Material Safety Data Sheet Material Name: Warren Premium Oil Dry Absorbent

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1 * * * Section 1 - Chemical Product and Company Identification * * * Part Number: All containers Chemical Name: Diatomaceous Earth, Calcined Product Use: Industrial Absorbent Manufacturer Information Warren Oil Phone: Hwy. 301 Chemtrec number Dunn, North Carolina Domestic: International: * * * Section 2 - Composition / Information on Ingredients * * * CAS # Component Percent Diatomaceous Earth, Calcined Crystalline Silica (Quartz) < Silica, cristobalite < 1 Component Information/Information on Non-Hazardous Components This product is considered hazardous under 29 CFR (Hazard Communication). * * * Section 3 - Hazards Identification * * * Emergency Overview Product is a non-flammable, buff to off-white granular solid with no odor. This product may be harmful by inhalation. Potential Health Effects: Eyes This product may produce mechanical eye irritation. Potential Health Effects: Skin This product may produce mechanical skin irritation. Potential Health Effects: Ingestion No significant adverse effects are expected upon ingestion of the product. Ingestion of large amounts of this product may result in gastrointestinal disturbances. Potential Health Effects: Inhalation This product may cause irritation to the respiratory system. This material may release particles of crystalline silica (quartz). Overexposure to airborne particles may cause lung damage including a risk of cancer. HMIS Ratings: Health: 1 Fire: 0 Reactivity: 0 Pers. Prot.: Goggles Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 4 - First Aid Measures * * * First Aid: Eyes Flush eyes with large amounts of water for 15 minutes. Get medical attention if eye irritation develops or persists. First Aid: Skin Rinse skin with water to remove dusts. Get medical attention if skin disorder develops. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. First Aid: Inhalation If powder or dust from this material is inhaled, remove the person immediately to fresh air. Get medical attention if symptoms develop or persist. Page 1 of 5 Issue Date: Print Date: 11/15/2007

2 * * * Section 5 - Fire Fighting Measures * * * Flash Point: Not applicable Method Used: Not applicable Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable Auto Ignition: Not applicable Flammability Classification: Not flammable Rate of Burning: Not applicable General Fire Hazards Product is not flammable. Product may be used to extinguish fires. Hazardous Combustion Products No combustion products are known. Any absorbed materials may be released upon combustion. Extinguishing Media Fire Fighting Equipment/Instructions NFPA Ratings:Health: 1 Fire: 0 Reactivity: 0 Other: Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures None necessary Clean-Up Procedures Vacuum or sweep up spilled material. Product may be reused. Evacuation Procedures Special Procedures This product is designed to absorb oil and other spills. If the spills contain hazardous material wear appropriate personal protection equipment. * * * Section 7 - Handling and Storage * * * Handling Procedures Avoid getting this material into contact with your eyes. Avoid prolonged or repeated breathing of this material. Use this product with adequate ventilation. Storage Procedures Keep the container tightly closed and dry. * * * Section 8 - Exposure Controls / Personal Protection * * * Exposure Guidelines Observe recommended exposure limits. B: Component Exposure Limits Crystalline Silica (Quartz) ( ) ACGIH: 0.1 mg/m3 TWA (this TLV is for the respirable fraction of dust) OSHA: respirable dust: 0.1 mg/m3 TWA NIOSH: as respirable dust: 0.05 mg/m3 TWA; NIOSH Potential Occupational Carcinogen - see Appendix A Silica, cristobalite ( ) ACGIH: 0.05 mg/m3 TWA (this TLV is for the respirable fraction of dust) OSHA: respirable dust: 0.05 mg/m3 TWA Engineering Controls Use general ventilation. Additional area ventilation or local exhaust may be required to maintain air concentrations below recommended exposure limits. Page 2 of 5 Issue Date: 11/14/07 Print Date: 11/15/2007

3 PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear dust goggles. Personal Protective Equipment: Skin Wear impervious gloves for prolonged contact. Personal Protective Equipment: Respiratory. If ventilation is not sufficient to effectively prevent buildup of dusts, appropriate NIOSH/MSHA respiratory protection must be provided. Personal Protective Equipment: General If handling used absorbent, wear personal protection equipment applicable for that material. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Buff to off-white Odor: None Physical State: Solid particulate ph: 7 (10% Slurry) Vapor Pressure: Not applicable Vapor Density: Not applicable Boiling Point: Not applicable Melting Point: Not applicable Solubility (H2O): <2% Specific Gravity: 2.2 * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Chemical Stability: Conditions to Avoid None known. Incompatibility Hydrofluoric acid and hydrogenated vegetable oils. Hazardous Decomposition None known. Hazardous Polymerization Hazardous polymerization will not occur. * * * Section 11 - Toxicological Information * * * Acute Toxicity Inhalation of this product may cause irritation including dryness and congestion upon acute exposure. Prolonged or repeated inhalation overexposure may result in silicosis, a progressive sometimes deadly lung disease characterized by a slowly progressive fibrosis of the lungs, which may result in impairment of lung function and predisposition to secondary lung infections. B: Component Analysis - LD50 Carcinogenicity Silica, cristobalite has been shown to cause tumors of the blood in rats when administered intrapleurally. Silica crystalline, quartz has been shown to cause liver tumors when administered by inhalation to rats; lung tumors when administered to rats intratracheally; blood tumors when administered to rats intrapleurally. B: Component Carcinogenicity Crystalline Silica (Quartz) ( ) NIOSH: occupational carcinogen NTP: respirable dust: suspect carcinogen (Listed under 'Silica, crystalline') (Possible Select Carcinogen) IARC: Monograph 68, 1997 (inhaled in the form of quartz or cristobalite from occupational sources) (Group 1 (carcinogenic to humans)) Page 3 of 5 Issue Date: 11/14/07 Print Date: 11/15/2007

4 Silica, cristobalite ( ) NTP: respirable dust: suspect carcinogen (Listed under 'Silica, crystalline') (Possible Select Carcinogen) Epidemiology No epidemiological data is available for this product. Neurotoxicity Mutagenicity Teratogenicity * * * Section 12 - Ecological Information * * * Ecotoxicity No information available for the product. Environmental Fate * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions No information available for the product. B: Component Waste Numbers Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Not regulated as dangerous goods. Hazard Class: NA UN/NA #: NA Packing Group: NA Required Label(s): NA Additional Info.: NA * * * Section 15 - Regulatory Information * * * US Federal Regulations No additional information. B: Component Analysis None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR ), or CERCLA (40 CFR 302.4). State Regulations Other state regulations may apply. Check individual state requirements. B: Component Analysis - State Component CAS # CA FL MA MN NJ PA Crystalline Silica (Quartz) N Y Y Y Y Y Silica, cristobalite N Y Y Y Y Y Other Regulations No additional information. B: Component Analysis - Inventory Page 4 of 5 Issue Date: 11/14/07 Print Date: 11/15/2007

5 Component CAS # TSCA DSL EINECS Diatomaceous Earth, Calcined Yes Yes Yes Crystalline Silica (Quartz) Yes Yes Yes Silica, cristobalite Yes Yes Yes C: Component Analysis - WHMIS IDL * * * Section 16 - Other Information * * * Other Information This information is, to the best of Warren Oil s knowledge and belief, accurate and reliable. However, no representation, warranty, or guarantee is made to its accuracy, reliability, or completeness. It is the user's responsibility to satisfy himself as to the suitableness and completeness of such information for his own particular use. New MSDS: 9/19/97. Key/Legend N = No; Y = Yes; ppm - parts per million; mg/m3 = milligrams per cubic meter of air; ACGIH = American Conference of Governmental Industrial Hygienists; OSHA = Occupational Safety and Health Administration; TLV = Threshold Limit Value; NIOSH = National Institute of Occupational Safety and Health; NTP = National Toxicology Program; IARC = International Agency for Research on Cancer; EPA = Environmental Protection Agency. Page 5 of 5 Issue Date: 11/14/07 Print Date: 11/15/2007

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