SAFETY DATA SHEET. Petitgrain Oil Natural
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1 Page : 1/8 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : REACH REGISTRATION NUMBER : TYPE OF PRODUCT : CHEMICAL NAME : Essential Oil CAS NUMBER : EINECS NUMBER : CAS EINECS : FEMA NUMBER : 2855 INCI NAME : IDENTIFICATION OF USAGE : SUPPLIER : Citrus aurantium L. subsp aurantium CITRUS AURANTIUM LEAF/TWIG OIL Industrial 21 Progress Edison, New Jersey United States of America Ph: Fax : hours emergency telephone number (CHEMTREC) : HAZARDS IDENTIFICATIONS CLASSIFICATION ACCORDING TO GHS REGULATION : Physical hazard : FL 4 Health Hazards : AH 1,EDI 1,SCI 2,SS 1 Environmental Hazards : EH-A 2,EH-C 3 WORDS OF WARNING: PARTICULAR RISKS : DANGER H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects.
2 Date : Version : Revision : 5G 10/29/15 PREVENTION : RESPONSE : STORAGE : DISPOSAL : PARTICULAR MENTION : OTHERS : LIMITS OF EXPOSURE : Replace : 09/24/15 Page : 2/8 P210 Keep away from heat, sparks, open flames or hot surfaces. No smoking. P261 Avoid breathing dust, fume, gas, mist, vapours, spray. P264 Wash parts in contact thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 IF SWALLOWED : Immediately call a POISON CENTER or doctor/physician. P302+P352 IF ON SKIN : Wash with plenty of soap and water. P305+P351+P338 IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment. P331 Do NOT induce vomiting. P332+P313 If skin irritation occurs : Get medical advice. P333+P313 If skin irritation or rash occurs : Get medical advice. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire : Use CO2 foam, dry chemical for extinction. P403+P235 Store in well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents and/or container in accordance with local, regional, national and/or international regulation.
3 Page : 3/8 3. COMPOSITION INFORMATION INGREDIENT CONTRIBUTING TO THE HAZARD Linalyl acetate (CAS : ) 1999/45/CE : XI;R38;S36/37 GHS : EDI 2A, EH-A 3, FL 4, SCI 2 Linalol (CAS : ) 1999/45/CE : Xi;R38;S37 GHS : ATO 5 (2,790), EDI 2A, EH-A 3, FL 4, SCI 2 alpha terpinéol (CAS : ) 1999/45/CE : Xi;R36/38;S26;S37 GHS : ATO 5 (4,300), EDI 2A, EH-A 2, FL 4, SCI 2 Pinènes (CAS : (alpha) (beta)) 1999/45/CE : N;XI;XN;R10;R38;R43;R50/53;R65;S24;S36/37;S62 GHS : AH 1, ATO 5 (3,500), EH-A 1, EH-C 1, FL 3, SCI 2, SS 1 Ocimène (CAS : (Z) (E)) 1999/45/CE : Xn;R65;S62 GHS : AH 1, FL 3, SCI 3 Geraniol (CAS : ) 1999/45/CE : XI;R38;R41;R43;S24;S26;S37;S39 GHS : ATO 5 (3,600), EDI 1, EH-A 3, SCI 2, SS 1 Geranyl acetate (CAS : ) 1999/45/CE : N;XI;R38;R43;R51/53;S24;S37;S61 GHS : EH-A 2, EH-C 3, SCI 2, SS 1 Neryl acetate (CAS : ) 1999/45/CE : -; Limonène (CAS : ) 1999/45/CE : N;XN;R10;R38;R43;R50/53;R65;S02;S24;S37;S60;S61;S62 GHS : AH 1, EH-A 1, EH-C 1, FL 3, SCI 2, SS 1 Myrcene (CAS : ) 1999/45/CE : XN;R10;R38;R65;S62 GHS : AH 1, EDI 2A, FL 3, SCI 2 Nerol (CAS : ) 1999/45/CE : XI;R36/38;R43;S24;S26;S36/37 GHS : ATO 5 (4,500), EDI 2A, EH-A 3, SCI 2, SS 1 Beta caryophyllene (CAS : ) 1999/45/CE : Xn;R65;S62 GHS : AH 1, SCI 3 CONTENT 35 % - 60% 10 % - 40% 2.5 % - 10% 0.5 % - 5% ~ 5 % 2 % - 5% 2 % - 5% ~ 5 % 0.5 % - 5% <5% 0 % - 2% 0 % - 1% 4. FIRST-AID MEASURES INGESTION : EYE CONTACT : SKIN CONTACT : INHALATION : Do not try to vomit. Rinse mouth. Consult a doctor. Wash immediately and abundantly the eyes with a good running water at low pressure. Consult an ophthalmologist. Sprinkle abundantly with water during at least 15 minutes. Remove victim to fresh air
4 Page : 4/8 5. FIRE FIGHTING EXTINGUISHING MEDIA : SUITABLE : CO2 foam, dry chemical. NON SUITABLE : Water. SPECIFIC METHODS OF FIRE FIGHTING : None. SPECIAL EQUIPMENT FOR THE PROTECTION OF FIRE FIGHTERS : No. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : ENVIRONNEMENTAL PRECAUTIONS : METHODS FOR CLEANING-UP : Avoid all contact with eyes and mucous. Don't throw it in sewer nor in natural environment. Recover in a tight container. Wash with plenty of water after complete elimination of the product. 7. HANDLING AND SORAGE HANDLING : Avoid contact with eyes and mucous. STORAGE : Keep away from humidity in a fresh place. Keep container closed after using. OTHER : See Section EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION : HAND PROTECTION : EYE PROTECTION : SKIN AND BODY PROTECTION : INGESTION : INDUSTRIAL HYGIENE : Assure a good ventilation of work place. Plastic or synthetic rubber impermeable gloves. Goggles giving complete protection to eyes. Eyewash bottle with clean water. Clothes for chemical protection to avoid contact. Do not eat, drink and smoke while using Provide an extraction or global ventilation of the work place to reduce concentrations of the steams. 9. PHYSICAL AND CHEMICAL PROPERTIES FORM : COLOR : Clear Liquid Colorless to pale yellow ODOR : Fresh, Cologne-like, sweet and neroli-type. ODOR THRESHOLD : ph : MELTING POINT :
5 BOILING POINT : FLASHPOINT (closed cup) : 66 C / F EVAPORATION RATE: FLAMMABILITY : EXPLOSIVE LIMITS : VAPOR PRESSURE : VAPOR DENSITY : SPECIFIC GRAVITY : 0.89 SOLUBILITY IN WATER : Insoluble Log K (n-octanol/water) : AUTOIGNITION TEMP. : DECOMPOSITION TEMP. : VISCOSITY : EXPLOSIVE PROPRIETIES: OXIDIZING PROPRIETIES: OTHER DATA : Page : 5/8 10. STABILITY AND REACTIVITY REACTIVITY : CHEMICAL STABILITY : POSSIBILITY OF HAZARDOUS REACTION : CONDITIONS TO AVOID : INCOMPATIBLE MATERIALS: HAZARDOUS DECOMPOSITION PRODUCTS : OTHERS : No data available. No data available. None in normal conditions. Excessive heat. Strongly oxidising and reducing agents. None in normal conditions. None. 11. TOXICOLOGICAL INFORMATION INGESTION : SKIN CONTACT EYE CONTACT : INHALATION : ASPIRATION : SPECIFIC EFFECTS : Can be noxious. Can induce irritations. Serious eye damage/eye irritation No specific hazard in normal use. Aspiration hazard No information available. 12. ECOLOGICAL INFORMATION TOXICITY : See Section 2 PERSISTENCE / DEGRADABILITY : No information available.
6 BIOACCUMULATION POTENTIAL : RESULTS OF PBT AND vpvb ASSESSMENT : MOBILITY IN SOIL : WGK : 2 OTHER ADVERSE EFFECTS : No information available. No information available. No information available. Not known. Page : 6/8 13. DISPOSAL CONSIDERATION 14. TRANSPORT INFORMATION MEASURES To comply with the regulations and prefectoral orders in use. Throwing out forbidden. Packaging must be well emptied RID / ADR CLASS : 9 SUBSIDIARY RISK : UN NUMBER : UN 3082 PACKING GROUP : TUNNEL CODE : IMCO / IMDG CLASS : 9 SUBSIDIARY RISK : III (E) UN NUMBER : UN 3082 PACKING GROUP : EmFS : OACI / IATA CLASS : 9 SUBSIDIARY RISK : III F-A, S-F UN NUMBER : UN 3082 PACKING GROUP : TRAVELLER AIRPLANE PACKING INSTRUCTION : TRAVELLER AIRPLANE MAXIMUM QUANTITY : CARGO AIRPLANE PACKING INSTRUCTION : CARGO AIRPLANE MAXIMUM QUANTITY : III L L
7 Date : Version : Revision : 5G 10/29/15 Replace : 09/24/15 Page : 7/8 Labelling according to RID / ADR, IMCO / IMDG, OACI / IATA SHIPPING NAME : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S (CLOVE) 15. REGULATORY INFORMATION LABELLING ACCORDING TO GHS REGULATION : Physical hazard : FL 4 Health Hazards : AH 1,EDI 1,SCI 2,SS 1 Environmental Hazards : EH-A 2,EH-C 3 WORDS OF WARNING: PARTICULAR RISKS : PREVENTION : RESPONSE : DISPOSAL : PARTICULAR MENTION : OTHERS : LIMITS OF EXPOSURE : DANGER H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H401 Toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing, eye protection, face protection. P302+P352 IF ON SKIN : Wash with plenty of soap and water. P305+P351+P338 IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P501 Dispose of contents and/or container in accordance with local, regional, national and/or international regulation. OTHER CLASSIFICATIONS : DOT CLASSIFICATION : -
8 Date : Version : Revision : 5G 10/29/15 NFPA CLASSIFICATION : Replace : 09/24/15 Page : 8/8 NIOSH : THRESHOLD LIMIT VALUE - TLV : OSHA PERMISSIBLE EXPOSURE LIMIT - PEL : IAS THE SUBSTANCE BEEN LISTED AS CARCINOGEN : SARA 313 : 16. OTHER INFORMATION OTHER INVENTORIES Country Nom inventaire Datas Number AUSTRALIA AICS Listé CANADA DSL Listé TAIWAN ECN Listé JAPAN ENCS Listé USA FDA Listé CHINA IESC Listé 5149 JAPAN ISHL Listé SOUTH KOREA KECI Listé KE NEW ZEALAND THE PHILIPPINES NZIoC PICCS Listé Listé USA TSCA Listé The content and format of this safety data sheet are in accordance with EC Regulation No. 1907/2006 of the European Parliament and Council Respect safety measures usually applied during the production of perfumery products. This data sheet completes the technical use notice, but doesn't replace it. These information are based on our actual knowledge for the above mentioned product at the edition date of this data sheet. They are given in good faith. In any case user is not exempted to know and apply all texts which regulate this activity. He will take under his own responsibility the precautions for the utilisation of product he knows. Users should be aware of the other purposes than those for which it is concerned.
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