Innovation in agriculture.

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1 Innovation in agriculture FOLIAR NUTRITION

2 CONTENTS FOLIAR NUTRITION PAGE PRODUCT NAME CONTENTS 4 Bo-La 150 g/l boron and 7.5 g/l molybdenum. Soluble liquid. 6 Boron 15% 150 g/l boron as boron ethanolamine. Soluble liquid. 8 Boson Manganese, magnesium, zinc, boron and molybdenum blend. Suspension concentrate. 10 Brock 375 g/l manganese and 125 g/l copper. Suspension concentrate. 12 Bushel 150 g/l manganese and 30 g/l copper as the nitrates. Soluble liquid. 14 Carnival 225 g/l calcium (as CaO), 30 g/l magnesium (as MgO), 149 g/l nitrogen (total), 750 ppm boron, 300 ppm zinc. Soluble liquid. 17 Cereal Plus 37 g/l manganese, 15 g/l magnesium (25 g/l Mg0), 18 g/l copper and 6 g/l zinc. Soluble liquid. 19 Classic 500 g/l manganese. Suspension concentrate. 21 Complex Blend of nitrogen, phosphorus and potassium with chelated micronutrients. Soluble powder. 23 Copper 435 g/l copper oxychloride (256 g/l copper). Suspension concentrate. Recommended for use as both a nutrient and a fungicide. Suitable for use in certain organic regimes. 28 Hi-Phos 440 g/l phosphorus (as P2O5) with magnesium (80 g/l as MgO) and potassium (74 g/l as K2O). Soluble liquid. 30 Jett 200 g/l manganese as the nitrate. Soluble liquid. 33 Kosman 250 g/kg potassium (as K20), 150 g/kg manganese, 60 g/kg nitrogen and 90 g/kg sulphur. Soluble dry flowable. PAGE 1

3 CONTENTS 35 KudoS High-K fertiliser containing 360 g/l potassium (as K2O) and 630 g/l sulphur (as SO3). Soluble liquid. 37 MagnuS 480 g/l magnesium (as MgO) and 360 g/l sulphur (as S). Suspension concentrate. 39 Maize Micronutrient 50 g/l magnesium (83 g/l Mg0), 20 g/l Complex manganese, 10 g/l zinc and 75 g/l nitrogen. Soluble liquid. 41 Manganese 15% 150 g/l manganese as the sulphate. Soluble liquid. 43 Manganese g/l manganese (66 g/l as Mn nitrate, 334 g/l as Mn carbonate). Suspension concentrate. 45 Maple DF 310 g/kg manganese and 180 g/kg sulphur (450 g/kg SO3). Water-dispersible granule. 48 Molybdenum 60 g/l molybdenum. Soluble liquid. 50 Multiple 330 g/l manganese (Mn), 110 g/l copper (Cu), 84 g/l magnesium (as Mg) and 84 g/l zinc (Zn). Suspension concentrate. 52 Mycrobor DF 180 g/kg boron as sodium pentaborate decahydrate. Soluble powder. 54 Potato Micronutrient 43 g/l calcium (60 g/l as Ca0), 36 g/l Complex magnesium (60 g/l Mg0), 160 g/l nitrogen. Soluble liquid. 56 Prince/Super g/l magnesium (133 g/l Mg0) as the nitrate. Soluble liquid. 59 Promise 300 g/l magnesium (500 g/l Mg0) Suspension concentrate. 61 Root g/l magnesium (100 g/l Mg0) and 60 g/l manganese as nitrates. Soluble liquid. 63 Seamac Gold Ascophyllum based seaweed extract with 80 g/l nitrogen, 88 g/l phosphorus (as P205) and 62 g/l potassium (as K20). Soluble liquid. PAGE 2

4 CONTENTS 66 Seamac PCT Ascophyllum based seaweed extract. Soluble liquid. 68 SeamaXX Ascophyllum based seaweed extract with 38 g/l nitrogen, 17.5 g/l phosphorus (as P205), 30 g/l potassium and added micronutients. Soluble liquid. 71 Spirit 195 g/l manganese, 112 g/l sulphur (280 g/l as SO3), 53 g/l magnesium (88 g/l as Mg0) and 80 g/l nitrogen. Soluble suspension. 74 Stag 140 g/l manganese and 20 g/l magnesium (33 g/l Mg0) as nitrates. Soluble liquid. 76 Sulphur 800 g/l sulphur. Suspension concentrate. Recommended for use both as a nutrient and a fungicide. Suitable for use in certain organic regimes. 83 Thio-S 151 g/l nitrogen and 345 g/l sulphur (862 g/l SO3). Soluble liquid. 88 Trice 330 g/l manganese, 110 g/l copper and 84 g/l zinc. Suspension concentrate. 90 Vertex Hi-N g/l nitrogen, 21 g/l magnesium (35 g/l Mg0), 9 g/l manganese and 5 g/l copper. Soluble liquid. 92 Vertrace Magnesium, manganese, boron and molybdenum blend. Soluble powder. 94 Zinc 150 g/l zinc as the sulphate. Soluble liquid. 96 Zinc FL 690 g/l zinc. Suspension concentrate. 99 Trademarks Acknowledgements PAGE 3

5 BO-LA HEADLAND BO-LA Inorganic liquid micronutrient. Contains 150 g/l boron and 7.5 g/l molybdenum fully soluble in water. Crops: To correct boron and molybdenum deficiency in agricultural and horticultural crops. Pack size: Packs per pallet: 10 litres 36 x 2 x 10 litres Introduction: HEADLAND BO-LA is an inorganic liquid formulation of boron and molybdenum, designed for cost-effective correction of deficiency of these elements in crops. Boron is an essential micronutrient for regulating plant cell water balance and sugar translocation. It is also important in reproductive systems, ensuring healthy pollen development. Deficiency can affect many crops but particularly Vegetables, Brassicas, Root Crops and Oilseed Rape. Molybdenum is essential to the plant in small amounts for fixation of nitrogen by enzyme systems and for nitrate reduction. Molybdenum deficiency affects a number of crops, but particularly Cauliflowers and Lettuce, giving rise to the characteristic whiptail symptom. Other members of the Brassica family can also be affected. Deficiency is most likely to arise on acid soils. Formulation: HEADLAND BO-LA contains 150 g/l of boron as boron ethanolamine and 7.5 g/l of molybdenum as sodium molybdate, formulated with buffering agents and a modern surfactant system to ensure stability and effective cover and adhesion to foliage. Rates of Use: Marginal deficiency and Autumn applications: Moderate deficiency: Severe deficiency: 1.0 l/ha in at least 200 l/ha of water. 2.0 l/ha in at least 200 l/ha of water l/ha initially followed by further applications as required if symptoms should re-appear. Higher application rates or repeat doses may be required where moderate or severe deficiency is known or identified by analysis. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. PAGE 4

6 BO-LA Timing: Apply whenever a boron deficiency is observed or expected but after the 3-leaf stage or as soon as there is sufficient foliage available to allow uptake by the plant. Best results will be obtained from applications during the evening or early morning when moisture is present in the plant. Do not apply in extremes of temperature, very bright sunlight or when the crop is under drought or other stress. Application: Half-fill the spray tank with clean water and begin agitation. Add the required quantity of HEADLAND BO-LA slowly to the tank, maintaining agitation. Add the rest of the water and apply without delay. Do not allow the spray mixture to stand idle without agitation. Thoroughly clean the sprayer after use. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND BO-LA is physically compatible with many spray-applied agricultural chemicals. Consult your distributor for the latest information. Alternatively, up-to-date compatibility information is available at Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Keep away from food, drink and animal feedingstuffs and out of reach of children. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or product label for more information. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: None. PAGE 5

7 BORON 15% HEADLAND BORON 15% Soluble inorganic micronutrient. Contains 150 g/l boron as boron ethanolamine. Crops: To correct micronutrient deficiency or imbalance in a wide range of agricultural and horticultural crops. Pack size: 10, 200 or 1000 litres Packs per pallet: 36 x 2 x 10 litres, 4 x 200 litres or 1000 litre (IBC) Introduction: Boron is an essential micronutrient for regulating plant cell water balance and sugar translocation. It is also of importance in reproductive systems, ensuring healthy pollen development. Deficiency can adversely affect most crops, including Vegetables, Brassicas, Root Crops, Horticultural Crops and Oilseed Rape, impairing growth, yield and quality. Formulation: HEADLAND BORON 15% contains 150 g/l of boron soluble in water as the ethanolamine. It is rapidly taken up by the plant when applied to foliage and contains a surfactant and wetter system to ensure efficient retention by the leaf. Rates of Use: Marginal deficiency: 1.25 l/ha in at least 200 l/ha water Moderate deficiency: 2.5 l/ha in at least 200 l/ha water Severe deficiency: 2.5 l/ha in at least 200 l/ha water followed by a further application 3-4 weeks later and again if symptoms re-appear Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Timing of Application: HEADLAND BORON 15% can be applied to crops whenever a boron deficiency is observed or expected but after the 3-leaf stage, or when there is sufficient foliage present to absorb the spray. Best results will be obtained when HEADLAND BORON 15% is applied during the early morning or evening when moisture is present in the plant. Do not apply in extremes of temperature, very bright sunlight or when the crop is under drought or other stress. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. PAGE 6

8 BORON 15% Mixing: Shake the container well before opening and use. Fill the spray-tank with at least half the required amount of water and begin agitation. Add the required amount of HEADLAND BORON 15% slowly to the tank, maintaining agitation. Add the rest of the water and apply without delay. Do not allow the diluted mixture to stand idle without agitation. Thoroughly clean the sprayer after use. Compatibility: HEADLAND BORON 15% is physically compatible with most spray-applied agricultural chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information may be found at Read the label of the partner product carefully before mixing with HEADLAND BORON 15%. HEADLAND BORON 15% is incompatible with HEADLAND SPIRIT, HEADLAND CARNIVAL, HEADLAND MANGANESE 15%, JETT, MAPLE DF and HEADLAND STAG. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or product label for more information. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: None. PAGE 7

9 BOSON HEADLAND BOSON A suspension concentrate formulation of micronutrients. Contains manganese, magnesium, boron, zinc and molybdenum with nitrogen and sulphur. Crops: To maintain nutrient balance in Oilseed Rape, Brassicas, Peas, Beans and other arable crops. Pack size: 5 litres Packs per pallet: 51 x 2 x 5 litres Introduction: HEADLAND BOSON is an advanced suspension formulation of manganese, magnesium, boron, zinc and molybdenum with nitrogen and sulphur for foliar application. The formulation provides superior foliar cover and adhesion optimising availability, uptake and adsorption of the application. Formulation: HEADLAND BOSON is a suspension concentrate containing: Boron: 73 g/l (5.5% w/w) Magnesium: 54 g/l (4.1% w/w) expressed as MgO Manganese: 22 g/l (1.65% w/w) Zinc: 2.0 g/l (0.15% w/w) Molybdenum: 2.0 g/l (0.15% w/w) Sulphur: 148 g/l (11.1% w/w) Nitrogen: 32 g/l (2.4% w/w) (29.2 g/l ammoniacal nitrogen) (2.8 g/l ureic nitrogen) Rate of Use: Apply 2.5 l/ha. Timings: Oilseed Rape: Start at the 4-leaf stage and repeat if necessary at day intervals. Repeat when stems begin to elongate rapidly. Leaf Brassicas: Apply early in the season when the plants have sufficient leaf area to intercept the spray. Repeat if necessary at day intervals until 4 weeks before harvest. PAGE 8

10 BOSON Pulses (Beans, Peas, Soya Beans): Apply early in the season when the plants have sufficient leaf area to intercept the spray. Repeat if necessary at day intervals until 4 weeks before harvest. Other Agricultural and Horticultural Crops: HEADLAND BOSON is suitable for application to other agricultural and horticultural crops where nutrient deficiency has been identified or is suspected. Applications may begin as soon as the target crop has sufficient foliage to intercept the spray and repeated as required. Water Volume: Apply in at least 200 l/ha of water. Ensure thorough cover of the foliage. Note: Do not apply to crops under stress from spray damage, frost or drought. Apply in the early morning or evening for best results. Do not apply in very bright sunlight or very high temperatures. Mixing: Spray equipment should be clean and free of residues from previous use. Shake the container thoroughly before opening. Add the required dose to the required amount of water in the spray tank. Maintain continuous agitation when mixing and spraying; do not allow the spray mixture to stand idle at any time. Compatibility: This product is chemically compatible with many approved agrochemicals. Contact your advisor for the latest recommendations and advice or refer to the Headland website Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or product label for further details. Transport: This product is not classified as hazardous for transport. Date of Issue: November Significant changes since last issue: None. PAGE 9

11 BROCK HEADLAND BROCK Suspension micronutrient. Contains 375 g/l manganese and 125 g/l copper as a suspension concentrate. Crops: To correct manganese and copper deficiency in agricultural crops. Pack size: Packs per pallet: 5 litres 51 x 2 x 5 litres Introduction: HEADLAND BROCK is a ready-to-use liquid formulation for correction of manganese and copper deficiencies in crops or for use as a maintenance treatment. Formulation: HEADLAND BROCK contains 375 g/l of manganese and 125 g/l of copper. As well as providing a highly concentrated source of these nutrients, its excellent suspension formulation is tolerant of wide ranges of ph and can be mixed with many tank-mix partners including a number of materials which may be incompatible with other forms of manganese. Rate of Use: 1.0 l/ha in at least 200 l/ha water. Repeat if the deficiency is severe. Do not apply more than 5.0 l/ha per crop per season. Do not apply to protected crops. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Timing: Apply whenever deficiency is observed or expected or as a routine maintenance treatment. Applications to Cereals may commence after the 3-leaf stage. Autumn-sown Cereals will benefit from an application before the onset of Winter. Applications to other crops may be made as soon as there is sufficient leaf area available to absorb the spray. Best results will be obtained when HEADLAND BROCK is applied during the evening or early morning when moisture is present in the plant. Do not apply in extremes of temperature, very bright sunlight or when the crop is under drought or other stress. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. PAGE 10

12 BROCK Application: SHAKE THE CONTAINER WELL BEFORE OPENING AND USE. Half-fill the spray tank with clean water, begin agitation, and slowly add the required quantity of HEADLAND BROCK. Add the rest of the water and apply without delay. Do not allow the mixture to stand idle without agitation. Thoroughly clean the sprayer after use. Compatibility: HEADLAND BROCK is physically compatible with most spray-applied agricultural chemicals. Consult your distributor for the latest information. Alternatively, up-to-date compatibility information can be found at Read the label of the partner product carefully before mixing with HEADLAND BROCK. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Safety Precautions: The Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Dangerous for the Environment N. Risk Phrases: R51 Toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. Safety Phrases: S61 Avoid release to the environment. Refer to special instructions/safety data sheet. Transport: This product is classified as hazardous for transport. UN Number: UN3082 Shipping name: Environmentally hazardous substance, liquid N.O.S. (Copper oxychloride) Transport class: 9 Packing group: III Environmental hazard: Yes, environmentally hazardous Special precautions for users: No special precautions Date of latest revision: November Significant changes since last issue: Risk and Safety Phrases and Transport classification. PAGE 11

13 BUSHEL HEADLAND BUSHEL Soluble inorganic micronutrient. Contains 150 g/l manganese and 30 g/l copper as the nitrates. Crops: To correct micronutrient deficiency or imbalance in a wide range of agricultural and horticultural crops. Pack size: 10, 200 or 1000 litres Packs per pallet: 36 x 2 x 10 litres, 4 x 200 litres or 1000 litre (IBC) Formulation: HEADLAND BUSHEL contains manganese and copper in the ratio of 5:1 as the highly soluble and plant available nitrates. Plants can utilise nitrates up to 25% more efficiently than the same amount of element from sulphate sources and the solubility of nitrates allows more concentrated formulations to be produced. Rates of Use: Marginal deficiency: 1.5 l/ha in at least 200 l/ha water Moderate deficiency: 3.0 l/ha in at least 200 l/ha water Severe deficiency: 3.0 l/ha in at least 200 l/ha water. Repeat after 3-4 weeks and again if symptoms return It is often desirable to apply HEADLAND BUSHEL as part of a planned nutrition programme to avoid low-level deficiency arising and compromising yields. Suitable applications would include: Winter Cereals (3 applications at GS20-21, and 37). Spring Cereals (GS13-15 and 32-37). Potatoes, Sugar Beet and Top Fruit can also benefit from a programmed approach. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Mixing and Application: Half-fill the spray tank with clean water, begin agitation and add the required quantity of HEADLAND BUSHEL. Add the rest of the water and apply without delay. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND BUSHEL is physically compatible with many spray-applied agricultural chemicals. Consult your distributor for the latest information. PAGE 12

14 BUSHEL Alternatively, up-to-date compatibility information may be found at Read the label of the partner product carefully before mixing with HEADLAND BUSHEL. HEADLAND BUSHEL is incompatible with formulations containing phenoxy herbicides, fenpropimorph and cyproconazole. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight or near direct sources of heat. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Corrosive C Risk Phrase: R34 Corrosive-causes burns. Safety Phrases: S2 Keep out of reach of children. S23 Do not breathe vapours or spray mist. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 In case of contact with skin rinse immediately with plenty of water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This product is classified as hazardous for transport. Road Transport: Corrosive. UN Number: 1760 Proper Shipping Name: Corrosive liquid, N.O.S. (manganese dinitrate) IMDG Class: 8 CPL Packing Group: III Date of latest revision: November Significant changes since last issue: Revised risk and safety phrases, revised transport classification. PAGE 13

15 CARNIVAL HEADLAND CARNIVAL Soluble inorganic micronutrient. Contains 225 g/l calcium (as CaO), 30 g/l magnesium (as Mg0), 149 g/l nitrogen (total), 750 ppm boron, 300 ppm zinc. Crops: To correct micronutrient imbalance and to prevent disorders related to calcium shortage in a wide range of agricultural, horticultural and fruit crops. Pack size: 10, 200 or 1000 litres Packs per pallet: 36 x 2 x 10 litres, 4 x 200 litres or 1000 litre (IBC) Introduction: HEADLAND CARNIVAL contains calcium, magnesium, nitrogen, zinc and boron formulated to maximise uptake of calcium with additional nutrients to aid the production of quality Fruit and Vegetables. Formulation Analysis: Calcium as CaO 22.5% w/v 15.0% w/w Magnesium as MgO 3.0% w/v 2.0% w/w Total nitrogen 14.9% w/v 10.0% w/w Nitrate nitrogen 14.1% w/v 9.47% w/w Ammoniacal nitrogen 0.8% w/v 0.53% w/w Zinc 300ppm w/v 200ppm w/w Boron 750 ppm w/v 500ppm w/w A concentrated stable liquid formulation for easy mixing and handling. Rates of Use: Apples: Low levels of calcium increase the risk of bitter pit, russetting, skin splitting, cracking and surface rupture and seriously affect the potential for crop storage. Calcium also helps to condition the tree throughout the growing season. Rate: l/ha Water: Timing: Depending on tree size 500 l/ha, applying sufficient water to reach incipient runoff. Apply from petal fall and repeat at day intervals with final application days prior to harvest, depending on the cultivar. The exact rates and timings can be manipulated to suit local spraying practices. PAGE 14

16 CARNIVAL Avoid spraying in high temperatures. If the temperature exceeds 21 C and spraying cannot be delayed, use the lower rate and apply at shorter intervals to give the same total amount over the season. Spraying in the late afternoon or early evening has been shown to reduce the risk of scorch. Young foliage is more susceptible to phytotoxicity. Strawberries: To improve fruit firmness and prolong shelf life. Rate: Maintenance 2.5 l/ha Deficiency 5.0 l/ha Water: l/ha Timing: Apply from start of flowering. Repeat at day intervals as necessary. Carrots: For prevention of deficiency. Rate: 5.0 l/ha Water: Use at least 200 l/ha Timing: 2-3 applications at day intervals beginning at the pencil stage. Celery: Blackheart, a localised calcium deficiency usually occurs in young immature leaves at the centre of the plant. Spray to ensure HEADLAND CARNIVAL reaches the heart of the plant. Rate: Up to 5.0 l/ha Water: Use at least 200 l/ha Timing: When symptoms of deficiency are first seen. Outdoor Lettuce: In order to prevent tip burn it is essential that HEADLAND CARNIVAL is applied directly to the susceptible tissue. Early treatment is essential. Do not apply to protected Lettuce. Rate : Water: Timing: 5.0 l/ha Use at least 200 l/ha Begin application before head formation and repeat every days as necessary. Potatoes: For the reduction of calcium deficiency related disorders. Rate: 5.0 l/ha Water: Use sufficient water to ensure good cover of the haulm. Timing: When required; repeat after days. PAGE 15

17 CARNIVAL Vegetable Brassicas: For the prevention of deficiency problems in Cauliflower, Cabbage, Brussel Sprouts and Chinese Leaves. Rate: 5.0 l/ha Water: Use at least 200 l/ha Timing: Spray early in the growing season at 7-10 day intervals. Mixing and Application: Half fill the spray tank with clean water, begin agitation and add the required quantity of HEADLAND CARNIVAL. Add the rest of the water and apply without delay. Maintain agitation whilst travelling and spraying. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND CARNIVAL is compatible with most spray applied agricultural chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information may be found at HEADLAND CARNIVAL is incompatible with the following: HEADLAND BORON 15%, SEAMAC PCT, SEAMAC GOLD, HEADLAND KUDOS, manganese sulphate, magnesium sulphate, HEADLAND ZINC, zinc sulphate. Should additional manganese/magnesium need to be applied, use a Headland nitrate formulation. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or product label for more information. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: None. PAGE 16

18 CEREAL PLUS HEADLAND CEREAL PLUS A formulated micronutrient blend for application to Cereal crops. Contains: 37 g/l manganese, 15 g/l magnesium (25 g/l MgO), 18 g/l copper and 6 g/l zinc. Crops: All Cereal crops. Pack size: 10 or 1000 litres Packs per pallet: 36 x 2 x 10 litres or 1000 litre (IBC) Introduction: HEADLAND CEREAL PLUS contains a carefully balanced blend of nitrate ansulphate based micronutrients specifically formulated to meet the nutrient needs of Cereal crops. Rates of Use: Apply l/ha in at least 200 l/ha of water. Applications may be made at any time after the 3-leaf stage when the plant has sufficient leaf area to absorb the spray. For Cereals, apply in the Autumn from GS13, once sufficient foliage is present in the crop to absorb the spray. Apply at or around GS31 in the Spring. Avoid spraying in very strong sunlight, in temperatures above 25 C or when the crop is suffering from drought stress. Mixing and Application: Shake the container well before opening and use. Half fill the sprayer tank with clean water. Begin agitation and add the required quantity of HEADLAND CEREAL PLUS. Add the rest of the water and apply without delay. Maintain agitation while travelling and throughout the spraying operation. Compatibility: HEADLAND CEREAL PLUS is compatible with many spray-applied agricultural chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information may be found at HEADLAND CEREAL PLUS is incompatible with Colstar, Corbel and Ensign. Storage: Keep dry and cool in a suitable store. PROTECT FROM FROST. Store above 5 C. Do not store in direct sunlight. Keep out of reach of children. PAGE 17

19 CEREAL PLUS Safety Precautions: Regulatory Information: The European Regulation (EC) No.1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures (CLP Regulation) the EU Globally Harmonised System (GHS) apply to this product. Label elements under CLP: Hazard Statements: H314 H411 Signal Words: Causes severe skin burns and eye damage. Toxic to aquatic life with long lasting effects. Danger. Precautionary P264 Wash hands thoroughly after handling. Statements: P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/ eye protection/face protection. P IF IN EYES rinse cautiously with water for +338 several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P391 Collect spillage. Transport: This product is classified as hazardous for transport. UN number: UN3082 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (COPPER SULPHATE; ZINC SULPHATE) Transport class: 9 Packing group: Environmental hazards: III Environmentally hazardous: Yes Marine pollutant: No Date of latest revision: November Significant changes since last issue: Contents statement, Classification to CLP and Transport classification. PAGE 18

20 CLASSIC HEADLAND CLASSIC Inorganic micronutrient. Contains 500 g/l manganese as a suspension concentrate. Crops: To correct manganese deficiency in a wide range of agricultural and horticultural crops. Pack size: Packs per pallet: 5 litres 51 x 2 x 5 litres Introduction: HEADLAND CLASSIC is a ready-to-use liquid formulation for correction of manganese deficiency. Manganese is used in the plant in conjunction with other essential nutrients for stimulation of various enzyme systems. Its major role is in the synthesis of chlorophyll and metabolism of nitrogen. Most crops are sensitive to manganese levels, particularly Cereals, Vegetables, Brassicas, Root Crops and Fruit. Formulation: HEADLAND CLASSIC contains 500 g/l of manganese formulated as a suspension concentrate. It contains an advanced surfactant/suspension system to ensure rapid and even dispersion in the spray tank and superior adhesive properties on foliage. Rate of Use: 1.0 l/ha in at least 200 l/ha water. Increase the water volume as necessary for application to Bush, Cane or Top Fruit. Repeat at day intervals if required. Do not apply more than 5.0 l/ha per crop per season. Do not apply to protected crops. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Timing: Cereals: Apply from the 3-leaf stage. Oilseed Rape, Leaf and Root Brassicas: Apply from 4-6 leaf stage. Peas and Beans: Apply from commencement of flowering. Potatoes: Apply from full emergence. PAGE 19

21 CLASSIC Grassland: Apply from when growth re-starts in the Spring. Other crops: Apply from when there is sufficient foliage present to absorb the spray. Application: Shake the container well before opening and use. Half-fill the spray tank with clean water, begin agitation, and add the required quantity of HEADLAND CLASSIC. Add the rest of the water and apply without delay. Maintain agitation while travelling and throughout the spraying operation. Do not allow the mixture to stand idle without agitation. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND CLASSIC is physically compatible with most spray-applied agricultural chemicals. Contact your distributor for the latest information. Alternatively, up-to-date information on compatibilities may be found at Read the label of the partner product carefully before mixing with HEADLAND CLASSIC. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Keep away from food, drink and animal feedingstuffs and out of reach of children. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) do not apply to this product. Its use should not present a hazard in normal circumstances. Refer to the Material Safety Data Sheet or product label for full details. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: None. PAGE 20

22 COMPLEX HEADLAND COMPLEX A foliar-applied soluble micronutrient blend for use in agriculture. Crops: To maintain nutrient balance in agricultural and horticultural crops. Pack size: 10 kgs Packs per pallet: 100 x 10 kgs Introduction: HEADLAND COMPLEX is a carefully formulated fully soluble blend of NPK and micronutrients. It is suitable for optimising nutrient balance in a wide range of crops. HEADLAND COMPLEX may be used as a routine nutrient source for maintaining healthy crop growth and development and also to provide a source of rapidly absorbed additional nutrients at a time of crop stress or during periods of particularly rapid growth and development. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Formulation: HEADLAND COMPLEX contains a balanced ratio of fully soluble and plant-available nutrients formulated for easy and straightforward mixing and application. HEADLAND COMPLEX contains: Total nitrogen: 20% w/w (nitrate nitrogen 2.0% w/w) (ammoniacal nitrogen 4.7% w/w) (ureic nitrogen 13.3% w/w) Phosphorus 8.0% w/w as P2O5 Potassium 14% w/w as K2O Sulphur 9.7% w/w S soluble in water (24% w/w as SO3) Magnesium 2.0% w/w as MgO With chelated micronutrients. Rates of Use: kg/ha in at least 200 l/ha water. Timing: Apply when required or as indicated by the results of tissue analysis, once the crop has sufficient leaf area present to absorb the spray (e.g. the 3-leaf stage in Cereals). Repeat at 7-14 day intervals as required. PAGE 21

23 COMPLEX Application: Half-fill the spray tank with clean water, begin agitation and add the required quantity of HEADLAND COMPLEX. Add the rest of the water and apply without delay. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND COMPLEX is physically compatible with many spray-applied agricultural chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information may be found at Read the label of the partner product carefully before mixing with HEADLAND COMPLEX. Storage: Keep dry and cool in original container in a suitable agricultural chemical store. Keep out of direct sunlight and away from direct sources of heat. Safety Precautions: The European Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures (CLP Regulation) the EU Globally Harmonised System (GHS) apply to this product. Label elements under CLP: Hazard statements: H318 Causes serious eye damage. Signal words: Danger Hazard pictograms: GHS05 Corrosion. Precautionary statements: P280 Wear protective gloves/protective clothing/ eye protection/face protection. P IF IN EYES rinse cautiously with water for +338 several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or Doctor. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: Formulation statement, Pack size and Classification to CLP. PAGE 22

24 COPPER HEADLAND COPPER An inorganic micronutrient and fungicide. Contains 435 g/l (32.2% w/w) of copper oxychloride (equivalent to 256 g/l copper). Crops: To correct copper deficiency in a wide range of agricultural and horticultural crops and as a fungicide in Potatoes, Hops, Vines, Tomatoes, Celery, Blackcurrants, Blackberries, Apples, Pears and Cherries. For use as a fungicide, refer to Rates of Use - Fungicide Application below. Pack size: Packs per pallet: 5 litres 51 x 2 x 5 litres Introduction: Copper is essential to crops for stimulation of enzyme systems in association with other elements, and is particularly active in many of the metabolic pathways within the cell. All crops can be affected by copper deficiency including Cereals, Vegetables, Fruit, Brassicas, Root Crops, Horticultural Crops and Grassland. Crops grown on peaty soils, shallow organic chalks, heathland and heavily leached soils are most likely to exhibit copper deficiency. Formulation: HEADLAND COPPER is a suspension concentrate formulation containing 435 g/l copper oxychloride (equivalent to 256 g/l elemental copper). It contains an advanced wetter/surfactant system for optimum leaf coverage and absorption. HEADLAND COPPER is also approved for use as a fungicide in certain crops - see below. Rates of Use: Copper deficiency Marginal deficiency: 0.25 l/ha in at least 200 l/ha water Moderate deficiency: 0.5 l/ha in at least 200 l/ha water Severe deficiency: 0.5 l/ha in at least 200 l/ha water. Repeat after 3-4 weeks and again if symptoms return. Applications should be made during periods of active growth when there is enough foliage present to absorb the spray. Do not apply before the 3-leaf stage. Do not apply when the crop is under stress due to drought or extremes of temperature. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. PAGE 23

25 COPPER Mixing: Shake the container thoroughly before opening and use. Add to the required quantity of water in the spray tank with agitation. Do not allow the mixture to stand in the tank without agitation. Rates of Use: Fungicide Application These recommendations form part of the product label approved under the Control of Pesticides Regulations 1986 (MAPP No ). Do not exceed the maximum stated application rates. HEADLAND COPPER may be used as a fungicide in organic Potato crops if there is a need recognised by the inspection body or inspecting authority (permission must be granted by your specific certifying body before use). No more than 6 kg of copper/ha/year may be applied to organic Potatoes. This use is expected to continue to be permitted under organic standards until alternative control measures are developed. Apples and Pears Canker Use 10 l/ha in 1000 litres of water. Apply immediately prior to leaf fall. Repeat at 50% leaf fall and again at bud break if necessary. Do not apply more than 3 sprays per crop. Blackberries Purple Blotch Disease Use l/ha in 1000 litres of water depending on disease severity. Apply during mid-may and repeat twice at 10-day intervals. Do not apply more than 3 sprays per crop. Blackcurrants Rust Use l/ha in 1000 litres of water depending on the severity of the disease. Apply to affected bushes after harvest. Celery Celery Leaf Spot Use l/ha in litres of water. Spray at the seedling stage and when planting out. Repeat at day intervals as required. Cherry Bacterial Canker Use 6.0 l/ha in 1000 litres of water. Apply 3 sprays at 3 week intervals, beginning in mid-august. Some varieties may show symptoms of phytotoxicity. Hops Downy Mildew Use 4.0 litres per 1000 litres of water as a high volume spray. Spray at day intervals from mid-june until 7 days before harvest. Remove all infected terminal, lateral and basal spikes. This treatment will also reduce the development of powdery mildew. PAGE 24

26 COPPER Potato Potato Blight Use 10.0 l/ha in 1000 litres of water. Increase the water volume to 1300 litres during July and August. Apply immediately after a blight warning before onset of disease, followed by further sprays from mid-june to mid-august at day intervals. Tomato Blight and Buckeye Rot Use 6.0 l/ha in 1000 litres of water. Apply before onset of the disease and repeat at day intervals throughout the season. For control of Buckeye rot, also spray the lower parts of the plant and the soil. Wine Grapes and Table Grapes Downy Mildew Use 10.0 l/ha in 1000 litres of water. Apply at bud burst and repeat at day intervals as necessary. Compatibility: HEADLAND COPPER is physically compatible with many spray-applied agricultural chemicals. Consult your supplier for the latest information. Up-to-date compatibility information is also available at Read the label of the partner product carefully before mixing with HEADLAND COPPER. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight. Safety Precautions: a. Operator Protection Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment: WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate. However, engineering controls may replace personal protective equipment if a CoSHH assessment shows they provide an equal or higher standard of protection. WASH HANDS AND EXPOSED SKIN before meals and after work. WHEN USING DO NOT EAT, DRINK OR SMOKE. b. Environmental Protection Do not contaminate surface waters or ditches with chemical or used container. c. Storage and Disposal KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS. WASH OUT CONTAINER THOROUGHLY, empty washings into spray tank and dispose of safely. KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place. PAGE 25

27 COPPER d. Other Specific Restrictions A minimum interval of 10 days must be observed between applications. HARMFUL TO LIVESTOCK. Keep livestock out of treated areas for at least 3 weeks. DO NOT RE-USE CONTAINER for any purpose. IMPORTANT INFORMATION: FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL FUNGICIDE. Apple, Pear Maximum individual dose: 10.0 l/ha Maximum number of applications: 3 per crop Blackcurrant, Wine Grapes, Table Grapes, Celery, Potato Maximum individual dose: 10.0 l/ha Tomato Maximum individual dose: Cherry Maximum individual dose: Maximum number of applications: Blackberry Maximum individual dose: Maximum number of applications: Hops Maximum individual dose: 6.0 l/ha 6.0 l/ha 3 per crop 1.0 l/ha 3 per crop 4.0 l/ha Read the label before use. Using this product in a manner that is inconsistent with the label may be an offence. Follow the Code of Practice for using plant protection products. Regulatory Information: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbols: Harmful Xn Dangerous for the Environment N Risk Phrases: R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R50 Very toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. PAGE 26

28 COPPER Safety Phrases: S2 Keep out of reach of children. S23 Do not breathe spray. S35 This material and its container must be disposed of in a safe way. S46 If swallowed, seek medical advice immediately and show the container label. S57 Use appropriate containment to avoid environmental contamination. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. To avoid risks to man and the environment, comply with the instructions for use. Product registration number MAPP The (CoSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. Note: Extensions of Authorisation for Minor uses in the UK have been issued for this product. For details see the Chemicals Regulation Directorate website ( Transport: This product is classified as hazardous for transport. Road Transport: Environmentally hazardous liquid UN Number: 3082 Proper Shipping Name: Environmentally hazardous substance, liquid (contains copper oxychloride 32.2% w/w) UN Class: 9 Packing Group: III ADR/RID Description: Marine pollutant IMDG Class: Marine pollutant 9 Other Registrations: HEADLAND COPPER is also registered for use as a fungicide in Australia and New Zealand. Contact Headland Agrochemicals for further details. Date of latest revision: November Significant changes since last issue: Risk and Safety Phrases. PAGE 27

29 HI-PHOS HEADLAND HI-PHOS Inorganic fertiliser for foliar application. Contains 440 g/l phosphorus (as P2O5) with 80 g/l magnesium (as MgO) and 74 g/l potassium (as K2O). Soluble liquid. Crops: For application to agricultural crops to provide additional phosphorus, potassium and magnesium during periods of peak demand. Pack size: Packs per pallet: 10 litres 36 x 2 x 10 litres Introduction: HEADLAND HI-PHOS is a liquid formulation containing magnesium, potassium and phosphorus in carefully balanced proportions for application to Potatoes, Cereals, Peas, Beans, Sugar Beet and other crops. Formulation: HEADLAND HI-PHOS is formulated as a soluble liquid for straightforward mixing and application. Rates of Use and Timing: Potatoes: 1. To encourage tuber numbers Apply 10.0 l/ha in at least 200 l/ha of water at tuber initiation. 2. To encourage bulking Apply 5.0 l/ha in at least 200 l/ha of water at the onset of bulking and repeat at least once during bulking. The timing of the second application should be based on tissue analysis and should not be less than 10 days after the first. Cereals: Apply 5.0 l/ha in at least 200 l/ha of water at tillering and repeat at day intervals as required. An application between ear emergence and the end of flowering may also be beneficial. Oilseed Rape: Apply l/ha in at least 200 l/ha of water. Apply in the Autumn when the crop has 6-8 leaves and repeat in the Spring at early stem extension. Peas and Beans: Apply 5.0 l/ha in at least 200 l/ha of water when the crop is cms high and repeat after days. Sugar Beet: Apply 5.0 l/ha in at least 200 l/ha of water at the 4-6 leaf stage. Repeat at day intervals as required. PAGE 28

30 HI-PHOS Maize Apply l/ha in at least 200 l/ha of water at the 4-8 leaf stage. Repeat at day intervals if required. Mixing: Shake the container well before opening and use. Half-fill the spray tank with clean water, begin agitation, and add the required quantity of HEADLAND HI-PHOS. Add the rest of the water and apply without delay. Maintain agitation while travelling and throughout the spraying operation. Compatibility: HEADLAND HI-PHOS is compatible with many foliar-applied crop chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information is available on our website at Do not mix HEADLAND HI-PHOS with HEADLAND BORON 15% or any highly alkaline products. HEADLAND HI-PHOS is incompatible with Corbel. Storage: Store in original container, tightly closed in a suitable store away from food, drink and animal feedingstuffs and out of reach of children. Protect from frost. Store above 5 C. Do not store in direct sunlight or near direct sources of heat. Safety Precautions: The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) apply to this product. Hazard Symbol: Irritant Xi Risk Phrase: R36/38 Irritating to eyes and skin. Safety Phrases: S2 Keep out of reach of children. S26/27 After contact with skin or eyes wash immediately with plenty of water. S37/39 Wear suitable protective gloves and face protection. S49 Keep in original container. Transport: This product is not classified as hazardous for transport. Date of latest revision: November Significant changes since last issue: Contents statement, crops and rates. PAGE 29

31 JETT HEADLAND JETT Soluble inorganic micronutrient. Contains 200 g/l manganese as the nitrate. Crops: To correct micronutrient deficiency or imbalance in a wide range of agricultural and horticultural crops. Pack size: 10 or 1000 litres Packs per pallet: 36 x 2 x 10 litres, or 1000 litre (IBC) Introduction: HEADLAND JETT is an advanced formulation of manganese that is rapidly taken up by the plant. Manganese is used in the plant in conjunction with other essential nutrients for stimulation of various enzyme systems. Its major role is in the synthesis of chlorophyll and metabolism of nitrogen. Most crops are sensitive to manganese levels, particularly Cereals, Vegetables, Brassicas, Root Crops and Fruit. Formulation: HEADLAND JETT is a liquid formulation containing manganese as the highly soluble and plant available nitrate. Plants can utilise nitrates up to 25% more efficiently than the same amount of element from sulphate sources and the solubility of nitrates allows more concentrated formulations to be produced. Rates of Use: Marginal deficiency: 1.25 l/ha in at least 200 l/ha water Moderate deficiency: 2.5 l/ha in at least 200 l/ha water In areas of severe or known deficiency a programme of applications throughout the growing season may be necessary. Do not exceed more than 12.0 litres per season. Note: A crop s nutrient status can only be determined accurately by tissue analysis. Headland recommends that tissue analysis results are used whenever possible to optimise micronutrient applications. Timing: Apply whenever a manganese deficiency is observed or expected or as a routine maintenance treatment. Applications may commence after the 3-leaf stage or as soon as there is sufficient foliage to absorb the spray. Best results will be obtained from applications made during the early morning or evening when moisture is present in the plant. Do not apply in extremes of temperature, very bright sunlight or when crops are under drought or other stress. PAGE 30

32 JETT Winter Cereals and Winter Oilseed Rape will have a requirement for manganese in the Autumn. This should be followed in the Spring by a further application if required pre-stem extension to ensure adequate levels at a time of rapid growth. Peas, Potatoes and Sugar Beet can benefit from a programmed approach. The use of HEADLAND GUARD 2000 at 0.1% v/v is recommended to improve spray retention and rainfastness. Contact Headland Agrochemicals for more information. Compatibility: HEADLAND JETT is physically compatible with most spray applied agricultural chemicals. Consult your supplier for the latest information. Alternatively, up-to-date compatibility information is available at Read the label of the partner product carefully before mixing with HEADLAND JETT. HEADLAND JETT is incompatible with the following: HEADLAND BORON 15%, fenpropimorph, bentazone+mcpb and triflusulfuron-methyl. Storage: Protect from frost. Store above 5 C. Do not store in direct sunlight or near direct sources of heat. Safety Precautions: The Globally Harmonized System of Classification and Labelling of Chemicals (CLP) applies to this product. Label elements under CLP: Signal words: Danger Hazard pictograms: GHS05 Corrosion. GHS07 Exclamation mark. GHS08 Health hazard. Hazard statements: H373 May cause damage to organs through prolonged or repeated exposure. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects. Precautionary statements: P260 Do not breathe spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P IF SWALLOWED: Immediately call a POISON CENTRE or doctor. PAGE 31

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