Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 01/28/ PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE 3554 Indigo VISIBLE IDH number: LIGHT ADHESIVE PART NO Product type: Acrylics Item number: Region: United States Company address: Contact information: Henkel Corporation Telephone: One Henkel Way Rocky Hill, Connecticut MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Pale yellow FLAMMABILITY: 2 Odor: Mild PHYSICAL HAZARD: 1 Personal Protection: See MSDS Section 8 WARNING: COMBUSTIBLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED, ABSORBED THROUGH SKIN OR INHALED. DO NOT SPRAY. DO NOT HEAT. CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Modified acrylamide is harmful if inhaled. Vapors and mists will irritate nose and throat and possibly eyes. Headache. Nausea. Causes respiratory tract irritation. DO NOT heat or spray as this increases the inhalation hazard. Modified acrylamide may be absorbed through skin in harmful amounts. Toxic. May cause allergic skin reaction. May be harmful if absorbed through skin. Causes skin irritation. Redness. Swelling. Contact with eyes will cause irritation. Modified acrylamide is harmful if swallowed. Toxic. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Aliphatic urethane acrylate oligomer Unknown N,N-Dimethylacrylamide ,6-Hexanediol diacrylate Urethane Acrylate Oligomer Unknown Page 1 of 6

2 Acrylic ester Unknown 5-10 Hexafunctional urethane acrylate ester Unknown 5-10 Methacrylate ester Proprietary 1-5 Photoinitiator Proprietary FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). Wash clothing before reuse. If symptoms develop and persist, get medical attention. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get immediate medical attention. Keep individual calm. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get immediate medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 91.5 C (196.7 F) Water spray (fog), foam, dry chemical or carbon dioxide. Do not use high volume water jet. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers. Oxides of carbon. Oxides of nitrogen. Irritating organic vapours. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Page 2 of 6

3 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. DO NOT heat or spray. Use only with adequate ventilation. Keep container closed. Refer to Section 8. For safe storage, store at or below 26 C (78.8 F) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Store away from heat, sparks, flames, or other sources of ignition. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Aliphatic urethane acrylate oligomer N,N-Dimethylacrylamide 1,6-Hexanediol diacrylate 0.11 ppm (1 mg/m3) TWA (Skin sensitizer) 0.1 mg/m3 TWA (Skin) ppm TWA (Skin) Urethane Acrylate Oligomer Acrylic ester Hexafunctional urethane acrylate ester Methacrylate ester Photoinitiator Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). If this material is handled at elevated temperature or under mist forming conditions, a NIOSH approved respirator must be used. Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Pale yellow Odor: Mild Odor threshold: ph: Not applicable Vapor pressure: < 5 mbar (20 C (68 F)) Boiling point/range: > 149 C (> F) Melting point/ range: Specific gravity: Vapor density: Flash point: 91.5 C (196.7 F) Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Page 3 of 6

4 Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Slight 0.52 %; 1.09 g/l 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable under normal conditions of storage and use. May occur. Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Isocyanates. Amines. Irritating organic vapours. Oxidizing agents. Reducing agents. Free radical initiators. Oxygen scavengers. Acids and bases. Alkalis. Amines. Other polymerization initiators. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Direct sunlight. Freezing conditions. UV light. Inert gas blanketing. 11. TOXICOLOGICAL INFORMATION Product toxicity data: Modified acrylamide: LD50 (oral, rat) 316 mg/kg LD50 (dermal, rabbit) 518 mg/kg LC50 (vapor, 1hour, rat) greater than 776 ppm. Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Aliphatic urethane acrylate oligomer No No No N,N-Dimethylacrylamide No No No 1,6-Hexanediol diacrylate No No No Urethane Acrylate Oligomer No No No Acrylic ester No No No Hexafunctional urethane acrylate ester No No No Methacrylate ester No No No Photoinitiator No No No Hazardous components Aliphatic urethane acrylate oligomer N,N-Dimethylacrylamide 1,6-Hexanediol diacrylate Urethane Acrylate Oligomer Acrylic ester Hexafunctional urethane acrylate ester Methacrylate ester Photoinitiator Health Effects/Target Organs Allergen, Irritant Irritant, Eyes, Mutagen, Kidney, Less weight gain and food intake. Irritant, Allergen Allergen, Irritant No Data No Data Irritant, Allergen No Target Organs 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6

5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Combustible liquid, n.o.s. (Modified Acrylamide) Hazard class or division: Combustible Liquid Identification number: NA 1993 Packing group: III International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimis above reporting de minimis Immediate Health, Delayed Health, Fire above reporting de minimis This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. B.3, D.1.B, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 16 Prepared by: Diane Annis, Sr. Regulatory Affairs Specialist Page 5 of 6

6 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6