: 805 BIG GAP FILLER PU FOAM

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Trade name : Mixture Product code : 805 : 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet AKKİM YAPI KİMYASALLARI SANAYİ ve TİCARET A.Ş. 22 Yeşilbayır mahallesi Şimşir sokak No:22 İSTANBUL, TURKEY T F info@akfix.com Emergency telephone number For Hazardous Materials [or Dangerous Goods] Incident Spill, Leak, Fire, Exposure, or Accident Call CHEMTREC Day or Night SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable aerosol Category 1 Acute toxicity (inhalation:gas) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Respiratory sensitisation Category 1 Skin sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 H222 H332 H315 H319 H334 H317 H351 H335 H373 Full text of H statements : see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS02 GHS07 GHS08 : H222 - Extremely flammable aerosol H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing gas, spray, vapors 04/21/2016 EN (English US) Page 1

2 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substance 3.2. Mixture P280 - Wear eye protection, face protection, protective clothing, protective gloves P284 - [In case of inadequate ventilation] wear respiratory protection P302+P352 - If on skin: Wash with plenty of water P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - If exposed or concerned: Get medical advice/attention P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation Name Product identifier % GHS-US classification Isocyanic acid, polymethylenepolyphenylene ester (CAS No) Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 isobutane (CAS No) Flam. Gas 1, H220 propane (CAS No) Flam. Gas 1, H220 dimethyl ether (CAS No) Flam. Gas 1, H220 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : IF exposed or concerned: Get medical advice/attention. Call a poison center/doctor/physician if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. : Irritation. May cause an allergic skin reaction. : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity : Extremely flammable aerosol. : Pressurized container: may burst if heated. : Extremely flammable aerosol. Pressurized container: may burst if heated. 04/21/2016 EN (English US) 2/7

3 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. No open flames, no sparks, and no smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters Isocyanic acid, polymethylenepolyphenylene ester ( ) isobutane ( ) dimethyl ether ( ) propane ( ) : Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection : Ensure good ventilation of the work station. : Protective gloves. : Safety glasses. : Wear suitable protective clothing. : Wear respiratory protection. 04/21/2016 EN (English US) 3/7

4 Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid under pressure. Color : Light yellow Odor : Characteristic Odor threshold ph Melting point Freezing point Boiling point Flash point : 0 C Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties : Pressurized container: may burst if heated. Oxidizing properties Vapor pressure : 5 bar Relative density Relative vapor density at 20 C Specific gravity / density : kg/m³ Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information VOC content : < 2 g/l SECTION 10: Stability and reactivity Reactivity Extremely flammable aerosol. Pressurized container: may burst if heated Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Inhalation:gas: Harmful if inhaled. 04/21/2016 EN (English US) 4/7

5 ATE US (gases) ppmv/4h Isocyanic acid, polymethylenepolyphenylene ester ( ) ATE US (gases) ppmv/4h ATE US (vapors) mg/l/4h ATE US (dust, mist) mg/l/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity : Causes skin irritation. : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Not classified : Suspected of causing cancer. Reproductive toxicity Specific target organ toxicity (single exposure) : Not classified : May cause respiratory irritation. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information Toxicity Ecology - general : Not classified : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. : Irritation. May cause an allergic skin reaction. : Eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1950 Aerosols (flammable, (each not exceeding 1 L capacity)), /21/2016 EN (English US) 5/7

6 UN-No.(DOT) Proper Shipping Name (DOT) : UN1950 : Aerosols flammable, (each not exceeding 1 L capacity) Class (DOT) : Class Flammable gas 49 CFR Hazard labels (DOT) : Flammable gas DOT Packaging Non Bulk (49 CFR 173.xxx) DOT Packaging Bulk (49 CFR 173.xxx) DOT Special Provisions (49 CFR ) : None : None DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Quantity Limitations Passenger aircraft/rail (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 CFR ) DOT Vessel Stowage Location DOT Vessel Stowage Other : N82 - See of this subchapter for classification criteria for flammable aerosols : 75 kg : 150 kg Emergency Response Guide (ERG) Number : 126 : A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel : 25 - Shade from radiant heat,87 - Stow separated from Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials Other information : No supplementary information available. TDG Transport by sea UN-No. (IMDG) : 1950 Proper Shipping Name (IMDG) : AEROSOLS Class (IMDG) : 2 - Gases MFAG-No : 126 Air transport UN-No. (IATA) : 1950 Proper Shipping Name (IATA) : Aerosols, flammable Class (IATA) : 2 SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations National regulations US State regulations 04/21/2016 EN (English US) 6/7

7 SECTION 16: Other information Full text of H-phrases: H220 Extremely flammable gas H222 Extremely flammable aerosol H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure SDS US AKFIX This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 04/21/2016 EN (English US) 7/7