MATERIAL SAFETY DATA SHEET

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Mildred Sims
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1 Page 1 of 5 SECTION I: PRODUCT INFORMATION PRODUCT: Sikagard AG PART A REVISION DATE: February 1 st, 2015 USAGE: Water-Borne, semi sacrificial anti-graffiti Sealant MANUFACTURER/SUPPLIER: SIKA CANADA INC. 601, avenue Delmar Pointe Claire, QC H9R 4A9 EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) TDG CLASSIFICATION: Not regulated TDG Class: Not regulated UN NUMBER: Not regulated Packaging Group: Not regulated WHMIS Classification: Not regulated SECTION II: HAZARDOUS INGREDIENTS Hazardous ingredients % T.L.V. # CAS None on the IDL LD 50 (mg/kg) (species, route) LC 50 (species, route) SECTION III: PHYSICAL CHARACTERISTICS Physical State: Liquid Appearance and Odor: Milky with ammonia odor Odor Threshold: Evaporation Rate: Vapor Density: Vapor Pressure: VOC: Boiling Point: Freezing Point: Density (g/ml): ~ 1.02 g/ml Water Solubility: Soluble ph: % volatility: Water/Oil Distribution: % Solids:

2 Page 2 of 5 PRODUCT: Sikagard AG PART A SECTION IV: FIRE AND EXPLOSION HAZARDS Flammability: If Yes, under what conditions: Extinguishing methods: No Carbon Dioxide, Water Fog, Dry Chemical Foam TDG flammability Class: Not regulated Flammable upper limits (% vol.): Flammable lower limits (% vol.): Flash Point (method used): > 100ºC Auto-ignition temperature: Dangerous Combustion Products: Protect from mechanical impact: Special Methods: Fire fighters should wear the adequate protective gear and a self-contained breathing apparatus. Protect from static discharge: SECTION V: REACTIVITY DATA Chemical stability: Stable Dangerous decomposition products: Carbon oxides If not, under what conditions: Excessive heat, sparks and open flames in the presence of oxidizing material Incompatibility with other material: Yes Polymerisation Risks: Will not occur If Yes, which ones: Oxidizing agents

3 Page 3 of 5 PRODUCT: Sikagard AG PART A SECTION VI: TOXIC PROPERTIES ROUTE OF ENTRY / CONTACT Irritant. Carcinogenicity: Skin: Irritant. Repeated contact may cause dermatitis in sensitive individuals. Toxic effects on reproduction: Inhalation: Nose and throat irritant Teratogenicity: Ingestion: May cause headache, nausea, vomiting and weakness Mutagenicity: Product with synergistic effects: Not known Acute: May cause eye and skin irritation, and sensitization. An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory problems.

4 Page 4 of 5 PRODUCT: Sikagard AG PART A SECTION VII: PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT OTHERS Gloves: Impervious gloves Respiratory equipment: Not required with a good ventilation. Shoes: Clothing: Safety glasses Safety shoes Barrier cream Ventilation: Procedure in case of leaks: Local and mechanical exhaust is recommended to minimize exposure. Avoid contact with eyes, skin or clothing. Avoid breathing vapour, mist or spray. Contain spill and collect with absorbent material. Flush area with water. Other: Wash thoroughly after handling Handling and Equipment methods: Avoid every skin, eye and clothing contact. Avoid breathing vapour, mist or spray. Wash thoroughly with soap and water after handling. Warehouse Requirements: Store in cool, dry and well ventilated area. Store away from heat and ignition sources. Special Shipping Instructions: See TDG Waste Disposal: provincial regulations. According to municipal, and federal

5 Page 5 of 5 PRODUCT: Sikagard AG PART A SECTION VIII: FIRST AID Skin: Remove contaminated clothing and shoes. Wash immediately with plenty of soap and water. Consult a physician if required. Rinse eyes immediately with plenty of water for at least 30 minutes, while holding eyelids to ensure a proper wash. Consult a physician immediately. Inhalation: In the case of overexposure, evacuate to fresh air. If not breathing, give oxygen. Consult a physician if necessary. Ingestion: Do not induce vomiting. Drink plenty of water. Do not give anything by mouth to an unconscious person. See a physician immediately. SECTION IX: PREPARATION INFORMATION Prepared By: Sika Canada R & D Telephone #: (514) Fax #: (514) Notice To Reader The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed in Section IX of this MSDS. SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS. All sales of Sika products are subject to its current terms and conditions of sale available at or AQ 191 A Date: 2012/02/01 App: S.G

6 Page 1 of 5 SECTION I: PRODUCT INFORMATION PRODUCT: Sikagard AG PART B REVISION DATE: February 1 st, 2015 USAGE: Water-Borne, semi sacrificial anti-graffiti Sealant MANUFACTURER/SUPPLIER: SIKA CANADA INC. 601, avenue Delmar Pointe Claire, QC H9R 4A9 EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) TDG CLASSIFICATION: Not regulated TDG Class : Not regulated UN NUMBER: Not regulated Packaging Group: Not regulated WHMIS Classification: D2A, D2B SECTION II: HAZARDOUS INGREDIENTS Hazardous ingredients % T.L.V. # CAS LD 50 (mg/kg) (species, route) LC 50 (species, route) ALIPHATIC POLYISOCYANATES mg/m 3 TWA 1.0mg/m 3 STEL N/A N/A N/A HEXAMETHYLENE DIISOCYANATE BASED POLYISOCYANATE mg/m 3 TWA 1.0 mg/m 3 STEL N/A N/A N/A HEXAMETHYLE DIISOCYANATE ppm TWA (ACGIH) (rabbit, skin) 350 (mouse, oral) 768 (rat, oral) Mouse: 3.1 ppm for 4hrs Rat: 45 ppm for 4 hrs SECTION III: PHYSICAL CHARACTERISTICS Physical State: Liquid Appearance and Odour: Not specified; slight, if any odour Odor Threshold: Evaporation Rate: Vapor Density: Vapor Pressure: % volatility: Boiling Point: Freezing Point: Density (g/ml): Water Solubility: ph: Water/Oil Distribution: Resin is not soluble. Reacts slowly with water to liberate CO 2 gas

7 Page 2 of 5 PRODUCT: Sikagard AG PART B SECTION IV: FIRE AND EXPLOSION HAZARDS Flammability: If Yes, under what conditions: Extinguishing methods: Special Methods: No Media suitable for other combustible materials in the area. Carbon Dioxide, Water Fog, Dry Chemical Foam. Fire fighters should wear the full protective gear and a self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Heat will cause pressure build-up and may cause explosive rupture. TDG flammability Class: Flammable upper limits (% vol.): Flammable lower limits (% vol.): Flash Point (method used): Auto-ignition temperature: Dangerous Combustion Products: Protect from mechanical impact: Protect from static discharge: Not regulated > 93.3 C PMCC Carbon monoxide, nitrogen oxides, isocyanates. Traces of hydrogen cyanide. SECTION V: REACTIVITY DATA Chemical stability: If not, under what conditions: Stable Moisture and other materials will react with isocyanates. Exposure to high heat. React with water, forming carbon dioxide. Dangerous decomposition products: Thermal decomposition may produce toxic fumes. At high temperature, by fire: carbon oxides, oxides of nitrogen, hydrogen cyanide, HID. Incompatibility with other material: Yes Polymerisation Risks: Will not occur If Yes, which ones: Water, amines, strong bases, alcohols, metal compounds. Surface active materials.

8 Page 3 of 5 PRODUCT: Sikagard AG PART B SECTION VI: TOXIC PROPERTIES ROUTE OF ENTRY / CONTACT Liquid product, aerosols or vapours are irritating. Can cause tearing, reddening and swelling. May cause discomfort. Prolonged contact can cause corneal damage. Carcinogenicity: Toxic effects on reproduction: Skin: Irritant. Can cause rash, scaling or blistering. May cause sensitization by skin contact. Teratogenicity: Mutagenicity: Inhalation: Vapour/mists at concentrations above the exposure limits can irritate (burning sensation) the mucous membranes in the respiratory tract. Causes runny nose, sore throat, coughing, chest discomfort, difficult breathing and reduced pulmonary functioning. People with pre-existing, nonspecific bronchial hyperactivity can respond to concentrations below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary oedema. Effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms has also been reported. These symptoms can be delayed up to several hours after exposure. Product with synergistic effects: Not known Ingestion: Can cause burning of the mouth. Can result in irritation of the stomach tissue and/or the digestive tract. An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory problems.

9 Page 4 of 5 PRODUCT: Sikagard AG PART B SECTION VII: PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT OTHERS Gloves: Chemical resistant. Barrier cream. Respiratory equipment: Avoid breathing vapours. Positive pressure, supplied air respirator is recommended. Shoes: Clothing: Other: Ventilation: Safety glasses or chemical proof goggles or 8 face shield. Contact lenses should not be worn when working with this chemical.. Adequate protective clothes Practice good hygiene; wash thoroughly before handling any food. Eyewash fountain. Emergency shower should be in close proximity. Ventilate adequately. Local and mechanical exhaust is recommended to minimize exposure. Procedure in case of leaks: Handling and Equipment methods: Warehouse Requirements: Special Shipping Instructions: Evacuate all non-essential personnel. Wear full protective equipment during clean-up. Use a dry absorbent material. Shovel into suitable unsealed containers. Transport to well-ventilated area (outside) and treat water to neutralized.. Allow to stand uncovered for hours. Avoid skin, eye and clothing contact. Avoid breathing vapour, mist or spray. Wash thoroughly hands and arms with soap and water after handling. Remove contaminated clothing. Keep away from heat, sparks and open flame. Equipment must be grounded. Store in cool, dry and well ventilated area. Ideal storage is C Store in tightly closed containers to prevent moisture contamination. See TDG Waste Disposal: According to municipal, provincial and federal regulations.

10 Page 5 of 5 PRODUCT: Sikagard AG PART B SECTION VIII: FIRST AID Skin: Remove contaminated clothing and shoes. Wash immediately with plenty of soap and water. Consult a physician if required. Rinse eyes immediately with plenty of water for at least 30 minutes, while holding eyelids to ensure a proper wash. Consult a physician immediately. Inhalation: In the case of overexposure, evacuate to fresh air. If not breathing, give oxygen. Consult a physician if necessary. Ingestion: Do not induce vomiting. Drink plenty of water. Do not give anything by mouth to an unconscious person. See a physician immediately. SECTION IX: PREPARATION INFORMATION Prepared By: R & D of Sika Canada Inc. Telephone #: (514) Fax #: (514) Notice To Reader The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed in Section IX of this MSDS. SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS. All sales of Sika products are subject to its current terms and conditions of sale available at or AQ 191 A Date: 2012/02/01 App: S.G

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET Page 1 of 5 SECTION I: PRODUCT INFORMATION REVISION DATE: February 1 st, 2015 USAGE: ONE COMPONENT URETHANE BASED SEALANT / ADHESIVE MANUFACTURER/SUPPLIER: SIKA CANADA INC. 601, avenue Delmar Pointe Claire,