kg bodyweight N/A mg/kg bodyweight/day SECTION 12: Ecological information Toxicity LC50 fish 1 > 1000 mg/l (LC50; 96 h) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Bioaccumulative potential Bioaccumulative potential Mobility in soil Biodegradability: not applicable. No (test)data on mobility of the substance available. Bioaccumulation: not applicable Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) 01/29/2016 EN (English) 5/7
6 IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Portland cement is listed : Portland cement is listed 01/29/2016 EN (English) 6/7
7 NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks Recommendations Danish Regulation : None of the components are listed : None of the components are listed : None of the components are listed : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-statements: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 Skin Sens. 1A Sensitisation Skin, category 1A STOT SE 3 H302 H315 H317 H319 H332 H335 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Harmful if swallowed Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Harmful if inhaled May cause respiratory irritation SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/29/2016 EN (English) 7/7
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