27/06/2018 vpvb (Article 57e)

Transcription

1 SVHC DECLARATION We, Polinas Plastik Sanayii ve Ticareti A.S., hereby declare that our BOPP, BOPET, CPP, Coated and Barrier Films do not contain in their composition more than 0,1% (w/w) concentration of the substances listed in SVHC (substances very high concern). SUBSTANCE NAME EC NUMBER CAS NUMBER DATE OF REASON FOR INCLUSION INCLUSION Benzene-1,2,4-tricarboxylic acid 1,2 anhydride trimellitic anhydride; TMA Respiratory sensitising properties (Article 57(f) - human health) Benzo[ghi]perylene PBT (Article Decamethylcyclopentasiloxane D PBT (Article Dicyclohexyl phthalate DCHP Toxic for reproduction (Article 57c) Endocrine disrupting properties (Article Disodium octaborate Toxic for reproduction (Article 57c) Dodecamethylcyclohexasiloxane D PBT (Article Ethylenediamine EDA Respiratory sensitising properties (Article 57(f) - human health) Lead Toxic for reproduction (Article 57c) Octamethylcyclotetrasiloxane D PBT (Article Terphenyl, hydrogenated 27/06/ /01/2018 Carcinogenic (Article 57a)#PBT (Article #vpvb Benz[a]anthracene (Article 57e) /01/2018 Carcinogenic (Article 57a)#Mutagenic (Article Cadmium carbonate /01/2018 Carcinogenic (Article 57a)#Mutagenic (Article Cadmium hydroxide /01/2018 Carcinogenic (Article 57a)#Mutagenic (Article Cadmium nitrate Chrysene /01/2018 Carcinogenic (Article 57a)#PBT (Article #vpvb (Article 57e) Dodecachloropentacyclo[ ,9.02,13.05,10]octadeca-7, /01/2018 diene ( Dechlorane Plus ) Reaction products of 1,3,4-thiadiazolidine-2,5-dithione, formaldehyde and 4-heptylphenol, branched and linear (RP-HP) /01/2018 Endocrine disrupting properties (Article 57(f) - Perfluorohexane-1-sulphonic acid and its salts /07/2017 4,4'-isopropylidenediphenol /01/2017 Toxic for reproduction (Article 57c)#Endocrine disrupting properties (Article 57(f) - 4-heptylphenol, branched and linear /01/2017 Endocrine disrupting properties (Article 57(f) - Nonadecafluorodecanoic acid (PFDA) and its sodium and ammonium /01/2017 Toxic for reproduction (Article 57c)#PBT (Article salts Nonadecafluorodecanoic acid /01/2017 Toxic for reproduction (Article 57c)#PBT (Article Ammonium nonadecafluorodecanoate /01/2017 Toxic for reproduction (Article 57c)#PBT (Article Decanoic acid, nonadecafluoro-, sodium salt /01/2017 Toxic for reproduction (Article 57c)#PBT (Article p-(1,1-dimethylpropyl)phenol /01/2017 Endocrine disrupting properties (Article 57(f) - Benzo[def]chrysene Carcinogenic (Article 57a); Mutagenic ; Toxic for reproduction (Article 57c); PBT vpvb (Article 57 e) 1,3-propanesultone Carcinogenic (Article 57 a) 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol (UV-327) vpvb (Article 57 e) 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl)phenol (UV vpvb (Article 57 e) 350) Nitrobenzene Toxic for reproduction (Article 57 c) Perfluorononan-1-oic-acid and its sodium and ammonium salts ,2-benzenedicarboxylic acid, di-c6-10-alkyl esters; 1,2- benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate (EC No ) 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3- dioxane [1], 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5- methyl-1,3-dioxane [2] [covering any of the individual stereoisomers of [1] and [2] or any combination thereof] Bis (2-ethylhexyl)phthalate (DEHP) /12/17; 2008/10/ Toxic for reproduction (Article 57 c) PBT Toxic for reproduction (Article 57 c) Equivalent level of concern having ; Toxic for reproduction (article 57c) Cadmium fluoride Carcinogenic (Article 57 a); Mutagenic (Article 57 b); Toxic for reproduction (Article 57 c); Equivalent level of concern having probable serious effects to human health

2 reaction mass of 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3, Toxic for reproduction (Article 57 c) dithia-4-stannatetradecanoate and 2-ethylhexyl 10-ethyl-4-[[2-[(2- ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4- stannatetradecanoate (reaction mass of DOTE and MOTE) 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4- stannatetradecanoate (DOTE) Toxic for reproduction (Article 57 c) 2-benzotriazol-2-yl-4,6-di-tert-butylphenol (UV-320) PBT ; vpvb (Article 57 e) Cadmium sulphate , Carcinogenic (Article 57 a); Mutagenic (Article 57 b); Toxic for reproduction (Article 57 c); Equivalent level of concern having probable serious effects to human health 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (UV-328) PBT ; vpvb (Article 57 e) 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear Toxic for reproduction (Article 57 c) Sodium perborate; perboric acid, sodium salt ; Toxic for reproduction (Article 57 c) Sodium peroxometaborate Toxic for reproduction (Article 57 c) Cadmium chloride Carcinogenic (Article 57a); Mutagenic ; Toxic for reproduction (Article 57c); Equivalent level of concern having Cadmium sulphide Carcinogenic (Article 57a); Equivalent level to human health Disodium 4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]- 4-yl]azo] -5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate (C.I. Direct Black 38) Carcinogenic (Article 57a); Dihexyl phthalate Toxic for reproduction (Article 57 c); Imidazolidine-2-thione; (2-imidazoline-2-thiol) Toxic for reproduction (Article 57 c); Trixylyl phosphate Toxic for reproduction (Article 57 c); Disodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4- aminonaphthalene-1-sulphonate) (C.I. Direct Red 28) Carcinogenic (Article 57a); Lead di(acetate) Toxic for reproduction (Article 57 c); Cadmium Carcinogenic (Article 57a); Equivalent level to human health Ammonium pentadecafluorooctanoate (APFO) Toxic for reproduction (Article 57 c); PBT Pentadecafluorooctanoic acid (PFOA) Toxic for reproduction (Article 57 c); PBT Dipentyl phthalate (DPP) Toxic for reproduction (Article 57 c); 4-Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof] Equivalent level of concern having Cadmium oxide Carcinogenic (Article 57a); Equivalent level to human health Lead bis(tetrafluoroborate) Toxic for reproduction (Article 57 c) Lead dinitrate Toxic for reproduction (Article 57 c) Silicic acid, lead salt Toxic for reproduction (Article 57 c) 4-Aminoazobenzene Carcinogenic (Article 57a) Lead titanium zirconium oxide Toxic for reproduction (Article 57 c) Lead monoxide (lead oxide) Toxic for reproduction (Article 57 c) o-toluidine Carcinogenic (Article 57a) 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine Toxic for reproduction (Article 57 c) Silicic acid (H2Si2O5), barium salt (1:1), lead-doped Toxic for reproduction (Article 57 c) [with lead (Pb) content above the applicable generic concentration limit for toxicity for reproduction Repr. 1A (CLP) or category 1 (DSD),the substance is a member of the group entry of lead compounds, with index number in Regulation (EC) No 1272/2008] Trilead bis(carbonate)dihydroxide Toxic for reproduction (Article 57 c) Furan Carcinogenic (Article 57a) N,N-dimethylformamide Toxic for reproduction (Article 57 c) 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated [covering welldefined substances and UVCB substances, polymers and homologues] Equivalent level of concern having 4-Nonylphenol, branched and linear [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, covering also UVCB- and well-defined Equivalent level of concern having substances which include any of the individual isomers or a combination thereof] 4,4'-methylenedi-o-toluidine Carcinogenic (Article 57a) Diethyl sulphate Carcinogenic (Article 57a); Mutagenic Dimethyl sulphate Carcinogenic (Article 57a) Lead oxide sulfate Toxic for reproduction (Article 57 c) Lead titanium trioxide Toxic for reproduction (Article 57 c) Acetic acid, lead salt, basic Toxic for reproduction (Article 57 c) [Phthalato(2-)]dioxotrilead Toxic for reproduction (Article 57 c)

3 Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE) PBT ; vpvb (Article 57 e) N-methylacetamide Toxic for reproduction (Article 57 c) Dinoseb (6-sec-butyl-2,4-dinitrophenol) Toxic for reproduction (Article 57 c) 1,2-Diethoxyethane Toxic for reproduction (Article 57 c) Tetralead trioxide sulphate Toxic for reproduction (Article 57 c) N-pentyl-isopentylphthalate Toxic for reproduction (Article 57 c) Dioxobis(stearato)trilead Toxic for reproduction (Article 57 c) Tetraethyllead Toxic for reproduction (Article 57 c) Pentalead tetraoxide sulphate Toxic for reproduction (Article 57 c) Pentacosafluorotridecanoic acid vpvb (Article 57 e) Tricosafluorododecanoic acid vpvb (Article 57 e) Heptacosafluorotetradecanoic acid vpvb (Article 57 e) 1-bromopropane (n-propyl bromide) Toxic for reproduction (Article 57 c) Methoxyacetic acid Toxic for reproduction (Article 57 c) 4-methyl-m-phenylenediamine (toluene-2,4-diamine) Carcinogenic (Article 57a) Methyloxirane (Propylene oxide) Carcinogenic (Article 57a); Mutagenic Trilead dioxide phosphonate Toxic for reproduction (Article 57 c) o-aminoazotoluene Carcinogenic (Article 57a) 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear Toxic for reproduction (Article 57 c) 4,4'-oxydianiline and its salts Carcinogenic (Article 57a); Mutagenic Orange lead (lead tetroxide) Toxic for reproduction (Article 57 c) Biphenyl-4-ylamine Carcinogenic (Article 57a) Diisopentylphthalate Toxic for reproduction (Article 57 c) Fatty acids, C16-18, lead salts Toxic for reproduction (Article 57 c) Diazene-1,2-dicarboxamide (C,C'-azodi(formamide)) Equivalent level of concern having Sulfurous acid, lead salt, dibasic Toxic for reproduction (Article 57 c) 6-methoxy-m-toluidine (p-cresidine) Carcinogenic (Article 57a) Cyclohexane-1,2-dicarboxylic anhydride [1], cis-cyclohexane-1,2- dicarboxylic anhydride [2], trans-cyclohexane-1,2-dicarboxylic anhydride [3] [The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis- and transisomers [1] are covered by this entry] Equivalent level of concern having Dibutyltin dichloride (DBTC) Toxic for reproduction (Article 57 c) Henicosafluoroundecanoic acid vpvb (Article 57 e) Hexahydromethylphthalic anhydride [1], Hexahydro-4- methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3-methylphthalic anhydride [4] [The individual isomers [2], [3] and [4] (including their cis- and transstereo isomeric forms) and all possible combinations of the isomers [1] are covered by this entry] Equivalent level of concern having Lead cyanamidate Toxic for reproduction (Article 57 c) α,α-bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1- methanol (C.I. Solvent Blue 4) [with 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )] Carcinogenic (Article 57a) N,N,N',N'-tetramethyl-4,4'-methylenedianiline (Michler s base) Carcinogenic (Article 57a) 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6- (1H,3H,5H)-trione (β-tgic) Mutagenic Diboron trioxide Toxic for reproduction (Article 57 c) 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) Toxic for reproduction (Article 57 c) 4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with Carcinogenic (Article 57a) 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )] Lead(II) bis(methanesulfonate) Toxic for reproduction (Article 57 c) Formamide Toxic for reproduction (Article 57 c) [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien Carcinogenic (Article 57a) ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )] 1,2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) Toxic for reproduction (Article 57 c) [4-[[4-anilino-1-naphthyl][ Carcinogenic (Article 57a) (dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene] dimethylammonium chloride (C.I. Basic Blue 26) [with 0.1% of Michler's ketone (EC No ) or Michler's base (EC No )] 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione (TGIC) Mutagenic 4,4'-bis(dimethylamino)benzophenone (Michler s ketone) Carcinogenic (Article 57a) 4-(1,1,3,3-tetramethylbutyl)phenol Equivalent level of concern having (article 57 f) N,N-dimethylacetamide Toxic for reproduction (article 57 c) Phenolphthalein Carcinogenic (article 57 a) Lead diazide, Lead azide Toxic for reproduction (article 57 c), Lead dipicrate Toxic for reproduction (article 57 c) 1,2-dichloroethane Carcinogenic (article 57 a) Calcium arsenate Carcinogenic (article 57 a) Dichromium tris(chromate) Carcinogenic (article 57 a) 2-Methoxyaniline; o-anisidine Carcinogenic (article 57 a) Pentazinc chromate octahydroxide Carcinogenic (article 57 a) Arsenic acid Carcinogenic (article 57 a) Potassium hydroxyoctaoxodizincatedichromate Carcinogenic (article 57 a) Formaldehyde, oligomeric reaction products with aniline Carcinogenic (article 57 a) Lead styphnate Toxic for reproduction (article 57 c) Trilead diarsenate Carcinogenic and toxic for reproduction

4 Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight Carcinogenic (article 57 a) Bis(2-methoxyethyl) phthalate Toxic for reproduction (article 57 c) Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (µm) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight Carcinogenic (article 57 a) Bis(2-methoxyethyl) ether Toxic for reproduction (article 57 c) 2,2'-dichloro-4,4'-methylenedianiline Carcinogenic (article 57 a) Cobalt dichloride /06/20 - Carcinogenic and toxic for reproduction 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C Toxic for reproduction (article 57c) rich 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl Toxic for reproduction (article 57c) esters Strontium chromate Carcinogenic (article 57a) 1-Methyl-2-pyrrolidone Toxic for reproduction (article 57c) 1,2,3-Trichloropropane Carcinogenic and toxic for reproduction 2-Ethoxyethyl acetate Toxic for reproduction (article 57c) Hydrazine , Carcinogenic (article 57a) 57-8 Cobalt(II) diacetate Carcinogenic and toxic for reproduction Cobalt(II) sulphate Carcinogenic and toxic for reproduction 2-Ethoxyethanol Toxic for reproduction (article 57c) Acids generated from chromium trioxide and their oligomers. Names of the acids and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid , , Carcinogenic (article 57a) 2-Methoxyethanol Toxic for reproduction (article 57c) Chromium trioxide Carcinogenic and mutagenic (articles 57 a and 57 b) Cobalt(II) carbonate Carcinogenic and toxic for reproduction Cobalt(II) dinitrate Carcinogenic and toxic for reproduction Trichloroethylene Carcinogenic (article 57 a) Potassium dichromate Carcinogenic, mutagenic and toxic for Tetraboron disodium heptaoxide, hydrate Toxic for reproduction (article 57 c) Ammonium dichromate Carcinogenic, mutagenic and toxic for Boric acid , , Toxic for reproduction (article 57 c) Sodium chromate Carcinogenic, mutagenic and toxic for Disodium tetraborate, anhydrous , Toxic for reproduction (article 57 c) 43-4, Potassium chromate Carcinogenic and mutagenic (articles 57 a and 57 b). Acrylamide Carcinogenic and mutagenic (articles 57 a and 57 b) Lead sulfochromate yellow (C.I. Pigment Yellow 34) Carcinogenic and toxic for reproduction ) Lead chromate molybdate sulphate red (C.I. Pigment Red 104) Carcinogenic and toxic for reproduction Anthracene oil Carcinogenic1, PBT and vpvb (articles 57a, 57d and 57e) 2,4-Dinitrotoluene Carcinogenic (article 57a) Anthracene oil, anthracene paste, anthracene fraction Carcinogenic2, mutagenic3, PBT and vpvb Anthracene oil, anthracene-low Carcinogenic2, mutagenic3, PBT and vpvb Tris(2-chloroethyl)phosphate Toxic for reproduction (article 57c) Diisobutyl phthalate Toxic for reproduction (article 57c) Lead chromate Carcinogenic and toxic for reproduction Anthracene oil, anthracene paste Carcinogenic2, mutagenic3, PBT and vpvb Pitch, coal tar, high temp Carcinogenic, PBT and vpvb (articles 57a, 57d and 57e) Anthracene oil, anthracene paste,distn. lights Carcinogenic2, mutagenic3, PBT and vpvb Lead hydrogen arsenate Carcinogenic and toxic for reproduction Benzyl butyl phthalate (BBP) Toxic for reproduction (article 57c)

5 Bis (2-ethylhexyl)phthalate (DEHP) Toxic for reproduction (article 57c) 5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) vpvb (article 57e) Diarsenic trioxide Carcinogenic (article 57a) Bis(tributyltin)oxide (TBTO) PBT (article Triethyl arsenate Carcinogenic (article 57a) Diarsenic pentaoxide Carcinogenic (article 57a) Sodium dichromate , Carcinogenic, mutagenic and toxic for reproduction (articles 57a, 57b and 57c) Dibutyl phthalate (DBP) Toxic for reproduction (article 57c) 4,4'- Diaminodiphenylmethane (MDA) Carcinogenic (article 57a) Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) PBT and vpvb (articles 57 d and 57 e) Anthracene PBT (article Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified: Alpha-hexabromocyclododecane Betahexabromocyclododecane Gamma-hexabromocyclododecane and , ( ) ( ) ( ) PBT (article