MCPD and Glycidol in Edible Oils Post Refining Formation, Decomposition and Analysis SGS Germany GmbH J. Kuhlmann
|
|
- Laurel Eugenia Randall
- 6 years ago
- Views:
Transcription
1 MCPD and Glycidol in Edible Oils Post Refining Formation, Decomposition and Analysis SGS Germany GmbH J. Kuhlmann 1
2 Introduction, & Glycidol: Derivates of glycerol free : non-genotoxic carcinogen MCPD fatty acid esters release most of MCPD during digestion (3-Chloropropane-1,2-diol) (2-Chloropropane-1,3-diol) free glycidol: reproductive toxicity [1B] germ cell mutagenicity [2] carcenogenicity [1B etc. glycidyl fatty acid esters release glycidol completely during digestion [Classification according to Regulation (EC) No 1272/28 [EU-GHS/CLP]] - HCl + HCl Glycidol 2
3 (fatty acid) bound Glycidol & MCPD in oils & fats Introduction crude oil refining refined oil Bound MCPD & Glycidol are generated mainly during deodorisation at high temperatures. The vast majority of refined oils & fats contain bound MCPD & glycidol potential of contaminant formation is dependant upon the oil type & quality degree of formation is dependant upon refining conditions mono esters are more volatile and might get into equilibrium of formation evaporation 3
4 Introduction Precursors of bound Glycidol & MCPD in natural oils Mono(acyl)glycerides / Di(acyl)glycerides / Tri(acyl)glycerides e.g. > 2 C - H 2 O/-FA bound glyicdol Glycidyl fatty acid esters mono esters rather volatile and less stable < 2 C + HCl* bound MCPD e.g. *natural sources e.g. FeCl x, chlorinated phytosphingosines 1) 2- & fatty acid esters - H 2 O/-FA 1-/2- mono esters << 1,2-/1,3- di esters less volatile and highly stable Glycidylpalmitate -1,2-bis-pamitoyl ester 1) K. Nagy et al.: Mass-defect filtering of isotope signatures to reveal the source of chlorinated palm oil contaminants; Food Addit. Contam. 211, 28,
5 Analytical approach glycidol fatty acid(s) 3-MBPD Indirect analysis by SGS 3-in-1 method (identical to AOCS Official Method Cd 29b-13) Oil containing a complex mixture of 2- & - & glycidyl mono- & diesters SGS 3-in-1 -method: -better glycidol-precision as DGF C-VI 18 (1) -lowest LOQs -covers bound & free analytes -higher troughput in comparison to direct analysis ester cleavage (alkaline, mild) matrix clean-up (e.g. (l/l) - extraction) derivatisation (e.g. HFBA/acetone/PBA) Glycidol GC-MS 5
6 Analytical approach glycidol fatty acid(s) 3-MBPD Indirect analysis by SGS 3-in-1 method (identical to AOCS Official Method Cd 29b-13) Oil containing a complex mixture of 2- & - & glycidyl mono- & diesters SGS 3-in-1 -method: -better glycidol-precision as DGF C-VI 18 (1) -lowest LOQs -covers bound & free analytes -higher troughput in comparison to direct analysis ester cleavage (alkaline, mild) Glycidol transformation into MBPD! matrix clean-up (e.g. (l/l) - extraction) derivatisation (e.g. HFBA/acetone/PBA) Glycidol Glycidol as 3-MBPD GC-MS 6
7 Formation of bound MCPD and glycidol Analyte formation by simple heat treatment of oils & fats Temperature induced formation of and glycidol in edible oils and fats Analyte conce entration Temperatureramping. 27 C 2 C ca. 2 min 15 min 7
8 Formation of bound MCPD and glycidol Glycidol Analyte formation by simple heat treatment of oils & fats Temperature Temperature induced induced formation formation of of glycidol and glycidol in edible in edible oils andoils fats and fats Glycidol[ [mg/kg] Analyte conce entration C LOQ:,1 mg/kg Liquid frying Temperature-. fat Butter,3 % saltramping Sunflower oil- margarine Spreadfat; butter-rapeseedoil, 1 % salt Vegetable Margarine,.3 % salt Butter, unsalted Spread fat; butter-rape seed oil, unsalted Clarified butter Crude palm oil Olive oilrefined+ e.v. 27 C X Olive oile.v.+ 3 % NaCl Refined sunflower oil Refined coconut fat Olive oil extra virgin Refined rape seed oil Cold press. sunflower oil Refined safflour oil Cold press. rape seed oil ca. 2 min 15 min -The generation of bound glycidol starts at apr. 25 C by heating of various oils, fats and spread fats - The glycidol-formation ability of various oils, fats & spreads is very similar except for crude palm oil 8
9 Formation formation by simple heat treatment of oils & fats Temperature induced formation of bound in edible oils and fats 3,6 3-MC CPD [mg/kg] 2,4 1,2 Crude palm oil X Olive oil e.v. + 3 % NaCl refined oils LOQ:.1 mg/kg ca. 2 min 15 min non-refined oils; Olive rape seed - sunflower There was no significant formation of bound observed when different pristine or refined oils were heated up to 27 C, Refined - except rape seed foroil crude palm Refined oilpalm oil Olive oil ref. & e.v. High loads of sodium chloride present during heating of olive oil caused medium levels of bound 3- MCPD Refined sunflower oil 9
10 Temperature induced formation of in edible oils and fats Formation formation by simple heat treatment of spreads etc. 13 Butter,3 % salt [m mg/kg] 97, ,5 Liquid frying fat, 1.5% salt Vegetable Margarine,.3 % salt Butter, unsalted Sunflower oil based margarine Clarified butter ca. 2 min 15 min High loads of bound were generated; salt content correlated to MCPD-formation The formation of bound started at apr. 17 C 19 C 1
11 Temperature induced formation of in edible oils and fats Formation formation by simple heat treatment of spreads etc. 13 SpreadfatA; butter-rapeseedoil, 1 % seasalt Butter,3 % salt [m mg/kg] 97, ,5 Spread fat C; butter-rape seed oil Liquid frying fat, 1.5% salt Spread fat B; butter-rape seedoil, 1 % salt Vegetable Margarine,.3 % salt Butter, unsalted Sunflower oil based margarine Clarified butter ca. 2 min 15 min High loads of bound were generated; salt content correlated to MCPD-formation The formation of bound started at apr. 17 C 19 C The observed generation slopes were different in dependancy upon the spread composition 11
12 [mg/k kg] Formation Chemically induced formation of bound MCPD in olive oil Generation of bound glycidol and MCPD during heat treatment of customary extra virgine oliveoilcontaining,13 % FeCl. 3 6 H 2 O ca. 2 min 15 min 12
13 Formation Chemically induced formation of bound MCPD in olive oil Generation of bound MCPD during heat treatment of customary extra virgine olive oil containing,7 % AlCl. 3 6 H 2 O [mg/k kg] ca. 2min 2 min 13
14 [mg/k kg] Formation Chemically induced formation of bound MCPD in olive oil Generation of of ofboundmcpd glycidol and duringheattreatmentoffryingfaton MCPD treatment treatment customary customary extra palmoilbasein virgine extra olive virgine oil oliveoilcontaining,13 presenceof2.1 containing,7 % AlCl %. FeCl H 3 2 O6 H 2 O sum MCPD ca. 2min ca. ca. min 2 min 2 min 15 min 14
15 Formation Chemically induced formation of bound MCPD in olive oil Generation Generation of of bound of ofboundmcpd glycidol and duringheattreatmentoffryingfaton MCPD treatment treatment customary frying customary extra palmoilbasein fat virgine on extra olive virgine oil base oliveoilcontaining,13 presenceof2.1 containing,7 of % 5 AlCl %. FeCl.. AlCl H 3 2 O6 H 2 O [mg/k kg] sum sum MCPD ca. 2min ca. ca. min 2 min 2 min 15 2 min AlCl 3. 6 H 2 O acted as much stronger MCPD-precurser than FeCl 3. 6 H 2 O Around 23 C starts to isomerise into to generate an equilibrium of apr. 2:1 ratio With waterfree AlCl 3 bound is generated already at room temperature ( 1%) 15
16 Formation Can bound MCPD be generated during industrial or individual frying of foods? Olive oil extra virgin Olive oil in parts refined Butter Liquid paraffine frying oil bound bound bound glycidol x 3! analyte mg/kg f start start afo: after frying of m.t.: moderate temperature h.t.: high temperature 16
17 Formation Can bound MCPD be generated during industrial or individual frying of foods? 2 Shift of analyte contents in frying oils after theire use for private houshold frying of various foods mg/kg 1,5 1,5 -,5 Glycidol Glycidol 17
18 Formation Can bound MCPD be generated during industrial or individual frying of foods? 2 Fomation of bound MCPD during industrial frying 16 mg/kg bound bound bound glycidol Unter certain conditions private or industrial frying may be a relevant source of bound MCPD as well. 18
19 Removal Is removal of the analytes in edible oils by acid treatment in the heat feasible? Determination of bound glycidol and MCPD during heat treatment of frying fat on palm oil base 2 15 glycidol [mg/kg] 1 temp.-ramping 5 ca. 35 min 3 min 4 h 19
20 Removal [mg/kg] Is removal of the analytes in edible oils by acid treatment in the heat feasible? Determination of ofboundglycidol and andmcpd duringheattreatmentofrefinedpalmoilin treatment frying fat on oil presenceof.7 base % AlF. 3 3 H 2 O glycidol glycidol temp.-ramping Glycidol minimum: 23 C ca. 35 min ca. 3 min 3 min 2 min4 h 2
21 Removal [mg/kg] g] Is removal of the analytes in edible oils by acid treatment in the heat feasible? Determination of ofboundglycidol and andmcpd duringheattreatmentofrefinedpalmoilin treatment frying fat on oil presenceof.7 base % AlF % H. 33 BO 3 H 32 O glycidol glycidol glycidol temp.-ramping Glycidol Glycidol minimum: minimum: 23 C 25 C ca. 35 min ca. 3 min 3 min 2 min4 h Glycidyl esters can be removed in oils & fats by heating in presence of certain inorganic salts/acids 21
22 Stability Long-term stability of analytes during sample storage Repeated analysis of one & the same sample: Reference oil: mix rape seed oil /palm oil (stored at room temperature),8 mg g/kg,6,4,2, glycidol 22
23 Stability Long-term stability of analytes during sample storage Repeated analysis of one & the same sample: Reference oil: mix rape seed oil /palm oil (stored at room temperature) 1 RBD Palm oil: 3 aliquotsstoredatdifferent stored at different temperatures (RT vs.6 C vs.-2 C) mg g/kg,8,6 mg/ /kg,4,2, 12, 12, 1, 1, 8, 8, 6, 6, 4, 4, 2, 2,,, -2 C / RT / 6 C / C -2 C C / Glycidol RT RT / Glycidol 6 C C / Glycidol glycidol 6 C / Glycidol RT / Glycidol -2 C / Glycidol 6 C / RT / -2 C / Bound MCPD seems to be of high long-term stability whereas bound glycidol can exhibit significant decomposition at low temperatures in some cases. 23
24 Conclusions The formation of bound MCPD is not only related to high temperature deodorisation In presence of suitable precusors/catalysts/reactands bound MCPD might be formed as well at medium temperatures e.g. during frying of food, especially fish & meat The reaction of waterfree AlCl 3 with oils can be used as easy snthesis of bound As many others before we found no easy way to remove bound once it has appeared in oils & fats Bound glycidol seems to have a minimum in stability at temperatures around 6 C. On the other hand it might be removed at high temperatures by the presence of certain inorganic acidic components. 24
25 SGS Germany GmbH Dr. Jan Kuhlmann Weidenbaumsweg 137 D-2135 Hamburg Tel.: +49 () mobile: +49 () Thank you for your kind attention! 25
Analysis & occurrence of bound glycidol and MCPD in oil containing foods SGS Germany GmbH J. Kuhlmann
Analysis & occurrence of bound glycidol and MCPD in oil containing foods SGS Germany GmbH J. Kuhlmann 1 Introduction 2-MCPD, 3-MCPD & Glycidol: Glycerolderivates + HCl - H 2 O 3-MCPD (3-Chloropropane-1,2-diol)
More informationSGS Germany GmbH J. Kuhlmann
Symposium on MCPD Esters and Glycidyl Esters Analytics, Toxicology, Risk Assessment, Mitigation Where we are today? 20-21 June 2017, Rocket Tower Conference Center, Berlin Symposium on MCPD Esters and
More informationMCPDs Esters & Glycidyl Esters: Validation of the Analytical Method and Occurrence in Vegetable Oils
MCPDs Esters & Glycidyl Esters: Validation of the Analytical Method and Occurrence in Vegetable Oils Florence LACOSTE, ITERG Recherche. Innovation. Qualité SISSG Workshop on 3-MCPD in Vegetable Oils UDINE,
More informationAnalytical solutions today available for measuring 2/3 MCPD and GE and other critical contaminants in food oils J. Kuhlmann, SGS, Hamburg, Germany
Analytical solutions today available for measuring 2/3 MCPD and GE and other critical contaminants in food oils J. Kuhlmann, SGS, Hamburg, Germany jan.kuhlmann@sgs.com 1 Introduction 3-MCPD 3-mono-chloropropane-1,2-diol
More informationThis document is a preview generated by EVS
INTERNATIONAL STANDARD ISO 18363-1 First edition 2015-08-15 Animal and vegetable fats and oils Determination of fatty-acid-bound chloropropanediols (MCPDs) and glycidol by GC/MS Part 1: Method using fast
More informationCurrent status of MCPD and Glycidol Analysis in Oils
Current status of MCPD and Glycidol Analysis in Oils Mark W. Collison, Ph. D., Director, Analytical Chemistry Research Division Archer Daniels Midland Company and Chair of the Uniform Methods Committee
More informationIndirect methods for the Analysis of MCPD and Glycidyl Esters: A Critical Overview
Indirect methods for the Analysis of MCPD and Glycidyl Esters: A Critical Overview Karel Hrncirik Unilever, The Netherlands ILSI EUROPE WORKSHOP ON MCPD AND GLYCIDYL ESTERS IN FOOD PRODUCTS 9-10 November
More informationMethods and Materials
Introduction Esterified and free forms of 2MCPD, 3MCPD and glycidol (Figure 1) are heatinduced contaminants found in various types of processed food. [1] Following ingestion, esterified forms of these
More informationA review on ten years 3-MCPD esters and Glycidyl esters in fats and oils
A review on ten years 3-MCPD esters and Glycidyl esters in fats and oils Bertrand Matthäus Max Rubner-Institut, Institut für Sicherheit und Qualität bei Getreide, Arbeitsgruppe für Lipidforschung, Schützenberg
More informationAdvantages and disadvantages of different analytical techniques used to determine chloropropanols in food lipid matrices
Advantages and disadvantages of different analytical techniques used to determine chloropropanols in food lipid matrices Agnieszka Głowacz, Renata Jędrkieiwcz Gdańsk University of Technology Department
More informationREP18/CF-Appendix VI 1
REP18/CF-Appendix VI 1 APPENDIX VI PROPOSED DRAFT CODE OF PRACTICE FOR THE REDUCTION OF 3-MONOCHLOROPROPANE-1,2- DIOL ESTERS (3-MCPDE) AND GLYCIDYL ESTERS (GE) IN REFINED OILS AND FOOD PRODUCTS MADE WITH
More informationThe Development and Application of the Automated Method for the Quantification of 3-MCPD-,2-MCPD-, and Glycidylesters in Edible Oils and Fats
The Development and Application of the Automated Method for the Quantification of 3-MCPD-,2-MCPD-, and Glycidylesters in Edible Oils and Fats Ralph Zwagerman, 21-06-2017, 3-MCPD Symposium, Berlin 1 Motivation
More informationToolbox for the Mitigation of 3-MCPD Esters and Glycidyl Esters in Food
Toolbox for the Mitigation of 3-MCPD Esters and Glycidyl Esters in Food Dr. Birgit Christall Bund für Lebensmittelrecht und Lebensmittelkunde e. V. (BLL) German Federation for Food Law and Food Science
More informationMCPD ESTERS AND GLYCIDYL ESTERS. Review of mitigation measures Revision 2015
Ref. 15SAF108 MCPD ESTERS AND GLYCIDYL ESTERS Review of mitigation measures Revision 2015 Table of Contents 1. Background... 2 2. Purpose and limitations of the document... 2 3. Formation of 3-MCPD Esters
More informationSTUDY OF 3-MCPD ESTERS AND GLYCIDYL ESTERS IN MALAYSIA
DGF Symposium on MCPD Esters and Glycidyl Esters, 20 21 June 2017, Berlin, Germany STUDY OF 3-MCPD ESTERS AND GLYCIDYL ESTERS IN MALAYSIA Raznim Arni Abd. Razak Product Development & Advisory Services
More informationComparison of Indirect and Direct Quantification of Glycidol Fatty Acid Ester in Edible Oils
Journal of Oleo Science Copyright 2010 by Japan Oil Chemists Society RAPID PAPER Comparison of Indirect and Direct Quantification of Glycidol Fatty Acid Ester in Edible Oils Masao Shimizu 1, Naoto Kudo
More information3-MCPD esters in edible oils: analytical aspects
French Institute for Fats and Oïl 3-MCPD esters in edible oils: analytical aspects Florent JOFFRE, Hugues GRIFFON, Bénédicte SOULET and Florence LACOSTE 3-MCPD esters in oils: context Analysis of 3-MCPD:
More informationApplication Note No. 301/2017
Application Note No. 301/2017 3-MCPD and glycidol in infant formula SpeedExtractor E-916, Multivapor P-6: Extraction of 3-MCPD and glycidyl-esters from infant formula www.buchi.com Quality in your hands
More informationProduction and trade of vegetable oils p. 1 Extraction, refining and processing p. 1 Vegetable oils--production, disappearance and trade p.
Production and trade of vegetable oils p. 1 Extraction, refining and processing p. 1 Vegetable oils--production, disappearance and trade p. 3 Soybean oil p. 7 Palm oil p. 8 Rapeseed/canola oil p. 8 Sunflowerseed
More informationSECTION III ANIMAL OR VEGETABLE FATS AND OILS AND THEIR CLEAVAGE PRODUCTS; PREPARED EDIBLE FATS; ANIMAL OR VEGETABLE WAXES CHAPTER 15
SECTION III ANIMAL OR VEGETABLE FATS AND OILS AND THEIR CLEAVAGE PRODUCTS; PREPARED EDIBLE FATS; ANIMAL OR VEGETABLE WAXES CHAPTER 15 ANIMAL OR VEGETABLE FATS AND OILS AND THEIR CLEAVAGE PRODUCTS; PREPARED
More information3-MCPD & 3-MCPD ester Food processed contaminants
-MCPD esters: Current Knowledge and Status Nuzul Amri Ibrahim Muhamad oddy amli aznim Arni Abdul azak Ainie Kuntom Malaysian Palm il Board Introduction utline -MCPD and -MCPD ester esearch by others Mechanism
More informationKEYWORDS ABSTRACT. 3-MCPD, Glycidol, edible oil, lab automation, ISO , AOCS Cd 29c-13, DGF C-VI 18 (10)
Fully Automated Determination of 3-MCPD and Glycidol in Edible Oils by GC/MS Based on the Commonly Used Methods ISO 18363-1, AOCS Cd 29c-13, and DGF C-VI 18 (10) Dominik Lucas, Andreas Hoffmann, Carlos
More informationUpdate on the Development of a Sensitive, Accurate, and User- Friendly Method for the Direct Determination of 3-MCPD 3
Update on the Development of a Sensitive, Accurate, and User- Friendly Method for the Direct Determination of 3-MCPD 3 Esters J. D. Pinkston, P.J. Stoffolano, P. Y. Lin The Procter & Gamble Company, Winton
More informationFatty acid esters of chloropropanols and glycidol in foods analysis and exposure
Fatty acid esters of chloropropanols and glycidol in foods analysis and exposure International Association for Food Protection European Symposium on Food Safety Warsaw 21-23 May 2012 Colin Crews 1 MCPD
More informationMitigation of 3-monochloropropane-1,2-diol and glycidol esters in refined palm oil via modified refining process. Chin Ping TAN
Mitigation of 3-monochloropropane-1,2-diol and glycidol esters in refined palm oil via modified refining process Chin Ping TAN Contents Introduction Recent scientific opinion on MCPDE and GE issues (2016
More informationDirect determination of MCPD esters and glycidyl esters by LC-TOFMS
1 AOCS Meeting May 16-19, Phoenix, AZ Direct determination of MCPD esters and glycidyl esters by LC-TOFMS Mark W. Collison, Ph. D., Director, Analytical Chemistry, Troy Haines, Analytical Laboratory Manager,
More information3-MCPD Esters in Edible Oils Current Knowledge
ILSI SEA Region 6th Asian Conference on Food and Nutrition Safety (Nov 2012) http://www.ilsi.org/sea_region/pages/vieweventdetails.aspx?webid=4d540914-eeb6-40e4-89eb-0b73ba3d76c1&listid=478be3cb-581b-4ba2-a280-8e00ccb26f9c&itemid=66
More informationCobraCZ/shutterstock.com. 6 BfR 2 GO
CobraCZ/shutterstock.com 6 BfR 2 GO HEAT-INDUCED CONTAMINANTS Dangerous substances from the pan, the deep fryer and the oven: heating causes changes in unprocessed foods or ingredients. It makes them easier
More informationLimitation of Indirect Quantification for Glycidol Fatty Acid Ester in Edible Oils
Limitation of Indirect Quantification for Glycidol Fatty Acid Ester in Edible Oils Kao Corporation Global RD, Healthcare Food Labs. Indirect Quantification for GE (DGF Method) Combination of two different
More informationAttention is drawn to the following places, which may be of interest for search:
A23D EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS (animal feeding-stuffs A23K 10/00-A23K 20/30, A23K 30/00-A23K 50/90; foods or foodstuffs containing edible oils or fats A21D, A23C,
More informationGC/MS Application Note
GC/MS Application Note Determination of 2- and 3-MCPD and glycidyl esters in foodstuff www.palsystem.com Determination of MCPD and glycidyl esters in foodstuff Tobias Uber, Marco Nestola Axel Semrau GmbH,
More informationAnalysis of MCPD- and Glycidyl- Esters in edible oils
Analysis of MCPD- and Glycidyl- Esters in edible oils IZMIR, TURKEY Dubois Mathieu Nestlé-Research-Center Quality and Safety Agenda 2 MCPD- and glycidyl-esters Esters of Mono-Chloro-Propane-Diol H ccurrence:
More informationHow to choose your culinary oil
How to choose your culinary oil 12 February 2014 There is an increasing variety of vegetable oils for cooking and food preparation. How do you decide which one to use? Considerations include taste, functional
More informationLABORATORIES. Mar Verhoeff. Lab. Dr. A. Verwey Rotterdam. MVO course, June 2016
LABORATORIES Mar Verhoeff Lab. Dr. A. Verwey Rotterdam MVO course, June 2016 1 Agenda Role of an independent laboratory Contract organisations Contractual methods of analyses Types of analyses Laboratory
More informationDevelopments in Edible Oil Refining for the Production of High Quality Food Oils
1 101 st ACS Annual Meeting Phoenix, Arizona Developments in Edible il Refining for the Production of High Quality Food ils Wim De Greyt Desmet Ballestra Group, Zaventem, Belgium 101 st ACS Annual Meeting
More information14th Biennial Sunflower Conference June Consumer Trends & Usage of Fats & Oils. Charles Aldersey
14th Biennial Sunflower Conference June 2003 Consumer Trends & Usage of Fats & Oils Charles Aldersey Contents World Usage of Fats & Oils World Consumption Trends in Fats & oils Domestic Consumer Trends
More informationIn Situ Destruction of MCPD and Glycidyl Esters during Triglyceride Production
In Situ Destruction of MCPD and Glycidyl Esters during Triglyceride Production Joseph ongione Jenifer Heydinger Galante Nothing contained herein grants or extends a license, express or implied, in connection
More informationCurrent status of Benchmark Dose Modeling for 3-Monochloropropane-1,2-diol (3-MCPD)
Current status of Benchmark Dose Modeling for 3-Monochloropropane-1,2-diol (3-MCPD) Michael Dourson, PhD, DABT, FATS, FSRA Professor, Risk Science Center (formerly TERA) Department of Environmental Health
More informationAnalysis of MCPD- and Glycidyl- Esters in edible oils
Analysis of MCPD- and Glycidyl- Esters in edible oils Dubois Mathieu Nestlé Research Center Lausanne Switzerland Extraction methods Direct vs Indirect method comparison Analytical standard management LC-MS
More informationProgress and Update on Grant Allocation for 3-MCPDE & GE
PORAM ANNUAL FORUM 2018 Progress and Update on Grant Allocation for 3-MCPDE & GE Rosidah Radzian Malaysian Palm Oil Board 26.10.2018 Presentation Outline 1.Should we be worried about 3-MCPDE & GE? 2.Update
More informationResearch Article Critical factors of indirect determination of 3-chloropropane- 1,2-diol esters
Eur. J. Lipid Sci. Technol. 2011, 000, 0000 0000 1 esearch Article Critical factors of indirect determination of 3chloropropane 1,2diol esters Karel Hrncirik 1, Zuzana Zelinkova 2 and Alessia Ermacora
More informationIntroduction to fats IGD 2017 UPDATED NOV
Introduction to fats IGD 2017 UPDATED NOV 2017 1 What is fat? Fats are an important part of our diet, they provide: Energy (9 kcal/g higher in kcal than other macronutrients) Important vitamins (for example,
More informationDocumentary evidence to the operator according to Article 29 (1) of Regulation (EC) No. 834/2007. The operator: Spack B.V.
Documentary evidence to the operator according to Article 29 (1) of Regulation (EC) No. 834/2007 ORGANIC CERTIFICATE The operator: Spack B.V. Spack B.V. \\ Oudelandsedijk 10A, 3244 LR NIEUWE TONGE, NETHERLANDS
More informationOverview of the food science behind fatty acid technology
Overview of the food science behind fatty acid technology Pamela J. White, Ph.D. Food Chemist/Scientist Food Science and Human Nutrition Dept. & Center for Crops Utilization Research Iowa State University
More informationNew Approaches for Improving Edible Oil Quality
New Approaches for Improving Edible Oil Quality Selma Turkay and Hale Gurbuz Istanbul Technical University, Chemical Engineering Department OFI TURKEY 2014 13 May Istanbul Introduction In recent years,
More informationMAJOR DIFFERENCES BETWEEN COBRAM ESTATE EXTRA VIRGIN OLIVE OIL, VIRGIN OLIVE OIL AND OLIVE OIL (REFINED BLENDS)
, VIRGIN OLIVE OIL AND OLIVE OIL (REFINED BLENDS) NATURAL OLIVE OILS OBTAINED BY SOLE MECHANICAL/PHYSICAL MEANS NO ALTERATIONS IN THE OIL REFINED OLIVE OILS REFINING PROCESS LEADS TO ALTERATIONS IN NATURAL
More informationdoi: / Vol.16,2017 ComprehensiveReviewsinFoodScienceandFoodSafety 263 C 2017 Institute of Food Technologists
Glycidyl Fatty Acid Esters in Refined Edible Oils: A Review on Formation, Occurrence, Analysis, and Elimination Methods Wei-wei Cheng, Guo-qin Liu, Li-qing Wang, and Zeng-she Liu Abstract: Glycidyl fatty
More informationFood Safety Forum. Munich, 14 th Sept 2017
Food Safety Forum Munich, 14 th Sept 2017 1 Insights on how to deal practically with food safety and new consumer concerns and expectations Dr. Adina Creanga Product Safety Director Bunge EMEA 2 200 years
More informationFood & Feed safety and quality
Food & Feed safety and quality Gerrit van Duijn gerritvanduijn consultancy MVO course, June 2016 1 Agenda Supply chain control Impurities and contaminants in crude oil The refining process The fate of
More informationTHE TRADE NEWS SERVICE
Volume 98, No. 6 Page 2 EXPORT FIGURES for the month of December 211 as released by the Commerce Department. All figures in TONNES: DEC NOV DEC OCT-DEC PCT SOYBEAN OIL Crude 18,566 38,533 152,92 86,428
More informationILSI Europe Report Series
ILSI Europe Report Series 3-MCPD Esters in Food Products Summary Report of a Workshop held in February 2009 in Brussels, Belgium Organised by the ILSI Europe Process-related Compounds and Natural Toxins
More informationThe EU association of the vegetable oils and protein meal industry
The EU association of the vegetable oils and protein meal industry 1 2 3 4 Fediol: Key actor in food, feed, non-food value chains n 85% of the sector s activity in the EU n 150 oilseed crushing and/or
More informationMULTIDIMENSIONALE SCHEIDINGEN IN DE GAS- EN VLOEISTOF CHROMATOGRAFIE
MULTIDIMENSINALE SCHEIDINGEN IN DE GAS- EN VLEISTF CHRMATGRAFIE Hans-Gerd Janssen and many others Unilever Foods R&D Vlaardingen, Vlaardingen, the Netherlands University of Amsterdam, Amsterdam, the Netherlands
More informationUsing RP-HPLC with Fluorescence Detection and SEC C for Sample Preparation and Its Application for Different Food Samples
Modified Analytical Assay for PAH P Using RP-HPLC with Fluorescence Detection and SEC C for Sample Preparation and Its Application for Different Food Samples Ewa Węgrzyn, Stanisław Grześkiewicz,, Wiesława
More informationHYPHENATED AND COMPREHENSIVE CHROMATOGRAPHIC TECHNIQUES FOR TRACE ANALYSIS IN EDIBLE OILS AND FATS
HYPHENATED AND COMPREHENSIVE CHROMATOGRAPHIC TECHNIQUES FOR TRACE ANALYSIS IN EDIBLE OILS AND FATS Hans-Gerd Janssen Unilever Foods R&D Vlaardingen, Vlaardingen, the Netherlands University of Amsterdam,
More informationAS Application Note 1602
Determination of the fatty acid composition in refined oils and fats by alkaline transesterification by the ASAN 1602 Status: February 2018 Page 1 / 12 Introduction Animal and vegetable fats play a key
More informationMOSH/MOAH QUESTIONS AND ANSWERS
MOSH/MOAH QUESTIONS AND ANSWERS WHAT IS MOSH/MOAH? MOSH/MOAH is the umbrella term describing mineral oil hydrocarbons that can migrate from packaging materials into foodstuffs during transportation and
More informationSession Three: Fats and Sodium
Dining with Diabetes 5:1 Chapter 5 Session Three: Fats and Sodium Lesson Plans Learning Objectives Participants will recognize that Heart-Healthy eating may help lower the risk of cardiovascular disease
More informationQuality criteria for edible argan oil Results from a market survey
Quality criteria for edible argan oil Results from a market survey Bertrand Matthäus und Ludger Brühl Max Rubner-Institut, Bundesforschungsinsitut für Ernährung und Lebensmittel Schützenberg 1; D-3756
More informationFatty Acid Data in the USDA National Nutrient Databank: Data handling and currency issues
Fatty Acid Data in the USDA National Nutrient Databank: Data handling and currency issues Linda Lemar Nutrient Data Laboratory 32 nd National Nutrient Databank Conference Topics to be Covered Enhancements
More informationG.C.C STANDARDIZATION ORGANIZATION (GSO)
G.C.C STANDARDIZATION ORGANIZATION (GSO) Final Draft GSO/DS 1929/2011 Edible Vegetable Oils Part II Prepared by: Gulf Technical Committee for Sector Standards of Food and Agriculture Product This document
More informationOlive oil. This document is a proposal only. The Standards Institution of Israel
Draft Israeli Standard SI 191 SI 191 June 2008 2008 ICS code: 6.200.10 Olive oil This document is a proposal only The Standards Institution of Israel 42 Chaim Levanon Street, Tel-Aviv 699, tel. 92-3-6465154,
More informationA Healthy Lifestyle. Session 1. Introduction
A Healthy Lifestyle Session 1 Introduction Introduction A Healthy Eating Plan How Can Healthy Eating Improve Your Health? Healthy eating can improve your health in many ways. It helps to: Prevent many
More informationToolbox for the Mitigation of 3-MCPD Esters and Glycidyl Esters in Food
Toolbox for the Mitigation of 3-MCPD Esters and Glycidyl Esters in Food Bund für Lebensmittelrecht und Lebensmittelkunde e. V. (BLL) German Federation for Food Law and Food Science Table of contents Table
More informationDetermination of Triglycerides and Waxes in Food Products Using Cool On-Column Injection and the MET- Biodiesel Capillary Column
Page 1 of 6 Page 1 of 6 Return to Web Version Determination of Triglycerides and Waxes in Food Products Using Cool On-Column Injection and the MET- Biodiesel Capillary Column By: Michael D. Buchanan, Reporter
More information3-MCPD and glycidol and their esters
Toxicological Risk Assessment of 3-monochloropropane-1,2-diol (3-MCPD) Esters and Glycidol Esters: Is there a Need for Concern? Ivonne M.C.M. Rietjens Division of Toxicology Wageningen University ivonne.rietjens@wur.nl
More informationQUESTION 1 Fats and oils vary in their degree of solubility in aqueous solutions. Give a reason for this observation.
QUESTIN 1 Fats and oils vary in their degree of solubility in aqueous solutions. Give a reason for this observation. QUESTIN Why are fatty acids such as palmitic acid, insoluble in water, while ethanoic
More informationAOAC Research Institute Performance Tested Methods SM Program. Measurement of Free Fatty Acids Using FASafe Standard Test Kit. Certificate Report
Performance Tested Methods SM Program Measurement of Free Fatty Acids Using FASafe Standard Test Kit Certificate Number 030405 June 23, 2003 SāfTest, Inc.,. 2414 West 12 th Street, Suite 4 Tempe, Arizona
More informationWhich Oil Should I Cook With? Would you put the wrong oil in your car? Of course not. So why would you put the wrong oil in your body?
Which Oil Should I Cook With? Would you put the wrong oil in your car? Of course not. So why would you put the wrong oil in your body? Not all cooking oils are made equally. You ll find UNSAFE oils in
More informationAlternative Techniques for Edible Oil Refining
Alternative Techniques for Edible Oil Refining Prof Dr Aytac Saygin Gumuskesen Assistant Prof Dr Fahri Yemiscioglu Res. Assoc. Onur Ozdikicierler Ege University, Food Engineering Dept., Turkey Oils & Fats
More information(12) United States Patent (10) Patent No.: US 9.217,120 B2
US0092.17120B2 (12) United States Patent () Patent No.: US 9.217,120 B2 Bhaggan et al. (45) Date of Patent: Dec. 22, 20 (54) METHOD OF TREATING AVEGETABLE OIL WO WO 2011/009843 A1 1/2011 WO WO 20169028
More informationDRAFT UGANDA STANDARD
DRAFT UGANDA STANDARD DUS DEAS 14 Second Edition 2016-mm-dd PU BL IC R EV IE W D R AF T Fat spreads and blended spreads Specification Reference number DUS DEAS 14: 2016 UNBS 2016 DUS DEAS 14:2016 Compliance
More informationFood ingredients & oils
Food ingredients & oils www.mosselman.eu Trading & Production of Oleochemicals and related products Tradition in customer relation. Innovation in chemistry and customer service. An extra touch with the
More informationHIGH OLEIC LOW LINOLENIC WINTER OILSEED RAPE OIL
HIGH OLEIC LOW LINOLENIC WINTER OILSEED RAPE OIL Rich in Oleic Acid Source of Alpha Linolenic Acid HOLL IN 4 POINTS PRODUCERS & SUPPLIERS CONSUMERS AGRONOMIC TECHNOLOGIC NUTRITIONAL ORGANOLEPTIC Resistance
More informationTeachers: Cut out and laminate these cards for future use.
Teachers: Cut out and laminate these cards for future use. Fatoid Card # 1 Fats are vital to your health they help kids grow and develop. Fats contain energy, make up part of our cell membranes, and are
More informationCHEMISTRY OF LIFE 30 JANUARY 2013
CHEMISTRY OF LIFE 30 JANUARY 2013 Lesson Description In this lesson, we will: Investigate the structure and function of molecules that are essential for life. Key Concepts Terminology A molecule is any
More informationFood Science & Nutrition: Food Analogs
Food Science & Nutrition: Food Analogs Objectives Compare the performance of fat replacers to the performance of fat. Describe advantages and disadvantages of potassium chloride as a salt substitute. Review:
More informationFATS & OILS GLOSSARY
FATS & OILS GLOSSARY Antioxidant A substance that slows or interferes with the reaction of a fat or oil with oxygen. The addition of antioxidants to fats or foods containing them retard rancidity and increases
More informationAre you eating a balanced diet?
Are you eating a balanced diet? Do you know WHAT A BALANCED DIET IS? Eating a balanced diet means choosing a variety of foods & drinks from all the food groups Health Canada recommends 2-3 Tbsp of oil/day
More information2.3 Carbon Compounds 12/19/2011 BIOLOGY MRS. MICHAELSEN. Lesson Overview. Carbon Compounds The Chemistry of Carbon. Lesson Overview.
2.3 The Chemistry of Carbon A. Carbon atoms have four valence electrons 1. Form strong covalent bonds with many other elements: H, O, P, S, N. 2. Living organisms are made up of carbon and these other
More information-SQA-SCOTTISH QUALIFICATIONS AUTHORITY. Hanover House 24 Douglas Street GLASGOW G2 7NG NATIONAL CERTIFICATE MODULE DESCRIPTOR
-SQA-SCOTTISH QUALIFICATIONS AUTHORITY Hanover House 24 Douglas Street GLASGOW G2 7NG NATIONAL CERTIFICATE MODULE DESCRIPTOR -Module Number- 0097425 -Session-1989-90 -Superclass- WM -Title- FATS AND OILS
More informationProficiency test on the determination of 3-MCPD esters in edible oil
Proficiency test on the determination of 3-MCPD esters in edible oil Final Report Lubomir Karasek, Thomas Wenzl and Franz Ulberth EUR 24356 EN - 2010 The mission of the JRC-IRMM is to promote a common
More informationFeed ingredients
www.mosselman.eu Feed ingredients Trading & Production of Oleochemicals and related products Tradition in customer relation. Innovation in chemistry and customer service. An extra touch with the use of
More informationForensic Chemistry: Differentiation of Olive Oil and Sunflower Oil by GCxGC-TOFMS and Determination of Fraudulent Material.
Forensic Chemistry: Differentiation of Olive Oil and Sunflower Oil by GCxGC-TOFMS and Determination of Fraudulent Material. Peter Gorst-Allman, LECO Africa Pty. Ltd (peter@lecoafrica.co.za) Introduction
More informationPART A FINISHED PRODUCT SPECIFICATION - GENERAL DISTRIBUTION
Cerebos Supplier Code ( or Bulk Code (Manufactured Supplier s Item Code & Supplier s Item Description ( Document : Issue : 1.0 Page Number: 1 of 8 FINISHED PRODUCT SPECIFICATION - GENERAL DISTRIBUTION
More informationBioavailability of Esters of 3-MCPD: in vitro and in vivo Studies
AOCS meeting April 2014, Huiles Bioavailability of Esters of 3-MCPD: in vitro and in vivo Studies F. JOFFRE, S. AMARA, F. CARRIERE, L. COUËDELO and C. VAYSSE French Institute for Fats and Oils (ITERG)
More informationMore performance, more quality. Additives for the industrial deep-frying of meat, poultry and fish
More performance, more quality Additives for the industrial deep-frying of meat, poultry and fish Healthy deep-frying Breaded fish as well as meat and poultry probably present the greatest challenge to
More informationExpert support to create cost-effective dairy taste and texture
Milk Fat Replacers Expert support to create cost-effective dairy taste and texture With the growing trend for healthier food, more and more consumers are looking for lower trans fat options, dairy-free
More information5.20 PROTHIOCONAZOLE (232)
Prothioconazole 251 5.20 PROTHIOCONAZOLE (232) RESIDUE AND ANALYTICAL ASPECTS Prothioconazole was evaluated for the first time by the 2008 JMPR which recommended maximum residue limits for barley, oats,
More informationLipids. PBHL 211 Darine Hachem, MS, LD
Lipids PBHL 211 Darine Hachem, MS, LD Outline Functions of lipids in our body Types of lipids Sources of lipids Recommendation of fat intake Fat association with heart diseases Provide energy (9Kcal/g
More informationLearning Objectives. Understand the different types and uses of fats and oils in food preparation - functions.
FATS AND OILS Learning Objectives Understand the different types and uses of fats and oils in food preparation - functions. Name some of the different fats and oils. Explain how fats shorten pastry. Think
More informationNutrients. Nutrition. Carbohydrates. - ex. Carbs, Fats, Protein, Water. - ex. vitamins, minerals
Nutrients Nutrition Introduction elements and compounds an organism needs but can not manufacture itself 6 Basic Nutrients carbohydrates fats proteins water vitamins minerals Macronutrients supply energy
More informationهيئة التقييس لدول مجلس التعاون لدول الخليج العربية
هيئة التقييس لدول مجلس التعاون لدول الخليج العربية G.C.C STANDARDIZATION ORGANIZATION (GSO) Final Draft GSO 05/FDS ---- / 2012 الزيوت النباتية المعدة للطعام الجزء الثالث زيت بذرة الكتان Edible Vegetable
More information(FAD ; CRL/170025)
EUROPEAN COMMISSION DIRECTORATE GENERAL JOINT RESEARCH CENTRE Directorate F Health, Consumers and Reference Materials European Union Reference Laboratory for Feed Additives Ref. Ares(2018)911021-16/02/2018
More informationProduct Specification. RDW Sunflower Oil
Product Specification RDW Sunflower Oil Description: Appearance: Odour: Flavour: This oil is produced by the refining, bleaching and deodorisation of the crude oil obtained from sunflower seeds. Clear
More information04/2013. Collaborative Study for the Determination of 3-MCPD- and 2-MCPD- Fatty Acid Esters in Fat Containing Foods
04/2013 Collaborative Study for the Determination of 3-MCPD- and 2-MCPD- Fatty Acid Esters in Fat Containing Foods Federal Institute for Risk Assessment Hildburg Fry, Caro Schödel, Anja These and Angelika
More informationCODEX STAN Page 1 of 5 CODEX STANDARD FOR EDIBLE FATS AND OILS NOT COVERED BY INDIVIDUAL STANDARDS CODEX STAN
CODEX STAN 19-1981 Page 1 of 5 CODEX STANDARD FOR EDIBLE FATS AND OILS NOT COVERED BY INDIVIDUAL STANDARDS CODEX STAN 19-1981 The Appendix to this Standard is intended for voluntary application by commercial
More informationUnderstanding Ingredients. Fats and Oils
Understanding Ingredients Fats and Oils Topics Types of Fats and Oils Structures of Fats and Oils Nutritive Value of Fats and Oils Choice and Storage of Fats and Oils Uses of Fats and Oils in Cooking /
More informationL III: DIETARY APPROACH
L III: DIETARY APPROACH FOR CARDIOVASCULAR DISEASE PREVENTION General Guidelines For Dietary Interventions 1. Obtain a healthy body weight 2. Obtain a desirable blood cholesterol and lipoprotein profile
More informationJOINT FAO/WHO FOOD STANDARDS PROGRAMME CODEX COMMITTEE ON FATS AND OILS 25 th Session Kuala Lumpur, Malaysia, 27 February - 3 March 2017
E Agenda Item 12 JOINT FAO/WHO FOOD STANDARDS PROGRAMME CODEX COMMITTEE ON FATS AND OILS 25 th Session Kuala Lumpur, Malaysia, 27 February - 3 March 2017 CX/FO17/25/12rev1 January 2017 DISCUSSION PAPER
More information