Sigurnosno-tehnički list U skladu s 1907/2006/EU, članak 31

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1 Strana: 1/8 * ODJELJAK 1: Identifikacija tvari/smjese i podaci o tvrtki/poduzeću 1.1 Identifikacijska oznaka proizvoda Šifra proizvoda: 17590/ Relevantne identificirane uporabe tvari ili smjese i uporabe koje se ne preporučuju Uporaba tvari/pripravaka sloj bitumena 1.3 Podaci o dobavljaču koji isporučuje sigurnosno-tehnički list Proizvođač/uvoznik/distributer: MUREXIN AG Istarska tvornica vapna d.o.o. Franz v. Furtenbachstr Most Rasa A-2700 Wiener Neustadt Kroatien Tel.: + 43 (0)2622/27401 Tel.: Daljnje informacije se mogu nabaviti: l.gobo@itv-murexin.hr 1.4 Broj telefona za izvanredna stanja Emergency Number: 112 (medical information on (0) * ODJELJAK 2: Identifikacija opasnosti 2.1 Razvrstavanje tvari ili smjese Razvrstavanje u skladu s Uredbom (EZ) br. 1272/2008 GHS02 plamen Flam. Liq. 3 H226 Zapaljiva tekućina i para. GHS09 okoliš Aquatic Chronic 2 H411 Otrovno za vodeni okoliš s dugotrajnim učincima. GHS07 STOT SE 3 H336 Može izazvati pospanost ili vrtoglavicu. Svrstavanje u skladu s Direktivom 67/548/EEZ ili Direktivom 1999/45/EG N; Opasno za okoliš R51/53: Otrovno za organizme koji žive u vodi, može dugotrajno štetno djelovati u vodi. R : Zapaljivo. Učestalo izlaganje može prouzročiti sušenje ili pucanje kože. Pare mogu izazvati pospanost ili vrtoglavicu. Posebne upute glede opasnosti za čovjeka i okoliš: Proizvod mora biti označen na temelju analitičkog postupka "Općih smjernica EZ-a za klasificiranje pripravaka" u posljednjoj važećoj verziji. U slučaju dužeg ili višestrukog dodira s kožom može nastati dermatitis (upala kože) zbog toga što otapalo ima odmašćujuće djelovanje Ima narkotičko djelovanje. Klasifikacijski sustav: Klasifikacija odgovara aktualnim popisima Europske unije; ista je međutim dopunjena podacima iz stručne literature i podacima poduzeća. 2.2 Elementi označavanja Označivanje sukladno Uredbi (EG) br. 1272/2008 Proizvod je razvrstan i označen sukladno Uredbi o razvrstavanju, označavanju i pakiranju. (Nastavak na strani 2)

2 Strana: 2/8 Piktogrami opasnosti (Nastavak sa strane 1) GHS02 GHS07 GHS09 Oznaka opasnosti Upozorenje Oznake koje označavaju opasnost: Kohlenwasserstoffe, C9-C12, n-alkane, Isoalkane, Cycloalkane, Aromaten (2-25%) Oznake upozorenja H226 Zapaljiva tekućina i para. H336 Može izazvati pospanost ili vrtoglavicu. H411 Otrovno za vodeni okoliš s dugotrajnim učincima. Oznake obavijesti P101 Ako je potrebna liječnička pomoć pokazati spremnik ili naljepnicu P102 Čuvati izvan dohvata djece. P103 Prije uporabe pročitati naljepnicu. P280 Nositi zaštitne rukavice/zaštitnu odjeću/zaštitu za oči/zaštitu za lice. P210 Čuvati odvojeno od topline, vrućih površina, iskri, otvorenih plamena i ostalih izvora paljenja. Ne pušiti. P261 Izbjegavati udisanje maglice/para/aerosola. P243 Poduzeti mjere protiv pojave statičkog elektriciteta. P303+P361+P353 U SLUČAJU DODIRA S KOŽOM (ili kosom): Odmah skinuti svu zagađenu odjeću. Isprati kožu vodom/tuširanjem. P501 Odložite sadržaje /spremnike u skladu s lokalnim/regionalnim/nacionalni/ međunarodnim odredbama. Dodatni podaci: EUH066 Ponavljano izlaganje može prouzročiti sušenje ili pucanje kože. Sadrži N-[3-(dimethylamino)propyl)]-C18-ungesättigte Alkylamide. Može izazvati alergijsku reakciju. 2.3 Ostale opasnosti Rezultati PBT- i vpvb procjena PBT: Ne primjenjuje se. vpvb: Ne primjenjuje se. * ODJELJAK 3: Sastav/informacije o sastojcima 3.2 Kemijska svojstva: Smjese Opis: Smjesa: koja se sastoji od sljedećih navedenih materijala. Sastojci koji pridonose opasnosti proizvoda: (Nastavak na strani 3)

3 Strana: 3/8 EK broj: Broj registracije: xxxx CAS: EK broj: Kohlenwasserstoffe, C9-C12, n-alkane, Isoalkane, Cycloalkane, Aromaten (2-25%) Xn R65 N R51/53 R Flam. Liq. 3, H226 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 STOT SE 3, H336 N-[3-(dimethylamino)propyl)]-C18-ungesättigte Alkylamide C R35 Xi R41 Xi R43 N R50/53 Skin Corr. 1B, H314; Eye Dam. 1, H318 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Skin Sens. 1B, H317 (Nastavak sa strane 2) Dodatne informacije: Tekst navedenih napomena o opasnostima nalazi se u 16. poglavlju % 0,5-1,0% * ODJELJAK 4: Mjere prve pomoći 4.1 Opis mjera prve pomoći Nakon udisanja: Dotok svježeg zraka, u slučaju smetnji potražiti liječničku pomoć. Nakon dodira s kožom: Odmah oprati vodom i sapunom te dobro isprati. Ako je koža trajno nadražena potražiti liječničku pomoć. Nakon dodira s očima: Isprati oči tekućom vodom nekoliko minuta i savjetovati se s liječnikom. Oči prilikom ispiranja moraju biti otvorene. Nakon gutanja: Ne izazvati povraćanje, već odmah pozvati liječnika. 4.2 Najvažniji simptomi i učinci, akutni i odgođeni 4.3 Navod o slučaju potrebe za hitnom liječničkom pomoći i posebnom obradom ODJELJAK 5: Mjere gašenja požara 5.1 Sredstva za gašenje Prikladna: CO2, pijesak, prah za gašenje. Ne koristiti vodu. Ne smiju se upotrebljavati: Puni mlaz vode 5.2 Posebne opasnosti koje proizlaze iz tvari ili smjese 5.3 Savjeti za gasitelje požara Posebna oprema za zaštitu vatrogasaca: Nisu potrebite nikakve posebne mjere. * ODJELJAK 6: Mjere kod slučajnog ispuštanja 6.1 Osobne mjere opreza, zaštitna oprema i postupci za izvanredna stanja Nositi zaštitnu opremu. Nezaštićene osobe držati podalje. 6.2 Mjere zaštite okoliša Ne smije dospjeti u kanalizaciju ili vode. U slučaju dospjeća u vode ili kanalizaciju izvijestiti nadležne organe. (Nastavak na strani 4)

4 Strana: 4/8 (Nastavak sa strane 3) 6.3 Metode i materijal za sprječavanje širenja i čišćenje Pokupiti pomoću materijala koji vežu tekućinu na sebe (pijesak, kremena zemlja, vezivo kiselina, univerzalna veziva, piljevina). Ne isprati vodom ili vodnastim sredstvima za čišćenje. 6.4 Uputa na druge odjeljke Informacije o sigurnom rukovanje vidi poglavlje 7. Informacije o osobnoj zaštitnoj opremi vidi poglavlje 8. Informacije o zbrinjavanju vidi poglavlje 13. * ODJELJAK 7: Rukovanje i skladištenje 7.1 Mjere opreza za sigurno rukovanje Spremnici moraju biti dobro zatvoreni. Upute za zaštitu od požara i eksplozije: Izvore paljenja držati podalje - ne pušiti. Poduzeti mjere protiv elektrostatičkog punjenja. 7.2 Uvjeti sigurnog skladištenja, uzimajući u obzir moguće inkompatibilnosti Skladištenje: Zahtjevi koje skladišni prostori i spremnici moraju ispunjavati: Čuvati samo u originalnim bačvama. Upute za zajedničko skladištenje: Ne skladištiti zajedno s oksidirajućim i kiselim materijalima. Dodatne informacije o uvjetima skladištenja: Spremnici moraju biti nepropustno zatvoreni. Zaštititi od vrućine i neposredne izloženosti sunčevim zrakama. 7.3 Posebna krajnja uporaba ili uporabe * ODJELJAK 8: Nadzor nad izloženošću/osobna zaštita Dodatne upute za oblikovanje tehničkih sustava: Nema daljnjih podataka, vidi točka Nadzorni parametri Nadzor izloženosti na radnom mjestu: Proizvod ne sadrži nikakve relevantne količine materijala, čije bi se granične vrijednosti glede radnog mjesta trebale kontrolirati. Dodatne informacije: Kao osnova su služili popisi, koji su bili važeći u trenutku izrade. 8.2 Nadzor nad izloženošću Mjere osobne zaštite: Opće zaštitne i higijenske mjere: Držati dalje od živežnih namirnica, pića i krme. Odmah skinuti zamazanu i tekućinom natopljenu odjeću. Prije pauze i kraja radnog vremena oprati ruke. Zaštita organa za disanje: Prilikom kratkotrajnog ili neznatnog opterećenja koristiti uređaj za disanje s filtrom; u slučaju intenzivnog, odnosno dužeg izlaganja koristiti uređaj za zaštitu disanja koji je neovisan od okolnog zraka. Zaštita ruku: Zaštitne rukavice Materijal za rukavice Koristiti rukavice od stabilnog materijala (npr. nitril) - eventualno podstavljene trikoom za udobnije nošenje. Vrijeme prodiranja materijala za rukavice Točno vrijeme perforacije materijala može se saznati kod proizvođača zaštitnih rukavica i treba ga se pridržavati. zaštita očiju: Zaštitne naočale (Nastavak na strani 5)

5 Strana: 5/8 Zaštita tijela: Radna zaštitna odjeća (Nastavak sa strane 4) * ODJELJAK 9: Fizikalna i kemijska svojstva 9.1 Informacije o osnovnim fizikalnim i kemijskim svojstvima Opće informacije Agregatno stanje: Oblik: tekuć Boja: Crn Miris: Poput benzina ph vrijednost kod 20 C: n.a. Promjena stanja Talište/područje taljenja: Vrelište/područje vrenja: Plamište: 38 C Neodređen. Neodređen. Zapaljivost (kruta tvar, plin): Nije primjenjiv. Temperatura paljenja: 240 C Samozapaljivost: Proizvod nije samozapaljiv. Opasnost od eksplozije: Ne postoji opasnost od eksplozije proizvoda, međutim moguće je nastajanje smjesa para / zraka, koje mogu eksplodirati. Granice eksplozivnosti: Donja: 0,6 Vol % Gornja: 6,5 Vol % Tlak pare kod 20 C: 33 hpa Gustoća kod 20 C: 0,9 g/cm 3 Topivost u / Miješanje s vodom: Može se u potpunosti miješati. Koncentracija otapala: organska otapala: 0,0 % 9.2 Ostale informacije ODJELJAK 10: Stabilnost i reaktivnost 10.1 Reaktivnost 10.2 Kemijska stabilnost Termičko raspadanje / Uvjeti koje treba izbjegavati: Ne rastvara se kod predviđene uporabe Mogućnost opasnih reakcija Nisu poznate opasne reakcije Uvjeti koje treba izbjegavati 10.5 Inkompatibilni materijali 10.6 Opasni proizvodi raspadanja Nisu poznati nikakvi opasni proizvodi rastvaranja. (Nastavak na strani 6)

6 Strana: 6/8 (Nastavak sa strane 5) * ODJELJAK 11: Toksikološke informacije 11.1 Informacije o toksikološkim učincima Akutna toksičnost LD/LC50-vrijednosti koje su relevantne za stupnjevanje: N-[3-(dimethylamino)propyl)]-C18-ungesättigte Alkylamide Oralno LD50 >2000 mg/kg (rat) Primarno nadražujuće djelovanje: Nagrizanje/nadraživanje kože Ozbiljno oštećenje/nadraživanje očiju Izazivanje preosjetljivosti dišnih putova ili kože Informacije o sljedećim grupama potencijalnih učinaka: CMR djelovanje (kancerogeno, mutageno i za reproduktivni sistem toksično djelovanje) Mutageni učinak na spolne stanice Karcinogenost Reproduktivna toksičnost TCO jednokratno izlaganje Može izazvati pospanost ili vrtoglavicu. TCO ponavljano izlaganje Opasnost od aspiracije * ODJELJAK 12: Ekološke informacije 12.1 Toksičnost Akvatična toksičnost: N-[3-(dimethylamino)propyl)]-C18-ungesättigte Alkylamide EC 50 >0,96 mg/l (Pseudokirchneriella subcapitata (Alge)) EC 50/48h 0,28 mg/l (Daphnia magna (Großer Wasserfloh)) LC50 0,94 mg/l (Brachydanio rerio (Zebrabärbling)) 12.2 Postojanost i razgradivost 12.3 Bioakumulacijski potencijal 12.4 Pokretljivost u tlu Eko-toksično djelovanje: Napomena: Otrovno za ribe. Daljnje ekološke upute: Opće upute: Klasa zagađenja vode 1 (Samostupnjevanje): slabo zagađuje vodu Ne dospustiti da nerazrijeđen, odn. u većim količinama dopije u podzemene vode, vodu ili kanlizaciju. U vodi otrovan za ribe i planktone. otrovno za vodene organizme 12.5 Rezultati ocjenjivanja svojstava PBT i vpvb PBT: Nije primjenjiv. vpvb: Nije primjenjiv. (Nastavak na strani 7)

7 Strana: 7/ Ostali štetni učinci (Nastavak sa strane 6) * ODJELJAK 13: Zbrinjavanje 13.1 Metode obrade otpada Preporuka: Ne smije se zbrinjavati zajedno s komunalnim otpadom. Ne smije dospjeti u kanalizaciju. Onečišćena ambalaža: Preporuka: Odlaganje shodno propisima nadležnih organa. * ODJELJAK 14: Informacije o prijevozu 14.1 UN broj ADR, IMDG, IATA UN Pravilno otpremno ime prema UN-u IMDG, IATA FLAMMABLE LIQUID, N.O.S. (TURPENTINE SUBSTITUTE) 14.3 Razred(i) opasnosti pri prijevozu ADR, IMDG klasa 3 zapaljive tekućine Popis opasnosti 3 IATA Class 3 zapaljive tekućine Label Skupina pakiranja ADR, IMDG, IATA III 14.5 Opasnosti za okoliš Proizvod sadrži materijale, koji su štetni za okoliš: Naphtha (petroleum), hydrotreated heavy Zagađivač mora: Da Simbol (ribe i stabla) Posebno označavanje (ADR): Simbol (ribe i stabla) 14.6 Posebne mjere opreza za korisnika Upozorenje: zapaljive tekućine Kemler-broj: 30 EMS-broj: F-E,S-E 14.7 Prijevoz u razlivenom stanju u skladu s Prilogom II. Konvenciji MARPOL i Kodeksom IBC Nije primjenjiv. Transport/daljnji podaci: ADR Ograničene količine 5L Prijevozna kategorija 3 (Nastavak na strani 8)

8 Strana: 8/8 Tunelska restrikcijska oznaka D/E (Nastavak sa strane 7) UN "Regulacija modela": UN1993, ZAPALJIVA TEKUĆINA, N.D.N. (TERPENTINOV NADOMJESTAK), OPASNO ZA OKOLIŠ, 3, III * ODJELJAK 15: Informacije o propisima 15.1 Propisi u području sigurnosti, zdravlja i okoliša/posebni propisi za tvar ili smjesu 15.2 Procjena kemijske sigurnosti Nije izvršena procjena sigurnosti tvari. * ODJELJAK 16: Ostale informacije Značenje oznakaupozorenja: H226 Zapaljiva tekućina i para. H304 Može biti smrtonosno ako se proguta i uđe u dišni sustav. H314 Uzrokuje teške opekline kože i ozljede oka. H317 Može izazvati alergijsku reakciju na koži. H318 Uzrokuje teške ozljede oka. H336 Može izazvati pospanost ili vrtoglavicu. H400 Vrlo otrovno za vodeni okoliš. H410 Vrlo otrovno za vodeni okoliš, s dugotrajnim učincima. H411 Otrovno za vodeni okoliš s dugotrajnim učincima. R10 Zapaljivo. R35 Izaziva teške opekotine. R41 Opasnost od teških ozljeda očiju. R43 U dodiru s kožom može izazvati preosjetljivost. R50/53 Vrlo otrovno za organizme koji žive u vodi, može dugotrajno štetno djelovati u vodi. R51/53 Otrovno za organizme koji žive u vodi, može dugotrajno štetno djelovati u vodi. R65 Štetno: može izazvati oštećenje pluća ako se proguta. R66 Učestalo izlaganje može prouzročiti sušenje ili pucanje kože. R67 Pare mogu izazvati pospanost ili vrtoglavicu. Osoba za kontakt: l.gobo@itv-murexin.hr Skraćenice i kratice: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids, Hazard Category 3 Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Skin Sens. 1B: Sensitisation - Skin, Hazard Category 1B STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 * Podaci koji su promijenjeni u odnosu na prethodnu verziju

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