Polyurethane Foam Sealants

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Diane Harrington
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Johns Manville Address : P.O. Box 5108 Denver, CO USA 80127 Telephone : +1 303-978-2000 8:00 a.m.

1 SAFETY DATA SHEET SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Trade name : Johns Manville Fireblock Polyurethane Foam Sealant, Johns Manville Window & Door Polyurethane Foam Sealant Manufacturer or supplier's details Company : Johns Manville Address : P.O. Box 5108 Denver, CO USA Telephone : :00 a.m.-5:00 p.m. M-F Emergency telephone number : (Chemtrec, in English) Recommended use of the chemical and restrictions on use Recommended use : Sealant Restrictions on use : For professional users only. Prepared by : productsafety@jm.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable aerosols : Category 1 Gases under pressure : Compressed gas Acute toxicity (Inhalation) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Respiratory sensitisation : Category 1 Skin sensitisation : Category 1 Effects on or via lactation Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure (Inhalation) : Category 3 (Respiratory system) : Category 2 (Respiratory system) GHS label elements Hazard pictograms : 1 / 14 US/EN

2 Signal word : Danger Hazard statements : H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H362 May cause harm to breast-fed children. H373 May cause damage to organs (Respiratory system) through prolonged or repeated exposure if inhaled. Precautionary statements : Prevention: P201 Obtain special instructions before use. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P263 Avoid contact during pregnancy/ while nursing. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. P285 In case of inadequate ventilation wear respiratory protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P362 Take off contaminated clothing and wash before reuse. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste 2 / 14 US/EN

3 disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) paraffin waxes and hydrocarbon waxes, chloro >= 10 - <= 30 4,4'-methylenediphenyl diisocyanate >= 5 - <= 10 polymethylenepolyphenylene isocyanate >= 5 - <= 10 isobutane >= 3 - <= 7 dimethyl ether >= 3 - <= 7 propane >= 1 - <= 5 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If inhaled, remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. If breathing is difficult, give oxygen. Call a physician or poison control centre immediately. In case of skin contact : Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Call a physician if irritation develops or persists. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. Remove contact lenses. Keep eye wide open while rinsing. Protect unharmed eye. If swallowed : If swallowed, DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical attention. Most important symptoms and effects, both acute and delayed : None known. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) 3 / 14 US/EN

4 SAFETY DATA SHEET Dry chemical Halons Water spray Unsuitable extinguishing media Hazardous combustion products : High volume water jet : Carbon oxides Nitrogen oxides Fluorine compounds hydrogen cyanide Further information : Standard procedure for chemical fires. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Keep away from open flames, hot surfaces and sources of ignition. Advice on safe handling : Keep away from heat and flame. Take precautionary measures against static discharges. Do not puncture. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. 4 / 14 US/EN

5 SAFETY DATA SHEET For personal protection see section 8. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open b y force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Recommended storage temperature : C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) 4,4'-methylenediphenyl diisocyanate Control parameters / Permissible concentration Basis TWA ppm ACGIH TWA ppm NIOSH REL 0.05 mg/m3 C 0.02 ppm NIOSH REL 0.2 mg/m3 C 0.02 ppm OSHA 0.2 mg/m3 isobutane TWA 800 ppm NIOSH REL 1,900 mg/m3 STEL 1,000 ppm ACGIH dimethyl ether TWA 1,000 ppm US WEEL propane TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm 1,800 mg/m3 OSHA Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR ) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Solvent-resistant gloves 5 / 14 US/EN

6 SAFETY DATA SHEET Remarks : Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Eye protection : Tightly fitting safety goggles Safety glasses with side-shields Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Written instructions for handling must be available at the work place. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range : viscous liquid : off-white, yellow, orange : hydrocarbon-like Flash point : ca C Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : not determined Relative density : ca. 1.1(Water = 1.0) Solubility(ies) Water solubility : insoluble 6 / 14 US/EN

7 Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, dynamic Viscosity, kinematic SECTION 10. STABILITY AND REACTIVITY Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Vapours may form explosive mixture with air. No decomposition if stored and applied as directed. Conditions to avoid : Do not expose to temperatures above: 38 C Heat, flames and sparks. Incompatible materials : Alcohols Strong bases Strong oxidizing agents Amines Ammonia Heavy metal salts Hazardous decomposition products : Carbon oxides Hydrogen fluoride Hydrogen cyanide (hydrocyanic acid) SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute inhalation toxicity : Acute toxicity estimate : 1.5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Acute toxicity paraffin waxes and hydrocarbon waxes, chloro: Acute oral toxicity : LD50 (Rat): > 26,100 mg/kg 7 / 14 US/EN

8 Acute toxicity 4,4'-methylenediphenyl diisocyanate: Acute oral toxicity : LD50 (Rat): 31,600 mg/kg LD50 (Rat): > 7,616 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity Acute dermal toxicity : LC50 (Rat, male): mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 : LD50 (Rabbit, male and female): > 9,400 mg/kg Method: OECD Test Guideline 402 Acute toxicity polymethylenepolyphenylene isocyanate: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Acute inhalation toxicity Acute dermal toxicity : LC50 (Rat): 0.49 mg/l Exposure time: 4 h Test atmosphere: dust/mist : LD50 (Rabbit, male and female): > 9,400 mg/kg Method: OECD Test Guideline 402 Acute toxicity dimethyl ether: Acute inhalation toxicity : LC50 (Rat, male): ppm Exposure time: 4 h Acute toxicity propane: Acute inhalation toxicity : LC50 (Rat): 1,442,847 mg/l, > ppm Exposure time: 15 min LC50 (Rat): > 1,464 mg/l Exposure time: 15 min Skin corrosion/irritation Product: Remarks: May cause skin irritation and/or dermatitis. Skin corrosion/irritation 4,4'-methylenediphenyl diisocyanate: Species: Rabbit Method: Draize Test Result: Mild skin irritant Species: Human Result: irritating 8 / 14 US/EN

9 Skin corrosion/irritation polymethylenepolyphenylene isocyanate: Species: Rabbit Result: Skin irritation Serious eye damage/eye irritation Product: Remarks: Causes serious eye irritation. Serious eye damage/eye irritation 4,4'-methylenediphenyl diisocyanate: Species: Rabbit Result: Moderate eye irritation Method: Draize Test Species: Human Result: irritating Serious eye damage/eye irritation polymethylenepolyphenylene isocyanate: Species: Rabbit Result: Mild eye irritation Respiratory or skin sensitisation Product: Remarks: May cause sensitisation of susceptible persons by skin contact or by inhalation of aerosol or dust. Respiratory or skin sensitisation 4,4'-methylenediphenyl diisocyanate: Exposure routes: Dermal Species: Mouse Assessment: May cause sensitisation by skin contact. Method: OECD Test Guideline 429 Result: positive Exposure routes: Inhalation Species: Guinea pig Assessment: May cause sensitisation by inhalation. Result: positive Respiratory or skin sensitisation polymethylenepolyphenylene isocyanate: Exposure routes: Dermal Species: Mouse Assessment: May cause sensitisation by skin contact. 9 / 14 US/EN

10 Method: OECD Test Guideline 429 Result: positive Exposure routes: Inhalation Species: Guinea pig Assessment: May cause sensitisation by inhalation. Result: positive IARC OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reasonably anticipated to be a human carcinogen paraffin waxes and hydrocarbon waxes, chloro STOT - single exposure 4,4'-methylenediphenyl diisocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. STOT - single exposure polymethylenepolyphenylene isocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. STOT - repeated exposure 4,4'-methylenediphenyl diisocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: Causes damage to organs through prolonged or repeated exposure. STOT - repeated exposure polymethylenepolyphenylene isocyanate: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: Causes damage to organs through prolonged or repeated exposure. Further information Product: Remarks 10 / 14 US/EN

11 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity paraffin waxes and hydrocarbon waxes, chloro: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): mg/l Exposure time: 96 h Test Type: flow-through test LC50 (Lepomis macrochirus (Bluegill sunfish)): 300 mg/l Exposure time: 96 h Test Type: static test LC50 (Oncorhynchus mykiss (rainbow trout)): 94.5 mg/l Exposure time: 96 h Test Type: static test LC50 (Lepomis macrochirus (Bluegill sunfish)): 0.1 mg/l Exposure time: 96 h Test Type: flow-through test LC50 (Pimephales promelas (fathead minnow)): 100 mg/l Exposure time: 96 h Test Type: static test M-Factor (Acute aquatic toxicity) : 10 Persistence and degradability No data available Bioaccumulative potential paraffin waxes and hydrocarbon waxes, chloro: Partition coefficient: n- octanol/water : log Pow: ca. 6 propane: Partition coefficient: n- octanol/water : log Pow: 2.36 Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances 11 / 14 US/EN

12 SAFETY DATA SHEET Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information paraffin waxes and hydrocarbon waxes, chloro: Additional ecological information : Marine pollutant SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal of residual product : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. SECTION 14. TRANSPORT INFORMATION International transport regulations US DOT: UN 1950, Aerosols, 2.1. LIMITED QUANTITY if shipped in containers less than or equal to 61.0 cubic inches (1.0 liter). SECTION 15. REGULATORY INFORMATION TSCA list TSCA - 5(a) Significant New Use Rule List of Chemicals : No substances are subject to a Significant New Use Rule. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) : No substances are subject to TSCA 12(b) export notification requirements. EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) 4,4'-Methylenediphenyl diisocyanate (MDI) * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity 12 / 14 US/EN

13 SAFETY DATA SHEET This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards SARA 302 SARA 313 : Acute Health Hazard Chronic Health Hazard Fire Hazard Reactivity Hazard Sudden Release of Pressure Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : The following components are subject to reporting levels established by SARA Title III, Section 313: Clean Air Act 4,4'-methylenediphenyl diisocyanate polymethylenepolyphenyle ne isocyanate The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): 4,4'-methylenediphenyl diisocyanate % The following chemical(s) are listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F): isobutane % dimethyl ether % propane % The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR ): 4,4'-methylenediphenyl % diisocyanate dimethyl ether % US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section ) 4,4'-methylenediphenyl diisocyanate isobutane dimethyl ether propane US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap ) urethane prepolymer blend (polyol blend) Not Assigned paraffin waxes and hydrocarbon waxes, chloro ,4'-methylenediphenyl diisocyanate polymethylenepolyphenylene isocyanate isobutane dimethyl ether propane US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) urethane prepolymer blend (polyol blend) Not Assigned paraffin waxes and hydrocarbon waxes, chloro / 14 US/EN

14 4,4'-methylenediphenyl diisocyanate polymethylenepolyphenylene isocyanate isobutane dimethyl ether propane US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65) This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA : On the inventory, or in compliance with the inventory DSL : On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION Further information Revision Date : 08/04/2017 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 14 / 14 US/EN

JM Roofing System Urethane Adhesive, Part 1

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Trade name : JM Roofing System Urethane Adhesive, Part 1 Manufacturer or supplier's details Company : Johns Manville Address : P.O. Box 5108 Denver, CO USA