1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 according to 1907/2006/EC, Article 31, amended by Regulation (EU) No. 453/2010 FRAGONIA OIL Date: 17/10/ Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Trade Name: Fragonia Oil INCI: Agonis Fragrans Leaf/Branch Oil Biological Definition: Agonis Fragrans Branch/Leaf Oil is the volatile oil obtained by steam distillation from the branches and leaves of Agonis fragrans, Myrtaceae. Reach Registration Number (According to EU Reg 1907/2006): - FEMA No.: - FDA No.: - CoE No.: - CAS No.: - EC No.: - EINECS No.: Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Aromantic Ltd 17 Tytler Street Forres Moray IV36 1EL Tel: Fax: info@aromantic.co.uk 1.4 Emergency telephone number Health and Safety Executive (HSE) Chemicals Regulation Directorate 5S.1 Redgrave Court, Merton Road, Bootle, Merseyside. L20 7HS Telephone: biocidesenquiries@hse.gsi.gov.uk REACH and CLP UK CA Help Desk, Health and Safety Executive 1

2 2.3 Redgrave Court, Merton Road, L20 7HS Bootle, Merseyside 2. Hazards Identification 2.1 Classification of the substance or mixture Classification (1999/45): The full text for all Hazard statements are displayed in Section 16. Classification (EC 1272/2008): Physical and Chemical Hazards: Flammable Liquid Category 3. Human Health: Aspirational. Tox. 1 Skin Irritation Category 2 Skin Sensitizer Category 1A Eye Irritation Category 2A Environment: Aquatic Chronic Label elements Label in accordance with (EC) No 1272/2008: GHS02 GHS08 GHS07 GHS Other hazards Signal Word: Danger. Contains: α-pinene, β-pinene, Limonene, para-cymene, Myrcene, Geraniol. Hazard Statements: H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary Statements: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331: Do NOT induce vomiting. P501: Dispose of contents in accordance with local, state or national legislation. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing. And wash it before reuse. P302+P352: IF ON SKIN: Wash with plenty of water. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P273: Avoid release to the environment. P391: Collect spillage. Supplementary Precautionary Statements: 2

3 P233: Keep container tightly closed. P264: Wash hands and exposed skin thoroughly after handling. P332+P313: If skin irritation occurs: Get medical advice/attention. P272: Contaminated work clothing should not be allowed out of the workplace. PBT or vpvb according to Annex XIII: Adverse physio-chemical properties: Adverse effects on human health: 3. Composition/Information on ingredients 3.1 Substances 3.2 Mixtures 1,8 Cineole % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 H226, Skin Sens. 1 H317 alpha-pinene % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 H304, Skin Irrit. 2 - H315, Skin Sens. 1A - H317, Aquatic Acute 1 - H400, Aquatic Chronic 1 H410 Linalool % CAS No : EC No : Classification (EC 1272/2008) H315 Skin Irrit. 2 - H315, Eye Irrit. 2 H319 alpha-terpineol % CAS No: EC No: Classification (EC 1272/2008) H315 Skin Irrit. 2 - H315, Eye Irrit. 2 H319 Limonene % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 - H226, Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Asp. Tox. 1 - H304 Aquatic Acute 1 - H400, Aquatic Chronic 1 - H410 para-cymene % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 H226, Asp. Tox. 1 - H304, Aquatic Chronic 2 H411 terpinen-4-ol % CAS No: EC No: Classification (EC 1272/2008) Acute Tox. 4 -H302, Skin Irrit. 2 H315, Eye Irrit. 2 H319 beta-pinene % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 H304, Skin Irrit. 2 - H315, Skin Sens. 1A - H317, Aquatic Acute 1 - H400, Aquatic Chronic 1 H410 Myrcene % CAS No: EC No: Classification (EC 1272/2008) Flam. Liq. 3 - H226, Asp. Tox. 1 H304, Skin Irrit. 2 - H315, Eye Irrit. 2 H319 3

4 Citronellol < 2.0% CAS No: EC No: Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1B H317, Eye Irrit. 2 H319 Geraniol < 2.0% CAS No: EC No: Classification (EC 1272/2008) Skin Irrit. 2 - H315, Skin Sens. 1B H317, Eye Dam. 1 H First Aid Measures 4.1 Description of first aid measures General Information: No additional data. Inhalation: Remove from exposure site to fresh air and keep at rest, seek medical advice if nausea persists. Ingestion: Give water to rinse out mouth, then provide water slowly and as much as can comfortably drink. DO NOT INDUCE VOMITING, call a POISON CENTRE and/or seek medical advice if nausea occurs. Skin Contact: Wash with warm, soapy water & remove contaminated clothing, seek medical advice if irritation occurs. Pre-existing skin, eye or respiratory problems may be aggravated by exposure. Eye Contact: Flush with water, remove contact lenses, if present and easy to do so, seek medical advice if irritation occurs. Pre-existing skin, eye or respiratory problems may be aggravated by exposure. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. Fire Fighting Measures 5.1 Extinguishing media Extinguishing Media: Carbon dioxide (CO2), dry chemical or foam. 5.2 Special hazards arising from the substance or mixture Specific Hazards: Flammable liquid and vapour, avoid contamination with oxidising agents as ignition may result, heat may cause violent rupture of containers if involved in a fire cool with water spray, when heated to decomposition will produce acrid smoke and fumes. 5.3 Advice for firefighters Protective Measures in Fire: Wear Self-Contained Breathing Apparatus (S.C.B.A.) and full protective clothing. Evacuate vicinity, contain spills. Special Fire Fighting Procedures: - 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures 4

5 Personal Precautions: Wear protective clothing as described in Section 8 of this safety data sheet. 6.2 Environmental precautions Do not discharge into drains, water courses or onto the ground. 6.3 Methods and material for containment and cleaning up In the event of a spillage or leak, remove all sources of ignition, do not smoke. If necessary use respiratory protection, protective clothing should be worn i.e., safety glasses or googles and gloves. Gather up in an inert medium like sand or earth, avoiding contamination of drains, surface and ground water and soil. In event of such a contamination notify the relevant authority. 6.4 Reference to other sections 7. Handling and Storage 7.1 Precautions for safe handling Usage Precautions: 7.2 Conditions for safe storage, including any incompatibilities Storage Precautions: Keep away from heat, sparks and open flame. It is recommended that this product is stored in well filled, tightly closed containers away from heat, light and ignition sources. 7.3 Specific end use(s) 8. Exposure Controls/Personal Protection 8.1 Control parameters 8.2 Exposure controls Protective Equipment: Engineering Measures: Provide adequate ventilation. Respiratory Equipment: For high concentrations use respiratory equipment. Hand Protection: Chemical resistant gloves (PVC). Eye Protection: Wear approved safety goggles. Other Protection: Oil resistant apron, eyewash and safety shower recommended. Wash contaminated clothing before reuse. Hygiene Measures: Good personal hygiene practices are always advisable, especially when working with chemicals / oils. Keep away from foodstuffs, beverages and feed. 9. Physical and Chemical Properties 5

6 9.1 Information on basic physical and chemical properties Appearance: Liquid. Colour: Colourless to pale yellow. Odour: Characteristic. Relative Density: Approx. 20 C Flash Point ( C): 46 C Refractive Index: Approx. 20 C Melting Point ( C): Boiling Point ( C): Vapour Pressure: Solubility in C: Auto-ignition temperature ( C): 9.2 Other information 10. Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions 10.4 Conditions to avoid High temperatures and ignition sources Incompatible materials Materials to avoid: Acids and bases, strong oxidizing agents Hazardous decomposition products 11. Toxicological Information 11.1 Information on toxicological effects Acute Toxicity: Skin corrosion / irritation: Causes skin irritation. Serious eye damage / irritation: Causes serious eye irritation. Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ Cell Mutagenicity: Carcinogenicity: Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: May be fatal if swallowed and enters airways. Photo-toxicity: Other Information: 12. Ecological Information 6

7 12.1 Toxicity Ecotoxicity: 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Precautions: 13. Disposal Considerations 13.1 Waste treatment methods Disposal Methods: Dispose of in compliance with all local and national regulations. 14. Transport Information Warning Icon: 14.1 UN number UN No. Road: 1169 UN No. SEA: 1169 UN No. AIR: UN proper shipping name EXTRACTS, AROMATIC, LIQUID Transport hazard class(es) ADR Class: 3 IMDG Class: 3 AIR Class: Packing group IMDG Pack Gr.: III AIR Pack Gr.: III 14.5 Environmental hazards 14.6 Special precautions for user 7

8 Hazard No (ADR): 30 Flammable liquid (flash-point between 23 C and 60 C, inclusive) or flammable liquid or solid in the molten state with a flash-point above 60 C, heated to a temperature equal to or above its flash-point, or self-heating liquid Hazchem Code: 3YE EMS: F-E,S-D 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Directives: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Statutory Instruments: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No Approved Code of Practice: - Guidance Notes: Workplace Exposure Limits EH40. CHIP for everyone HSG(108) Chemical safety assessment 16. Other Information Risk Phrases in Full: - Hazard Statements in Full: H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Other Information: - This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. The information contained in this SDS is accurate to the best of our knowledge and has been obtained from a variety of sources. No liability can be accepted arising out of the use, application or processing of this product. It is the users responsibility to determine the safe conditions for the use of this product. Revision Date: Version: 1 8