MATERIAL SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
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1 MATERIAL SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name: TruTone Denture Base Acrylic Powder Product Number: 89249, 89250, 89251, 89252, 89253, 89254, 89255, 89256, MSDS Code Number: 167 Manufacturer: Dentsply Prosthetics Address: 570 West College Ave. York, PA Information Telephone Number: Emergency Telephone Number: Chemtrec Prosthetics_MSDS@Dentsply.com Product Use: Resin used in removable dental appliances. Date of Last Revision: December 7, 2007 SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Dust may cause mild eye and respiratory irritation. Individuals with sensitivity to methacrylates may develop an allergic reaction when exposed to this product. EU Preparation Classification (1999/45/EC): Not classified as dangerous SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS Ingredient CAS No./EINECS No. Percent EC Substance Classification (67/548/EEC) Polymethylmethacrylate Polymer / Styrene Ethyl Methyl Methacrylate Copolymer Proprietary Not applicable See Section 16 for further information on EU Classification. SECTION 4 FIRST AID MEASURES Eye Contact: Flush victim's eyes with large quantities of water. Get medical attention if irritation develops. Skin Contact: Wash skin with soap and water. Remove contaminated clothing and shoes. Get medical attention if irritation develops. Launder clothing before re-use. Ingestion: Do not induce vomiting. If conscious, give 8 ounces of water to dilute. Never give anything by mouth to an unconscious or convulsing person Get medical attention. Inhalation: Remove victim to fresh air. If breathing is difficult have qualified personnel administer oxygen. Get medical attention if symptoms persist. Page 1 of 5
2 SECTION 5 FIRE FIGHTING PROCEDURES Extinguishing Media: Water fog, carbon dioxide dry chemical. Do not use a water stream. Water stream can disperse dust in air producing a fire hazard and possible explosion hazard if exposed to ignition source. Firefighting Procedures: Firefighters should wear full emergency equipment and approved positive pressure self-contained breathing apparatus. Cool exposed intact containers with water spray. Unusual Fire/Explosion Hazards: High concentrations of dust in air may be explosive. Known or Anticipated Hazardous Products of Combustion: Thermal decomposition products may include carbon oxides, styrene and methyl methacrylate. SECTION 6 ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Carefully collect and place into a container for disposal. Remove all sources of ignition. Do not generate airborne dust. Do not allow water to enter lakes, streams, ponds, groundwater or soil. Spilled powder can be a slip hazard. Personal Precautions: Avoid contact with skin, eyes or clothing. Environmental Precautions: Prevent entry into sewers and waterways. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes and skin. Do not breathe dust. Wash thoroughly after handling. Wear protective clothing and equipment as described in Section 8. Use with adequate ventilation. Use good housekeeping to minimize accumulation of dust on equipment and surfaces. Keep away from sources of heat or ignition sources. Empty containers retain product residues can be hazardous. Follow all MSDS precautions when handling empty containers. Storage: Store in a dry, well ventilated area. Keep container closed when not in use. SECTION 8 EXPOSURE CONTROL/PERSONAL PROTECTION Occupational Exposure Limits: Polymethylmethacrylate Polymer / Styrene Methyl/Ethyl Methacrylate Copolymer 5 mg/m3 TWA OSHA PEL (as nuisance dust) Engineering Controls: Use with adequate general or local exhaust ventilation to minimize exposures levels. Personal Protective Equipment: Eye Protection: Chemical safety glasses with sideshields or chemical goggles. Skin Protection: Wear impervious gloves such as rubber to avoid skin contact. Respiratory Protection: None should be needed for normal use. If the exposure levels are excessive a NIOSH approved particulate respirator appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with OSHA and good industrial hygiene practice. Other Protective Clothing or Equipment: Impervious clothing as needed to prevent contact. A safety shower and eye wash should be available in the immediate work area. Page 2 of 5
3 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Pink free flowing powder with a faint methacrylate odor. Boiling Point: Not applicable Decomposition Point: 392 F (200 C) Freezing Point: Not applicable Specific Gravity: Not available Solubility in Water: Insoluble ph: Not applicable Vapor Pressure (mmhg): Not applicable Vapor Density: Not applicable Evaporation Rate: Not applicable Viscosity: Not applicable % Volatile by Volume: Not determined Flashpoint: 579 F (304 C) Flammable Limits in Air: Autoignition Temperature: Not available LEL: 20 g/m 3 UEL: Not applicable SECTION 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Excessive heat (temperatures greater than 572 F (300 C) Incompatibility with Other Materials: Avoid oxidizing agents. Keep away heat, sparks or ignition sources. Hazardous Decomposition Products: Thermal decomposition may release carbon oxides, styrene, ethyl methacrylate and methyl methacrylate. SECTION 11 TOXICOLOGICAL INFORMATION Potential Health Effects: Eyes: Dust may cause irritation with redness and tearing. Skin: No adverse effects are normally expected. Individuals with sensitivity to methacrylates may develop an allergic reaction. Ingestion: Swallowing large amounts may cause nausea, vomiting and diarrhea. Inhalation: Inhalation of dust may cause irritation of the nose, throat and upper respiratory tract. Chronic Health Effects: Prolonged or repeated overexposure may cause skin irritation or sensitization in some individuals. Carcinogenicity: None of the components of this product are listed as carcinogens by OSHA, IARC or NTP or the EU directive. Medical Conditions Aggravated by Exposure: Individuals with pre-existing skin and respiratory disorders may be at increased risk from exposure. Acute Toxicity Data: Polymethylmethacrylate Polymer / Styrene Methyl / ethyl Methacrylate Copolymer: No data available No data is currently available. SECTION 12 ECOLOGICAL INFORMATION SECTION 13 DISPOSAL CONSIDERATIONS Dispose in accordance with national and local regulations. DOT Shipping Name: Not Regulated DOT Hazard Class: N/A DOT Labels Required (49CFR ): N/A SECTION 14 TRANSPORT INFORMATION Page 3 of 5
4 IATA Shipping Name: Not Regulated IATA Hazard Class: N/A IATA Hazard Labels Required: N/A IMDG Shipping Name: Not Regulated IMDG Class: N/A IMDG Label: N/A U.S. FEDERAL REGULATIONS: SECTION 15 REGULATORY INFORMATION CERCLA: This product is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Not hazardous Section 313 Toxic Chemicals: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: This product is a medical device and not subject to U.S. STATE REGULATIONS California Proposition 65: This product contains the following substances known to the state of California to cause cancer and/or reproductive toxicity: None. INTERNATIONAL REGULATIONS: Canadian WHMIS Classification: Medical devices are not covered by WHMIS. Canadian Environmental Protection Act: This product is a medical device and not subject to chemical notification requirements. Canadian WHMIS Classification: Not a controlled product European Community Labeling: Not classified as hazardous European Inventory of New and Existing Chemicals Substances (EINECS): This product is a medical device and not subject to Australian Inventory of Chemical Substances: This product is a medical device and not subject to China Inventory of Existing Chemicals and Chemical Substances: This product is a medical device and not subject to Page 4 of 5
5 Japanese Existing and New Chemical Substances: This product is a medical device and not subject to Korean Existing Chemicals List: This product is a medical device and not subject to chemical notification requirements. Philippine Inventory of Chemicals and Chemical Substances: This product is a medical device and not subject to SECTION 16 OTHER INFORMATION HMIS Hazard Rating: Health 1 Fire Hazard 1 Reactivity 0 Revision Date: 12/07/2007 Supercedes: 6/19/1997 EU Classes and Risk Phrases for Reference (See Sections 2 and 3): None Page 5 of 5
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