: Green Line - DASH & GLASS
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1 Date of issue: 12/08/2015 Revision date: : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Green Line - DASH & GLASS 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category Use of the substance/mixture : Consumer use : Automotive Care Products Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet Turtle Wax Europe Limited 4th Floor Alaska House, Atlantic Park, Dunnings Bridge Road Liverpool, L30 4AB - United Kingdom T MSDS@turtlewaxeurope.com 1.4. Emergency telephone number Emergency number : Office hours only 08:30-17:00 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Precautionary statements (CLP) : P102 - Keep out of reach of children 2.3. Other hazards Adverse physicochemical, human health and environmental effects Other hazards not contributing to the classification : To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. ne under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Sorbitan monolaurate, ethoxylated (1-6.5 EO) (CAS No) (EC no) Octahydro-2;3;8;8-tetramethyl-2-acetonaphthone (CAS No) (EC no) ;6-DIMETHYL-7-OCTEN-2-OL (CAS No) (EC no) (REACH-no) < 0.1 Not classified 12/08/2015 EN (English) 1/9
2 Pyrithione Zinc (CAS No) Acute Tox. 4 (Inhalation:dust,mist), H332 Eye Dam. 1, H318 2-methylisothiazol-3(2H)-one (CAS No) Acute Tox. 3 (Inhalation:dust,mist), H331 Skin Corr. 1B, H314 LINALYL ACETATE (CAS No) (EC no) (REACH-no) ,2-Benzisothiazolin-3-one (CAS No) (EC no) (EC index no) ACETYL HEXAMETHYL TETRALIN(AHTN) (CAS No) (EC no) (2-Hydroxy-5-t-octylphenyl) benzotriazole (CAS No) (EC no) ISOAMYL ALLYLGLYCOLATE (CAS No) (EC no) PHENETHYL ALCOHOL (CAS No) (EC no) TERPINEOL ACETATE (CAS No) (EC no) Linalool (CAS No) (EC no) (REACH-no) (L) HEXYL CINNAMAL (CAS No) (EC no) (REACH-no) ;4-DIMETHYL-3-CYCLOHEXEN-1-CARBOXALDEHYDE (CAS No) (EC no) ACETYL CEDRENE (CAS No) (EC no) (REACH-no) METHYL-BETA NAPHTHYL ETHER (CAS No) (EC no) (REACH-no) (2,2,6-TRIMETHYLCYCLOHEXYL)-3-HEXANOL (CAS No) (EC no) BUTYLPHENYL METHYLPROPIONAL (CAS No) (EC no) (REACH-no) CITRONELLYL NITRILE (CAS No) (EC no) (REACH-no) (L) COUMARIN (CAS No) (EC no) (REACH-no) METHYL ANTHRANILATE (CAS No) (EC no) SCENTENAL (CAS No) (EC no) (EC index no) ALPHA-ISOMETHYL IONONE (CAS No) (EC no) METHYL IONONE (CAS No) (EC no) Methanol (CAS No) (EC no) ; Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 1, H410 < 0.1 Aquatic Chronic 3, H412 Skin Irrit. 2, H315 Eye Irrit. 2, H319 < 0.1 Eye Irrit. 2, H319 Aquatic Chronic 3, H412 < 0.1 Aquatic Chronic 1, H410 Skin Irrit. 2, H315 Repr. 2, H361f < 0.1 Aquatic Chronic 3, H412 < 0.1 Eye Irrit. 2, H319 < 0.1 Skin Sens. 1B, H317 < 0.1 Eye Irrit. 2, H319 < 0.1 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 STOT SE 1, H370 Specific concentration limits: Name Product identifier Specific concentration limits 1,2-Benzisothiazolin-3-one (CAS No) (EC no) (EC index no) (C >= 0.05) 12/08/2015 EN (English) 2/9
3 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If you feel unwell, seek medical advice (show the label where possible). t expected to present a significant hazard under anticipated conditions of normal use. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. t expected to present a significant hazard under anticipated conditions of normal use. Rinse mouth Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. ne under normal use. : May cause slight irritation. : May cause slight irritation. : May cause slight irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity in case of fire Hazardous decomposition products in case of fire : The product is not flammable. : Product is not explosive. t known. : Toxic fumes may be released Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting. : Use extinguishing media appropriate for surrounding fire. : Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Avoid release to the environment For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures t required for normal conditions of use. : Ventilate spillage area. t required for normal conditions of use. For further information refer to section 8: "Exposure controls/personal protection". : Ventilate area. Stop leak if safe to do so Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections : Collect spillage. : Take up liquid spill into absorbent material. Shovel into suitable and closed container for disposal. This material and its container must be disposed of in a safe way, and as per local legislation. : This material and its container must be disposed of as hazardous waste. For further information refer to section 13. For further information refer to section 8: "Exposure controls/personal protection". 12/08/2015 EN (English) 3/9
4 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Always wash hands after handling the product. Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Storage conditions Packaging materials 7.3. Specific end use(s) Automotive Care Products. : Store in a well-ventilated place. Keep cool. Store in original container. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Methanol ( ) United Kingdom Local name Methanol United Kingdom WEL TWA (mg/m³) 266 mg/m³ United Kingdom WEL TWA (ppm) 200 ppm United Kingdom WEL STEL (mg/m³) 333 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm United Kingdom Remark (WEL) Sk 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. t required for normal conditions of use. : protective gloves : Safety glasses : Wear suitable protective clothing t required for normal conditions of use : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : clear. Odour : characteristic. Odour threshold ph : Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties : Product is not explosive. Oxidising properties : Oxidising liquids Not applicable. Explosive limits 12/08/2015 EN (English) 4/9
5 9.2. Other information No additional information available SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Acids. Oxidizing agent Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity 1,2-Benzisothiazolin-3-one ( ) LC50 inhalation rat (Dust/Mist - mg/l/4h) 1020 mg/kg bodyweight > 2000 mg/kg bodyweight 100 mg/m³ 2;4-DIMETHYL-3-CYCLOHEXEN-1-CARBOXALDEHYDE ( ) 2500 mg/kg bodyweight 2500 mg/kg bodyweight 2;6-DIMETHYL-7-OCTEN-2-OL ( ) 3600 mg/kg bodyweight ACETYL HEXAMETHYL TETRALIN(AHTN) ( ) 1000 mg/kg bodyweight BUTYLPHENYL METHYLPROPIONAL ( ) 1390 mg/kg bodyweight > 5000 mg/kg bodyweight CITRONELLYL NITRILE ( ) (L) COUMARIN ( ) (L) HEXYL CINNAMAL ( ) LC50 inhalation rat (Dust/Mist - mg/l/4h) ISOAMYL ALLYLGLYCOLATE ( ) Linalool ( ) METHYL ANTHRANILATE ( ) PHENETHYL ALCOHOL ( ) METHYL-BETA NAPHTHYL ETHER ( ) SCENTENAL ( ) 4490 mg/kg bodyweight 500 mg/kg bodyweight 3100 mg/kg bodyweight > 3000 mg/kg bodyweight > 5000 mg/m³ 730 mg/kg bodyweight 2780 mg/kg bodyweight 5610 mg/kg bodyweight 2780 mg/kg bodyweight 1610 mg/kg bodyweight 2500 mg/kg bodyweight 1736 mg/kg bodyweight 2800 mg/kg bodyweight 12/08/2015 EN (English) 5/9
6 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard ph: ph: SECTION 12: Ecological information Toxicity Ecology - general Ecology - water : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 1,2-Benzisothiazolin-3-one ( ) > 1.6 mg/l EC50 other aquatic organisms 1 > 1.35 mg/l EC50 waterflea (48 h) > 0.07 mg/l IC50 algea (72 h) mg/l BUTYLPHENYL METHYLPROPIONAL ( ) 2.2 mg/l EC50 other aquatic organisms mg/l IC50 algea (72 h) mg/l (L) COUMARIN ( ) EC50 other aquatic organisms 1 56 mg/l 13.5 mg/l IC50 algea (72 h) mg/l (L) HEXYL CINNAMAL ( ) 1.7 mg/l EC50 other aquatic organisms 1 EC50 waterflea (48 h) > 0.32 mg/l Linalool ( ) 27.8 mg/l EC50 other aquatic organisms 1 20 mg/l EC50 waterflea (48 h) 88.3 mg/l IC50 algea (72 h) mg/l Persistence and degradability Green Line - DASH & GLASS Persistence and degradability Not established Bioaccumulative potential Green Line - DASH & GLASS Bioaccumulative potential Not established. 1,2-Benzisothiazolin-3-one ( ) Log Pow 0.64 Sorbitan monolaurate, ethoxylated (1-6.5 EO) ( ) Log Pow 1.23 (L) COUMARIN ( ) Log Pow 1.39 (L) HEXYL CINNAMAL ( ) Log Pow 4.82 Linalool ( ) Log Pow /08/2015 EN (English) 6/9
7 12.4. Mobility in soil Green Line - DASH & GLASS Ecology - soil Not established Results of PBT and vpvb assessment No additional information available Other adverse effects Other adverse effects Additional information ne known. : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport No data available 12/08/2015 EN (English) 7/9
8 - Transport by sea No data available - Air transport No data available - Inland waterway transport Carriage prohibited (ADN) Not subject to ADN - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Detergent Regulation : Ingredient data sheet: Component CAS No % AQUA >=10% ISOPROPYL ALCOHOL % Sorbitan monolaurate, ethoxylated (1-6.5 EO) <0.1% Octahydro-2;3;8;8-tetramethyl-2-acetonaphthone <0.1% 2;6-DIMETHYL-7-OCTEN-2-OL <0.1% Pyrithione Zinc <0.1% 2-methylisothiazol-3(2H)-one <0.1% LINALYL ACETATE <0.1% BENZISOTHIAZOLINONE <0.1% ACETYL HEXAMETHYL TETRALIN(AHTN) <0.1% 2-(2-Hydroxy-5-t-octylphenyl) benzotriazole <0.1% ISOAMYL ALLYLGLYCOLATE <0.1% PHENETHYL ALCOHOL <0.1% TERPINEOL ACETATE <0.1% 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE <0.1% ACETYL CEDRENE <0.1% METHYL-BETA NAPHTHYL ETHER <0.1% 1-(2,2,6-TRIMETHYLCYCLOHEXYL)-3-HEXANOL <0.1% CITRONELLYL NITRILE <0.1% METHYL ANTHRANILATE <0.1% SCENTENAL <0.1% METHYL IONONE <0.1% Methanol <0.1% Detergent Regulation : Labelling of contents: Component % BENZISOTHIAZOLINONE Parfum National regulations No additional information available Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information 12/08/2015 EN (English) 8/9
9 Full text of H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 Skin Sens. 1B Sensitisation Skin, category 1B STOT SE 1 Specific target organ toxicity single exposure, Category 1 H301 Toxic if swallowed H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H331 Toxic if inhaled H332 Harmful if inhaled H361f Suspected of damaging fertility H370 Causes damage to organs H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects SDS EU TURTLEWAX This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/08/2015 EN (English) 9/9
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