MATERIAL SAFETY DATA SHEET Date: April 5, 2000

Transcription

1 CLEANER II PART A Page 1 of 5 MATERIAL SAFETY DATA SHEET Date: April 5, PRODUCT AND Trade Name: CLEANER II Part A COMPANY Chemical Name: Mixture, see below. IDENTIFICATION SUPPLIER: ILFORD IMAGING USA INC W. 70 Century Road Paramus, NJ MEDICAL EMERGENCIES (24 HRS): (800) (Product Misuse) TRANSPORTATION EMERGENCY: CALL CHEMTREC (800) GENERAL INFORMATION (24 HRS): COMPOSITION/INFORMATION ON INGREDIENTS Component CAS Number % By Weight OSHA 8-HR PEL ppm (1989) mg/m 3 ACGIH TLV ppm mg/m 3 Ferric Ammonium EDTA Water NE = Not Established 3. HAZARDS IDENTIFICATION CAUTION! MAY CAUSE EYE AND SKIN IRRITATION. May cause an allergic skin reaction. Harmful if swallowed. Do not get in eyes. Avoid prolonged skin contact. HAZARD RATINGS Degree of hazard (0 = low, 4 = extreme) National Fire Protection Association Health: 3 Flammability: 0 Reactivity: 1 Specific Hazard: N/A Hazardous Materials Information System Health: 3 Flammability: 0 Reactivity: 1 Protective Equipment: Must be determined by end user according to local conditions of use. NOTE: NFPA and HMIS ratings are intended to permit speedy general identification of the extent of particular hazards. These hazard ratings involve interpretations of data which may vary between companies. All of the information contained in this MSDS must be considered in order to correctly address the safe handling of this product.

2 CLEANER II PART A Page 2 of 5 4. FIRST AID MEASURES EYE CONTACT: SKIN CONTACT: INHALATION: SWALLOWING: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Consult a physician immediately. Wash the contaminated skin with soap and water. If clothing becomes contaminated, remove immediately and launder before reuse. If irritation or pain develops, get medical attention. If eye, nose or throat irritation from vapors develops, move to fresh air until symptoms disappear. If breathing is difficult, administer oxygen and call a physician. Ensure adequate ventilation to prevent vapors from accumulating before returning to work. Contact a physician immediately. Administer one or two glasses of water, but DO NOT give anything by mouth if person is having convulsions or is unconscious. DO NOT induce vomiting. 5. FIRE FIGHTING Flash Point: NF Lower Explosive Limit: NF Upper Explosive Limit: NF MEASURES Test Method: NF Autoignition Temp: NF ND = No data. NF = Non Flammable EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: Water mist, alcohol foam, CO 2 dry chemical. Use extinguishing media appropriate for surrounding materials. Cool containers with water spray. Use protective clothing, and always use self-contained breathing apparatus when fighting fires. Fire and heat will cause product to release ammonia. 6. ACCIDENTAL RELEASE Contain spill, MEASURES then absorb with inert materials. Use protective equipment to prevent skin and eye exposure during cleanup (see Section 8). 7. HANDLING/STORAGE Protect from temperature extremes. Store and ship above 40F (5C) and below 100F (40C). Optimum storage temperature: 68F (20C). 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION EYE PROTECTION: SKIN PROTECTION: VENTILATION: Wear chemical splash goggles if any potential for splashing or generation of mists or spray exists. Have emergency eye wash equipment nearby. Wear protective covering (chemical apron) and chemical resistant gloves to prevent skin contact. Wash hands immediately if skin contact occurs. If clothing is contaminated with product, remove immediately and launder before reuse. Mechanical ventilation should be used to control airborne contaminant levels. Accepted practice is to provide general ventilation at the rate of at least air changes per hour. Work environment and ventilation rates should be matched.

3 CLEANER II PART A Page 3 of 5 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION (CONT'D) RESPIRATORY PROTECTION No additional respiratory protection should be needed if sufficient ventilation is provided. If there is a possibility that the airborne concentration may exceed allowable limits, a respirator equipped with OSHA/MSHA approved multi gas (acid gas/organic vapor, ammonia) cartridges should be worn. Consult respirator manufacturer for respirator limitations. If respirators are worn, comply with the OSHA requirements in 29 CFR for a respirator protection program. 9. PHYSICAL AND Boiling Point: >100C Vapor Density: N/A CHEMICAL PROPERTIES % Volatile by Weight: N/A ph: 7.10 Vapor Pressure (mm Hg): N/A Solubility in Water (20C): Complete Grams VOC/L: Not applicable Evaporation Rate: Less than water Product Density: g/l Appearance: Dark brown liquid Odor: Bland 10. STABILITY/REACTIVITY Stability: Stable under normal conditions. CONDITIONS TO AVOID: Do not freeze (see Section 7). INCOMPATIBLE MATERIALS: Avoid contact with metals. HAZARDOUS DECOMPOSITION PRODUCTS: POLYMERIZATION: Fire and heating will release ammonia. Hazardous polymerization will not occur. 11. TOXICOLOGICAL This product has not been tested for health effects. Effects reported INFORMATION below are based on the components of this product. Under conditions of typical use, this product does not present a serious hazard. POTENTIAL ROUTES OF EXPOSURE: SIGNS, SYMPTOMS, AND TOXIC EFFECTS OF OVEREXPOSURE: Skin and eyes are the most likely routes of exposure. Significant inhalation exposure to this product is unlikely unless mist or spray is generated, or if product is heated. DO NOT INGEST THIS PRODUCT! CAUTION! This product may cause eye and skin irritation on contact. Skin contact may result in an allergic reaction in sensitive individuals, with pain, redness, and itching of skin. Inhalation exposure to vapor, mists, or spray may cause respiratory tract irritation. If this product is ingested, irritation of the gastrointestinal tract with pain and nausea may occur; an allergic reaction may also occur. Chronic skin exposure to this product may result in dermatitis or development of an allergic dermatitis. Other effects of chronic exposure to the mixture of chemicals in this product are not known. ANIMAL TOXICITY DATA: Component Inhalation LC 50 Dermal LD 50 Oral LD 50 Ferric Ammonia EDTA No data found. No data found. rat, 2,200 mg/kg

4 CLEANER II PART A Page 4 of TOXICOLOGICAL INFORMATION (CONT'D) REPRODUCTIVE EFFECTS: MUTAGENICITY DATA: There are no data on reproductive effects of the chemicals in this product in human populations. There are no data on mutagenicity effects of the chemicals in this product in human populations. DESIGNATION AS POTENTIAL CARCINOGEN: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None of the components of this product are considered to be potential carcinogens by IARC, NTP, or OSHA. Preexisting skin or respiratory conditions may be aggravated by exposure to this product. Persons with existing allergies (especially to sulfites) may be sensitive to this product. INTERACTIONS WITH CHEMICALS THAT ENHANCE TOXICITY: No relevant data found. 12. ECOLOGICAL This chemical mixture has not been tested for environmental effects. INFORMATION Do not dispose of in waterways. 13. DISPOSAL Product should be disposed of in accordance with federal (40 CFR part 261), CONSIDERATIONS state and local regulations. Before attempting cleanup, refer to hazard information and protection measures (chemical gloves, etc.). 14. TRANSPORT INFORMATION PACKAGING DESCRIPTION: U.S.D.O.T. PROPER SHIPPING NAME (HM181 PART ): Fiberboard carton containing: 3-1 quart HD Polyethylene plastic screw cap bottles containing Parts A,B&C, Part C is corrosive. Corrosive liquid NOS UN1760 (Phosphoric Acid) UN IDENTIFICATION NO.: UN 1760 HAZARD CLASS: PACKING GROUP: MARINE POLLUTANT DESIGNATION: IATA CLASS: DOMESTIC AIR CLASS: LABEL REQUIRED: SHIPPING RESTRICTIONS: 8 Corrosive III None of the components of this product are designated as marine pollutants by D.O.T. Corrosive liquid NOS UN1760 (Phosphoric acid) Cl8, PKG GPIII Corrosive liquid NOS UN1760 (Phosphoric acid) Cl8, PKG GPIII Corrosive Cargo aircraft only

5 CLEANER II PART A Page 5 of REGULATORY INFORMATION SARA 313 LISTING: SARA 312 HAZARD CLASS: None of the components of this product are listed under Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. None of the components of this product are listed as an "immediate health hazard" under 40 CFR SARA EXTREMELY HAZARDOUS SUBSTANCES: None of the components of this product are listed under 40 CFR 355. CA PROPOSITION 65: None of the components of this product are listed under CA Prop. 65 PENN. RIGHT-TO-KNOW: N.J. RIGHT-TO-KNOW: TSCA INVENTORY STATUS: All required components of this product are identified. All required components of this product are identified. All components of this product are listed on the TSCA inventory. 16. OTHER INFORMATION MANUFACTURER'S STATEMENT: ILFORD IMAGING USA INC BELIEVES THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON CORRECT AND FACTUAL DATA. HOWEVER, NO EXPRESS OR IMPLIED GUARANTEE OR WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THIS INFORMATION. USE THIS INFORMATION ONLY TO SUPPLEMENT OTHER INFORMATION YOU HAVE GATHERED AND THEN MAKE AN INDEPENDENT DETERMINATION ABOUT THE COMPLETENESS AND SUITABILITY OF ALL INFORMATION TO INSURE PROTECTION OF THE ENVIRONMENT, THE PROPER USE AND DISPOSAL OF THIS PRODUCT AND THE HEALTH AND SAFETY OF EMPLOYEES AND CUSTOMERS. REVISIONS: (1) 04/04/00 PREPARED BY: Bryan Sammartino Date: 04/04/00