Silicone Products for Personal Care (For North and South America)

Transcription

1 Silicone Products for Personal Care (For North and South America)

2 Contents Product List 1 Dimethyl Silicone Fluids P3 2 Volatile Silicone Fluids P4 3 Methyl Phenyl Silicone Fluids P4 4 Amino Modified Silicones P4 5 Other Modified Silicone P4 6 Fluid Compounds P4 7 Dimethyl Silicone Blends P5 8 High Polymerization Dimethiconols P5 9 Amino Gums P5 11 Polyether Modified Silicones P7 12 Polyglycerin Modified Silicones P7 13 Silicone Gels P Silicone Acrylates P10 15 Trimethylsiloxysilicates P11 16 Silicone Film Formers P11 17 Silicone Powders P12 18 Powder Treatments P12 19 Powder Dispersions P13 10 Silicone Emulsions P6 Data Dimethyl silicone fluid soluble in various solvents P14 Volatile Data P14 Bake-on Temperature and Processing Time Methyl Hydrogen Polysiloxane P14 Solubility Dimethicone P15 Compatibility (20%) Polyether Modified Silicone Fluid, Polyglycerin Modified Silicone Fluid P15 Handling Precautions P15 2

3 Product List 1 Dimethyl Silicone Fluids Parameter Viscosity Specific Gravity Refractive Index Volatile Matter Pour Point Flash Point Grade 25 C, mm 2 /s 25 C 25 C 150 C x 24 h, % C C DM-FLUID-A-1cs TRISILOXANE Boiling point 153 C DM-FLUID-1.5cs Boiling point 194 C < DM-FLUID-2cs Boiling point 229 C < DM-FLUID-A-5cs < 40 ]1 < DM-FLUID-A-6cs < 5.0 ]1 < DM-FLUID-A-10cs < 40 < -100 > 160 DM-FLUID-A-20cs < 4.0 < -60 > 260 DM-FLUID-A-30cs < 1.5 < -55 > 280 DM-FLUID-A-50cs < 0.5 < -50 > 310 DM-FLUID-A-100cs < 0.5 < -50 > 315 DM-FLUID-A-200cs < 0.5 < -50 > 315 DM-FLUID-A-300cs < 0.5 < -50 > 315 DM-FLUID-A-350cs < 0.5 < -50 > 315 DM-FLUID-A-500cs < 0.5 < -50 > 315 DM-FLUID-1,000cs 1, < 0.5 < -50 > 315 DM-FLUID-3,000cs 3, < 0.5 < -50 > 315 DM-FLUID-A-5,000cs 5, < 0.5 < -50 > 315 DM-FLUID-6,000cs 6, < 0.5 < -50 > 315 DM-FLUID-10,000cs 10, < 0.5 < -50 > 315 DM-FLUID-12,500cs 12, < 0.5 < -50 > 315 DM-FLUID-30,000cs 30, < 0.5 < -50 > 315 DM-FLUID-50,000cs 50, < 0.5 < -50 > 315 DM-FLUID-60,000cs 60, < 0.5 < -50 > 315 DM-FLUID-100,000cs 100, < 0.5 < -50 > 315 DM-FLUID-300,000cs 300, < 0.5 < -50 > 315 DM-FLUID-500,000cs 500, < 0.5 < -50 > 315 DM-FLUID-1,000,000cs 1,000, < 0.5 < -50 > 315 ] The commercial name in US is DM-FLUID-xxx, outside of US is 96-xxx. ]1: 105 C x 3 h ] names are subject to change without notice. 3

4 Product List 2 Volatile Silicone Fluids Parameter Viscosity Specific Gravity Refractive Index Freezing Point Boiling Point Flash Point Surface Tension Grade 25 C, mm 2 /s 25 C 25 C C C C 25 C, mn/m TMF-1.5 METHYL TRIMETHICONE ] Non-linear type 3 Methyl Phenyl Silicone Fluids Parameter Viscosity Specific Gravity Refractive Index Volatile Matter Pour Point Flash Point Grade 25 C, mm 2 /s 25 C 25 C 150 C x 24 h, % C C F-5W-0-100cs DIPHENYL < 0.5 < -65 > 315 F-5W-0-1,000cs DIPHENYL 1, < 0.5 < -65 > DIPHENYL < 0.3 < -30 > DIPHENYL < 0.5 < -30 > A DIPHENYLSILOXY PHENYL TRIMETHICONE ] < -55 > HV DIPHENYL 5, < 0.5 < -30 > 315 ] 105 C x 3h 4 Amino Modified Silicones Parameter Viscosity Specific Gravity Refractive Index Grade 25 C, mm 2 /s 25 C 25 C 8004 AMO S AMINOETHYLAMINOPROPYL 1, AMINOPROPYL 50, , S AMO 1, Other Modified Silicone Parameter Melting Point Specific Gravity Modified Type Grade C 25 C 7002 STEAROXYMETHICONE/ COPOLYMER Stearoxy Fluid Compounds Parameter Viscosity Specific Gravity Appearance Grade 25 C, mpa s 25 C S-6W-6 SIMETHICONE Light gray translucent liquid S-6W-9 SIMETHICONE Light gray translucent 2, ] names are subject to change without notice.

5 7 Dimethyl Silicone Blends Parameter Component A Grade Component B MK-15H X Viscosity Specific Gravity Refractive Index Dimethicone Gum 25 C, mpa s 25 C 25 C Content, % Solvent 30, , , DM-FLUID-A-20cs 6, , DM-FLUID-A-20cs 3, , , DM-FLUID-A-20cs 8 High Polymerization Dimethiconols Parameter Component A Viscosity Specific Gravity Refractive Index Dimethiconol Solvent Grade Component B 25 C, mpa s 25 C 25 C Content, % DIMETHICONOL X , DM-FLUID-A-20cs DIMETHICONOL X , X DIMETHICONOL 22, X DIMETHICONOL 100, Amino Gums Parameter Component A Viscosity Specific Gravity Refractive Index Amino Gum Content Solvent Grade Component B 25 C, mm 2 /s 25 C 25 C % AMINOPROPYL , DM-FLUID-A-20cs AMINOPROPYL , AMINOPROPYL , DM-FLUID-A-20cs 5

6 Product List 10 Silicone Emulsions Parameter Composition Viscosity Silicone Silicone Appearance Base Oil Content Grade % 25 C, mpa s Solvent % PH Ionic 25 C Property KM-901 Component A : 50.0 Milky white DM-FLUID- 100 Others 6.25 emulsion 60,000cs Nonionic KM-902 Component A : 50.0 Milky white DM-FLUID- 100 Others 6.15 emulsion 500,000cs Nonionic Component A : 18.0 KM-903 Component B : 42.0 Milky white Dimethicone DM-FLUID- 1,000 emulsion gum A-200cs Nonionic Others 6.25 Component A : 36.0 KM-910 Component B : 24.0 Milky white Dimethicone DM-FLUID- 2,500 emulsion gum A-200cs Nonionic Others 6.75 KM-9729 Component A : /VINYL CROSSPOLYMER 50.0 Milky white Silicone Others 2.75 emulsion rubber powder Nonionic Component A : 33.0 X Component B : 27.0 Milky white Dimethicone DM-FLUID- 1,000 emulsion gum A-200cs Nonionic Others 6.25 Component A : 30.0 X Component B : 45.0 Milky white Dimethicone DM-FLUID- 4,000 emulsion gum A-200cs Cationic Others 4.5 Component A : 26.0 X Component B : 39.0 Milky white Dimethicone DM-FLUID- 3,000 emulsion gum A-200cs Nonionic Others 5.25 X Component A : AMO 40.0 Amino Milky white modified emulsion Others 10.1 silicone Nonionic X Component A : AMINOPROPYL 12.0 Amino Milky white DM-FLUID- Component B : ,000 modified emulsion A-20cs Others 9.5 gum Nonionic 6 ] names are subject to change without notice.

7 11 Polyether Modified Silicones Parameter Viscosity Specific Gravity Refractive Index Calculated HLB Cloud Point Grade 25 C, mm 2 /s 25 C 25 C wt%, EO/5 C 6011 PEG-11 METHYL ETHER P PEG-11 METHYL ETHER PEG/PPG-20/22 BUTYL ETHER 1, PEG PEG PEG-9 METHYL ETHER PEG P PEG PEG-32 METHYL ETHER Solid (melting point 45 C) PEG-9 POLYDIMETHYLSILOXYETHYL P PEG-9 POLYDIMETHYLSILOXYETHYL LAURYL PEG-9 POLYDIMETHYLSILOXYETHYL PEG CETYL PEG/PPG-10/1 2, ] P Grade: odorless versions created using an improved deodorization process. 12 Polyglycerin Modified Silicones Parameter Viscosity Specific Gravity Refractive Index Grade 25 C, mpa s 25 C 25 C Estimated HLB 6100 POLYGLYCERYL-3 DISILOXANE 40, Medium 6104 POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL 4, Low 6105 LAURYL POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL 4, Low 6106 POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL 3, Low 7

8 Product List 13 Silicone Gels Parameter Component A Penetration Refractive Index Cross-linked Appearance Base Oil polymer Grade Component B (worked), 25 C 25 C % KSG-15 KSG-1510 /VINYL CROSSPOLYMER /VINYL CROSSPOLYMER METHYL TRIMETHICONE Colorless transparent Colorless translucent TMF USG-103 /VINYL CROSSPOLYMER Colorless transparent KSG-16 /VINYL CROSSPOLYMER Colorless translucent DM-FLUID-A-6cs KSG-1610 /VINYL CROSSPOLYMER METHYL TRIMETHICONE Colorless translucent TMF USG-106 /VINYL CROSSPOLYMER Colorless transparent KSG-18A KSG-19 KSG-016F KSG-41A KSG-42A KSG-43 KSG-44 /PHENYL VINYL CROSSPOLYMER Colorless translucent A DIPHENYLSILOXY PHENYL TRIMETHICONE /VINYL CROSSPOLYMER Colorless translucent DM-FLUID-A-6cs /VINYL CROSSPOLYMER Colorless translucent DM-FLUID-A-6cs VINYL /LAURYL CROSSPOLYMER Colorless translucent MINERAL OIL MINERAL OIL VINYL /LAURYL CROSSPOLYMER Colorless translucent VINYL /LAURYL CROSSPOLYMER Colorless translucent TRIETHYLHEXANOIN TRIETHYLHEXANOIN VINYL /LAURYL CROSSPOLYMER Colorless translucent SQUALANE SQUALANE LAURYL POLYDIMETHYLSILOXYETHYL / KSG-042Z BIS-VINYL CROSSPOLYMER Colorless transparent LAURYL POLYDIMETHYLSILOXYETHYL / KSG-045Z BIS-VINYL CROSSPOLYMER Colorless translucent LAURYL POLYDIMETHYLSILOXYETHYL / KSG-048Z BIS-VINYL CROSSPOLYMER Colorless transparent DM-FLUID-2cs KSG-210 /PEG-10/15 CROSSPOLYMER DM-FLUID-A-6cs KSG-240 /PEG-10/15 CROSSPOLYMER ] names are subject to change without notice.

9 Silicone Gels Parameter Component A Penetration Refractive Index Cross-linked Appearance Base Oil polymer Grade Component B (worked), 25 C 25 C % KSG-310 KSG-320 KSG-330 PEG-15/LAURYL CROSSPOLYMER MINERAL OIL PEG-15/LAURYL CROSSPOLYMER PEG-15/LAURYL CROSSPOLYMER TRIETHYLHEXANOIN MINERAL OIL TRIETHYLHEXANOIN PEG-10/LAURYL CROSSPOLYMER KSG-340 PEG-15/LAURYL CROSSPOLYMER SQUALANE SQUALANE PEG-15/LAURYL POLYDIMETHYLSILOXYETHYL KSG-320Z CROSSPOLYMER PEG-15/LAURYL POLYDIMETHYLSILOXYETHYL KSG-350Z CROSSPOLYMER PEG-15/LAURYL POLYDIMETHYLSILOXYETHYL KSG-360Z CROSSPOLYMER DM-FLUID-A-6cs PEG-15/LAURYL POLYDIMETHYLSILOXYETHYL KSG-380Z CROSSPOLYMER Colorless translucent DM-FLUID-2cs KSG-710 /POLYGLYCERIN-3 CROSSPOLYMER DM-FLUID-A-6cs KSG-810 KSG-820 KSG-830 KSG-840 LAURYL /POLYGLYCERIN-3 CROSSPOLYMER MINERAL OIL MINERAL OIL LAURYL /POLYGLYCERIN-3 CROSSPOLYMER LAURYL /POLYGLYCERIN-3 CROSSPOLYMER TRIETHYLHEXANOIN TRIETHYLHEXANOIN LAURYL /POLYGLYCERIN-3 CROSSPOLYMER SQUALANE SQUALANE POLYGLYCERYL-3/LAURYL POLYDIMETHYLSILOXYETHYL KSG-820Z CROSSPOLYMER POLYGLYCERYL-3/LAURYL POLYDIMETHYLSILOXYETHYL KSG-850Z CROSSPOLYMER

10 Product List 14 Silicone Acrylates Parameter Component A Viscosity Content Solvent Grade Component B 25 C, mm 2 /s % ACRYLATES/ COPOLYMER KP ,000 mpa s 60 ISOPROPYL ALCOHOL ISOPROPYL ALCOHOL ACRYLATES/ COPOLYMER KP , BUTYL ACETATE BUTYL ACETATE ACRYLATES/ COPOLYMER KP ACRYLATES/ COPOLYMER KP , TMF-1.5 METHYL TRIMETHICONE ACRYLATES/ COPOLYMER KP , ACRYLATES/ COPOLYMER KP-545L 800-8, DM-FLUID-2cs KP-578 ACRYLATES/ETHYLHEXYL ACRYLATE/ METHACRYLATE COPOLYMER KP-561P ACRYLATES/STEARYL ACRYLATE/ METHACRYLATE COPOLYMER Solid (melting point C) 100 KP-562P ACRYLATES/BEHENYL ACRYLATE/ METHACRYLATE COPOLYMER Solid (melting point C) ] names are subject to change without notice.

11 15 Trimethylsiloxysilicates Parameter Component A Viscosity Specific Gravity Refractive Index Resin Content Solvent Film Hardness Grade Component B 25 C, mm 2 /s 25 C 25 C % X X L X X X L 7312J 7312K 7312L 7312T X L METHYL TRIMETHICONE Soft DM-FLUID-2cs Soft Soft Medium DM-FLUID-2cs Medium Hard 5, DM-FLUID-A-6cs Hard DM-FLUID-2cs Hard TMF-1.5 Hard Hard 2, Very hard DM-FLUID-2cs Very hard 16 Silicone Film Formers Parameter Component A Viscosity Content Solvent Grade Component B 25 C % NORBORNENE/TRIS (TRIMETHYLSILOXY) SILYLNORBORNENE COPOLYMER NBN-30-ID 300 Pa s 30 TRIMETHYLSILOXYSILYLCARBAMOYL PULLULAN TSPL-30-ID 600 mm 2 /s 30 TSPL-30-D5 TRIMETHYLSILOXYSILYLCARBAMOYL PULLULAN 8,000 mm 2 /s

12 Product List 17 Silicone Powders Parameter Loss on drying True Specific Average Particle Hardness Appearance Grade 105 C x 3 h, % Gravity Size, µm Durometer A KMP-590 POLYMETHYLSILSESQUIOXANE KMP-591 POLYMETHYLSILSESQUIOXANE KSP-100 VINYL / METHICONE SILSESQUIOXANE CROSSPOLYMER KSP-101 VINYL / METHICONE SILSESQUIOXANE CROSSPOLYMER KSP-102 VINYL / METHICONE SILSESQUIOXANE CROSSPOLYMER KSP-105 VINYL / METHICONE SILSESQUIOXANE CROSSPOLYMER KSP-300 DIPHENYL /VINYL DIPHENYL /SILSESQUIOXANE CROSSPOLYMER KSP-411 POLYSILICONE-1 CROSSPOLYMER KSP-441 POLYSILICONE Powder Treatments Parameter Viscosity Specific Gravity Refractive Index Volatile Content Grade 25 C, mm 2 /s 25 C 25 C 105 C x 3 h, % F-9W-9P METHICONE < HYDROGEN < TRIETHOXYSILYLETHYL POLYDIMETHYLSILOXYETHYL < TRIETHOXYSILYLETHYL POLYDIMETHYLSILOXYETHYL HEXYL < 5 KP-574 ACRYLATES/TRIDECYL ACRYLATE/TRIETHOXYSILYLPROPYL METHACRYLATE/ METHACRYLATE COPOLYMER < 5 AES-3083 TRIETHOXYCAPRYLYLSILANE Boiling point 100 C/2 mmhg 12 ] names are subject to change without notice.

13 19 Powder Dispersions Parameter Powder Content Viscosity Specific Gravity Powder Solvent Appearance Grade wt% 25 C, mpa s 25 C TITANIUM DIOXIDE SPD-T5 POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL TiO light gray fluid < 4, ALUMINUM HYDROXIDE STEARIC ACID TITANIUM DIOXIDE SPD-T5L POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL TiO2 DM-FLUID-2cs 40 -light gray fluid < 4, ALUMINUM HYDROXIDE STEARIC ACID ZINC OXIDE SPD-Z5 POLYGLYCERYL-3 POLYDIMETHYLSILOXYETHYL ZnO light yellow fluid < 4, TRIETHOXYSILYLETHYL POLYDIMETHYLSILOXYETHYL HEXYL 13

14 Data Dimethyl silicone fluid soluble in various solvents DM-FLUID (dimethyl silicone fluid) : Solubility of medium viscosity grades Note that low viscosity grades of DM-FLUID (5 mm 2 /s and below) also dissolve in ethanol and other solvents, so check prior to use. Volatile Data Volatility at 25 C (measured by filter paper method) Solvent Solvent naphtha Industrial Gasoline Mineral Spirits Kerosene Cyclohexane n-hexane n-heptane Ethyl Ether Diisopropyl Ether Hexyl Ether Ethyl Acetate Butyl Acetate Isopropyl Ether Isopropyl Laurate Isopropyl Palmitate Isopropyl Myristate Methyl Ethyl Ketone Methyl Isobutyl Ketone Lauryl Alcohol Acetone Dioxane Butanol 2-Ethylhexanol Amyl Acetate Glacial Acetate Acid Naphthene-based Lubricating Oils Methanol Ethanol Cyclohexanol Ethylene Glycol Carbitol Glycerin Diethylene Glycol Stearate Propylene Glycol Liquid Paraffin Paraffin Wax Petrolatums Lubricating Oils Fatty Acid (other than Glacial Acetic Acid) Animal and Vegetable Oils Methyl Phthalate Water Result Solbule Partially Partially Partially Partially Partially Partially Partially Volatile rate (%) Water DM-FLUID-A-1cs TMF-1.5 Time (h) 995 DM-FLUID-2cs Volatility at 37 C (measured by filter paper method) Volatile rate (%) Bake-on Temperature and Processing Time Methyl Hydrogen Polysiloxane (without solvent) Processing Time (min) DM-FLUID-A-1cs Time (h) Temperature ( C) Testing Condition Processing Liquid: 10% F-9W-9P Solution Testing Substrate: Glass DM-FLUID-2cs 14

15 Solubility Dimethicone DM-FLUID-L. DM-FLUID Composition Rate Silicone Fluid : Cosmetic Ingredient Silicone Fluid 10:1 1:1 1:10 Cosmetic Ingredient DM-FLUID-L DM-FLUID DM-FLUID-L DM-FLUID DM-FLUID-L DM-FLUID Cetyl Alcohol S I S I S I Bees Wax I I I I S I Lanolin I I I I I I Glycerine I I I I I I Liquid Paraffin S I S I S I Stearic Acid P I I I I I Squalane S S S I S I Jojoba Oil S I P I P I Vaseline I I I I S I S: P: at 60 to 80 C I: DM-FLUID-L: DM-FLUID-1 to 5cs Compatibility (20%) Polyether Modified Silicone Fluid, Polyglycerin Modified Silicone Fluid P P DM-FLUID-A-6cs (Dimethicone) I I I I S S S S I I I S S S S TMF-1.5 (Methyl Trimethicone) I I I S S S S S I S I S S S S 995 (Cyclopentasiloxane) I I I S S S S S I S I S S S S P KP A (Diphenylsiloxy Phenyl Trimethicone) S S I S S S S S I S I S S S S Mineral Oil I I I I I I I S I S I I S I I Isotridecyl Isononanoate I S S S S I I S I S I S S S S Triethylhexanoin S S S S S S S S S S I I S I S Ethyl Alcohol S S S S S S S I S I S I I I I 1, 3-Butylene Glycol S I S I I I I I S I S I I I I Glycerin I I I I I I I I I I S I I I I Water S S I I I I I I S I I I I I I S: I: Handling Precautions Quality, Storage and Handling Since changes in quality may occur due to exposure to heat, humidity, light or acidic or alkaline environments, be sure to close tightly and store in a cool, dark location. Wear rubber gloves, safety glasses and other protective gear to prevent contact with the skin and mucous membranes. In case of eye contact, immediately flush eyes with plenty of running water, and consult a physician if necessary. To clean, wipe off excess with a rag and then wash with water. Please read the Safety Data Sheet (SDS) before use. SDS can be obtained from our Sales Department. 15

16 Silicone Division Sales and Marketing Department I 6-1, Ohtemachi 2-chome, Chiyoda-ku, Tokyo, Japan Phone : +81-(0) Fax : +81-(0) Shin-Etsu Silicones of America, Inc Damar Drive, Akron, OH 44305, U.S.A. Phone : Fax : Shin-Etsu do Brasil Representação de Produtos Químicos Ltda. Rua Coronel Oscar Porto, º Andar - 114/115 Paraíso São Paulo - SP Brasil CEP: Phone : Fax : The data and information presented in this catalog may not be relied upon to represent standard values. Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice. Users are solely responsible for making preliminary tests to determine the suitability of products for their intended use. Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of no patent infringement. Users are solely responsible for exporting or importing the silicone products described herein, and complying with all applicable laws, regulations, and rules relating to the use of such products. Shin-Etsu recommends checking each pertinent country's laws, regulations, and rules in advance, when exporting or importing, and before using the products. Please contact Shin-Etsu before reproducing any part of this catalog. Copyright belongs to Shin-Etsu Chemical Co., Ltd. The silicone products described herein have been designed, manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use. Users must never use the silicone products described herein for the purpose of implantation into the human body and/or injection into humans. Shin-Etsu Silicone is a registered trademark of Shin-Etsu Chemical Co., Ltd. The Development and Manufacture of Shin-Etsu Silicones are based on the following registered international quality and environmental management standards. Gunma Complex ISO 9001 ISO (JCQA-0004 JCQA-E-0002) Naoetsu Plant ISO 9001 ISO (JCQA-0018 JCQA-E-0064) Takefu Plant ISO 9001 ISO (JQA-0479 JQA-EM0298) This is an edited version of the product data released on Dec C Shin-Etsu / M.G. Printed in the USA.