SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking. Gibson Assembly HiFi 1 Step Kit

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1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number - Synonyms None. Product code GA1100 Issue date 13-October-2014 Version number 01 Revision date - Supersedes date Relevant identified uses of the substance or mixture and uses advised against Identified uses Research use only. Uses advised against None known Details of the supplier of the safety data sheet Manufacturer/Supplier SGI-DNA Inc Address 4570 Executive Drive, San Diego, CA United States Telephone number (855) info@sgidna.com Contact person Customer Service 1.4. Emergency telephone (858) number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended. Hazard summary Physical hazards Not classified for physical hazards. Health hazards Not classified for health hazards. However, occupational exposure to the mixture or substance(s) may cause adverse health effects. Environmental hazards Not classified for hazards to the environment. Specific hazards None known. Main symptoms Irritant effects Label elements Label according to Regulation (EC) No. 1272/2008 as amended Hazard pictograms None. Signal word None. Hazard statements The mixture does not meet the criteria for classification. Precautionary statements Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Supplemental label information None Other hazards None known Version #: 01 Revision date: - Issue date: 13-October / 7

2 SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes Tris-(hydroxymethyl)aminomethane 3-5 Classification: DSD: CLP: Xi;R36/37/38 Skin Irrit. 2;H315, Eye Irrit. 2;H319, STOT SE 3;H List of abbreviations and symbols that may be used above CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. Composition comments SECTION 4: First aid measures The full text for all R- and H-phrases is displayed in section 16. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible) Description of first aid measures Inhalation Move to fresh air. Get medical attention, if needed. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Rinse with water. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Rinse mouth. Do not induce vomiting without advice from poison control center. Get medical attention if symptoms occur. Irritant effects. SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Specific methods SECTION 6: Accidental release measures Provide general supportive measures and treat symptomatically. No unusual fire or explosion hazards noted. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials Personal precautions, protective equipment and emergency procedures For non-emergency Ensure adequate ventilation. Wear appropriate protective equipment and clothing during clean-up. personnel Local authorities should be advised if significant spillages cannot be contained. For emergency responders Keep unnecessary personnel away. Use personal protection recommended in section 8 of the SDS Environmental precautions Avoid discharge into drains, water courses or onto the ground Version #: 01 Revision date: - Issue date: 13-October / 7

3 6.3. Methods and material for containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination Reference to other sections Never return spills to original containers for re-use. For personal protection, see section 8. For waste disposal, see section 13 of the SDS. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Research use only. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Austria. MAK List Provide adequate ventilation. Avoid inhalation of vapours and contact with skin and eyes. Wear appropriate personal protective equipment. Wash thoroughly after handling. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see section 10 of the SDS). MAK 1000 mg/m3 Inhalable fraction. STEL 4000 mg/m3 Inhalable fraction. Denmark. Exposure Limit s TLV 1000 mg/m3 Germany. DFG MAK List (advisory OELs). Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (DFG) Germany. TRGS 900, Limit s in the Ambient Air at the Workplace TWA 1000 mg/m3 Inhalable fraction. AGW 1000 mg/m3 Inhalable fraction. Slovakia. OELs. Decree of the government of the Slovak Republic concerning protection of health in work with chemical agents TWA 1000 mg/m3 Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia) TWA 1000 mg/m3 Inhalable fraction Version #: 01 Revision date: - Issue date: 13-October / 7

4 Switzerland. SUVA Grenzwerte am Arbeitsplatz Biological limit values Recommended monitoring procedures Derived no-effect level (DNEL) Predicted no effect concentrations (PNECs) TWA 1000 ppm No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures Exposure controls Appropriate engineering General ventilation normally adequate. controls Individual protection measures, such as personal protective equipment General information Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection If contact is likely, safety glasses with side shields are recommended. Skin protection - Hand protection Gloves are recommended for prolonged use. Nitrile gloves are recommended. Suitable gloves can be recommended by the glove supplier. - Other Wear suitable protective clothing. Gloves are recommended for prolonged use. Respiratory protection No personal respiratory protective equipment normally required. In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Environmental exposure controls SECTION 9: Physical and chemical properties Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental manager must be informed of all major releases Information on basic physical and chemical properties Appearance Physical state Liquid. Liquid. Colour Colourless. Odour Slight. Odour threshold ph 7-9 Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density Solubility(ies) 100 % (25 C) Completely soluble in water. Partition coefficient (n-octanol/water) Version #: 01 Revision date: - Issue date: 13-October / 7

5 Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information Bulk density VOC (Weight %) SECTION 10: Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport Chemical stability Material is stable under normal conditions Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Contact with incompatible materials Incompatible materials Strong oxidising agents Hazardous No hazardous decomposition products are known. decomposition products SECTION 11: Toxicological information General information Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact Prolonged skin contact may cause temporary irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms Irritant effects Information on toxicological effects Acute toxicity Species Tris-(hydroxymethyl)aminomethane (CAS ) Acute Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information Other information May cause discomfort if swallowed. Rat Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation. No data available for this product. SECTION 12: Ecological information No information available. This product has no known adverse effect on human health. Test results 5900 mg/kg Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Persistence and degradability Version #: 01 Revision date: - Issue date: 13-October / 7

6 12.3. Bioaccumulative potential Partition coefficient n-octanol/water (log Kow) Tris-(hydroxymethyl)aminomethane (CAS ) -2,31 (20 C) Bioconcentration factor (BCF) Mobility in soil The product is water soluble and may spread in water systems Results of PBT Not a PBT or vpvb substance or mixture. and vpvb assessment Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: Disposal considerations Waste treatment methods Residual waste Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal methods/information Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Special precautions Dispose in accordance with all applicable regulations. SECTION 14: Transport information ADR RID ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not established. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Version #: 01 Revision date: - Issue date: 13-October / 7

7 Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Other EU regulations Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances Directive 94/33/EC on the protection of young people at work Other regulations The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. National regulations Follow national regulation for work with chemical agents Chemical safety No Chemical Safety Assessment has been carried out. assessment SECTION 16: Other information List of abbreviations CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. LD50: Lethal Dose, 50%. References HSDB - Hazardous Substances Data Bank Information on evaluation method leading to the classification of mixture Full text of any statements or R-phrases and H-statements under Sections 2 to 15 Training information Disclaimer The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. R36/37/38 Irritating to eyes, respiratory system and skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Follow training instructions when handling this material. SGI-DNA Inc cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available Version #: 01 Revision date: - Issue date: 13-October / 7

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