Material Safety Data Sheet. Nitrite-Nitrogen Standard, 1000ppm, Preserved with chloroform. Section 1 - Chemical Product and Company Identification

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1 ISO9001:2000 Certified Material Safety Data Sheet Section 1 - Chemical Product and Company Identification MSDS Name:, Catalog Numbers: LC17930 Synonyms: Company Identification: LabChem Inc 200 William Pitt Way Pittsburgh, PA Company Phone Number: (412) Emergency Phone Number: (800) CHEMTREC Phone Number: (800) Section 2 - Composition, Information on Ingredients CAS# Chemical Name: Percent Water balance Potassium nitrate Chloroform <0.2 Section 3 - Hazards Identification Emergency Overview Appearance: Colorless Caution! May cause skin irritation. May cause eye irritation. Contains chloroform, which may cause cancer and is known to cause adverse reproductive and fetal effects in animals. Target Organs: Kidneys, heart, central nervous system, liver, eyes, reproductive system, skin. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Chloroform can be absorbed through the skin in harmful amounts

2 Ingestion: At high concentrations of potassium nitrite, ingestion symptoms include abdominal spasms, collapse, coma, blood disorders, and fatal respiratory paralysis. Inhalation: Higher concentrations of potassium nitrite produce coughing, dyspnea, headache, flushing of skin, nausea, vomiting, shock, marked hypotension, cyanosis, convulsions, coma, and respiratory paralysis. Inhalation of chloroform may cause central nervous system depression, liver and kidney damage, and cardiac sensitization. Chronic: Possible cancer hazard based on animal data. May cause reproductive and fetal effects. Laboratory experiments with chloroform have resulted in mutagenic effects. Prolonged exposure may cause liver, kidney and heart damage. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid. Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid if irritation or symptoms occur. Inhalation: Move victim to fresh air immediately. Get medical aid if cough or other symptoms appear. Notes to Physician: Chloroform causes cardiac sensitization to endogenous catecholamines which may lead to cardiac arrhythmias. Do not use adrenergic agents such as epinephrine or pseudo epinephrine. Persons with liver, kidney, of central nervous system diseases may be at increased risk from exposure to this product. Effects may be delayed. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Chloroform can decompose at high temperatures, forming toxic and corrosive gases, such as phosgene, hydrogen chloride, and chlorine. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Autoignition Temperature: Not applicable. Flash Point: Not applicable. NFPA Rating: CAS# : Not published. CAS# : Not published

3 CAS# : H-2, F-0. I=0 Material Safety Data Sheet Explosion Limits: Lower: No information Upper: No information Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal. Section 7 - Handling and Storage Handling: Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a cool, dry area. Keep away from strong oxidizers. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA Water Potassium nitrite Chloroform 10ppm TWA 500ppm IDLH 50ppm Ceiling; 240mg/m 3 Ceiling OSHA Vacated PELs: Chloroform: 2 ppm TWA; 9.78 mg/m 3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: - 3 -

4 Follow the OSHA respirator regulations found in 29CFR Always use a NIOSH-approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Clear liquid Color: Colorless Odor: Odorless ph: No information found. Vapor Pressure: 14 mm Vapor Density: 0.7 Evaporation Rate: No information found. Viscosity: No information found. Boiling Point: 100 C ( F) Freezing/Melting Point: 0 C ( F) Decomposition Temperature: No information found. Solubility in water: No information found. Specific Gravity/Density: 1.0 Molecular Formula: Not applicable. Molecular Weight: No information found. Section 10 - Stability and Reactivity Chemical Stability: Stable. Conditions to Avoid: Excess heat. Incompatibilities with Other Materials: Reducing agents, fuels. Hazardous Decomposition Products: Nitrogen oxides, hydrogen chloride, chlorine, phosgene gas. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS: CAS# : ZC CAS# : TT CAS# : FS LD50/LC50: CAS# : Oral, rat: LD50 = >90 ml/kg. CAS# : Oral, rabbit: LD50 = 200 mg/kg Inhalation, rabbit: LC50 = 85 g/m3/2h. CAS# : Draize test, rabbit, eye: 20mg/24H moderate, Draize test, rabbit, skin: 500mg/24H mild, - 4 -

5 Inhalation, mouse: LC50 = mg/m3/2h, Inhalation, mouse: LC50 = 6000 mg/m3/6h, Inhalation, rat: LC50 = mg/m3/4h, Inhalation, rat: LC50 = 6000 mg/m3/6h, Oral, mouse: LD50 = 36mg/kg, Oral, rat: LD50 = 695mg/kg, Oral, rat: LD50 = 1250mg/kg, Skin, rabbit: LD50 = >20g/kg Carcinogenicity: CAS# : Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. CAS# : Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. CAS# : ACGIH: -A3- Confirmed animal carcinogen with unknown relevance to humans California: carcinogen NTP: Suspect carcinogen IARC: Group 2B carcinogen Epidemiology: Potassium nitrite is a blood poison which may be fatal. However, no toxic effects are anticipated at this concentration. Teratogenicity: Chloroform: Oral, rat: LDLo=1260mg/kg (female 6-15 days after conception) Effects on Embryo or fetus- fetotoxicity (except death), specific development abnormalitiesmusculoskeletal system. Inhalation, mouse: TCLo=100ppm/7H (female 8-15 days after conception) specific developmental abnormalities-craniofacial (including nose and tongue) Inhalation, rat: TCLo=100ppm/7H (female 6-15 days after conception) specific developmental abnormalities-gastrointestinal system and homeostasis. Reproductive: Chloroform: Inhalation, rat: TCLo=30ppm/7H (female 6-15 days after conception) fertility-other measures of fertility. Inhalation, rat: TCLo=300ppm/7H (female 6-15 days after conception) fertility-female fertility index (e.g. # females pregnant per # sperm positive females; #females pregnant per # females mated) and post-implantation mortality (e.g. dead and /or resorbed implants per total number of implants) Mutagenicity: Chloroform: DNA Inhibition: Human, HeLa cell=19mmol/l; sister chromatid exchange: human, lymphocyte=10mmol/l; micronucleus test: oral, rat=4mmol/kg; unscheduled DNA synthesis: oral, rat=1g/kg; sister chromatid exchange: hamster, embryo=100mmol/l Neurotoxicity: No information found. Section 12 - Ecological Information No information found

6 Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. Shipping Name: Hazard Class: UN Number: Packing Group: Section 14 - Transport Information US DOT Not regulated. Section 15 - Regulatory Information US Federal TSCA: CAS# is listed on the TSCA Inventory. CAS# is listed on the TSCA Inventory. CAS# is listed on the TSCA Inventory. SARA Reportable Quantities (RQ): CAS# : 101b. final RQ; 4.54kg final RQ CERCLA/SARA Section 313: This material contains chloroform (CAS# , <0.2%), which is subject to the reporting requirements of section 313 of SARA title III and 40CFR part 373. OSHA - Highly Hazardous: US State State Right to Know: Potassium nitrite can be found on the following state Right-to-Know lists: New Jersey. Chloroform can be found on the following state Right-to-Know lists: California, New Jersey, Pennsylvania, Minnesota, and Massachusetts. California Regulations: Warning: This product contains Chloroform, a chemical known to the state of California to cause cancer. European/International Regulations Canadian DSL/NDSL: CAS# is listed on Canada's DSL List. CAS# is listed on Canada's DSL List. CAS# is listed on Canada s DSL List. Canada Ingredient Disclosure List: CAS# is not listed on Canada's Ingredient Disclosure List. CAS# is listed on Canada's Ingredient Disclosure List. CAS# is listed on Canada's Ingredient Disclosure List

7 Section 16 - Other Information MSDS Creation Date: September 5, 2007 Revision Date: None Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application

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