: IMS Daily Clean. SECTION 1: Identification. SECTION 2: Hazard identification. SECTION 3: Composition/Information on ingredients. 1.1.

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1 SECTION 1: Identification 1.1. Identification Product form Product name Product code According to the Hazard Communication Standard (CFR ) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 Date of issue: 12/30/2016 Revision date: 12/30/2016 Version: 1.0 : Mixtures : : IMS-1218, IMS Relevant identified uses of the substance or mixture and uses advised against Recommended use : Cleaner 1.3. Details of the supplier of the safety data sheet Manufactured for Hu-Friedy Mfg. Co., LLC 3232 N. Rockwell Street Chicago, IL USA Hu-Friedy or Emergency telephone number Emergency number : SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS classification Eye Irrit Label elements GHS labeling Hazard pictograms (GHS) : Distributor Acmedent Corp. 91 Citation Dr, Unit 5, Concord L4K 2Y Central Dental Supply Saulteaux Crescent, Winnipeg R3J 3C Henry Schein Canada, Inc. 345 Townline Road, SS4, Niagara-On-The-Lake L0S 1J K-Dental Inc. 750 Cochrane Drive, Markham L3R 8E Patterson Dentaire Canada 1205, Boul.henri-Bourassa West, Montreal H3M 3E Sinclair Dental Company Ltd. 900 Harbourside Drive, North Vancouver V7P 3T Signal word (GHS) Hazard statements (GHS) Precautionary statements (GHS) GHS07 : Warning : Causes serious eye irritation : Wash hands, forearms and face thoroughly after handling. Wear eye protection, face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention 2.3. Other hazards 2.4. Unknown acute toxicity No data available SECTION 3: Composition/Information on ingredients 3.1. Substance 3.2. Mixtures 12/30/2016 EN (English US) Page 1

2 Name Product identifier % Disodium carbonate (CAS No) SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. : If skin irritation occurs: Wash skin with plenty of water. Obtain medical attention if irritation persists. : If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea Indication of any immediate medical attention and special treatment needed Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : None known Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Reactivity : No dangerous reactions known under normal conditions of use Advice for firefighters Protection during firefighting SECTION 6: Accidental release measures : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA) Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel For non-emergency personnel For emergency responders 6.2. Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up For containment : Contain spill, then place in a suitable container. Minimize dust generation. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. Avoid breathing dust, fume, gas, mist, spray, vapors. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. : Wash contaminated clothing before reuse. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. 12/30/2016 EN (English US) 2/5

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Color Odor Odor threshold : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. : Wear suitable gloves. : Wear eye/face protection. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. : Avoid release to the environment. : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. : Granular powder. : white : odorless ph : Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. SECTION 10: Stability and reactivity : Non flammable. : Soluble in water Reactivity No dangerous reactions known under normal conditions of use Chemical stability Stable under normal conditions. 12/30/2016 EN (English US) 3/5

4 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Heat. Incompatible materials Incompatible materials Avoid oxidizing agents and acids. Avoid contact with bare aluminum. Flammable hydrogen gas may be produced in contact with bare aluminum. Sodium Carbonate reacts with Fluorine, aluminum, phosphorous pentoxide, sulfuric acid, zinc, lithium, moisture, calcium hydroxide and 2,4,6-trinitrotoluene, and reacts violently with acids to form carbon dioxide. Urea reacts with calcium hypochlorite or sodium hypochlorite to form the explosive nitrogen trichloride. It is incompatible with sodium nitrite, gallium perchlorate, strong oxidizing agents (permanganate, dichromate, nitrate, chlorine), phosphorus pentachloride, nitrosyl perchlorate, titanium tetrachloride, and chromyl chloride Hazardous decomposition products Carbon dioxide and carbon monoxide may form when heated to decomposition. Urea decomposes upon heating and can form products including ammonia, oxides of nitrogen, cyanuric acid, cyanic acid, biuret, carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat > 2000 mg/kg (Calculated acute toxicity estimate) > 2000 mg/kg (Calculated acute toxicity estimate) > 20 mg/l/4h (Calculated acute toxicity estimate) LD50 oral rat 2800 mg/kg LD50 dermal rabbit > 2000 ml/kg LC50 inhalation rat 2300 mg/m³ (Exposure time: 2 h) Skin corrosion/irritation ph: Serious eye damage/irritation : Causes serious eye irritation. ph: Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 : May cause respiratory tract irritation. : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. : Likely routes of exposure: ingestion, inhalation, skin and eye. : May cause long-term adverse effects in the aquatic environment. 300 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) 12/30/2016 EN (English US) 4/5

5 EC50 Daphnia 1 LC50 fish Persistence and degradability Persistence and degradability Bioaccumulative potential Bioaccumulative potential BCF fish mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Not established. Not established. (no bioaccumulation) Mobility in soil Other adverse effects Effect on the global warming SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations SECTION 14: Transport information : No known effects from this product. : No other effects known. Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG) In accordance with DOT/TDG SECTION 15: Regulatory information Federal regulations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. The generation of waste should be avoided or minimized wherever possible. All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories International regulations US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Date of issue : 12/30/2016 Revision date : 12/30/2016 : None. Prepared by : Nexreg Compliance Inc. SDS HazCom WHMIS 2015 (NexReg) Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. 12/30/2016 EN (English US) 5/5