PRINTING INK ADDITIVES

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1 PRINTING INK ADDITIVES

2 2 3 PRINTING INK ADDITIVES CONTENT WATER BASED SYSTEMS 4 13 Defoamers 4 5 Dispersing Agents 6 7 Rheology Modifiers 8 9 Wetting & Leveling Agents Waterbased Wax Dispersions and Emulsions WATER & SOLVENT BASED SYSTEMS Micronized Waxes Coated & Surface-Modified Waxes SOLVENT BASED SYSTEMS Defoamers, Dispersing, Wetting & Leveling Agents Wax Dispersions Non Micronized Waxes OIL BASED DISPERSIONS & SPECIAL ADDITIVES RADIATION CURED SYSTEMS Micronized & Coated Waxes, UV Dispersion Defoamers & Dispersing Agents 26 27

3 Printing Ink Additives MÜNZING is a highly regarded, privately owned specialty additive company with headquarters in Abstatt, Germany. We have a presence in over 40 countries and are a technology driven organization with an extensive staff of highly experienced R&D and technical service personnel in Europe and the Americas. Our manufacturing plants in Germany and USA have broad synthesis and formulation capabilities in order to best serve our global customer base. We are committed to creating value and improving our customers formulations with our complete range of specialty additives. These additives, which include d efoamers, dispersants, rheology modifiers, emulsifiers, wetting and leveling agents, micronized and coated waxes as well as wax dispersions and emulsions, have achieved worldwide recognition for their performance, quality and technical innovation. The technical mission of MÜNZING is to solve ink and coating formulation problems. We offer state-of-the-art technical service testing to all customers, regardless of their company size. Based on our broad range of additive chemistries, MÜNZING s technical service work provides our customers the optimum solutions with respect to both technical performance and value. Printing inks are part of our daily life. They are used for means of information or decorative purpose in print media, catalogs and brochures, on packaging, textiles and articles of daily use. The major application processes are flexographic, gravure, offset and screen printing. Depending on the application printing inks have to meet many different requirements. MÜNZING has a long lasting expertise in printing inks and offers a broad portfolio of additives to the printing ink manufacturers. Our Application Technology Center is willing to support you during the development of products, which provide your customers with best possible solutions.

4 4 5 PRINTING INK ADDITIVES Water Based Systems Water Based Systems Defoamers Surface active agents (surfac tants) especially emulsifiers, wetting and dispersing agents are used to emulsify and stabilize hydrophobic substances e.g. binder particles, pigments and fillers in water based printing inks. These surfactants tend to create foam by stabilizing incorporated air in aqueous systems, that can lead to problems during the production as well as the application of water based printing inks. When selecting a suitable defoamer, special attention has to be paid to the balance between defoaming efficiency and compatibility with the printing ink. Our broad range of defoamers and deaerators based on different chemical technologies enables us to offer you the optimal defoamer for each type and application of your water based printing inks. DEFOAMERS Product Type Mineral oil free Silicone free VOC free Incorporation Flexographic and gravure inks (2004/42/EC) Corrugated board & porous paper AGITAN 105 poa, e easy AGITAN 109 veg, poa, e fair AGITAN 120 poa,oms,e fair AGITAN 155 oms,e easy AGITAN 156 poa,oms,e easy AGITAN 158 oms,e easy AGITAN 282 m easy AGITAN 299 poa easy AGITAN 350 poa hard AGITAN 351 poa hard AGITAN 731 oms, poa hard AGITAN 760 oms, poa hard AGITAN 761 oms hard AGITAN 766 oms, poa fair AGITAN 771 oms, poa fair AGITAN E 256 oms,e easy DEE FO PI-12 3D, e easy DEE FO PI-35 3D, e fair DEE FO PI-40 3D, e easy DEE FO PI-75 3D, oms, e easy 3D = 3D polysiloxane e = Aqueous emulsion poa = Polyoxalkylene technology m = Mineral oil oms = Organic modified polysiloxane veg = Vegetable oil All defoamers in this overview are APE free.

5 surfactant molecules Figure Foam bubble with surfactant double layer hydrophobic particle Additional Technical Information on Defoamer Technologies Defoamer Application Tables Defoamer Recommendations for Binders Water Based Systems Coated paper & packaging Film & foil Metallic inks Screen printing inks Ink Jet Overprint varnishes Press side Fountain solution Pigment grinding Applicable Recommended Highly recommended

6 6 7 PRINTING INK ADDITIVES Water Based Systems Water Based Systems Dispersing Agents For the dispersion of pigments, fillers as well as functional additives e.g. transparent inorganic pigments (iron oxide, titanium dioxide) and matting agents (silica) in water based printing inks we offer a broad range of high quality dispersing agents. In addition to the following product overview including recom mendations for various applications, there are also guide formulations for many pigments available. Furthermore we are offering you on request to prepare dispersant recommendations for specific pigments. Additional Technical Information on Dispersing Technologies Dispersant Recommendations Guide Formulations Technical s No. 5 DISPERSING AGENTS Product Type Charge Active content Solvent % EDAPLAN 395 High molecular copolymer anionic 30 Water EDAPLAN 396 High molecular copolymer anionic 35 Water EDAPLAN 397 Polyglycol esters nonionic 100 EDAPLAN 480 Acrylic based polymer anionic 85 Water EDAPLAN 482 Acrylic based polymer anionic 85 Water EDAPLAN 490 High molecular copolymer nonionic 40 Water EDAPLAN 492 High molecular copolymer nonionic 35 Water EDAPLAN 494 High molecular copolymer anionic 50 Water EDAPLAN 516 Acrylic based polymer anionic 20 Water METOLAT 390 Fatty derivative copolymer anionic 55 Water METOLAT 392 Olefinic polymer anionic 45 Water METOLAT 394 Olefinic polymer anionic 55 Water METOLAT 514 Acrylic based polymer anionic 34 Water All dispersants in this overview are APE free.

7 Water Based Systems Inorganic pigments Organic pigments Carbon blacks Transparent inorganic pigments Fillers Matting agents (Silicas) Laked azo pigments Binder containing grinds Applicable Recommended Highly recommended

8 8 9 PRINTING INK ADDITIVES Water Based Systems Water Based Systems Rheology Modifiers For the optimal application of printing inks it is necessary to adjust its rheology profile with the help of rheology modifiers. This can be mana ged by using associative thickeners based on polyurethanes. Polyurethane thickeners can be used solely or in combination with each other as well as with other types of thickeners (e.g. polyacrylates or cellulose ethers). In addition to the following product overview including recommendations for applications, our application technology team is at your disposal to identify the best rheo logy modifier or combination of thickeners for your speci fic formulations through lab tests. RHEOLOGY MODIFIERS Product Rheology profile Type Active content Solvent % TAFIGEL PUR 40 pseudoplastic PUR 40 Water / Butyltriglycol TAFIGEL PUR 41 pseudoplastic PUR 20 Water TAFIGEL PUR 44 pseudoplastic PUR 40 Water / Butyltriglycol TAFIGEL PUR 45 newtonian PUR 40 Water / Butyltriglycol TAFIGEL PUR 48 pseudoplastic PUR 40 Water / Butyltriglycol TAFIGEL PUR 50 pseudoplastic PUR 21 Water TAFIGEL PUR 52 pseudoplastic PUR 20 Water TAFIGEL PUR 54 pseudoplastic PUR 20 Water TAFIGEL PUR 60 strong pseudoplastic PUR 40 Water / Butyltriglycol TAFIGEL PUR 61 strong pseudoplastic PUR 25 Water TAFIGEL PUR 64 strong pseudoplastic PUR 40 Water / Butyltriglycol TAFIGEL PUR 65 strong pseudoplastic PUR 20 Water / Butyltriglycol TAFIGEL PUR 80 newtonian PUR 20 Water TAFIGEL PUR 82 newtonian PUR 20 Water TAFIGEL PUR 85 newtonian PUR 25 Water TAFIGEL AP 10 system dependent AP 31 Water TAFIGEL AP 15 system dependent AP 29 Water TAFIGEL AP 16 system dependent AP 29 Water PUR = Polyurethane (nonionic) AP = Anionic copolymer emulsion

9 PUR 60, PUR 61, PUR 64, PUR 65 PUR 40, PUR 41, PUR 44, PUR 48, PUR 50, PUR 52, PUR 54 PUR 45, PUR 80, PUR 82, PUR S -1 Figure Rheology profiles of TAFIGEL PUR thickeners Additional Technical Information on Rheology Modifiers Technical s No. 4 Water Based Systems Organo tin free APE free Flexographic & gravure inks Screen inks Overprint varnishes Pigment grinding < 0,1 % < 0,05 % Applicable Recommended Highly recommended

10 10 11 PRINTING INK ADDITIVES Water Based Systems Water Based Systems Wetting and Leveling Agents Wetting and leveling agents are used in water based printing inks to improve substrate wetting or leveling, to enhance gloss or to prevent cratering. They can influence the properties of printing inks in different ways. Therefore it is important to test and select these additives carefully. WETTING & LEVELING AGENTS The following table contains some important information on a selection of our wetting and leveling agents for water based printing inks. Our application techno logy team would be glad to support you through lab tests to identify the most suitable additive for your application. Additional Technical Information on Additives for Surface and Substrate Product Type Charge Active content Solvent Silicone free VOC free % (2004/42/EC) METOLAT 285 Ester anionic 50 Water METOLAT 288 Ester anionic 50 Water METOLAT 355 Nonionic compounds nonionic 100 METOLAT 362 Nonionic compounds nonionic 100 METOLAT 364 Nonionic compounds nonionic 100 METOLAT 367 Ester nonionic 100 METOLAT 368 Ester nonionic 100 METOLAT 388 Nonionic compounds nonionic 100 METOLAT 700 Nonionic compounds nonionic 100 METOLAT 775 Nonionic compounds nonionic 100 METOLAT 780 Nonionic compounds nonionic 100 METOLAT 1299 Ester anionic 66 Water / Propylene glycol EDAPLAN LA 402 Acrylic copolymer anionic 50 Butyl glycol EDAPLAN LA 403 Acrylic copolymer anionic 85 Water EDAPLAN LA 413 Organic modified polysiloxane nonionic 100 EDAPLAN LA 414 Organic modified polysiloxane nonionic 100 EDAPLAN LA 415 Organic modified polysiloxane nonionic 50 Methoxypropylacetate EDAPLAN LA 451 Ester anionic 68 Water / Ethanol EDAPLAN LA 452 Ester anionic 83 Water All wetting and leveling agents in this overview are APE free.

11 Water Based Systems Substrate wetting Substrate wetting in overprint varnishes Wetting of film & foil Wetting of pigments & fillers Improvement of print transfer Gloss Brilliance of metallic inks Compatibility agent Slip No foaming tendency Applicable Recommended Highly recommended

12 12 13 WAXES FOR PRINTING INKS Water Based Systems Water based wax dispersions and emulsions for printing inks MÜNZING s LUBA-print wax dispersions and emulsions formulation. Below overview highlights the properties help improve specific properties of your printing ink and attributes of our specific LUBA-print grades. Water Based Systems WAX DISPERSIONS AND EMULSIONS Product Wax type Solid content % D 98 Particle size D 50 Melting range C ph-value LUBA-print 184/W Polyethylene / PTFE , LUBA-print 185/B Polyethylene , LUBA-print 338 Polyethylene ,5 LUBA-print 499 Polyethylene LUBA-print 551/2 Polyethylene ,5 LUBA-print 760/D Polyethylene LUBA-print 3520 Polyethylene 35 < LUBA-print 5500 Polyethylene , LUBA-print W 5700 Polyethylene 47 7,5 3, LUBA-print WE 0520 Polyethylene 57, * 7 LUBA-print WXF 9510 Polyolefin / PTFE * 5,5 * = Drop point

13 Being an expert for wax additives our technical team in its modern laboratory provides excellent technical support and also offers customised solutions. Ionogenity Application Anti-Blocking Gloss Rub resistance Slip Over Print Varnish (OPV) nonionic Water Based Systems nonionic nonionic nonionic nonionic nonionic nonionic nonionic nonionic nonionic nonionic suitable highly suitable good very good

14 14 15 WAXES FOR PRINTING INKS Water and Solvent Based Systems Water and Solvent Based Systems Micronized waxes for printing inks The global market for packaging inks is growing steadily every year. There is a steady rise for demand on high quality printing inks, which can be achieved by using our high quality wax products. MÜNZING s versatile wax production capabilities one being a unique spraying technology leading to spherical particles allows to produce various types of wax chemistries to fullfil customer needs. CERETAN micronized waxes have a very narrow particle size distribution and D 99 values are always guaranteed. CERETAN micronized waxes help improve specific properties of your printing ink formulation. Below overview highlights the properties and attributes of our specific CERETAN grades MICRONIZED WAXES Product Wax type Particle size Drop point D 99 D 50 C CERETAN MCX 6610 Carnauba / Polyethylene CERETAN ME 0520 Polyethylene CERETAN ME 0825 Polyethylene CERETAN ME 1430 Polyethylene CERETAN ME 1715 Polyethylene CERETAN MF 5010 Polyethylene, PTFE modified (PTFE: ) CERETAN MF 5108 PTFE CERETAN MF 5715 Polyethylene, PTFE modified (PTFE: *) CERETAN MO 3220 Oxidized Polyethylene CERETAN MO 4715 Polar Polyolefin CERETAN MT 9115 Fischer-Tropsch CERETAN MT 9120 Fischer-Tropsch CERETAN MT 9220 Fischer-Tropsch CERETAN MX 9510 Polyolefin CERETAN MX 9815 Polyolefin CERETAN MX 9820 Polyolefin * = Melting point

15 Spherical micronized waxes Our spherical micronized waxes provide numerous advantages like ease of dispersing, reduced dust formation, improved surface properties in final printing ink application. The sphere makes the difference. Water and Solvent Based Systems Air milled waxes Spray micronized waxes Application Anti-Blocking Gloss Rub resistance Semi Gloss Slip Over Print Varnish (OPV) suitable good very good

16 16 17 WAXES FOR PRINTING INKS Water and Solvent Based Systems Water and Solvent Based Systems Coated waxes Our versatile wax technologies enable us to coat our spherical micronized waxes! Our functional blends coated with very fine PTFE particles, CERETAN MXF 9510 D and CERETAN MXF 9820 D, are the best selling grades for flexo inks. With CERETAN MXS 3815 we can offer a great 2 in 1 product that combines matting with excellent rub resistance. COATED WAXES CERETAN coated waxes help improve specific properties of your printing ink formulation. Below overview highlights the properties and attributes of our specific CERETAN grades Product Wax type Coating Particle size Drop point of the wax D 99 D 50 C CERETAN MCXF 6610 Carnauba / Polyethylene PTFE CERETAN MXF 9510 D Polyolefin PTFE CERETAN MXF 9820 D Polyolefin PTFE CERETAN MXS 3815 Wax blend Silica SURFACE-MODIFIED WAXES Product Wax type Particle size Drop point of the wax D 99 D 50 C CERETAN ME 0825 WD Polyethylene CERETAN MO 3220 WD CERETAN MX 9815 WD Oxidized Polyethylene Polyolefin CERETAN MX 9820 WD Polyolefin

17 Surface Modified Waxes: CERETAN WD Series Our CERETAN WD series has been specifically designed to ease incorporation of our micronized waxes into your waterbased formulation. With CERETAN ME 0825 WD, CERETAN MO 3220 WD, CERETAN 9820 WD and CERE TAN 9815 WD we offer a broad range of these easily dispersible waxes now. Application Anti-Blocking Gloss Matting Rub resistance Slip Over Print Varnish (OPV) Water and Solvent Based Systems Anti-Blocking Matting Rub resistance Slip Semi Gloss suitable good very good

18 18 19 PRINTING INK ADDITIVES Solvent Based Systems DEFOAMERS Product Type Incorporation AGITAN DF 311 M Mineral oil, few silicone easy AGITAN DF 6420 Mineral oil, few silicone easy FOAMTROL 110 Silicone compound easy DISPERSING AGENTS Product Type Charge Active content Solvent EDAPLAN 397 Polyglycol esters nonionic 100 % Solvent Based Systems EDAPLAN 711 Block copolymer nonionic 35 Butyl acetate EDAPLAN 930 EDAPLAN 935 High molecular copolymer 100 High molecular copolymer 100 METOLAT LA 524 Fatty derivative copolymer amphoteric 50 Xylene / Iso-butanol WETTING & LEVELING AGENTS Product Type Charge Active content % Solvent Silicone free METOLAT 355 Nonionic compounds nonionic 100 METOLAT 388 Nonionic compounds nonionic 100 EDAPLAN LA 402 Acrylic copolymer anionic 50 Glycol ether EDAPLAN LA 410 Organic modified polysiloxane nonionic 100 EDAPLAN LA 413 Organic modified polysiloxane nonionic 100 EDAPLAN LA 414 EDAPLAN LA 415 Organic modified polysiloxane nonionic 100 Organic modified polysiloxane nonionic 50 Methoxypropylacetate All products in these overviews are APE free.

19 Inorganic pigments Organic pigments Carbon blacks Fillers Solvent Based Systems Leveling Wetting of film & foil Anticratering Wetting of pigments & fillers Gloss Compatibility agent Slip No foaming tendency Applicable Recommended Highly recommended

20 20 21 WAXES FOR PRINTING INKS Solvent Based Systems Solvent based wax dispersions for flexographic inks MÜNZING s LUBA-print wax dispersions and emulsions help improve specific properties of your printing ink formulation. Below overview highlights the properties and attributes of our specific LUBA-print grades. WAX DISPERSIONS Product Wax type Solvent Solid content Particle size Melting range % D 98 D 50 C LUBA-print 121/C Hydrocarbon Ethyl acetate * LUBA-print 161/T Amide Ethanol LUBA-print 301/C Polyethylene Ethanol , LUBA-print 654/D Polyethylene Ethanol , Solvent Based Systems LUBA-print 654/DF 2 Polyethylene Ethanol LUBA-print 660 Polyethylene 2- Propanol (IPA) LUBA-print 754 Polyethylene Ethanol LUBA-print 887/H Carnauba Ethanol , LUBA-print 2036 A Polyethylene Ethanol LUBA-print 3036 A Polyethylene Ethanol / 2-Propanol (IPA) UBA-print SEB 0820 ET Biopolymer / Polyethylene Ethanol * * = Drop Point WAX SLIP ADDITIVES Product Wax type Drop point C CERETAN A 71 Erucamide CERETAN A 72 Stearamide CERETAN A 73 Oleamide CERETAN MA 7150 Erucamide CERETAN MA 7250 Stearamide

21 Being an expert for wax additives our technical team in its modern laboratory provides excellent technical support and also offers customised solutions. Application Anti-Blocking Gloss Hydrophobicity Rub resistance Semi Gloss Slip Over Print Varnish (OPV) Solvent Based Systems suitable Anti-Blocking Gloss Semi Gloss Slip good very good

22 22 23 WAXES FOR PRINTING INKS Oil Based Dispersions Oil based wax pastes for heatset inks We can offer you tailor made products from one source: highly concentrated wax pastes in your preferred oil with a very fine particle size, which can be added into your system without any additional grinding of the final product. We will be happy to create a specific product according to your needs. OIL BASED DISPERSIONS Product Wax type Solvent Solid content in % D 98 Particle size D 50 Drop point of the wax C LUBA-print OF 5108 PTFE Linseed oil LUBA-print OX 9815 Polyolefin Linseed oil LUBA-print OXF 9120 Polyolefin / PTFE Linseed oil LUBA-print OXF 9510 Polyolefin / PTFE Linseed oil Special Additives Special additives for heatset inks Individuality is standard! Our micronized complex-building additive PRINTPLEX MK 3025 has established itself as bestselling product throughout the last years. The improved LUBA-print OK 3010 is a very fine paste based on PRINTPLEX MK 3025, which has already been milled to the particle size needed in your heatset-ink. It saves time and energy just stir it in! HEATSET INKS Product Consistency Chemistry Solid content in % Dil Based Dispersions & Special Additives LUBA-print OK 3010 Paste EDTA 35 PRINTPLEX MK 3025 Solid EDTA 100

23 Anti-Blocking Gloss Hot Blocking Rub resistance Slip good very good Particle size Properties D 98 D Very fine dispersion of the chelating agent intended for direct stir-in < 25 Finely micronized chelating agent Dil Based Dispersions & Special Additives

24 24 25 WAXES FOR PRINTING INKS Radiation Cured Systems Micronized waxes, coated waxes and UV dispersions for UV inks Just like UV Coatings, the UV printing ink technology Our selected CERETAN and LUBA-print grades help is growing within the printing ink sector and offers improve specific properties of your UV printing ink new qualities and possibilities for the customers. This system. Below overview highlights the properties and techno logy has already been used in screen inks, flexographic packaging and offset printing for a long period attributes for each product. of time, and is nowadays followed by gravure inks and other special processes. MICRONIZED WAXES FOR UV INKS Product Wax type Particle size Drop point D 99 D 50 C CERETAN ME 0825 Polyethylene CERETAN ME 1715 Polyethylene CERETAN MF 5108 PTFE * CERETAN MM 8015 Montan CERETAN MO 3220 Oxidized Polyethylene CERETAN MX 9815 Polyolefin * = Melting range COATED WAXES Product Wax type Coating Particle size Drop point of the wax D 99 D 50 C Radiation Cured Systems CERETAN MXF 9510 D Polyolefin PTFE UV DISPERSION Product Wax type Solvent Solid content in % LUBA-print 309/C Polyethylene Oligotriacrylate 30

25 Application Anti-Blocking Gloss Rub resistance Semi Gloss Slip Over Print Varnish (OPV) Application Anti-Blocking Gloss Rub resistance Slip Over Print Varnish (OPV) D 99 Particle size D 50 Drop point of the wax C Rub resistance Slip Radiation Cured Systems suitable highly suitable good very good

26 26 27 PRINTING INK ADDITIVES Radiation Cured Systems DEFOAMERS Product Type APE free Incorporation AGITAN 760 Silicone compound fair AGITAN DF 6421 Mineral oil, few silicone fair FOAMTROL 110 Silicone compound fair DISPERSING AGENTS Product Type Charge Active content Solvent % EDAPLAN 710 Block copolymer nonionic 30 Dicarboxylic acid ester Radiation Cured Systems

27 APE free Inorganic pigments Organic pigments Carbon blacks Fillers Binder containing grinds Applicable Recommended Highly recommended Radiation Cured Systems

28 Contact MÜNZING CHEMIE GmbH Münzingstrasse Abstatt GERMANY Phone Fax info@munzing.com MÜNZING CHEMIE Iberia S.A.U. Carrer Temple, 15 1 derecha ES08911 Badalona (Barcelona) SPAIN Phone Fax iberia@munzing.com MÜNZING Micro Technologies GmbH Dr.-Bergius-Strasse Elsteraue GERMANY Phone Fax ceretan@munzing.com MÜNZING North America 1455 Broad Street, Suite #3 Bloomfield NJ USA Phone Toll Free Fax info@munzing.us MÜNZING International S.a.r.L. 23, rue Aldringen L-1118 LUXEMBOURG Phone Fax benelux@munzing.com MÜNZING Shanghai Co.Ltd. Rm 1701B-1703A No. 20, Lane 1228, ZRT Tower Jiangchang Rd. Shanghai P.R. CHINA Phone Fax info@munzing.cn Your local distribution contact MUNZING Mumbai Pvt. Ltd. Raheja Chambers 2nd Floor, 233 DBS Business Center, Nariman Point Mumbai INDIA Phone india@munzing.com Visit our website for more information for international representatives MUE_2018_008B_EN_V

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