HYBRID MONOMER. Copyright NIPPON SHOKUBAI CO., LTD. All rights reserved.

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1 HYBRID MNMER VEEA Copyright NIPPN SHKUBAI C., LTD. All rights reserved.

2 HYBRID MNMER 2(2Vinyloxyethoxy)ethyl acrylate (VEEA) H H 2 C C C radical curable acryloyl group cationic curable vinylether group not inhibited by moisture and bases not inhibited by oxygen many cocurable monomers good dilution no dark reaction good adhesion low skin irritating Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 2

3 Feature VEEA has different kinds of polymerizable groups such as radical polymerizable acryloyl group and cationic polymerizable vinylether group installed in one molecule. Reactive Polymers having acryloyl group or vinylether group are obtained from VEEA by selecting polymerization method. VEEA shows high performances in radiation curable formulations. VEEA shows high dilution performances. Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 3

4 Properties VEEA CAS No Chemical formula C 9 H 14 4 Molecule weight Appearance Boiling point Colorless liquid / 13.3 hpa Density 1.04 g/ml (15 ) Viscosity 3.65 mpa s Solubility in H 2 18 g/l (30 ) Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 4

5 Toxicological Information VEEA Acute toxicity (ralrat) Mutagenic effects LD mg/kg negative in the AMES test Primary Irritation Index P.I.I. = 2.00 Eye Irritation Biodegradability Non irritant 82.1 % (BD) Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 5

6 Regulation Country Status Remark / Specific status Japan ENCS: (2)4028 China Registered under MEP rder No.7 Not listed in IECSC (as New chemical) Korea Phasein substance under KREACH Non toxic substance ( ) Australia AICS: listed New Zealand NZIoC: listed May be used as a component in a product covered by a group standard but it is not approved for use as a chemical in its own right. Philippine PICCS: not listed USA TSCA inv.: listed SNUR * Canada DSL: listed EU Registered under REACH Tonnage band: T/Y (as Non Phasein Substance) Switzerland Registered under ChemV Not listed in EINECS Taiwan TCSI: listed As of 30th June 2016 * The conditions of SNUR for VEEA are as shown below. a) Making MSDS, b) Making Label, c) Wearing of gloves, d) Making Hazard Communication Program, e) Record Keeping Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 6

7 Dilution Performances visco osity (mp Pa 5 ) Unsaturated polyester resin Bisphenolic epoxy acrylate resin VEEA H H H H H H Diethyleneglycol diacrylate Unsaturated Bisphenolic NVinyl pyrrolidone polyester resin epoxyacrylate resin resin / diluent = 60 / 40 (wt / wt) Acryloylmorpholine Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 7

8 UV Curing Performance of VEEA Run No. 1 2 VEEA 100 Diethyleneglycol diacrylate 100 Diethyleneglycol divinyl ether Irgacure UV curing 0.2 J/cm 2 performance 1) 0.3 J/cm J/cm 2 + UV curing once performance 2) twice times 1) UV radiation device: PM25C100 (Ushio Inc.) with 250 W ultrahighpressure Hg vapor lamp, Thickness: 300 µm, Surface tackiness: evaluated by finger touch ( = loss of tack, = not cured) 2) UV radiation device: UB0315BM (EYEGRAPHICS Co., Ltd.) with 80 W highpressure Hg vapor lamp, Thickness: 30 µm, Line speed: 14 m/min, Distance between lamp and substance: 10 cm, Radiation energy of one time: 125 mj/cm 2, Surface tackiness: evaluated by finger touch ( is loss of tack, is not cured) Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 8

9 UV Curing Performance as Reactive Diluent Run No. Unsaturated polyester resin Bisphenolic epoxyacrylate resin VEEA Diethyleneglycol diacrylate Irgacure907 Viscosity (mpa s at 25 ) UV curing 1 time + performance 2) 2 times 4 times times + Pencil hardness (JIS K5400) Acetone resistance (100 times) F B F F 2) UV radiation device: UB0315BM (EYEGRAPHICS Co., Ltd.) with 80 W highpressure Hg vapor lamp, Thickness: 30 µm, Line speed: 14 m/min, Distance between lamp and substance: 10 cm, Radiation energy of one time: 125 mj/cm 2, Surface tackiness: evaluated by finger touch ( is loss of tack, is not cured) Pencil hardness: evaluated after 10 times cured Acetone resistance: evaluated after 10 times cured ( = no change in gloss, = complete loss of gloss) Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 9

10 Adhesion Performance of VEEA average ABS PS PC PMMA 81/100 83/100 91/100 82/100 PVC 39/ /100 47/100 PP Glass Copper VEEA/Irgacure819/Irugacure369 = 94/2/4 (wt ratio) UV radiation device: PM25C100 (Ushio Inc.) with 250 W ultrahighpressure Hg vapor lamp, Thickness: 300 µm Energy: 1.0 J/cm 2 Adhesion Performance: JIS K (IS 2409) Crosscut method Copyright NIPPN SHKUBAI C., LTD. All rights reserved. 10

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