CERTIFICATE DETERGENTS

Transcription

1 F028(GL)v01.1en Date of issue: 30/03/2016 1,00 DETEN 31/12/2017 AT CERTIFICATE DETERGENTS ECOCERT Greenlife SAS certifies that the products mentioned below, produced and/or sold on the market under the responsibility of the company: MEDIASHOP HOLDING GMBH Schwarzottstrasse 2a, 2620 NEUNKIRCHEN AUSTRIA comply with the certification scheme for Natural Detergents and Natural Detergents made with Organic (V3 August 2014): Products Certification level: NATURAL DETERGENTS Brand Granting date pure100 Allzweckreiniger pure100 29/03/2016 pure100 Fettlöser pure100 29/03/2016 pure100 Kalklöser pure100 24/03/2016 End of validity: 31/12/2017 Detergents Certification Manager, Aurélien ROUILLARD Issued in L'ISLE JOURDAIN ECOCERT Greenlife S.A.S. Capital BP L ISLE JOURDAIN FRANCE Intracommunity VAT n FR Phone : Fax : ecoproduits@ecocert.com The present document belongs to ECOCERT Greenlife SAS. It must be erased on ECOCERT request. WARNING: Except prior formal and written consent from ECOCERT Greenlife SAS, the reference to ECOCERT Greenlife (or ECOCERT ) certification and the use of the ECOCERT trademark for products referred to above, by any person or entity other than the beneficiary named herein, is prohibited. ECOCERT Greenlife, mark ECOCERT, accreditation n 50520, Products and Services Certification, scope available on

2 Feldkirch, Beständigkeit / Resistance Pure 100% Sehr geehrte Damen und Herren, hiermit bestätigen wir Ihnen, dass die unten aufgelisteten Verpackungsmittel gegenüber den Produkten Pure 100% Allzweckreiniger, Pure 100% Fettlöser und Pure 100% Kalklöser eine hervorragende chemische Stabilität aufweisen und deshalb zur Verpackung und Aufbewahrung dieser Produkte geeignet sind: 500 ml klarsichtige Rundflasche "Neville Round" (PET), 30 g/stück, Gewinde 24/410, Typ c /410 weiße Dispenserpumpe (PE), Typ SD ml weiße, einwandige Crémedose "F" (PP) weiße Zwischendeckel (PP), Durchmesser 94 mm, Serie "F" weißer Schraubdeckel (PP), Durchmesser 94 mm, Serie "F" Der Vertrieb der Produkte erfolgt durch die MediaShop Holding GmbH. Für Rückfragen stehen wir Ihnen gerne zur Verfügung. UNI SAPON Marion Reichart AlbertSchädlerStrasse 7 A6800 Feldkirch T: +43(0) office@unisapon.com

3 We hereby certify, that the below listed packaging means exhibit an excellent chemical resistance against the products Pure 100% Allzweckreiniger, Pure 100% Fettlöser and Pure 100% Kalklöser and are therefore qualified for packaging and storage of these products: 500 ml transparent round bottle "Neville Round" (PET), 30 g/piece, thread 24/410, type c /410 white dispenser pump (PE), type SD ml white, singlewalled cream jar "F" (PP) white intermediate cap (PP), diameter 94 mm, "F" series white screw cap (PP), diameter 94 mm, "F" series The products are distributed by the MediaShop Holding GmbH. For further questions, please feel free to contact us any time. Mit freundlichen Grüßen / With kind regards, Dr. Tobias Männel UNI SAPON Marion Reichart AlbertSchädlerStrasse 7 A6800 Feldkirch T: +43(0) office@unisapon.com

4 Materialspezifikation / Unbedenklichkeitsbescheinigung Inklusive Alternativmaterialien Die entsprechenden Dokumente finden Sie in den Anlagen zu diesem Deckblatt. Artikelnummer: Lieferant August Pohli GmbH & Co. KG Hölker Feld D Wuppertal Telefon: +49(0) Telefax: +49(0) info@pohli.de Vertriebsbüro Süd Flachsäckerweg 14 D72574 Bad UrachWittlingen Telefon : +49(0) Telefax : +49(0) Internet: Das Dokument wurde elektronisch erstellt und ist ohne Unterschrift gültig Kein Änderungsdienst

5 Food Contact Approval for CORDUSTAT 3978/PP Altenberge, / TO Requirement Explanation Result (EC)1935/2004 Regulation to 2002/72/EC respectively (EU) 10/2011 (e.g. 16 declaration of compliance, 17 traceability) conform (EC)2023/2006 GMP (Good Manufacturing Practice) conform (EU)10/2011 BfR Regulation for Plastic Food Contact Materials / Union list The specific migration and overall migration has to be tested at the finished parts. Furthermore the restrictions according to attachment II of this regulation are valid. Federal Institute for Risk Assessment on Plastics (restrictions possible) conform Contains no substances with SMLvalue see (EU) 10/2011 Under consideration of mentioned dosage recommendations, the addition limit is not exceeded. In addition to this limit, amounts of similar additives from other masterbatches or from the polymer must be considered. US FDA United States Food and Drug Administration conform 21 CFR / positive list restrictions: none (EC)428/2009 Dual Use Additives E 471 The information is based on information from our raw material suppliers and not on analytical inquests and complies with the latest status of creation date (see below). This declaration is issued automatically and valid without signature. Food Contact Approval CORDUSTAT 3978/PP page 1 of 1 version 03 dated: MS/CM

6 ExxonMobil Chemical Belgium A Division of ExxonMobil Petroleum & Chemical, BVBA Registered Office: Polderdijkweg B2030 Antwerp, RPR Antwerpen An ExxonMobil Subsidiary Mail Address : P.O. Box 100, B2060 Antwerp 6, Belgium Address: Issue Date: 01 OCT 2015 Subject: Regulatory Declaration and/or Product Stewardship Information Statement(s) Request Dear Sir/Madam: In response to your request, please find enclosed the regulatory declaration and/or product stewardship information statement(s) for the following product(s): EXXONMOBIL PP1063L1 EXXONMOBIL PP1064L1 These statements are provided by or on behalf of the above referenced ExxonMobil selling affiliate. If you have any questions or need additional information please contact your ExxonMobil sales representative. Enclosure(s): EXXONMOBIL PP1063L1 EUROPEAN FOOD LAW EXXONMOBIL PP1063L1 USA FOOD LAW (FDA) EXXONMOBIL PP1064L1 EUROPEAN FOOD LAW EXXONMOBIL PP1064L1 USA FOOD LAW (FDA) Reference Number: PAGE 1 of 11

7 STATEMENT Issue Date: 01 OCT 2015 At request of: MEADWESTVACO CALMAR GMBH Product Name(s): EXXONMOBIL PP1063L1 Material Code(s): With regard to the compliance status of the ExxonMobil Chemical product referenced above with the regulation(s) identified below the following can be declared: EU FOODCONTACT REGULATION The monomer(s) and the additive(s) intentionally used in the above polymer grade are listed in Annex 1 or are authorized in accordance with the requirements of Commission Regulation (EU) No 10/2011 of 14 January 2011, as amended up to Regulation (EU) No 2015/174, on plastic materials and articles intended to come into contact with food. The above polymer grade complies with the relevant requirements of Regulation (EC) No 1935/2004 in as far as: * the grade is produced using Good Manufacturing Practice as required in article 3.1 of Regulation (EC) No 1935/2004 and meets the guidelines for Good Manufacturing Practice as specified in Regulation (EC) No 2023/2006 (on good manufacturing practice for materials and articles intended to come in contact with food). * the production of the above grade ensures traceability as required in article 17.1 of Regulation (EC) No 1935/2004. * the polymer production aids and aids to polymerization are either permitted in one or more EU Member State(s) and/or have been risk assessed based on the following assumptions: 100% migration, 1kg/food packed with 6dm2 of packaging, article thickness of 250 microns EU MEMBER STATES As for the compliance status with EU Member States laws and/or recommendations where specific requirements exist for substances other than monomers and additives, the following can be stated: The polymer production aids (PPA) possibly present in the above polymer are permitted in the following countries: Belgium "Arrêté royal du 3 juillet 2005 relatif aux matériaux et aux objets en matière plastique destinés à entrer en contact avec les denrées alimentaires", as amended up to "Arrêté royal du 10 février 2011" France "Arrêté du 2 janvier 2003 relatif aux matériaux et objets en PAGE 2 of 11

8 matière plastique mis ou destinés à être mis au contact des denrées, produits et boissons alimentaires", as amended up to "Arrêté du 1er avril 2011" Germany "Bedarfsgegenständeverordnung in der Fassung der Bekanntmachung vom 23. Dezember 1997 (BGBl I S. 5)", as amended up to "Verordnung vom (BGBl. I S. 1682)" BfR Empfehlung VII "Polypropylen" from the Bundesinstitut fuer Risikobewertung "BfR" Italy "Decreto 21 marzo 1973, concernente la disciplina igienica degli imballaggi, recipienti, utensili destinati a venire in contatto con le sostanze alimentari o con sostanze d'uso personale", as amended up to "Decreto 04 febbraio 2013, n. 23 (G.U. Serie Generale n. 71 del 25 marzo 2013)" Spain "Real Decreto 866/2008, de 23 de mayo, por el que se aprueba la lista de sustancias permitidas para la fabricación de materiales y objetos plásticos destinados a entrar en contacto con los alimentos y se regulan determinadas condiciones de ensayo", as amended up to "Orden PRE/628/2011, de 22 de marzo" The Netherlands "Warenwetregeling verpakkingen en gebruiksartikelen" Staatscourant kenmerk VGP from March 14, Hoofdstuk 1 Kunststoffen SWITZERLAND: The composition of the above polymer grade meets the requirements of the Swiss Ordinance on material and objects in Plastic, SR of 23 Nov 2005 (stand 1 April 2013). The composition of the base polymeric component(s) in this polymer grade complies with the positive lists for allowed monomers in the above referenced legislation. The additives that may be present comply with the lists for additives in the above referenced legislation, unless explicitly referred to in the additives note below. Information regarding additives subject to a restriction in food (dual use additives) and information on lipophilic substances are not applicable in Switzerland. # Monomer restrictions: None of the monomers used in the production of this polymer is subject to a Specific Migration Limit (SML). # Presence of additives with SML None of the additives intentionally used in this polymer grade is subject to a Specific Migration Limit (SML). PAGE 3 of 11

9 # Presence of dual use additives The above polymer grade does contain one or more additive(s) that is/are subject to a restriction in food as referred to in Article 11.3 of EU Regulation 10/2011. Note For information purpose only This note contains information relative to the presence of additives subject to a restriction according to Regulation (EU) 10/2011, as described in this statement. Additive : Calcium Stearate EC Ref. No : Salt of Max. conc.* : 900 ppm Restriction : Dual use additive * This information is provided for general guidance purposes only and ExxonMobil Chemical provides no guarantees or warranties in respect of this information and has no responsibility or liability for any use by any third party of this information. Note on Overall Migration Limit ("OML") and on Specific Migration Limits ("SML's"), where applicable Finished plastics foodcontact materials or articles, made from or containing this product, need to comply with Overall Migration Limit ("OML") requirements and Specific Migration Limits ("SML"), where applicable and when tested on the foodcontact surface with the appropriate food simulants and time/temperature test conditions. This is the responsibility of the user of this polymer product. In addition to the above compositional compliance status certification, the polymer user is required to carry out the appropriate overall migration ("OML") and specific migration ("SML") tests on the final material or article to determine the regulatory suitability for contact with different foodtypes (aqueous, fat/oil, alcoholic, etc.) and various enduse conditions (material or article thickness, pure or in blends, volume, contact time of packaging, temperature of use, etc.), all of which are beyond control of the polymer manufacturer. GENERAL NOTE The manufacturer of foodcontact materials and articles made from or containing this polymer grade must ensure that the finished materials or articles meet the general regulatory requirements that they do not bring about an unacceptable change in the composition of the foodstuffs or a deterioration in the organoleptic characteristics thereof and do not release constituents in foodstuffs in quantities that can endanger human health. In addition, the finished foodcontact material or article must be PAGE 4 of 11

10 technically suitable for the intended use. VALIDITY DATE: This document is valid until the next relevant legislative and/or regulatory change with a maximum of one year as of the date of issue of the statement. Reference Number: PAGE 5 of 11

11 STATEMENT Issue Date: 01 OCT 2015 At request of: MEADWESTVACO CALMAR GMBH Product Name(s): EXXONMOBIL PP1063L1 Material Code(s): With regard to the compliance status of the ExxonMobil Chemical product referenced above with the regulation(s) identified below the following can be declared: This product complies with FDA regulation 21 CFR (Olefin polymers), paragraph (c)1.1a, and may be used as articles or components of articles which are intended to contact food. This product is produced under conditions of good manufacturing practice as required by 21 CFR 174.5(a) and is of a purity suitable for its intended use in food contact applications as allowed by the regulatory citations identified above. The manufacturer of any food, direct or indirect food additive, or food contact substance or article containing this product has the responsibility to ensure compliance with applicable FDA regulations and to ensure that any finished food contact article is technically suitable for the intended use. VALIDITY DATE: This document is valid until the next relevant legislative and/or regulatory change with a maximum of one year as of the date of issue of the statement. Reference Number: PAGE 6 of 11

12 STATEMENT Issue Date: 01 OCT 2015 At request of: MEADWESTVACO CALMAR GMBH Product Name(s): EXXONMOBIL PP1064L1 Material Code(s): With regard to the compliance status of the ExxonMobil Chemical product referenced above with the regulation(s) identified below the following can be declared: EU FOODCONTACT REGULATION The monomer(s) and the additive(s) intentionally used in the above polymer grade are listed in Annex 1 or are authorized in accordance with the requirements of Commission Regulation (EU) No 10/2011 of 14 January 2011, as amended up to Regulation (EU) No 2015/174, on plastic materials and articles intended to come into contact with food. The above polymer grade complies with the relevant requirements of Regulation (EC) No 1935/2004 in as far as: * the grade is produced using Good Manufacturing Practice as required in article 3.1 of Regulation (EC) No 1935/2004 and meets the guidelines for Good Manufacturing Practice as specified in Regulation (EC) No 2023/2006 (on good manufacturing practice for materials and articles intended to come in contact with food). * the production of the above grade ensures traceability as required in article 17.1 of Regulation (EC) No 1935/2004. * the polymer production aids and aids to polymerization are either permitted in one or more EU Member State(s) and/or have been risk assessed based on the following assumptions: 100% migration, 1kg/food packed with 6dm2 of packaging, article thickness of 250 microns EU MEMBER STATES As for the compliance status with EU Member States laws and/or recommendations where specific requirements exist for substances other than monomers and additives, the following can be stated: The polymer production aids (PPA) possibly present in the above polymer are permitted in the following countries: Belgium "Arrêté royal du 3 juillet 2005 relatif aux matériaux et aux objets en matière plastique destinés à entrer en contact avec les denrées alimentaires", as amended up to "Arrêté royal du 10 février 2011" France "Arrêté du 2 janvier 2003 relatif aux matériaux et objets en PAGE 7 of 11

13 matière plastique mis ou destinés à être mis au contact des denrées, produits et boissons alimentaires", as amended up to "Arrêté du 1er avril 2011" Germany "Bedarfsgegenständeverordnung in der Fassung der Bekanntmachung vom 23. Dezember 1997 (BGBl I S. 5)", as amended up to "Verordnung vom (BGBl. I S. 1682)" BfR Empfehlung VII "Polypropylen" from the Bundesinstitut fuer Risikobewertung "BfR" Italy "Decreto 21 marzo 1973, concernente la disciplina igienica degli imballaggi, recipienti, utensili destinati a venire in contatto con le sostanze alimentari o con sostanze d'uso personale", as amended up to "Decreto 04 febbraio 2013, n. 23 (G.U. Serie Generale n. 71 del 25 marzo 2013)" Spain "Real Decreto 866/2008, de 23 de mayo, por el que se aprueba la lista de sustancias permitidas para la fabricación de materiales y objetos plásticos destinados a entrar en contacto con los alimentos y se regulan determinadas condiciones de ensayo", as amended up to "Orden PRE/628/2011, de 22 de marzo" The Netherlands "Warenwetregeling verpakkingen en gebruiksartikelen" Staatscourant kenmerk VGP from March 14, Hoofdstuk 1 Kunststoffen SWITZERLAND: The composition of the above polymer grade meets the requirements of the Swiss Ordinance on material and objects in Plastic, SR of 23 Nov 2005 (stand 1 April 2013). The composition of the base polymeric component(s) in this polymer grade complies with the positive lists for allowed monomers in the above referenced legislation. The additives that may be present comply with the lists for additives in the above referenced legislation, unless explicitly referred to in the additives note below. Information regarding additives subject to a restriction in food (dual use additives) and information on lipophilic substances are not applicable in Switzerland. # Monomer restrictions: None of the monomers used in the production of this polymer is subject to a Specific Migration Limit (SML). # Presence of additives with SML None of the additives intentionally used in this polymer grade is subject to a Specific Migration Limit (SML). PAGE 8 of 11

14 # Presence of dual use additives The above polymer grade does contain one or more additive(s) that is/are subject to a restriction in food as referred to in Article 11.3 of EU Regulation 10/2011. Note For information purpose only This note contains information relative to the presence of additives subject to a restriction according to Regulation (EU) 10/2011, as described in this statement. Additive : Calcium Stearate EC Ref. No : Salt of Max. conc.* : 600 ppm Restriction : Dual use additive * This information is provided for general guidance purposes only and ExxonMobil Chemical provides no guarantees or warranties in respect of this information and has no responsibility or liability for any use by any third party of this information. # Specific note on the presence of active oxygen /peroxides: The above polymer grade as it leaves our factory can contain some residual peroxide with CAS Number However, this can possibly be deactivated with further processing. Restrictions applicable in various EU countries Austria, Germany: The surface of the final food contact material or article made from or containing this polymer grade as a component may not show a positive reaction for peroxides when tested according to the method specified (BfR Germany) Belgium: Peroxides are subject to an SML(T) of 0.05 mg/kg food (expressed as active oxygen) Netherlands: Migration of peroxides should be non detectable with a detection limit of SML(T)= 0.05 mg/kg food Italy: Peroxides are subject to an SML of 0.5mg/dm sq (expressed as active oxygen) Resolution of the Council of Europe Resolution (92)2 on control of aids to polymerisation for plastic materials and articles intended to come in contact with foodstuffs (19 October 1992): No peroxide compounds should be extracted from the final article after PAGE 9 of 11

15 immersion in distilled water for 24 hours at 23 deg C using an analytical method with a limit of detection of 0.05mg/kg of active oxygen. Note on Overall Migration Limit ("OML") and on Specific Migration Limits ("SML's"), where applicable Finished plastics foodcontact materials or articles, made from or containing this product, need to comply with Overall Migration Limit ("OML") requirements and Specific Migration Limits ("SML"), where applicable and when tested on the foodcontact surface with the appropriate food simulants and time/temperature test conditions. This is the responsibility of the user of this polymer product. In addition to the above compositional compliance status certification, the polymer user is required to carry out the appropriate overall migration ("OML") and specific migration ("SML") tests on the final material or article to determine the regulatory suitability for contact with different foodtypes (aqueous, fat/oil, alcoholic, etc.) and various enduse conditions (material or article thickness, pure or in blends, volume, contact time of packaging, temperature of use, etc.), all of which are beyond control of the polymer manufacturer. GENERAL NOTE The manufacturer of foodcontact materials and articles made from or containing this polymer grade must ensure that the finished materials or articles meet the general regulatory requirements that they do not bring about an unacceptable change in the composition of the foodstuffs or a deterioration in the organoleptic characteristics thereof and do not release constituents in foodstuffs in quantities that can endanger human health. In addition, the finished foodcontact material or article must be technically suitable for the intended use. VALIDITY DATE: This document is valid until the next relevant legislative and/or regulatory change with a maximum of one year as of the date of issue of the statement. Reference Number: PAGE 10 of 11

16 STATEMENT Issue Date: 01 OCT 2015 At request of: MEADWESTVACO CALMAR GMBH Product Name(s): EXXONMOBIL PP1064L1 Material Code(s): With regard to the compliance status of the ExxonMobil Chemical product referenced above with the regulation(s) identified below the following can be declared: This product complies with FDA regulation 21 CFR (Olefin polymers), paragraph (c)1.1a, and may be used as articles or components of articles which are intended to contact food. This product is produced under conditions of good manufacturing practice as required by 21 CFR 174.5(a) and is of a purity suitable for its intended use in food contact applications as allowed by the regulatory citations identified above. The manufacturer of any food, direct or indirect food additive, or food contact substance or article containing this product has the responsibility to ensure compliance with applicable FDA regulations and to ensure that any finished food contact article is technically suitable for the intended use. VALIDITY DATE: This document is valid until the next relevant legislative and/or regulatory change with a maximum of one year as of the date of issue of the statement. Reference Number: PAGE 11 of 11

17 October 23, 2015 Hostalen GD 7255 A product of Basell Sales & Marketing Company B.V. Dear Christiane Gräber: The following is in response to your request for Product Stewardship Information (PSInfo) for the product listed above. The attached Product Stewardship Bulletin (PSB) details the regulatory status of this product. LyondellBasell Industries responds to product stewardship requests with a standardized Product Stewardship Bulletin (PSB) which summarizes the global regulatory status of a product. LyondellBasell Industries will not complete customers forms or questionnaires. Standardized responses provide each customer with consistent information in a timely fashion. Each request is reviewed to ensure our response documents provide relevant information. Please note that compliance with these regulations should not be interpreted to guarantee that the product, will, in fact, perform in a particular application. Your Technical Service Representative can help you determine that the characteristics of the product are compatible with the desired conditions of use. Should you have any further questions concerning a LyondellBasell product, or if we can assist in any other way, please do not hesitate to contact us. Best regards, Micaela Poltronieri Product Safety Specialist micaela.poltronieri@lyondellbasell.com LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 1 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

18 Product Stewardship Bulletin Hostalen GD 7255 A product of Basell Sales & Marketing Company B.V. Global Food Contact Status: European Union This product complies with the relevant requirements of Regulation 1935/2004/EC (Framework Regulation) as applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). This product complies with the relevant requirements of Regulation 2023/2006/EC (GMP) and as amended, applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). This product complies with the relevant requirements of Regulation 10/2011/EC (PIM) as amended, applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). The monomers and additives used to produce this product are listed in the Union List of Authorized Substances of Regulation 10/2011/EC and subsequent amendments. EU Regulation 10/2011/EC specifies 10 mg/dm2 as the maximum overall migration (OML) from the finished plastic food contact material or article. The OML and SMLs (when applicable) should be determined according to the requirements specified in EU Regulation 10/2011/EC and subsequent amendments. The OML and SML determinations are the responsibility of the manufacturer of the finished plastic food contact material or article. In addition, we remind you that the manufacturers of the finished food contact material or article must verify that the finished material or article, manufactured according to good manufacturing practices, does not modify the organoleptic properties of the food. Specific Migration Limits This product does not contain monomers, additives or other components which have SMLs or QMAs as specified by Regulation 10/2011/EC. This product contains one or more Dual Use Additives as defined in Regulation 10/2011/EC. E 470a Calcium salts of fatty acids EU National Legislations LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 2 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

19 The composition of this product complies with the following National Legislations, Recommendations or Communications for the production of food packaging. Austria: "K.V.O." N.476/2003 as amended at last by BGBl Teil. II N.140/2009 Belgium: "Arrete royal du 5 juillet 2006 (amending Arrete royal du 11 mai 1992 and modifying "Arrete royal du 3 juillet 2005"). Denmark: Bekendtgorelse N.579 (01/06/2011) Finland: "KTM", Paatos 953/2002 of (amended by 107/2009 of 03/03/2009) France: "Materiaux au contact des aliments et de denre destine a l'alimentation humaine" Brochure n.1227 edition Janvier 1994 as updated. Arrete du 02 Janvier 2003 (as modified at last by Arrete 03/09/2010). Germany: Bedarfsgegenstaendeverordnung in der Fassung vom 23 Dezember 1997 (BGBI. I 1998 S.5), zuletzt geandert durch Art. 1 der Verordnung vom 24 Juni 2013 (BGBI I S. 1682) Greece: AXE Decision n.458/2003 modified by Decision n. 6/2011 Ireland: S.I. No. 587 of 2007, as amended by S.I. No.301 of 2010 Italy: "Decreto Ministeriale del 21/03/1973" amended on 26/4/1993 : D.M. N.220 and following updates (last update: D.M. of 16/02/2011). Luxembourg: "Reglement GrandDucal" n. 163 du 05/11/2008. Norway: Regulations 21 December 1993, No. 1381, on materials and articles intended to come into contact with foostuffs Chaper I General regulations, as amended. Portugal: DecretoLei No. 62/2008 of 31/03/2008, and Amend. DecretoLei No. 29/2009, of 02/02/2009. Spain: Real Decreto N /01/2003, modified by Real Decreto N.103/2009, of 06/02/2009. Sweden: Ordinance of the National Food Administration on materials and articles intended to come into contact with foodstuffs LIVSFS 2011:7. The Netherlands: Staatscourant n.6861 of England: "The Plastic Materials and Articles in Contact with Food (England) Regulations 2009", Statutory Instrument 2009 n Switzerland: BGVO of 23 November 2005, as amended. Czech Republic: Regulation of the Ministry of Health N.551/2006, modifying N.38/2001. United States LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 3 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

20 The base resin in this product meets the FDA requirements contained in the Code of Federal Regulations in 21 CFR (a)(3)(i) and (c)3.2a. This product may also contain adjuvant substances that may be safely used in polymers used for the manufacture of articles that come into direct contact with food. According to our information, the substances used in this product meet the requirements of their respective FDA regulations and 21 CFR (b). This product meets the FDA criteria in 21 CFR for food contact applications, including cooking, listed under conditions of use A through H in 21 CFR (c), Table 2, and can be used in contact with all food types as listed in 21 CFR (c), Table 1. Allergen Statements The food ingredients listed in Annex II of Regulation (EU) No 1169/2011, are not used in the manufacture of or formulation of this product. However, this product has not been tested for these substances. IMDS Information The companies of LyondellBasell enter data into IMDS directly to assist automobile companies in the recycling effort, to confirm the compliance of products manufactured by LyondellBasell companies with the heavy metals article of the EU End of Life Vehicle (ELV) Directive, and to declare the presence of substances listed in the Global Automotive Declarable Substances List (GADSL) if required. Note: LyondellBasell does not send MDS reports to customer recipient ID numbers. Our product MDSs are in a Published state accessible to every IMDS user through the IMDS website. Please use the following IMDS IDNo. for your reference: IMDS# Biomedical Policy LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 4 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

21 This product(s) may not be used in: (i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I Medical Devices, without prior notification to Seller for each specific product and application; or (ii) the manufacture of any of the following, without prior written approval by Seller for each specific product and application: (1) U.S. FDA Class II, Health Canada Class II or Class III, and/or European Union Class II Medical Devices; (2) film, overwrap and/or product packaging that is considered a part or component of one of the aforementioned Medical Devices; (3) packaging in direct contact with a pharmaceutical active ingredient and/or dosage form that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or topical (skin) administration; (4) tobacco related products and applications; (5) electronic cigarettes and similar devices. (iii) Additionally, the product(s) may not be used in: (1) U.S. FDA Class III, Health Canada Class IV, and/or European Class III Medical Devices; (2) applications involving permanent implantation into the body; (3) lifesustaining medical applications. All references to U.S. FDA, Health Canada, and European Union regulations include other country s equivalent regulatory classifications. Users should review the applicable Safety Data Sheet before handling the product. Animal Based RawMaterials (BSE/TSE) Tallow Tallow derived additives may be used in the manufacture of this product. Europe BSE/TSE "Mad Cow" Tallow derived materials used in this product fullfill the requirements laid down in the Regulations 1069/2009/EC, and 142/2011/EC, and the "Note for Guidance EMEA/410/01, rev. 3". Epoxy Derivatives The materials BADGE, BFDGE or NOGE are not intentionally added in this product as referenced in Commission Regulation 1895/2005/EC, on the use of certain epoxy derivatives in materials and articles intended to come into contact with foodstuffs as plasticizers, additives or raw materials. Conflict Minerals (DoddFrank Wall Street Reform and Consumer Protection Act September, 2010) Please see link below for the position of LyondellBasell concerning this Act: The link to this document is located in the right margin of this website landing page titled download our conflict minerals policy. Halal Certification LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 5 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

22 This product is not certified as Halal. Kosher Certification This product is not certified Kosher. Latex No materials containing latex or natural rubber are used in the manufacturing, handling and packaging processes for this product. Metals Content US CONEG Based on the available documentation provided by our raw material suppliers, this product complies with the CONEG Model Legislation for requirements regarding the defined limit for the sum of heavy metals (lead, mercury, cadmium and hexavalent chromium). EU Packaging and Packaging Waste Based on the available documentation from raw materials suppliers, this product complies with the directive 94/62/EC and its following amendments concerning the defined limit(s)of heavy metals. Restriction of Hazardous Substances in Electric and Electronic Equipment (RoHS) RoHS Regulation refers to electrical and electronic equipment and not specifically to plastic raw materials. However, based on the available documentation from raw materials suppliers, this product complies with the requirements of the Directives 2002/95/EC, as amended, and 2011/65/EU concerning the limits of cadmium, lead, mercury, hexavalent chromium, polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE). Nanomaterials Nanomaterials (defined as natural, incidental or manufactured materials containing particles, in an unbound state or as an aggregate or as an agglomerate and where, for 50 % or more of the particles in the number size distribution, one or more external dimensions is in the size range 1 nm 100 nm) are not used in the manufacture of or the formulation of this grade. However, this product has not been tested for these chemical substances. Other Chemicals The chemical materials listed below are not used in the manufacture or the formulation of this product and are not expected to be present. However, this product has not been tested for these chemical materials. 2(2H1, 2, 3Benzotriazol2yl)4,6ditertbutylphenol; (Benzotriazole); CAS# ; LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 6 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

23 2,4,4 trichloro2 hydroxydiphenyl ether; (Triclosan); CAS# ; 2mercaptobenzothiazole; MBT; CAS# ; Acrolein; (propenal); (CAS# ); Acrylamide; CAS# 79061; Aromatic amines; Asbestos; Azo Dyes and Pigments; Polyaromatic Hydrocarbons PAHs: 1,2dihydroacenaphthene; (CAS# 83329); 9HFluorene; (CAS# 86737); Acenaphthylene; (CAS# ); Anthracene; (CAS# ); Benz(a)anthracene; (CAS# 56553); Benzo(a)pyrene; (CAS# 50328); Benzo(b)fluoranthene; (CAS# ); Benzo(e)pyrene; (CAS# ); Benzo(ghi)perylene; (CAS# ); Benzo(j)fluoranthene; (CAS# ); Benzo(k)fluoranthene; (CAS# ); Chrysene; (CAS# ); Dibenz(a,h)anthracene; (CAS# 53703); Fluoranthene; (CAS# ); Indeno(1,2,3cd)pyrene; (CAS# ); Naphthalene; (CAS# 91203); Phenanthrene; (CAS# 85018); Pyrene; (CAS# ); Benzophenone; CAS RN ; Bisphenol A; (BPA); CAS# 80057; Bisphenol A diglycidyl ether; (BADGE); CAS# ; Bisphenol F diglycidyl ether; BFDGE; CAS# ; Butylated hydroxyanisole; (BHA); CAS# & ; Butylated hydroxytoluene; (BHT); CAS# Chlorinated paraffins; LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 7 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

24 Cyanuric acid; (Isocyanuric Acid or CYA); CAS# ; Dimethyl fumarate; (DMF); CAS# ; Dioxins; Epichlorohydrin; (ECH); CAS# ; Fluorocarbons; Fluorotelomers Formaldehyde; CAS# 50000; Formaldehyde in specific conditions could be formed during the resin processing (see MSDS) Gold(Au); CAS# ; Halogenated Flame Retardants Melamine; (1,3,5Triazine2,4,6triamine); CAS# ; Nonylphenol; CAS# ; Nonylphenol ethoxylates; Novolac glycidyl ether; Organotin compounds; Perfluorochemicals; (PFCs); Perfluorooctane sulfonate; (PFOS); CAS# ; Perfluorooctanoic acid; (PFOA); CAS# ; Polybrominated biphenyls; (PBBs); Polybrominated diphenyl ethers; (PDBEs); Polybrominated terphenyls; (PBTs); Polychlorinated biphenyls; (PCBs); LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 8 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

25 Polychlorinated naphthalenes; (PCNs); Polychlorinated terphenyls; (PCTs); Polystyrene; Polyvinyl chloride; (PVC); CAS# ; Radioactive substances; Radon; CAS# ; Styrene monomer; CAS# ; Sulphur dioxide; CAS# ; Tin oxide (SnO2); (Cassiterite); CAS# ; Trisnonylphenol phosphite; (TNPP); CAS# ; Vinyl chloride; CAS# 75014; Wolframite; Tungsten (W); CAS# ; Ozone Depleting Substances European Union The ozonedepleting substances (ODS), listed in the Annexes I & II of the Regulation ( EC ) No 1005/2009 of 16 September 2009, are not intentionally used in the manufacture of or formulation of this product. United States Materials listed in the Clean Air Act Amendments of 1990 (Class I, CFC s and Class II, HCFC s, Halons and the solvents, carbon tetrachloride and 1,1,1trichloroethane) are not intentionally used in the production of this product. Phthalates Phthalates are not used in the manufacture of or the formulation of this product. However, this product has not been tested for phthalates. REACh Information LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 9 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

26 This product is manufactured by affiliates and subsidiaries of the LyondellBasell group of companies around the world. Under the EC Regulation REACh this product is classified as a preparation. If the product has been purchased from Basell Sales & Marketing Company B.V. BSM), we confirm that all substances in this preparation have been preregistered or, where required under REACh, registered, and that we have the intention either to proceed with their registration in accordance with the deadlines set forth in REACh, or to procure substances only from suppliers from which confirmation has been received that the suppliers are aware of their REACh requirements, that they have met their preregistration and applicable registration obligations of their substances, and that they will supply the relevant Safety Data Sheets (SDS) with REACh registration numbers as soon as the registrations occur. In no event shall any LyondellBasell group be liable for any noncompliance deriving from false or incorrect statements of its suppliers. We remind you, if this product is purchased from any supplier, including other companies of the LyondellBasell group, which is not established in the European Union, the importer into the European Economic Area (EEA) is responsible for compliance with the requirements of REACh. Please contact REACh@LyondellBasell.com if you need to discuss the potential compliance with REACh before importing this product into the EEA. REACh Substances of Very High Concern (SVHC) This product does not contain any of the Annex XIV candidate chemicals proposed to be Substances of Very High Concern (List as of June 15, 2015) above the 0.1% threshold as stated in REACH (Article 57, Regulation No. 1907/2006) determined either through (i) nonuse of the substance, (ii) mass balance calculation, or (iii) specific testing. The current list of all SVHCs can be found at ECHA website link listed below: Global Chemical Control Regulations All ingredients in this product are in compliance with the following chemical inventories: See Section 15, of the SDS (Safety Data Sheet) for Global Chemical Inventories. Global Toy Regulations: CEN EN Standards refer to safety of toys and not specifically to plastic raw materials. According to the information provided by our raw material suppliers, we deem this product should comply with the requirements of CEN standards EN713 / EN719 (as amended) as applicable to plastic raw materials (pellets, powder, flakes). However, this product has not been tested according to these CEN Standards. VOC Content Switzerland VOC Declaration This product contains less than 3% VOC's of the substances in the positive lists of the Switzerland Regulations "VOCLENKUNGSABGABE." LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 10 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

27 CEN Standard pren This product is not suitable for composting. Energy Recovery CEN Standard pren The calorific gain from polyethylene in an energy recovery process is 22 MJ/Kg. Disclaimer The information in this document is, to our knowledge, true and accurate at the time and date of issue. However, information in this document may be updated periodically due to changes in the laws and regulations, or for other reasons, therefore we cannot guarantee that the status of this product will remain unchanged. Users are expected to regularly visit the PSInfo Website to obtain the most current information on this product. Product Stewardship Bulletins not directly received from the PSInfo system are uncontrolled documents. Before using a product sold by a company of the LyondellBasell family of companies, users should make their own independent determination that the product is suitable for the intended use and can be used safely and legally. SELLER MAKES NO WARRANTY; EXPRESS OR IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY WARRANTY) OTHER THAN AS SEPARATELY AGREED TO BY THE PARTIES IN A CONTRACT. This product(s) may not be used in: (i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I Medical Devices, without prior notification to Seller for each specific product and application; or (ii) the manufacture of any of the following, without prior written approval by Seller for each specific product and application: (1) U.S. FDA Class II, Health Canada Class II or Class III, and/or European Union Class II Medical Devices; (2) film, overwrap and/or product packaging that is considered a part or component of one of the aforementioned Medical Devices; (3) packaging in direct contact with a pharmaceutical active ingredient and/or dosage form that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or topical (skin) administration; (4) tobacco related products and applications; (5) electronic cigarettes and similar devices; and (6) pressure pipe or fittings that are considered a part or component of a nuclear reactor. (iii) Additionally, the product(s) may not be used in: (1) U.S. FDA Class III, Health Canada Class IV, and/or European Class III Medical Devices; (2) applications involving permanent implantation into the body; (3) lifesustaining medical applications; and (4) lead, asbestos or MTBE related applications. All references to U.S. FDA, Health Canada, and European Union regulations include other country s equivalent regulatory classifications. Users should review the applicable Safety Data Sheet before handling the product. Addhere, Adflex, Adstif, Adsyl, Akoafloor, Akoalit, Alathon, Amazing Chemistry, Aquamarine, Aquathene, Avant, Catalloy, Clyrell, CRP, Crystex, Dexflex, Explore & Experiment, Flexathene, Glacido, Hifax, Histif, Hostacom, Hostalen, Ideal, Integrate, Koattro, LIPP, Lucalen, Luflexen, Lupolen, Lupolex, Luposim, Lupostress, Lupotech, Metocene, Microthene, Moplen, Nerolex, Nexprene, Petrothene, Plexar, Pristene, Prodflex, ProFax, Purell, Sequel, Softell, Spherilene, Spheripol, Spherizone, Starflex, Stretchene, Superflex, Toppyl, Trans4m, Ultrathene, Vacido and Valtec are trademarks owned or used by the LyondellBasell family of companies. Adsyl, Akoafloor, Akoalit, Alathon, Aquamarine, Avant, CRP, Crystex, Dexflex, Explore & Experiment, Flexathene, Hifax, Hostacom, Hostalen, Ideal, Integrate, Koattro, Lucalen, Lupolen, Microthene, Moplen, Nexprene, Petrothene, Plexar, Pristene, ProFax, Purell, Sequel, Softell, Spheripol, Spherizone, Starflex, Toppyl, and Ultrathene are registered in the U.S. Patent and Trademark Office. LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 11 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

28 LyondellBasell Product Stewardship Information Date: 10/23/2015 Page 12 of 12 Hostalen GD 7255 Recipient Tracking #: Request #:

29 February 05, 2015 Moplen RP348R A product of Basell Sales & Marketing, BV Dear Christiane Gräber: The following is in response to your request for Product Stewardship Information (PSInfo) for the product listed above. The attached Product Stewardship Bulletin (PSB) details the regulatory status of this product. LyondellBasell Industries responds to product stewardship requests with a standardized Product Stewardship Bulletin (PSB) which summarizes the global regulatory status of a product. LyondellBasell Industries will not complete customers forms or questionnaires. Standardized responses provide each customer with consistent information in a timely fashion. Each request is reviewed to ensure our response documents provide relevant information. Please note that compliance with these regulations should not be interpreted to guarantee that the product, will, in fact, perform in a particular application. Your Technical Service Representative can help you determine that the characteristics of the product are compatible with the desired conditions of use. Should you have any further questions concerning a LyondellBasell product, or if we can assist in any other way, please do not hesitate to contact us. Best regards, Roberta Marzolla Product Safety Specialist Roberta.Marzolla@lyondellbasell.com LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 1 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

30 Product Stewardship Bulletin Moplen RP348R A product of Basell Sales & Marketing, BV Global Food Contact Status: European Union This product complies with the relevant requirements of Regulation 1935/2004/EC (Framework Regulation) as applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). This product complies with the relevant requirements of Regulation 2023/2006/EC (GMP) and as amended, applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). This product complies with the relevant requirements of Regulation 10/2011/EC (PIM) as amended, applicable to intermediate materials (e.g. plastic powders, plastic granules or plastic flakes). The monomers and additives used to produce this product are listed in the Union List of Authorized Substances of Regulation 10/2011/EC and subsequent amendments. EU Regulation 10/2011/EC specifies 10 mg/dm2 as the maximum overall migration (OML) from the finished plastic food contact material or article. The OML and SMLs (when applicable) should be determined according to the requirements specified in EU Regulation 10/2011/EC and subsequent amendments. The OML and SML determinations are the responsibility of the manufacturer of the finished plastic food contact material or article. In addition, we remind you that the manufacturers of the finished food contact material or article must verify that the finished material or article, manufactured according to good manufacturing practices, does not modify the organoleptic properties of the food. SML Components This product contains one or more components with Specific Migration Limits (SMLs) ; 9,9bis(methoxymethyl)9Hfluorene; SML 0.05mg/kg Reference No: 39090; N,Nbis(2hydroxyethyl)alkyl (C8C18)amine; SML(T)= 1,2 mg/kg Reference No: 39120; N,Nbis(2hydroxyethyl)alkyl (C8C18)amine hydrochlorides; SML (T) 1.2 mg/kg (Expressed as tertiary amine excluding HCl) Dual Use Additives LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 2 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

31 This product contains one or more Dual Use Additives as defined in Regulation 10/2011/EC. E 470a Calcium salts of fatty acids E 471 Mono and diglycerides of fatty acids EU National Legislations The composition of this product complies with the following National Legislations, Recommendations or Communications for the production of food packaging. Austria: "K.V.O." N.476/2003 as amended at last by BGBl Teil. II N.140/2009 Belgium: "Arrete royal du 5 juillet 2006 (amending Arrete royal du 11 mai 1992 and modifying "Arrete royal du 3 juillet 2005"). Denmark: Bekendtgorelse N.579 (01/06/2011) Finland: "KTM", Paatos 953/2002 of (amended by 107/2009 of 03/03/2009) France: "Materiaux au contact des aliments et de denre destine a l'alimentation humaine" Brochure n.1227 edition Janvier 1994 as updated. Arrete du 02 Janvier 2003 (as modified at last by Arrete 03/09/2010). Germany: Bedarfsgegenstaendeverordnung 07 February 2011 (BGBl I S.226) Greece: AXE Decision n.458/2003 modified by Decision n. 6/2011 Ireland: S.I. No. 587 of 2007, as amended by S.I. No.301 of 2010 Italy: "Decreto Ministeriale del 21/03/1973" amended on 26/4/1993 : D.M. N.220 and following updates (last update: D.M. of 16/02/2011). Luxembourg: "Reglement GrandDucal" n. 163 du 05/11/2008. Norway: Regulations 21 December 1993, No. 1381, on materials and articles intended to come into contact with foostuffs Chaper I General regulations, as amended. Portugal: DecretoLei No. 62/2008 of 31/03/2008, and Amend. DecretoLei No. 29/2009, of 02/02/2009. Spain: Real Decreto N /01/2003, modified by Real Decreto N.103/2009, of 06/02/2009. Sweden: Ordinance of the National Food Administration on materials and articles intended to come into contact with foodstuffs LIVSFS 2011:7. The Netherlands: Staatscourant n.6861 of LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 3 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

32 England: "The Plastic Materials and Articles in Contact with Food (England) Regulations 2009", Statutory Instrument 2009 n Switzerland: BGVO of 23 November 2005, as amended. Czech Republic: Regulation of the Ministry of Health N.551/2006, modifying N.38/2001. United States The base resin in this product meets the FDA requirements contained in the Code of Federal Regulations in 21 CFR (a)(3)(i) and (c)3.2a. This product may contain adjuvant substances that may be safely used in polymers used for the manufacture of articles that come into direct contact with food. According to our information, these substances used in this product meet the requirements of their respective FDA regulations, FCNs, and 21 CFR (b). This product meets the FDA criteria in 21 CFR for food contact applications, including cooking, listed under conditions of use A through H in 21 CFR (c), Table 2, and can be used in contact with all food types as listed in 21 CFR (c), Table 1. Allergen Statements The food ingredients listed in Annex II of Regulation (EU) No 1169/2011, are not used in the manufacture of or formulation of this product. However, this product has not been tested for these substances. Biomedical Policy This product(s) may not be used in: (i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I Medical Devices, without prior notification to Seller for each specific product and application; or (ii) the manufacture of any of the following, without prior written approval by Seller for each specific product and application: (1) U.S. FDA Class II, Health Canada Class II or Class III, and/or European Union Class II Medical Devices; (2) film, overwrap and/or product packaging that is considered a part or component of one of the aforementioned Medical Devices; (3) packaging in direct contact with a pharmaceutical active ingredient and/or dosage form that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or topical (skin) administration; (4) tobacco related products and applications; (5) electronic cigarettes and similar devices. (iii) Additionally, the product(s) may not be used in: (1) U.S. FDA Class III, Health Canada Class IV, and/or European Class III Medical Devices; (2) applications involving permanent implantation into the body; (3) lifesustaining medical applications. All references to U.S. FDA, Health Canada, and European Union regulations include other country s equivalent regulatory classifications. Users should review the applicable Safety Data Sheet before handling the product. LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 4 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

33 Animal Based RawMaterials (BSE/TSE) Tallow Tallow derived additives may be used in the manufacture of this product. Europe BSE/TSE "Mad Cow" Tallow derived materials used in this product fullfill the requirements laid down in the Regulations 1069/2009/EC, and 142/2011/EC, and the "Note for Guidance EMEA/410/01, rev. 3". Epoxy Derivatives The materials BADGE, BFDGE or NOGE are not intentionally added in this product as referenced in Commission Regulation 1895/2005/EC, on the use of certain epoxy derivatives in materials and articles intended to come into contact with foodstuffs as plasticizers, additives or raw materials. Conflict Minerals (DoddFrank Wall Street Reform and Consumer Protection Act September, 2010) Please see link below for the position of LyondellBasell concerning this Act: The link to this document is located in the right margin of this website landing page titled download our conflict minerals policy. Halal Certification This product is not certified as Halal. Kosher Certification This product is not certified Kosher. Latex No materials containing latex or natural rubber are used in the manufacturing, handling and packaging processes for this product. Metals Content US CONEG Based on the available documentation provided by our raw material suppliers, this product complies with the CONEG Model Legislation for requirements regarding the defined limit for the sum of heavy metals (lead, mercury, cadmium and hexavalent chromium). LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 5 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

34 EU Packaging and Packaging Waste Based on the available documentation from raw materials suppliers, this product complies with the directive 94/62/EC and its following amendments concerning the defined limit(s)of heavy metals. Restriction of Hazardous Substances in Electric and Electronic Equipment (RoHS) RoHS Regulation refers to electrical and electronic equipment and not specifically to plastic raw materials. However, based on the available documentation from raw materials suppliers, this product complies with the requirements of the Directives 2002/95/EC, as amended, and 2011/65/EU concerning the limits of cadmium, lead, mercury, hexavalent chromium, polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE). Nanomaterials Nanomaterials (defined as natural, incidental or manufactured materials containing particles, in an unbound state or as an aggregate or as an agglomerate and where, for 50 % or more of the particles in the number size distribution, one or more external dimensions is in the size range 1 nm 100 nm) are not used in the manufacture of or the formulation of this grade. However, this product has not been tested for these chemical substances. Other Chemicals The chemical materials listed below are not used in the manufacture or the formulation of this product and are not expected to be present. However, this product has not been tested for these chemical materials. 2(2H1, 2, 3Benzotriazol2yl)4,6ditertbutylphenol; (Benzotriazole); CAS# ; 2,4,4 trichloro2 hydroxydiphenyl ether; (Triclosan); CAS# ; 2mercaptobenzothiazole; MBT; CAS# ; Acrolein; (propenal); (CAS# ); Acrylamide; CAS# 79061; Aromatic amines; Asbestos; Azo Dyes and Pigments; LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 6 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

35 Polyaromatic Hydrocarbons PAHs: 1,2dihydroacenaphthene; (CAS# 83329); Acenaphthylene; (CAS# ); Anthracene; (CAS# ); Benz(a)anthracene; (CAS# 56553); Benzo(a)pyrene; (CAS# 50328); Benzo(b)fluoranthene; (CAS# ); Benzo(e)pyrene; (CAS# ); Benzo(ghi)perylene; (CAS# ); Benzo(j)fluoranthene; (CAS# ); Benzo(k)fluoranthene; (CAS# ); Chrysene; (CAS# ); Dibenz(a,h)anthracene; (CAS# 53703); Fluoranthene; (CAS# ); Indeno(1,2,3cd)pyrene; (CAS# ); Naphthalene; (CAS# 91203); Phenanthrene; (CAS# 85018); Pyrene; (CAS# ); Benzophenone; CAS RN ; Bisphenol A; (BPA); CAS# 80057; Bisphenol A diglycidyl ether; (BADGE); CAS# ; Bisphenol F diglycidyl ether; BFDGE; CAS# ; Butylated hydroxyanisole; (BHA); CAS# & ; Butylated hydroxytoluene; (BHT); CAS# Chlorinated paraffins; Cyanuric acid; (Isocyanuric Acid or CYA); CAS# ; Dimethyl fumarate; (DMF); CAS# ; Dioxins; Epichlorohydrin; (ECH); CAS# ; Fluorocarbons; Fluorotelomers Formaldehyde; CAS# 50000; LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 7 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

36 Formaldehyde in specific conditions could be formed during the resin processing (see MSDS) Gold(Au); CAS# ; Halogenated Flame Retardants Melamine; (1,3,5Triazine2,4,6triamine); CAS# ; Nonylphenol; CAS# ; Nonylphenol ethoxylates; Novolac glycidyl ether; Organotin compounds; Perfluorochemicals; (PFCs); Perfluorooctane sulfonate; (PFOS); CAS# ; Perfluorooctanoic acid; (PFOA); CAS# ; Polybrominated biphenyls; (PBBs); Polybrominated diphenyl ethers; (PDBEs); Polybrominated terphenyls; (PBTs); Polychlorinated biphenyls; (PCBs); Polychlorinated naphthalenes; (PCNs); Polychlorinated terphenyls; (PCTs); Polystyrene; Polyvinyl chloride; (PVC); CAS# ; Styrene monomer; CAS# ; Sulphur dioxide; CAS# ; Tin oxide (SnO2); (Cassiterite); CAS# ; Trisnonylphenol phosphite; (TNPP); CAS# ; LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 8 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

37 Vinyl chloride; CAS# 75014; Wolframite; Tungsten (W); CAS# ; Ozone Depleting Substances European Union The ozonedepleting substances (ODS), listed in the Annexes I & II of the Regulation ( EC ) No 1005/2009 of 16 September 2009, are not intentionally used in the manufacture of or formulation of this product. United States Materials listed in the Clean Air Act Amendments of 1990 (Class I, CFC s and Class II, HCFC s, Halons and the solvents, carbon tetrachloride and 1,1,1trichloroethane) are not intentionally used in the production of this product. Phthalates Phthalates are not used in the manufacture of or the formulation of this product. However, this product has not been tested for phthalates. REACh Information This product is manufactured by affiliates and subsidiaries of the LyondellBasell group of companies around the world. Under the EC Regulation REACh this product is classified as a preparation. If the product has been purchased from Basell Sales & Marketing Company B.V. BSM), we confirm that all substances in this preparation have been preregistered or, where required under REACh, registered, and that we have the intention either to proceed with their registration in accordance with the deadlines set forth in REACh, or to procure substances only from suppliers from which confirmation has been received that the suppliers are aware of their REACh requirements, that they have met their preregistration and applicable registration obligations of their substances, and that they will supply the relevant Safety Data Sheets (SDS) with REACh registration numbers as soon as the registrations occur. In no event shall any LyondellBasell group be liable for any noncompliance deriving from false or incorrect statements of its suppliers. We remind you, if this product is purchased from any supplier, including other companies of the LyondellBasell group, which is not established in the European Union, the importer into the European Economic Area (EEA) is responsible for compliance with the requirements of REACh. Please contact REACh@LyondellBasell.com if you need to discuss the potential compliance with REACh before importing this product into the EEA. REACh Substances of Very High Concern (SVHC) LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 9 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

38 This product does not contain any of the Annex XIV candidate chemicals proposed to be Substances of Very High Concern (List as of December 17, 2014) above the 0.1% threshold as stated in REACH (Article 57, Regulation No. 1907/2006) determined either through (i) nonuse of the substance, (ii) mass balance calculation, or (iii) specific testing. The current list of all SVHCs can be found at ECHA website link listed below: Global Chemical Control Regulations All ingredients in this product are in compliance with the following chemical inventories: See SDS for Global Chemical Inventories VOC Content Switzerland VOC Declaration This product contains less than 3% VOC's of the substances in the positive lists of the Switzerland Regulations "VOCLENKUNGSABGABE." CEN Standard pren This product is not suitable for composting. Energy Recovery CEN Standard pren The calorific gain from polypropylene in an energy recovery process is 24 MJ/kg. Disclaimer LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 10 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

39 The information in this document is, to our knowledge, true and accurate at the time and date of issue. However, information in this document may be updated periodically due to changes in the laws and regulations, or for other reasons, therefore we cannot guarantee that the status of this product will remain unchanged. Users are expected to regularly visit the PSInfo Website to obtain the most current information on this product. Product Stewardship Bulletins not directly received from the PSInfo system are uncontrolled documents. Before using a product sold by a company of the LyondellBasell family of companies, users should make their own independent determination that the product is suitable for the intended use and can be used safely and legally. SELLER MAKES NO WARRANTY; EXPRESS OR IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY WARRANTY) OTHER THAN AS SEPARATELY AGREED TO BY THE PARTIES IN A CONTRACT. This product(s) may not be used in: (i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I Medical Devices, without prior notification to Seller for each specific product and application; or (ii) the manufacture of any of the following, without prior written approval by Seller for each specific product and application: (1) U.S. FDA Class II, Health Canada Class II or Class III, and/or European Union Class II Medical Devices; (2) film, overwrap and/or product packaging that is considered a part or component of one of the aforementioned Medical Devices; (3) packaging in direct contact with a pharmaceutical active ingredient and/or dosage form that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or topical (skin) administration; (4) tobacco related products and applications; (5) electronic cigarettes and similar devices; and (6) pressure pipe or fittings that are considered a part or component of a nuclear reactor. (iii) Additionally, the product(s) may not be used in: (1) U.S. FDA Class III, Health Canada Class IV, and/or European Class III Medical Devices; (2) applications involving permanent implantation into the body; (3) lifesustaining medical applications; and (4) lead, asbestos or MTBE related applications. All references to U.S. FDA, Health Canada, and European Union regulations include other country s equivalent regulatory classifications. Users should review the applicable Material Safety Data Sheet before handling the product. Addhere, Adflex, Adstif, Adsyl, Akoafloor, Akoalit, Alathon, Amazing Chemistry, Aquamarine, Aquathene, Avant, Catalloy, Clyrell, CRP, Crystex, Dexflex, Explore & Experiment, Flexathene, Glacido, Hifax, Histif, Hostacom, Hostalen, Ideal, Integrate, Koattro, LIPP, Lucalen, Luflexen, Lupolen, Lupolex, Luposim, Lupostress, Lupotech, Metocene, Microthene, Moplen, Nerolex, Nexprene, Petrothene, Plexar, Pristene, Prodflex, ProFax, Purell, Sequel, Softell, Spherilene, Spheripol, Spherizone, Starflex, Stretchene, Superflex, Toppyl, Trans4m, Ultrathene, Vacido and Valtec are trademarks owned or used by the LyondellBasell family of companies. Adsyl, Akoafloor, Akoalit, Alathon, Aquamarine, Avant, CRP, Crystex, Dexflex, Explore & Experiment, Flexathene, Hifax, Hostacom, Hostalen, Ideal, Integrate, Koattro, Lucalen, Lupolen, Microthene, Moplen, Nexprene, Petrothene, Plexar, Pristene, ProFax, Purell, Sequel, Softell, Spheripol, Spherizone, Starflex, Toppyl, and Ultrathene are registered in the U.S. Patent and Trademark Office. LyondellBasell Product Stewardship Information Date: 2/5/2015 Page 11 of 11 Moplen RP348R Recipient Tracking #: Request #: 74598

40 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Product and Company Information 1.1 Product identificator Product name: Pure 100% Allzweckreiniger IndexNo.: ECNo.: CASNo.: REACHRegistration No.: Synonymies: 1.2 Relevant identified applications of the product and applications that are advised against. All purpose cleaner 1.3 Details of the distributor, providing the safety date sheet Producer / Distributor Mediashop Holding GmbH DRTV International Street Schwarzottstraße 2a Postal Code A2620 Neunkirchen Department for Information Mediashop, Customer Service Phone / Fax / (+423) kundendienst@mediashop.tv 1.4 EMERGENCY PHONE (+423) Hazards Identification 2.1 Classification: Classification according to regulation (EC) No. 1272/2008, Annex VII : Classification Hazard Category Classification according to regulation 67/548/EWG or regulation 1999/45/EC : Hazard Classification Description RPhrase Seite : 1 / 17

41 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Hazard symbols Hazard symbols according to regulation (EC) No. 1272/2008 / Regulation1999/45/EC Pictogram /Hazard symbol: Hazard information: Hazardous components for labelling contains: Alcohols, C1214, Ethoxylated, Sulfates, Sodium Salts CAS: DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Ethanol CAS: Orange, Sweet, Ext. CAS: Lavender, Lavandula Angustifolia, Ext. CAS: as well as nonhazardous additives Hazard phrases Precautionary phrases Additional information on hazards EUH208 Contains Orange, Sweet, Ext. May produce an allergic reaction. 2.3 Additional hazards vpvb Substances: None PBT Substances: None Other Hazards: No other hazards 3. Composition/Information on Ingredients 3.1 Substance Main component of substance Name: IndexNo.: ECNo.: CASNo.: Dangerous Impurities, Stabilization Agents Name: Seite : 2 / 17

42 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: IndexNo.: ECNo.: CASNo.: 3.2 Formulations Name: Alcohols, C1214, Ethoxylated, Sulfates, Sodium Salts ECNo.: CASNo. : IndexNo.: REACHRegistrationNo. : Content : < 10 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Irritation 2 Skin Irritation 2 Name: DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides EGNo.: CASNo. : IndexNo.: REACH RegistrationNo. : XXXX Content : < 10 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Damage 1 Name: Ethanol EGNo.: CASNo. : IndexNo.: REACH RegistrationNo. : xxxx Content : < 10 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Flammable Liquid 2 Name: Orange, Sweet, Ext. EGNo.: CASNo. : IndexNo.: REACH RegistrationNo.: xxxx Content : < 1 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Flammable Liquid 3 Aspiration Hazard 1 Seite : 3 / 17

43 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Skin Irritation 2 Skin Sensitisation 1 Hazardous to the aquatic 2 environment chronic Name: Lavender, Lavandula Angustifolia, Ext. EGNo.: CASNo. : IndexNo.: REACH RegistrationNo.: Content : < 1 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Aspiration Hazard 1 Skin Irritation 2 4. First Aid Measures 4.1 General Information: When assessing action take Risk & Safety Phrases into account After Inhalation: Remove casualty to fresh air and keep warm and at rest. After Skin Contact: Areas of the body that have or are only even suspected of having come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose off safely. After Eye Contact: After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately. Protect uninjured eye. After Ingestion: Wash the mouth thoroughly and drink plenty of water. In case of disease consult a physician immediately and present this safetydata sheet. 4.2 Symptoms and effects 4.3 Advices for the Medical Scientist (Symptoms, Hazards, Treatment) In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: (see paragraph 4.1) 5. Fire Fighting Measures 5.1 Extinguishing media Seite : 4 / 17

44 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Suitable: Carbon dioxide (CO2). Unsuitable: Do not use direct water jet on burning material. 5.2 Special Risks: The product does not present a fire hazard 5.3 Special protective equipment for firefighters: Use suitable breathing apparatus. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. 6. Accidental Release Measures 6.1 Personal precautions: Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and Environmental precautions: Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3 Methods for cleaning up: Rapidly recover the product, wearing protective clothing. Scoop into containers and seal for disposal. After the product has been recovered, rinse the area and materials involved with water. Wash with plenty of water. 6.4 Reference to other chapters See also section 8 and Handling and Storage 7.1 Advices for safe handling Advices for Fire and Explosion Protection: Keep away from open flames, heat and sparks. Measures for the Inhibition of Aerosol or Dust Formation: Measures for Protection of the Environment: Advices for safe exposure: Avoid contact with skin and eyes and exposure to high dust concentration. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment Seite : 5 / 17

45 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Technical Measures and Storage Conditions Advices for Storage Combinations: Keep away from water or from damp surroundings. Requirements for Storage Rooms and Containers: Always keep the containers tightly closed. Adequately ventilated premises. 7.3 Specific uses: References and business solutions Ask distributor previous to any specific use. 8. Exposure Controls / Personal Protection 8.1 Exposure Limit Values Working Place Limited Values and Biological Limited Values: Name: Ethanol CAS: Specification : MAK (AT) Value : ppm Short time value: Toxic to reproduction: No Recommended Monitoring: Name: Ethanol CAS: Specification : MAK (DE) Value : 500 ppm Short time value: ppm Toxic to reproduction: No Recommended Monitoring: Name: Ethanol CAS: Specification : AGW (DE) Value : 500 ppm Short time value: ppm Toxic to reproduction: No Recommended Monitoring: Name: Ethanol CAS: Specification : MAK (CH) Value : 500 ppm Short time value: ppm Toxic to reproduction: No Recommended Monitoring: DNEL and PNEC values Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Fresh water) Seite : 6 / 17

46 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sea water) mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Intermittent release) 0.27 mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sewage treatment plant) 560 mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Fresh water sediment) mg/kg sediment dw Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sea water sediment) mg/kg sediment dw Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, dermal, longterm) mg/kg bw/day Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, inhalative, longterm) 420 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population dermal, longterm) mg/kg bw/day Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, inhalative, shortterm) 10 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population inhalative, longterm) 124 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population oral, longterm) 35.7 mg/kg bw/day Stoffname: Ethanol CAS: PNEC (Fresh water) 0.96 mg/l Stoffname: Ethanol CAS: PNEC (Sea water) 0.79 mg/l Stoffname: Ethanol CAS: PNEC (Intermittent releases) 2.75 mg/l Seite : 7 / 17

47 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Stoffname: Ethanol CAS: PNEC (STP) 580 mg/l Stoffname: Ethanol CAS: PNEC sediment (freshwater) 3.6 mg/kg sediment dw Stoffname: Ethanol CAS: PNEC sediment (marine water) 2.9 mg/kg sediment dw Stoffname: Ethanol CAS: PNEC (Soil) 0.63 mg/kg soil dw Stoffname: Ethanol CAS: PNEC (Predators) 0.72 g/kg food Stoffname: Ethanol CAS: DNEL (Worker, inhalative, longterm) 950 mg/cm³ Stoffname: Ethanol CAS: DNEL (Worker, inhalative, shortterm) 1900 mg/cm³ Stoffname: Ethanol CAS: DNEL (Worker, dermal, longterm) 343 mg/kg bw/day Stoffname: Ethanol CAS: DNEL (General population, inhalative, longterm) 114 mg/m³ Stoffname: Ethanol CAS: DNEL (General population, dermal, longterm) 206 mg/kg bw/day Stoffname: Ethanol CAS: DNEL (General population, oral, longterm) 87 mg/kg bw/day Stoffname: Orange, Sweet, Ext. CAS: PNEC (Freshwater) 5.4 µg/l Stoffname: Orange, Sweet, Ext. CAS: PNEC (Marine water) 0.54 µg/l Stoffname: Orange, Sweet, Ext. CAS: PNEC (Intermittent release) 5.77 µg/l Stoffname: Orange, Sweet, Ext. CAS: PNEC (STP) Seite : 8 / 17

48 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: mg/l Stoffname: Orange, Sweet, Ext. CAS: PNEC (Fresh water sediment) 1.3 mg/kg sediment dw Stoffname: Orange, Sweet, Ext. CAS: PNEC (Marine water sediment) 0.13 mg/kg sediment dw Stoffname: Orange, Sweet, Ext. CAS: PNEC (Soil) mg/kg soil dw Stoffname: Orange, Sweet, Ext. CAS: PNEC (Predators) mg/kg food Stoffname: Orange, Sweet, Ext.CAS: DNEL (Worker, inhalative, longterm) 31.1 mg/cm³ Stoffname: Orange, Sweet, Ext. CAS: DNEL (Worker, dermal, longterm) 8.89 mg/kg bw/day Stoffname: Orange, Sweet, Ext. CAS: DNEL (Worker, dermal, shortterm) µg/cm² Stoffname: Orange, Sweet, Ext. CAS: DNEL (General population, inhalative, longterm) 7.78 mg/m³ Stoffname: Orange, Sweet, Ext. CAS: DNEL (General population, dermal, longterm) 4.44 mg/kg bw/day Stoffname: Orange, Sweet, Ext. CAS: DNEL (General population, dermal, shortterm) 92.9 µg/cm² Stoffname: Orange, Sweet, Ext. CAS: DNEL (General population, oral, longterm) 4.44 mg/kg bw/day ControlBanding (e.g.. ILO, EMKG) 8.2 Limiting and Monitoring of Exposition Technical Measures for Exposition Prevention: Ventilate the areas where the product is stored or handled. Seite : 9 / 17

49 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Personal protective equipment: Wash hands with soap & water after handling. Eye protection: Safety glasses. Skin protection Hand protection: Protective gloves. Body protection: The skin should be protected from contact with the product Respiratory protection: Not needed for normal use Heat coldness protection Limiting and Monitoring of Enviromental Exposition:. 9. Physical and Chemical Properties 9.1 SafetyRelevant Basic Data Physical State: Slightly viscous goldenyellowish liquid Colour : Odor : Orangelike Odor threshhold : phvalue : 6 8 Melting point : >100 C Boiling point : >100 C Flash point : Evaporation rate : Flammability : Explosion limits : Vapor pressure : Vapor density : Density : 1,06 g/cm 2 Solubility : Completely miscible noctanolwater Partition Coefficient (log Pow): Ignition Temperature: Decomposition Temperature : Viscosity : Explosive properties : Oxidizing properties : 9.2 Additional Information Seite : 10 / 17

50 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Stability and Reactivity 10.1 Reactivity The product shows low reactivity. Contact with strong oxidising agents shall however be avoided 10.2 Chemical Stability The product is stable if stored and handled properly. However, if stored at high temperature (above 50 C or between 40 and 50 C for a long period of time) or in contact with hot spots or if it enters in contact with small amount of strong acid, product may undergo acid hydrolysis and generate sulphuric acid. If this occurs, ph of the product will drop drastically Possibility of dangerous reactions None if stored and handled properly with the exception of the here above described hydrolysis conditions Conditions to avoid Temperatures in excess of 50 C Materials to avoid Avoid contact with acids (see here above) and with strong oxidising agents. Hazardous decomposition products 10.6 No decomposition at recommended handling temperature. However, in case of extreme hydrolysis (see here above), product may release a corrosive mixture of fatty alcohol and sulphuric acid. 11. Toxicological Information 11.1 Toxicokinetics, Metabolism and Distribution Seite : 11 / 17

51 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Acute Toxicity Alcohols, C1214, Ethoxylated, Sulfates, Sodium Salts CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) mg/kg Rat LD 50 (dermal) Rabbit LD 50 (inhalative) Rat DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) > mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Ethanol CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) 125 mg/l Rat Orange, Sweet, Ext. CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) > mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Irritating/Corrosive Impacts on Skin Slightly irritating Irritating/Corrosive Impacts on Eyes Not irritating Allergization of Skin/Respiratory Sytem Not investigated. Contains Orange, Sweet, Ext. May produce an allergic reaction. Mutagenicity: Not applicable (No evidence of mutagenicity based on expert assessment of all available relevant data). Cancerogenicity: Not applicable (No evidence of cancerogenicity based on expert assessment of all available relevant data). Reproduction Toxicity: Not applicable (No evidence of reproductive toxicity based on expert assessment of all available relevant data). Specific organ toxicity at onetime exposition No. Specific organ toxicity at repeated exposition No. Aspiration hazard Seite : 12 / 17

52 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Symptoms and impacts (delayed and chronical) No bioaccumulation potential based on study results. Contains Orange, Sweet, Ext. May produce an allergic reaction. 12. Ecological Information 12.1 Ecotoxicity Alcohols, C1214, Ethoxylated, Sulfates, Sodium Salts CAS: Acute Toxicity Time Species Method Assessment Notes LC50 >100 mg/l 96 h Fish OECD 203 EC50 48 h Daphnia OECD 202 EC50 72 h Algae OECD 201 DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Acute Toxicity Time Species Method Assessment Notes LC50 100,81 mg/l 96 h Fish OECD 203 EC50 > 100 mg/l 48 h Daphnia OECD 202 EC50 21 mg/l 72 h Algae OECD 201 Ethanol CAS: Acute Toxicity Time Species Method Assessment Notes LC mg/l 96 h Fish OECD 203 EC mg/l 48 h Daphnia OECD 202 EC mg/l 72 h Algae OECD 201 Orange, Sweet, Ext. CAS: Acute Toxicity Time Species Method Assessment Notes LC50 2,26 mg/l 96 h Fish OECD 203 EC50 0,67 mg/l 48 h Daphnie OECD 202 EC mg/l 72 h Algae OECD Persistence und Degradability Readily biodegradable in water. C1214 Alkyl Sulphate underwent complete biodegradation in Continuous Activated Sludge (CAS) units. At Day 67, the % biodegradation was and there was no indication of the presence of any biodegradation residues or nonbiodegradable minor components for this ingredient Bioaccumulation Potential: In accordance with column 2 of EC 1907/2006 Annex IX the testing on Bioaccumulation does not need to be performed if the test substance has a low potential for bioaccumulation (for instance a log Kow 3). The members of the category alcohol sulfates have a log Kow 3. Thus, bioaccumulation of the category members of sulphated alcohol sodium salts is not expected Mobility in soil compound: Not relevant (substance is readily biodegradable). Seite : 13 / 17

53 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Result of PBT and vpvbevaluation Based on data in the CSR, this product does not meet the criteria for either PBT or vpvb classification as it is readily biodegradable in the environment, has very low bioaccumulation potential, low chronic aquatic toxicity and is not classified as carcinogenic, mutagenic or toxic for reproducti on Other Harmful Properties: 13. Disposal Considerations 13.1 Process of Disposal Treatment Contaminated packaging: If recycling is not possible, dispose product and/or packaging according to local regulations and via authorised elimination channel (most probably controlled incineration). Product: Recycle as much as possible the recovered product. 14. Transport Information 14.1 UNNumber 14.2 Duly UNTransport Identifier ADR/RID IMDGCode / ICAOTI / IATADGR 14.3 Hazard Class 14.4 Packing group 14.5 Environmental Hazards Seite : 14 / 17

54 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Special Precaution Advises for End User KemlerNumber: Exemptional Quantity (EQ): Limited Quantity (LQ): Transport Category: Tunnel Restriction Code: 14.7 Bulk Cargo Transportation according to Annex II of the MARPOL Convention 73/78 and according to IBCCode Pollution Category (X, Y or Z) : Type of Ship (1, 2 or 3) : 15. Regulatory Information 15.1 Regulations on Safety, Health and Environment ECRegulations e.g. Regulation (EG) No. 2037/2000 Regulation (EG) No. 850/2004 Regulation (EG) No. 689/2008 Regulation (EG) No.. 648/2004 Restrictions according to item VIII of regulation (EC) 1907/2006: National Regulations e.g. Water Hazard Class 1 (SelfAssessment) Solvent Regulation (31. BImSchV) Statutory Order on Hazardous Incidents (12. BImSchV) Technical Instructions on Air Quality Further relevant regulations 15.2 Chemical Safety Assessment Conducted. Seite : 15 / 17

55 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Other Information Modifications compared to last version Abreviations: ADR Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) CAS Chemical Abstracts Service (division of the American Chemical Society) EINECS European Inventory of Existing Commercial Chemical Substances GHS Globally Harmonized System of Classification and Labelling of Chemicals IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent Règlement international concernant le transport des marchandises dangereuses par RID chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) References and data sources Wording of Hazard Statements and Precautionary Statements referred in chapter 2 15 According to regulation 67/548/EWG: According to regulation (EC) No. 1272/2008: Training for employees Additional information The data provided in this material safety data sheet is meant to represent typical data/analysis for this product and is correct to the best of our knowledge. The data was obtained from current and reliable sources, but is supplied without warranty, expressed or implied, regarding its correctness or accuracy. It is the user's responsibility to determine safe conditions for the use of this product, and to assume liability for loss, injury, damage or expense arising from improper use of this product. The information provided does not constitute a contract to supply to any specification, or for any given application, and buyers should seek to verify their requirements and product use. Issuing department: Product Development Contact: Robert Loder Seite : 16 / 17

56 Safety Data Sheet Pure 100% Allzweckreiniger Issued on: Valid since: Seite : 17 / 17

57 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Product and Company Information 1.1 Product identificator Product name: Pure 100% Kalklöser IndexNo.: ECNo.: CASNo.: REACHRegistration No.: Synonymies: 1.2 Relevant identified applications of the product and applications that are advised against. Descaler Sanitary Cleaner 1.3 Details of the distributor, providing the safety date sheet Producer / Distributor Mediashop Holding GmbH DRTV International Street Schwarzottstraße 2a Postal Code A2620 Neunkirchen Department for Information Mediashop, Customer Service Phone / Fax / (+423) kundendienst@mediashop.tv 1.4 EMERGENCY PHONE (+423) Hazards Identification 2.1 Classification: Classification according to regulation (EC) No. 1272/2008, Annex VII : Classification Hazard Category Eye Irritation Hazard symbols Seite : 1 / 14

58 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Hazard symbols according to regulation (EC) No. 1272/2008 / Regulation1999/45/EC Pictogram /Hazard symbol: Hazard information: WARNING Hazardous components for labelling contains: Citric Acid Monohydrate, CAS: Tartaric Acid CAS: Lactic Acid CAS: Hazard phrases H319 Causes serious eye irritation. Precautionary phrases Prevention P264 Wash thoroughly after handling. P280 Wear protective gloves and eye protection. Reaction P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337/313 If eye irritation persists: Get medical attention. Additional information on hazards 2.3 Additional hazards 3. Composition/Information on Ingredients 3.1 Substance Main component of substance Product name: IndexNo.: ECNo.: CASNo.: Dangerous Impurities, Stabilization Agents Seite : 2 / 14

59 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Name: IndexNo.: ECNo.: CASNo.: 3.2 Formulations Name: ECNo.: CASNo.: IndexNo.: REACHRegistrationNo. : Anteil : % Classification according to regulation 67/548/EWG: Classification according to regulation (EC) No. 1272/2008: Name: Citric Acid Monohydrate ECNo.: CASNo. : IndexNo.: REACHRegistrationNo. : xxxx Content : > 10 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Irritation 2 Name : Tartaric Acid ECNo.: CASNo. : IndexNo.: REACHRegistrationNo. : xxxx Content : 1 3 % Classification according to regulation (EC) No. 1272/2008: Classification Serious Eye Damage Hazard Category 1 Name: Lactic Acid EGNo.: CASNo. : IndexNo.: REACH RegistrationNo. : xxxx Content : 1 3 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Serious Eye 1 Damage Skin Irritation 2 Seite : 3 / 14

60 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: First Aid Measures 4.1 General Information: CAUTION! First aid personnel must be aware of own risk during rescue! Always consider any dangers in the vicinity before approaching to treat the casualty. First aid personnel must protect themselves with all necessary personal protective equipment during the assistance of casualties. When breathing is difficult, properly trained personnel may assist the casualty by administering oxygen. Place unconscious person on the side in the recovery position and ensure breathing can take place. Never give anything by mouth to an unconscious person. If other hazardous materials are involved in the incident avoid mouth to mouth contact, use a mechanical device such as a bag and mask. If medical assistance is needed take as much detail as possible about the incident and hazardous materials involved with the casualty. After Inhalation: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. After Skin Contact: Immediately remove contaminated clothing. Wash the skin immediately with soap and water. In serious cases obtain medical attention. After Eye Contact: Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids. If possible remove any contact lenses and continue to wash. Get medical attention if any discomfort continues. After Ingestion: Immediately rinse mouth and drink plenty of water. Get medical attention immediately! 4.2 Symptoms and effects 4.3 Advices for the Medical Scientist (Symptoms, Hazards, Treatment) 5. Fire Fighting Measures 5.1 Extinguishing media Suitable: Water spray, foam, dry powder or carbon dioxide. Unsuitable: Do not use direct water jet on burning material. 5.2 Special Risks: Prevent runoff from entering drains and watercourses. Dust may form explosive mixture with air. In case of fire, toxic fumes or vapours may be formed. Carbon monoxide (CO). Carbon dioxide (CO2). 5.3 Special protective equipment for firefighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental Release Measures Seite : 4 / 14

61 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Personal precautions: Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin and eyes. 6.2 Environmental precautions: Clean up any spillages immediately, prevent material from spreading and entering drains or sewage systems. Avoid unauthorised discharge to the environment. Large spillages or uncontrolled discharge to water systems must be alerted to the Environmental Agency or other regulatory body. If spillages to land cannot be treated safely or if contamination will occur the Environment Agency must be alerted immediately. 6.3 Methods for cleaning up: Avoid dust formation. Collect with scoop or shovel if possible to do so safely, otherwise mix with sand or other inert material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Flush area clean with lots of water. Be aware of potential for surfaces to become slippery. Ventilate area and allow to dry before allowing access. 6.4 Reference to other chapters 7. Handling and Storage 7.1 Advices for safe handling Advices for Fire and Explosion Protection: Keep away from ignition sources & naked flames. Take precautions to avoid static discharges in working area. Measures for the Inhibition of Aerosol or Dust Formation: Measures for Protection of the Environment: Advices for safe exposure: Avoid inhalation and spreading of dusts Avoid contact with skin and eyes. Do not eat, drink or smoke when handling. 7.2 Technical Measures and Storage Conditions Advices for Storage Combinations: Requirements for Storage Rooms and Containers: Store in closed original container at temperatures between 15 C and 25 C. Store away from heat, direct sunlight and moisture. Store above freezing. Store away from incompatible materials. 7.3 Specific uses: Seite : 5 / 14

62 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: References and business solutions Ask distributor previous to any specific use. 8. Exposure Controls / Personal Protection 8.1 Exposure Limit Values Working Place Limited Values and Biological Limited Values: Name: Tartaric Acid CAS: Specification : MAK (DE) Value : 2 mg/m³ Short time value: 4 mg/m³ Toxic to reproduction: No Recommended Monitoring: DNEL and PNEC values Name: Citric Acid; CASNr. : Specification : PNEC (Fresh water) 0,44 mg/l Name: Citric Acid; CASNr. : Specification : PNEC (Marine water) 0,044 mg/l Name: Citric Acid; CASNr. : Specification : PNEC (STP) mg/l Name: Citric Acid; CASNr. : Specification : PNEC (Fresh water sediment) 34.6 mg/kg sediment dw Name: Citric Acid; CASNr. : Specification : PNEC (Marine water sediment) 3.46 mg/kg sediment dw Name: Citric Acid; CASNr. : Specification : PNEC (Soil) 33.1 mg/kg soil dw Name: Tartaric Acid CAS: Specification : PNEC (Fresh water) 0,3125 mg/l Name: Tartaric Acid CAS: Specification : PNEC (Marine water) 0,3125 mg/l Name: Tartaric Acid CAS: Specification : PNEC (Intermittent releases) 0,514 mg/l Seite : 6 / 14

63 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Name: Tartaric Acid CAS: Specification : PNEC (STP) 10 mg/l Name: Tartaric Acid CAS: Specification : PNEC (Fresh water sediment) 1,141 mg/kg sediment dw Name: Tartaric Acid CAS: Specification : PNEC (Marine water sediment) 1,141 mg/kg sediment dw Name: Tartaric Acid CAS: Specification : PNEC (Soil) 0,0449 mg/kg soil dw Name: Tartaric Acid CAS: Specification : DNEL (Worker, dermal, longterm) 2.9 mg/kg bw/day Name: Tartaric Acid CAS: Specification : DNEL (Worker, inhalative, longterm) 5.2 mg/m³ Name: Tartaric Acid CAS: Specification : DNEL (General population, dermal, longterm) 1.5 mg/kg bw/day Name: Tartaric Acid CAS: Specification : DNEL (General population, oral, longterm) 8.1 mg/kg bw/day Name: Tartaric Acid CAS: Specification : DNEL (General population, inhalative, longterm) 1.3 mg/m³ ControlBanding (e.g.. ILO, EMKG) 8.2 Limiting and Monitoring of Exposition Technical Measures for Exposition Prevention: Provide adequate ventilation and appropriate extraction to avoid occupational exposure. Work in a flameproof fume cupboard if dusts are generated Personal protective equipment: Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. When using do not eat, drink or smoke. Seite : 7 / 14

64 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Eye protection: Wear approved safety goggles. Skin protection Hand protection: Wear protective gloves. Rubber or plastic Body protection: Wear suitable protective clothing as protection against splashing or contamination. Provide eyewash station and safety shower. Wear plastic apron and full length gloves if handling large amounts. Respiratory protection: Wear suitable dust respirator when dusts are generated Consult with the supplier as to the compatibility of the equipment with the chemical of concern. CAUTION: Air purifying respirators do not protect the user in oxygen deficient atmospheres, use air supplied system. Heat coldness protection Limiting and Monitoring of Enviromental Exposition:. 9. Physical and Chemical Properties 9.1 SafetyRelevant Basic Data Physical State: White yellowish powder Colour : Odor : Odorless Odor threshhold : phvalue : 1,5 2,0 (5% solution) Melting point : C Boiling point : Flash point : Evaporation rate : Flammability : Explosion limits : Vapor pressure : Vapor density : Density : 1,6 g/cm 2 Solubility : 680 g/l noctanolwater Partition 1,5 Log Pow Coefficient (log Pow): Ignition Temperature: > 350 C Decomposition Temperature : Viscosity : Explosive properties : Oxidizing properties : 9.2 Additional Information Seite : 8 / 14

65 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Stability and Reactivity 10.1 Reactivity It presents no significant reactivity hazards, by itself or in contact with water Chemical Stability Stable under normal temperature conditions Possibility of dangerous reactions 10.4 Conditions to avoid Avoid heat, direct sunlight and moisture. Avoid storage with incompatible materials Materials to avoid Oxidising agents. Bases. The possibility of reaction with other materials cannot be excluded Hazardous decomposition products Fire may create Carbon monoxide (CO). Carbon dioxide (CO2). Fire may result in the reaction with other substances to produce hazardous products. Above 175C, decomposes to e.g. Aconitic acid, Citraconic acid, Itaconic acid, Acetonedicarboxylic acid, Carbon dioxide and water. 11. Toxicological Information 11.1 Toxicokinetics, Metabolism and Distribution Seite : 9 / 14

66 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Acute Toxicity Citric Acid CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Tartaric Acid CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Lactic Acid CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) > 7,9 mg/l Rat Irritating/Corrosive Impacts on Skin May cause irritation on prolonged or repeated contact. Irritation on contact with broken skin. Irritating/Corrosive Impacts on Eyes Causes eye irritation. Allergization of Skin/Respiratory Sytem Based on available data the classification criteria are not met. Mutagenicity: Based on available data the classification criteria are not met. Cancerogenicity: Based on available data the classification criteria are not met. Reproduction Toxicity: Based on available data the classification criteria are not met. Specific organ toxicity at onetime exposition Dusts are irritating to the respiratory system. May cause irritation. Ingestion of large amounts may cause discomfort, nausea, vomiting or diarrhoea. Specific organ toxicity at repeated exposition Based on available data the classification criteria are not met. Aspiration hazard Based on available data the classification criteria are not met. Symptoms and impacts (delayed and chronical) Seite : 10 / 14

67 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Irritating to respiratory system. 12. Ecological Information 12.1 Ecotoxicity Citric Acid CAS: Acute Toxicity Time Species Method Assessment Notes LC mg/l 96 h Fish OECD 203 EC mg/l 48 h Daphniae OECD 202 EC50 80 mg/ 72 h Algae OECD 201 Tartaric Acid CAS: Acute Toxicity Time Species Method Assessment Notes LC50 > 100 mg/l 96 h Fish OECD 203 EC50 93 mg/l 48 h Daphniae OECD 202 EC50 51 mg/l 72 h Algae OECD 201 Lactic Acid CAS: Acute Toxicity Time Species Method Assessment Notes LC mg/l 96 h Fish OECD 203 EC mg/l 48 h Daphniae OECD 202 EC mg/l 72 h Algae OECD Persistence und Degradability Good biodegradability 12.3 Bioaccumulation Potential: Low bioaccumulation potential Mobility in soil compound: 12.5 Result of PBT and vpvbevaluation 12.6 Other Harmful Properties: The contained acids occur naturally in the environment and are found in all types of water and soil in small amounts. The product may affect the acidity (phfactor) in water with risk of harmful effects to aquatic organisms. Ecological effects cannot be excluded in the event of improper handling or disposal. 13. Disposal Considerations 13.1 Process of Disposal Treatment Contaminated packaging: Dispose of according to local regulations. Seite : 11 / 14

68 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Product: Any waste material is classed as hazardous waste, it should only be disposed of through licenced waste handlers and treatment sites. Do not allow unauthorised disposal to the environment. Dispose of waste and residues in accordance with local authority requirements. Avoid unauthorised disposal. Do not dump illegally onto land or into water. 14. Transport Information 14.1 UNNumber 14.2 Duly UNTransport Identifier ADR/RID IMDGCode / ICAOTI / IATADGR 14.3 Hazard Class 14.4 Packing group 14.5 Environmental Hazards 14.6 Special Precaution Advises for End User KemlerNumber: Exemptional Quantity (EQ): Limited Quantity (LQ): Transport Category: Tunnel Restriction Code: 14.7 Bulk Cargo Transportation according to Annex II of the MARPOL Convention 73/78 and according to IBCCode Pollution Category (X, Y or Z) : Type of Ship (1, 2 or 3) : 15. Regulatory Information Seite : 12 / 14

69 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: Regulations on Safety, Health and Environment ECRegulations e.g. Regulation (EG) No. 2037/2000 Regulation (EG) No. 850/2004 Regulation (EG) No. 689/2008 Regulation (EG) No.. 648/2004 Restrictions according to item VIII of regulation (EC) 1907/2006: National Regulations e.g. Water Hazard Class 1 (SelfAssessment) Solvent Regulation (31. BImSchV) Statutory Order on Hazardous Incidents (12. BImSchV) Technical Instructions on Air Quality Further relevant regulations 15.2 Chemical Safety Assessment Conducted. 16. Other Information Modifications compared to last version Abreviations: ADR Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) CAS Chemical Abstracts Service (division of the American Chemical Society) EINECS European Inventory of Existing Commercial Chemical Substances GHS Globally Harmonized System of Classification and Labelling of Chemicals IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent Seite : 13 / 14

70 Safety Data Sheet Pure 100% Kalklöser Issued on: Valid since: LD50 RID Lethal dose, 50 percent Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) References and data sources Wording of Hazard Statements and Precautionary Statements referred in chapter 2 15 According to regulation (EC) No. 1272/2008: H319 Causes serious eye irritation P264 Wash thoroughly after handling. P280 Wear protective gloves and eye protection. P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337/313 If eye irritation persists: Get medical attention. Training for employees Additional information The data provided in this material safety data sheet is meant to represent typical data/analysis for this product and is correct to the best of our knowledge. The data was obtained from current and reliable sources, but is supplied without warranty, expressed or implied, regarding its correctness or accuracy. It is the user's responsibility to determine safe conditions for the use of this product, and to assume liability for loss, injury, damage or expense arising from improper use of this product. The information provided does not constitute a contract to supply to any specification, or for any given application, and buyers should seek to verify their requirements and product use. Issuing department: Product Development Contact: R. Loder Seite : 14 / 14

71 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Product and Company Information 1.1 Product identificator Product name: Pure 100% Fettlöser IndexNo.: ECNo.: CASNo.: REACHRegistration No.: Synonymies: 1.2 Relevant identified applications of the product and applications that are advised against. Fat solvent All purpose cleaner 1.3 Details of the distributor, providing the safety date sheet Producer / Distributor Mediashop Holding GmbH DRTV International Street Schwarzottstraße 2a Postal Code A2620 Neunkirchen Department for Information Mediashop, Customer Service Phone / Fax / (+423) kundendienst@mediashop.tv 1.4 EMERGENCY PHONE (+423) Hazards Identification 2.1 Classification: Classification according to regulation (EC) No. 1272/2008, Annex VII : Classification Hazard Category Seite : 1 / 16

72 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Classification according to regulation 67/548/EWG or regulation 1999/45/EC : Hazard Classification Description RPhrase 2.2 Hazard symbols Hazard symbols according to regulation (EC) No. 1272/2008 / Regulation1999/45/EC Pictogram /Hazard symbol: Hazard information: Hazardous components for labelling contains: Fatty Acids, VegetableOil, Potassium Salts CAS: DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Orange, Sweet, Ext. CAS: Potassium Hydroxide CAS.Nr.: Potassium Carbonate CAS.Nr.: as well as nonhazardous additives Hazard phrases Precautionary phrases Additional information on hazards EUH208 Contains Orange, Sweet, Ext. May produce an allergic reaction. 2.3 Additional hazards vpvb Substances: None PBT Substances: None Other Hazards: No other hazards 3. Composition/Information on Ingredients 3.1 Substance Main component of substance Name: IndexNo.: ECNo.: CASNo.: Seite : 2 / 16

73 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Dangerous Impurities, Stabilization Agents Name: IndexNo.: ECNo.: CASNo.: 3.2 Formulations Name: Fatty Acids, VegetableOil, Potassium Salts ECNo.: CASNo. : IndexNo.: REACHRegistrationNo. : Content : > 30 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Irritation 2 Skin Irritation 2 Name: DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides EGNo.: CASNo. : IndexNo.: REACH RegistrationNo. : XXXX Content : < 10 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Damage 1 Name: Orange, Sweet, Ext. EGNo.: CASNo. : IndexNo.: REACH RegistrationNo.: xxxx Content : < 1 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Flammable Liquid 3 Aspiration Hazard 1 Skin Irritation 2 Skin Sensitisation 1 Hazardous to the aquatic 2 environment chronic Seite : 3 / 16

74 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Stoffname: Potassium Hydroxide EGNo.: CASNo. : IndexNr.: REACH RegistrationNo.: XXXX Content : < 1 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Skin Corrosion 1A Acute Toxicity Oral 4 Substances and Mixtures 1 corrosive to Metals Stoffname: Potassium Carbonate EGNo.: CASNo. : IndexNo.: REACH RegistrationNo.: XXXX Content : < 1 % Classification according to regulation (EC) No. 1272/2008: Classification Hazard Category Eye Irritation 2 Skin Irritation 2 Specific target organ toxicity 3 Single (respiratory system) 4. First Aid Measures 4.1 General Information: When assessing action take Risk & Safety Phrases into account After Inhalation: Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. After Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. After Eye Contact: Promptly wash eyes with plenty of water while lifting the eye lids. Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes and get medical attention. After Ingestion: Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Rinse nose, mouth and throat with water. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Get medical attention. 4.2 Symptoms and effects Seite : 4 / 16

75 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Inhalation. Spray mists irritate the respiratory system, and cause coughing and difficulties in breathing. Ingestion May cause discomfort if swallowed. May irritate and cause stomach pain, vomiting and diarrhoea. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact May cause temporary eye irritation. Spray and vapour in the eyes may cause irritation and smarting. 4.3 Advices for the Medical Scientist (Symptoms, Hazards, Treatment) In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: (see paragraph 4.1) 5. Fire Fighting Measures 5.1 Extinguishing media Suitable: Extinguish with foam, carbon dioxide, dry powder or water fog. Unsuitable: Do not use direct water jet on burning material. 5.2 Special Risks: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 5.3 Special protective equipment for firefighters: Avoid breathing fire vapours. Keep runoff water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities. Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental Release Measures 6.1 Personal precautions: Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with eyes and prolonged skin contact. Avoid forming spray/aerosol mists. In case of spills, beware of slippery floors and surfaces. 6.2 Environmental precautions: Do not discharge into drains, water courses or onto the ground. Avoid discharge to the aquatic environment. 6.3 Methods for cleaning up: Wear necessary protective equipment. Absorb spillage with noncombustible, absorbent material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Runoff or release to sewer, waterway or ground is forbidden. Inform Authorities if large amounts are involved. 6.4 Reference to other chapters Wear protective clothing as described in Section 8 of this safety data sheet. Collect and dispose of spillage as indicated in section 13. Seite : 5 / 16

76 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Handling and Storage 7.1 Advices for safe handling Advices for Fire and Explosion Protection: Keep away from open flames, heat and sparks. Measures for the Inhibition of Aerosol or Dust Formation: Avoid forming spray/aerosol mists. Measures for Protection of the Environment: Advices for safe exposure: Avoid contact with eyes and prolonged skin contact. Avoid eating, drinking and smoking when using the product. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. 7.2 Technical Measures and Storage Conditions Advices for Storage Combinations: Keep away from water or from damp surroundings. Requirements for Storage Rooms and Containers: Store in tightly closed original container in a dry, cool and wellventilated place. Protect from freezing 7.3 Specific uses: References and business solutions Ask distributor previous to any specific use. 8. Exposure Controls / Personal Protection 8.1 Exposure Limit Values Working Place Limited Values and Biological Limited Values: Name: Potassium Hydroxide CAS: Specification : MAK (AT) Value : 2 mg/m 3 Short time value: Toxic to reproduction: No Recommended Monitoring: Name: Potassium Hydroxide CAS: Specification : MAK (CH) Value : 2 mg/m 3 Short time value: Toxic to reproduction: No Recommended Monitoring: Seite : 6 / 16

77 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: DNEL and PNEC values Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Fresh water) mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sea water) mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Intermittent release) 0.27 mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sewage treatment plant) 560 mg/l Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Fresh water sediment) mg/kg sediment dw Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : PNEC (Sea water sediment) mg/kg sediment dw Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, dermal, longterm) mg/kg bw/day Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, inhalative, longterm) 420 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population dermal, longterm) mg/kg bw/day Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (Worker, inhalative, shortterm) 10 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population inhalative, longterm) 124 mg/cm³ Name: : DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CASNr. : DNEL (General population oral, longterm) 35.7 mg/kg bw/day Name: Orange, Sweet, Ext. CAS: PNEC (Freshwater) 5.4 µg/l Name: Orange, Sweet, Ext. CAS: PNEC (Marine water) 0.54 µg/l Seite : 7 / 16

78 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Name: Orange, Sweet, Ext. CAS: PNEC (Intermittent release) 5.77 µg/l Name: Orange, Sweet, Ext. CAS: PNEC (STP) 2.1 mg/l Name: Orange, Sweet, Ext. CAS: PNEC (Fresh water sediment) 1.3 mg/kg sediment dw Name: Orange, Sweet, Ext. CAS: PNEC (Marine water sediment) 0.13 mg/kg sediment dw Name: Orange, Sweet, Ext. CAS: PNEC (Soil) mg/kg soil dw Name: Orange, Sweet, Ext. CAS: PNEC (Predators) mg/kg food Name: Orange, Sweet, Ext.CAS: DNEL (Worker, inhalative, longterm) 31.1 mg/cm³ Name: Orange, Sweet, Ext. CAS: DNEL (Worker, dermal, longterm) 8.89 mg/kg bw/day Name: Orange, Sweet, Ext. CAS: DNEL (Worker, dermal, shortterm) µg/cm² Name: Orange, Sweet, Ext. CAS: DNEL (General population, inhalative, longterm) 7.78 mg/m³ Name: Orange, Sweet, Ext. CAS: DNEL (General population, dermal, longterm) 4.44 mg/kg bw/day Name: Orange, Sweet, Ext. CAS: DNEL (General population, dermal, shortterm) 92.9 µg/cm² Name: Orange, Sweet, Ext. CAS: DNEL (General population, oral, longterm) 4.44 mg/kg bw/day Name: Potassium Hydroxide CAS: DNEL (Worker, inhalative, longterm) 1 mg/m³ Name: Potassium Hydroxide CAS: DNEL (General population, inhalative, longterm) Seite : 8 / 16

79 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: mg/m³ Name: Potassium Carbonate CAS: DNEL (Worker, inhalative, longterm) 10 mg/m³ Name: Potassium Carbonate CAS: DNEL (Worker, dermal, longterm) 16 mg/cm² Name: Potassium Carbonate CAS: DNEL (General population, inhalative, longterm) 10 mg/m³ Name: Potassium Carbonate CAS: DNEL (General population, dermal, longterm) 8 mg/cm² ControlBanding (e.g.. ILO, EMKG) 8.2 Limiting and Monitoring of Exposition Technical Measures for Exposition Prevention: Provide adequate general and local exhaust ventilation. Provide eyewash station Personal protective equipment: Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after contact. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Eye protection: The use of eye protection is recommended. Skin protection Hand protection: For prolonged or repeated skin contact use suitable protective gloves. Nitrile gloves are recommended. Seek advice from local supervisor. Body protection: Wear appropriate clothing to prevent repeated or prolonged skin contact. Respiratory protection: No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. Seek advice from supervisor on the companies' respiratory protection standard. Heat coldness protection Seite : 9 / 16

80 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Limiting and Monitoring of Enviromental Exposition: Keep container tightly sealed when not in use. Residues and empty containers should be taken care of as waste according to local and national provisions. 9. Physical and Chemical Properties 9.1 SafetyRelevant Basic Data Physical State: Viscous goldenyellowish liquid Colour : Odor : Orangelike Odor threshhold : phvalue : Melting point : Boiling point : 100 C Flash point : Evaporation rate : Flammability : Explosion limits : Vapor pressure : Vapor density : Density : 1,0 g/cm 2 Solubility : Completely miscible noctanolwater Partition Coefficient (log Pow): Ignition Temperature: Decomposition Temperature : Viscosity : Explosive properties : Oxidizing properties : 9.2 Additional Information 10. Stability and Reactivity 10.1 Reactivity Stable under normal temperature conditions and recommended use Chemical Stability Stable under normal temperature conditions and recommended use Possibility of dangerous reactions Exothermic reaction with: Strong acids Conditions to avoid No specific conditions are likely to result in a hazardous situation Materials to avoid Strong acids Hazardous decomposition products Seite : 10 / 16

81 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: None under normal conditions. 11. Toxicological Information 11.1 Toxicokinetics, Metabolism and Distribution Acute Toxicity DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) > mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Orange, Sweet, Ext. CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) > mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) Rat Potassium Hydroxide CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) 333 mg/kg Rat LD 50 (dermal) Rabbit LD 50 (inhalative) Rat Potassium Carbonate CAS: Acute Toxicity Value Species Method Assessment LD 50 (oral) > mg/kg Rat LD 50 (dermal) > mg/kg Rabbit LD 50 (inhalative) > 4,96 mg/l Rat Irritating/Corrosive Impacts on Skin Based on available data the classification criteria are not met. Irritating/Corrosive Impacts on Eyes Based on available data the classification criteria are not met. Allergization of Skin/Respiratory Sytem Not investigated. Contains Orange, Sweet, Ext. May produce an allergic reaction. Mutagenicity: Does not contain any substances known to be mutagenic. Cancerogenicity: Does not contain any substances known to be carcinogenic. Reproduction Toxicity: Does not contain any substances known to be toxic to reproduction. Seite : 11 / 16

82 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Specific organ toxicity at onetime exposition Not classified as a specific target organ toxicant after a single exposure. Specific organ toxicity at repeated exposition Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Based on available data the classification criteria are not met. Symptoms and impacts (delayed and chronical) No bioaccumulation potential based on study results. Contains Orange, Sweet, Ext. May produce an allergic reaction. 12. Ecological Information 12.1 Ecotoxicity DGlucopyranose, Oligomeric, C1016 Alkyl Glycosides CAS: Acute Toxicity Time Species Method Assessment Notes LC50 100,81 mg/l 96 h Fish OECD 203 EC50 > 100 mg/l 48 h Daphnia OECD 202 EC50 21 mg/l 72 h Algae OECD 201 Orange, Sweet, Ext. CAS: Acute Toxicity Time Species Method Assessment Notes LC50 2,26 mg/l 96 h Fish OECD 203 EC50 0,67 mg/l 48 h Daphnie OECD 202 EC mg/l 72 h Algae OECD 201 Potassium Hydroxide CAS: Acute Toxicity Time Species Method Assessment Notes LC50 80 mg/l 96 h Fish OECD 203 EC50 5 mg/l 48 h Daphnie OECD 202 EC50 72 h Algae OECD 201 Potassium Carbonate CAS: Acute Toxicity Time Species Method Assessment Notes LC50 68 mg/l 96 h Fish OECD 203 EC mg/l 48 h Daphnie OECD 202 EC50 72 h Algae OECD Persistence und Degradability Readily biodegradable in water Bioaccumulation Potential: In accordance with column 2 of EC 1907/2006 Annex IX the testing on Bioaccumulation does not need to be Seite : 12 / 16

83 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: performed if the test substance has a low potential for bioaccumulation (for instance a log Kow 3) Mobility in soil compound: Not relevant (substance is readily biodegradable) Result of PBT and vpvbevaluation Based on data in the CSR, this product does not meet the criteria for either PBT or vpvb classification as it is readily biodegradable in the environment, has very low bioaccumulation potential, low chronic aquatic toxicity and is not classified as carcinogenic, mutagenic or toxic for reproducti on Other Harmful Properties: 13. Disposal Considerations 13.1 Process of Disposal Treatment Contaminated packaging: If recycling is not possible, dispose product and/or packaging according to local regulations and via authorised elimination channel (most probably controlled incineration). Product: Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority. When handling waste, consideration should be made to the safety precautions applying to handling of the product. Environmental manager must be informed of all major spillages. Dispose of waste and residues in accordance with local authority requirements. Do not allow runoff to sewer, waterway or ground. 14. Transport Information 14.1 UNNumber 14.2 Duly UNTransport Identifier ADR/RID IMDGCode / ICAOTI / IATADGR Seite : 13 / 16

84 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Hazard Class 14.4 Packing group 14.5 Environmental Hazards 14.6 Special Precaution Advises for End User KemlerNumber: Exemptional Quantity (EQ): Limited Quantity (LQ): Transport Category: Tunnel Restriction Code: 14.7 Bulk Cargo Transportation according to Annex II of the MARPOL Convention 73/78 and according to IBCCode Pollution Category (X, Y or Z) : Type of Ship (1, 2 or 3) : 15. Regulatory Information 15.1 Regulations on Safety, Health and Environment ECRegulations e.g. Regulation (EG) No. 2037/2000 Regulation (EG) No. 850/2004 Regulation (EG) No. 689/2008 Regulation (EG) No.. 648/2004 Restrictions according to item VIII of regulation (EC) 1907/2006: National Regulations e.g. Water Hazard Class 1 (SelfAssessment) Solvent Regulation (31. BImSchV) Statutory Order on Hazardous Incidents (12. BImSchV) Technical Instructions on Air Quality Seite : 14 / 16

85 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: Further relevant regulations 15.2 Chemical Safety Assessment Conducted. 16. Other Information Modifications compared to last version Abreviations: ADR Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) CAS Chemical Abstracts Service (division of the American Chemical Society) EINECS European Inventory of Existing Commercial Chemical Substances GHS Globally Harmonized System of Classification and Labelling of Chemicals IMDG International Maritime Code for Dangerous Goods LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent Règlement international concernant le transport des marchandises dangereuses par RID chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) References and data sources Wording of Hazard Statements and Precautionary Statements referred in chapter 2 15 According to regulation 67/548/EWG: According to regulation (EC) No. 1272/2008: Training for employees Additional information Seite : 15 / 16

86 Safety Data Sheet Pure 100% Fettlöser Issued on: Valid since: The data provided in this material safety data sheet is meant to represent typical data/analysis for this product and is correct to the best of our knowledge. The data was obtained from current and reliable sources, but is supplied without warranty, expressed or implied, regarding its correctness or accuracy. It is the user's responsibility to determine safe conditions for the use of this product, and to assume liability for loss, injury, damage or expense arising from improper use of this product. The information provided does not constitute a contract to supply to any specification, or for any given application, and buyers should seek to verify their requirements and product use. Issuing department: Product Development Contact: Robert Loder Seite : 16 / 16

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