PRODUCT TECHNICAL DOSSIER K-PURE MAGNESIUM BIS-GLYCINATE

Transcription

1 PRODUCT TECHNICAL DOSSIER K-PURE MAGNESIUM BIS-GLYCINATE Product Code: P14053 Raw Material Full Name: K-Pure Magnesium Bis-Glycinate This material is Food Grade Limit/Range/Specification (ICP): Mg Content 10.0%- 13.1% CAS Number: Molecular Formula for the raw material: Mg (C 2 H 4 NO 2 ) 2 2H 2 O Average Molecular weight: g/mol Particle Size (Ro-Tap): Min 90% Passed Through 40 Mesh Tapped Density (USP): Min 0.6g/ml Loss on Drying (Continuous 105 o C Until Stable) : Max 7% Country of Origin: USA Country of Origin of the Manufacture: USA

2 Base Source/Start Material: L-Glycine (derived from Sodium Glyconate), Magnesium Oxide (MgC12 (Sea Water) & CaOH(Mined), Citric Acid (Tapioca, Fermentation of Corn derivatives, Sugar Beets), Silicon Dioxide (Mined). Compound Ingredients: L-Glycine 61.2%-82.8% Magnesium Oxide 17.5%-23.7% Citric Acid 6.0%-8.1% Silicon Dioxide 0.34%-0.46% Shelf Life from Date of Manufacture: 3 Years Storage Conditions: Store in a tightly sealed bag/container and to be kept in a cool place away from moisture and direct sunlight. Appearance (Visual) Powder Colour (Visual): White to Off White Flavour/Taste (Organoleptic): Characteristic Odour (Organoleptic): Characteristic Microbiological Test Total Viable Count (AOAC): Max 3,000cfu/g Yeast & Moulds (AOAC): Max 300cfu/g E.Coli (AOAC): Negative

3 Salmonella (FDA/BAM): Absent in 25g Staphylococcus Aureus (FDA/BAM): Absent Metals Lead (Pb) (ICP-MS): Max 1ppm Cadmium (Cd) (ICP-MS): Max 1ppm Mercury (Hg) (Thermal Decomposition AA): Max 0.1ppm Arsenic (As) (ICP-MS): Max 1ppm There are no nuts in this recipe and are no nuts on site, however we cannot guarantee that the raw materials entering the site are nut free.

4 INTOLERANCE DATA If No please give details Free from All Animal Products (Beef, Pork, Poultry or other) Free from Bovine Products or Derivatives by using hormones to increase milk yield in cows Free from Bone Meal Free from Peanuts and Peanut Derivatives (including possible cross contamination) Free from other Nut and Nut Derivatives Free from Nut Derived Oil Free from Sesame Seeds and Sesame Seed Derivatives Free from Poppy Seeds and Poppy Seed Derivatives Free from Sunflower Seeds and Sunflower Seeds Derivatives Free from other Seeds and Seed Derivatives Free from Milk and Milk Derivatives (including lactose) Free from Egg and Egg Derivatives Free from Cereals containing Gluten (wheat / rye / oats / barley/ spelt/ kamut or their hybridised strains) and Derivatives Free from Soya and Soya Derivatives Free from Maize and Maize Derivatives NO Source of Citric Acid Free from Corn and Corn Derivatives NO Source of Citric Acid Free from Lupin and Lupin Derivatives Free from Yeast and Yeast Derivatives Free from Cotton Seeds (Flour) and Cotton Seed Derivatives Free from Rice and Rice Derivatives Free from Mustard and Mustard Derivatives Free from Celery or Celery Derivatives Free from Celeriac or Celeriac Derivatives Free from Fruit and Fruit Derivatives Free from Vegetable and Vegetable Derivatives Free from Carrot and Carrot Derivatives Free from Legumes / Pulses Free from Fish and Fish Derivatives Free from Crustaceans / Molluscs and their Derivatives Free from Additives Free from Added Salt Free from Added Sugar Free from Antioxidants Free from Artificial Glutamates Free from Aspartame Free from Azo and Coal Tar Dyes Free from Benzoates (E210 / E219) Free from BHA / BHT (E320 / E321) Free from Caffeine Free from Cinnamon Free from Cocoa Free from Colours (Artificial / Nature Identical / Natural / Smoked) Free from Dextrose Free from Dioxins Free from Ethanol

5 INTOLERANCE DATA If No please give details Free from Ethylene Oxide Free from Flavourings (Artificial / Nature Identical / Natural / Smoked) Free from Garlic Free from Gelatine Free from Glutamates (E620 to E625) Free from Histamine Free from Hickory Free from Honey Free from Lactose Free from Latex Free from MSG (Added and Naturally Occurring E621) Free from Nucleotides (E627, E630, E631, E635) Free from Polyols Free from Preservatives Free from Starch Products (Including Maltodextrin) Free from Sorbic Acid (E200, E203) Free from Sulphur Dioxide and Sulphites at levels above 10mg/kg or 10mg/litre expressed as SO 2 Free from Sulphites (E220, E228) Free from Sweeteners Free from Vannillin Suitable for Diabetics Suitable for Coeliacs Suitable for Ovo-Lacto Vegetarians Suitable for Vegans Kosher Certified NO Not Certified Halal Certified NO Not Certified

6 PRODUCT PROCESS FLOW DIAGRAM Raw materials are inspected and weighed. Raw materials are mixed to liquid state and allowed to react. The product is spray dried. The product is sampled, tested, and packaged.

7 CONFIRMATION OF BSE/TSE STATUS This is to certify that this product complies with all relevant current UK and EU Legislative requirements in regard to Transmissible Spongiform Encephalopathies (TSE) and Bovine Spongiform Encephalopathy (BSE) for human food, and so is free of TSE/BSE. This is also to certify that, during the course of their manufacture, the above-mentioned product did not come into contact with any materials, which could be derived from TSE/BSE risk materials. CONFIRMATION OF GM STATUS This is to certify that this product is not manufactured from GM raw materials and is therefore not subject to labelling under regulations 1829/2003/EC and 1830/2003/EC. CONFIRMATION OF NON IRRADIATION STATUS This is to certify that this product, whole or in part, has not been subjected to Ionising Radiation as per European Directives 1999/2/EC and 1000/3/EC. CONFIRMATION OF NANDROLONE STATUS This is to certify that this product, whole or in part, has not come into contact with Nandrolone or any of its precursors in any way. CONFIRMATION OF IOC PRODUCT STATUS This is to certify that this product, whole or in part, has not come into contact with any product/s, which is banned by the IOC (International Olympics Committee). CONFIRMATION OF ANIMAL TESTING STATUS This is to certify that all the products sold by Cambridge Commodities have not been tested on animals in any part of its manufacture in accordance with regulation 86/609/EEC. CONFIRMATION OF PESTICIDES STATUS This is to certify that the above-mentioned product complies with the regulation (EC) No.396/2005 of 23 rd February 2005 and commission Regulation (EU) No. 559/2011 of 7 th June 2011 amending annexes II and III of the above Regulation.

8 MATERIAL SAFETY DATA SHEET Section 1 Description PRODUCT NAME: PRODUCT CODE: Supplier: K-PURE MAGNESIUM BIS-GLYCINATE P14053 Cambridge Commodities Limited 78 Lancaster Way, Ely, Cambridgeshire, CB6 1NW. Tel: QC@c-c-l.com Section 2 Ingredients/Identity Information Components % in Product CAS Number Formula EINECS Number Magnesium Oxide N/A N/A Citric Acid N/A N/A L-Glycine N/A N/A Silicon Dioxide N/A N/A Section 3 Possible Hazards Magnesium Oxide: Emergency Overview: Potential Health Effects: White, odourless powder/granular. Will cause irritation to the eyes, respiratory tract and skin. Inhalation: Inhalation of dust can cause nasal and respiratory irritation. Eyes: Can cause irritation, redness and pain. Skin: Can cause irritation and redness. Ingestion: Can cause diarrhoea Carcinogenicity: Not listed under OSHA, IARC, NTP.

9 Citric Acid Emergency Overview: Potential Health Effects: L-Glycine Emergency Overview: Potential Health Effects: White translucent crystals or granular powder having no characteristic odour. This material can cause severe irritation to the eyes and irritation to the skin and respiratory tract. This material may cause allergic reactions in some sensitive individuals. It will react vigorously with strong caustics or alkali and strong oxidizers. Inhalation: Inhalation of dust may cause irritation, possibly severe, to the nose, mouth, throat, mucous membranes and lungs. Symptoms of expose may include sneezing, coughing, sore throat, chest discomfort or pain and shortness of breath. Inhalation of dust concentrations may cause permanent lung damage. Eye Contact: Exposure to powder, crystals and dust can cause severe eye irritation. Symptoms of exposure may include redness, swelling and discomfort or pain. Skin: No published reports indicate this material is absorbed through the skin. Ingestion: ingestion may cause severe irritation to the entire gastrointestinal tract, including stomach and intestines, characterized by nausea, vomiting, abdominal pain, possibly hypocalcaemia and/or diarrhoea. Chronic: Pro-longed skin exposure to this material may lead to dermatitis. Repeated or pro-longed to teeth may cause damage to tooth enamel. Otherwise, the chronic health effects or exposure to this material are expected to be same as for acute exposure. May be harmful by inhalation, in contact with skin and if swallowed. Product dust may be irritating to eyes, skin and respiratory system. It is white, crystalline, solid and odourless. Eyes: Contact with eyes may cause irritation, stinging, tears, redness and swelling. Avoid contact. Skin: May be harmful by skin contact. Substance may cause slight skin irritation. Avoid contact with skin. Inhalation: May be harmful by inhalation. May cause irritation of the mucous membranes. May cause irritation or respiratory tract. Ingestion: May be harmful swallowed. Ingestion of large amounts may cause gastrointestinal irritation.

10 Silicon Dioxide Emergency Overview: Potential Health Effects: Dust may be irritation to respiratory tract. Eye Contact: Possibly irritating. Skin Contact: May cause drying of the skin. Inhalation: Temporary discomfort to upper respiratory tract may occur due to mechanical irritation when exposures are above the occupational exposure limits. Ingestion: No hazard expected in normal use. General: Medical conditions which may be aggravated by exposure to this product include. Conjunctivitis of the eye, dermatitis of the skin, asthma and respiratory disease. Section 4 Emergency and First Aid Procedures HMIS Ratings: Health -1 Flammability- 0 Reactivity- 0 Rating Key: 4=Highest Standard, 0= Lowest Standard, *= Chronic Health Hazard, N= No rating for powders NFPA Rating: Health-1 Flammability-0 Reactivity-0 Rating Key= Highest standard, 0=Lowest Standard, N=No rating for powders Eyes In case of contact, immediately flush eyes with plenty of clean water for at least 15 minutes. Lifting the upper and lower lid occasionally. Remove contact lenses, if worn. Get medical attention immediately. Skin Ingestion Inhalation In case of contact, flush skin with plenty of clean running water. Remove contaminated clothing and shoes, and wash before reuse. If irritation occurs and persists, get medical attention. If swallowed, give plenty of water to drink. Call physician. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to unconscious person. If inhaled, immediately move to fresh air. If not breathing give artificial respiration. Preferably mouth to mouth. If breathing is difficult give oxygen. Call a physician.

11 Section 5 Fire and Hazard Data Citric Acid: Flashpoint and Method: The material does not flash. Auto Ignition Temperature: Powder 1,0100C General Hazards: Extinguishing Media: Fire Fighting Equipment: This material is granular or crystalline, organic solid. The Uniform Fire Code health hazard classification for this material is: Irritant- Avoid airborne dispersion of dust and powder in enclosed areas, to reduce the potential for a dust explosion, in the presences of an ignition source. This material may produce hazardous dusts or hazardous decomposition products. Water fog, CO 2, foam or dry chemical. Use the extinguishing media that is appropriate to the surrounding fire. Do not use a water spray as this could cause the dispersal of dust/powder in the air. Fire fighters should wear full protective equipment. Including self-contained breathing apparatus. L-Glycine Flammable Properties: Dust may form explosive mixture in air. Suitable Extinguishing Media:Water spray, carbon dioxide, dry powder foam. Hazardous Combustion Products: Thermal decomposition or combustion may produce hazardous gases and/or materials. Specific Hazards Arising from the Chemical: Keep product and empty container away from heat and sources of ignition. Protective Equipement and Precautions for Fire Fighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear NEPA: Health:1 Flamability:0 Instability:0

12 Silicon Dioxide Extinguishing Media: Use water spray or fog, foam, dry chemical or CO 2. Fire Fighting Procedures: Fire fighters must wear positive pressure self-contained breathing apparatus and full protective clothing. Section 6 Accidental release measures. Magnesium Oxide: Isolate hazard area and deny entry to unnecessary or unprotected personnel. Contain spill, sweep up, collect and place in a disposal container, taking care not to raise dust. Avoid runoff into storm sewers and ditches which lead to waterways. Citric Acid Water Spill: Land Spill: L-Glycinate Method for Cleaning Up: Personal Precautions: Environmental Precautions: Wear recommended protective equipment and clothing if contact with hazardous material can occur. Stop or divert water flow. Dike contaminated water remove for disposal and/or treatment. As appropriate, notify all downstream users of possible contamination. Wearing recommended protective equipment and clothing, pick up the spilled material and place in approved containers for recovery or disposal. Neutralize the acidity, of the remaining solid, using a dilute solution of soda, ash, lime or other agent appropriate to neutralizing the acidic solids. Flush the spill area with water, collect the reinstates for disposal or sewer, as appropriate. Evacuate personnel to safe area. Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Clean contaminated surface thoroughly. Evacuate personnel to safe area. Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. In of insufficient ventilation, wear suitable respiratory equipment. Local authorities should be advised if significant spillages cannot be contained. Silicon Dioxide Steps To Be Taken In Case The Material Is Released Or Spilled: Obey relevant local, state, provincial and federal laws and regulations. Do not contaminate any lakes, streams, pounds, groundwater or soil. Use personal protective equipment as described in Section 8. Shovel spilled material into a suitable container.

13 Section 7 Precautions for Safe Handling and Storage Magnesium Oxide Avoid contact with skin, eyes and clothing. Avoid breathing dust. Use normal personal hygiene and housekeeping. Store in cool, dry area away from incompatible material and product. Product is slightly hydroscopic and should be stored in a dry area to prevent moisture pick up and caking. Citric Acid Storage Pressure and Temperature: Ambient Store in a cool dry area away from incompatible material and product. Protect eyes, skin and clothing from contact with product. Wear recommended personal protective equipment. Avoid breathing dust. Use with adequate ventilation. Use good housekeeping practices to prevent accumulation of dust. Keep container tightly closed when not in use. Wash thoroughly after handling. L-Glycine Handling: Storage: Silicon Dioxide Handling: Storage: Use only in an area equipped with a safety shower. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation. Do not breathe vapours/dust. Avoid contact with skin, eyes and clothing. Avoid repeated exposure. Keep container tightly closed. Keep in properly labelled containers. Wash thoroughly after handling. Use with adequate ventilation. Follow MSDS/label precautions even after container is emptied because it may retain product residues. Take precautionary measures against static discharges Store in a cool, dry place. Keep container closed when not in use. Section 8 Control Methods/Personal Protection Magnesium Oxide Respiratory Protection: If dusty, use NIOSH?MSHA approved respire Ventilation Requirements: Ventilate if necessary to eliminate dust from the work area. Skin and Eye Protection: Use rubber or neoprene gloves, chemical goggles and clothing sufficient to protect skin from dust. Work, Hygiene Practices: As required to protect skin and eyes from dust, safety sowers and/or eye wash should be available. Do not leave food or smoke in the work area. Wash thoroughly and remove or clean any contaminated clothing. Exposure Guideline: AGGIH-TVL-10 mg/m 3 (Total Particulates) OSHA 15 mg/m 3 (Total Particulates) OSHA 5 mg/m 3 (Respirable Particulates)

14 IDLH 750 mg/m 3 Section 8 - Continued Citric Acid Control Measures: Respiratory: Eyes: Gloves: Clothing: Equipment: Footwear: L-Glycine Exposure Guidelines: Engineering Controls: Eyes/Face Protection: Skin Protection: Respiratory Protection: Use a local or general, mechanical exhaust ventilation system capable of maintaining dust levels in the work area, below the OSHA-PEL for Particulates Not Otherwise Regulated. If use causes dust levels to exceed the OSHA-PEL wear a NIOSH approved respirator equipped with a good dust/particulate cartridge or supplied air. Wear chemical goggles, unless a full face piece respirator is worn. Wear plastic or rubber gloves. Wear plastic or rubber apron when handling this material. An eye wash station and safety shower should be available in the work area. If contact is likely, wear rubber boots. This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Ensure adequate ventilation, especially in confined areas. Tightly fitting safety goggles. Wear protective gloves/clothing. In case of insufficient ventilation wear suitable respiratory equipment. Silicon Dioxide Exposure Limits Value Limit Reference 3 Silicon Dioxide, Amorphous, fumed, 6mg/m3 TWA OSHA crystalline free 10 mg/m3 TWA ACGIH N.E. STEL OSHA/ACGIH Engineering Controls: Respiratory Protection Eye Protection: Skin Protection: Use adequate ventilation. A respiratory protection program that meets OSHA and ANSI Z88.2 or applicable federal/provincial requirements must be followed whenever workplace conditions warrant respirator use. NIOSH s Respirator Decision logic may be useful in determining the suitable of various types of respirators. Wear safety glasses with side shields. Use impermeable gloves.

15 Section 8 - Continued Other Protection Equipment: A safety shower and eye wash fountain should be readily available. To identify additional Personal Protective Equipment requirements, it is recommended that a hazard assessment be conducted before using this product. Section 9 Physical and Chemical Properties Physical state Colour Odour Solubility Section 10 Stability and Reactivity Stability Incompatible Materials Hazardous Decomposition Products Conditions to Avoid Section 11 Toxicological Information Magnesium Oxide Citric Acid Eye Contact: Skin Contact: Oral Rat LD50: Intravenous Mouse LD50: Target Organs: Powder White / Off White Typical Partial Stable under normal temperatures and pressures. Strong oxidizers, caustics and alkali, aluminium. Magnesium, zinc, chloring releases, sulphides, cyanides, acids, aluminium powder, bromine pentafluroids, chlorine trifuoride, interhalogens, magnesium powder, phosphorous pentachloride, sulphur (sublimed). Carbon oxides, irritating smoke, nitrogen oxides, ammonia. Hot, humid storage and dispersion of dust into the air, heat, flames, sparks, operations that create dust. Decomposition temperature: above 2000 o C. Not available Rabbit: 750µ g/24 hours: Severe Rabbit: 500 mg/24 hour: Moderate 3mg/kg 42mg/kg Eyes, skin, mucous membranes and lungs.

16 Medical Condition Aggravated by Exposure: Skin or respiratory disorder. L-Glycine Acute Toxicity: Carcinogenicity: Silicon Dioxide Product toxicological Information Section 12 Ecological Information Magnesium Oxide Citric Acid Environmental Fate: Environmental Considerations: Aquatic Toxicity: L-Glycine Eco toxicity: Silicon Dioxide LD50 Oral= 7930 mg/kg Oral LD50 Rat There are no known carcinogenic chemical in this product. Oral LD50 (rat): >10000 mg/kg Dermal LD50 (rabbit): >5000 mg/kg No data available The environmental fate of this materialis expected to be: Land: biodegradation with some leaching into the groundwater. Water: biodegradation Air: Not expected to volatize due to low vapour pressure. This material is not expected to bioaccumulation. Goldfish LD0: 625 ma/liter, long-time exposure in hard water. Goldfish LD100: 894 ma/liter, long-time exposure in hard water Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. No Data Available Section 13 Disposal Considerations Waste must be disposed of in accordance with all local, state and federal regulations

17 Section 14 Transport Information Magnesium Oxides Citric Acid L-Glycine Silicon Dioxide D.O.T. Shipping Name : Magnesium Oxide DOT Proper Shipping Name: Not Restricted Primary Label: None Required Sudsidary Label: None Required DOT Reportable Quantity (RQ): Not Listed Marine Pollutant: No TDG Schedule XII: Not Listed Regulated Limit: Not Listed Not Regulated US DOT Transport Information :Not regulated Section 15 Regulatory Information Magnesium Oxide Citric Acid TSCA (Toxic Substance Control Act): This product is listed on the TSCA inventory. CERCLA Reportable Requirements (RQ): None SARA Title III Information: Section 302 Extremely Hazardous Substance: Unlisted Section 313 Toxic Chemicals: Unlisted Section 311/312 Hazard Category: Immediate (acute) health hazard OSHA Target Organs: Eyes, skin, mucous membrane and lungs Carcinogenic Potential: No Listed on NTP: No Listed by IARC: No ACGIH Appendix A: Not Listed Sara Title III: Hazardous Categories (product): Fire=N Sudden Release of Pressure=N Reactive=N Acute Health=Y Chronic Health=N Planning Threshold=10,000 lbs U.S. TSCA Status: Listed (40 CFR 710) Yes State Regulations: No

18 Section 15-Continued L-Glycine Canadian Regulation: Controlled Product= Yes WHMIS Hazard Symbol= Corrosive Material WHIM Class & Division= E IDL Substance= Yes DLS or NDSLK List= DSL USA (TSCA): Complies Canada (DSL): Complies EU (ELINCS): Does not comply Japan (ENCS): Complies China: Complies Korea (KECL): Complies Philippines (PICCS): Complies Australia (AICS): Complies USA Federal Regulation SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Art and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization: Acute Health= No Chronic Health= No Fire Hazard= No Reactive Hazard= No Sudden Release of Pressure Hazard= No Clean Air Act, Section 112 Hazardous Air Pollution (HAP s) (see 40 CFR 61) This product does not contain any HAPs. Chemical Name: Glycine CAS No: VOCs: Present State Regulations

19 California Proposition 65: This product does not contain Proposition 65 chemicals. State Right-to-Know Canada This product has been classified in accordance with the hazard citirea of the Controlled Products Regulation (CPR) and the MSDS contains all information required by CPR. WHMIS Hazard Class: Not determined Silicon Dioxide Not Regulated Section 16 Other Information This advice is given by Cambridge Commodities Ltd who accepts no legal liability for it. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. Individuals working with chemicals should consider all chemicals to be potentially hazardous even if their individual hazards may be uncharacterised or unknown. We confirm that the information above is sourced from the original manufacturers/suppliers Material Safety Data Sheet. CAMBRIDGE COMMODITIES LTD Issued 2013

20