Supplemental Table 1. Concentrations of anthocyanins of wild blueberry and Concord grape 1.
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1 Supplemental Table 1. Concentrations of anthocyanins of wild blueberry and Concord grape 1. Blueberry (Wild) 1 Delphinidin 3-galactoside % 2 Delphinidin 3-glucoside % 3 Cyanidin 3-galactoside % 4 Delphinidin 3-arabinoside % 5 Cyanidin 3-glucoside % 6 Petunidin 3-galactoside % 7 Cyanidin 3-arabinoside % 8 Petunidin 3-glucoside % 9 Peonidin 3-galactoside % 10 Petunidin 3-arabinoside % 11 Peonidin 3-glucoside % 12 Malvidin 3-galactoside % 13 Malvidin 3-glucoside % 14 Malvidin 3-arabinoside % 16 Cyanidin 3-(6"-acetyl)galactoside % 18 Petunidin + pentose % 21 Delphinidin 3-(6"-acetyl)glucoside % 23 Cyanidin 3-(6"-acetyl)glucoside % 24 Malvidin 3-(6"-acetyl)galactoside % 25 Petunidin 3-(6"-acetyl)glucoside % 26 Peonidin 3-(6"-acetyl)glucoside % 27 Malvidin 3-(6"-acetyl)glucoside % Concord Grape 1 Delphinidin + pentose % 2 Delphinidin 3,5-diglucoside % 4 Cyanidin 3,5-diglucoside % 5 Petunidin 3,5-diglucoside % 6 Delphinidin 3-glucoside % 7 Peonidin 3,5-diglucoside % 8 Malvidin 3,5-glucoside % 9 Cyanidin 3-glucoside % 11 Petunidin 3-glucoside % 13 Peonidin 3-glucoside % 14 Malvidin 3-glucoside % 15 Cyanidin + pentose % 16 Delphinidin 3-(6"-acetyl)glucoside % 17 Delphinidin 3-(6"-coumaroyl)-5-diglucoside % 18 Cyanidin 3-(6"-acetyl)glucoside % 19 Cyanidin 3-(6"-coumaroyl)-5-diglucoside % 20 Delphinidin + coumaroyl + hexose % 22 Petunidin 3-(6"-acetyl)glucoside % 23 Malvidin 3-(coumaroyl)-5-diglucoside % 24 Peonidin 3-(coumaroyl)-5-diglucoside % 25 Peonidin 3-(6"-acetyl)glucoside % 26 Malvidin 3-(6"-acetyl)glucoside % 27 Delphinidin 3-(6"-coumaroyl)glucoside % 28 Cyanidin 3-(6"-coumaroyl)glucoside % 29 Petunidin 3-(6"-coumaroyl)glucoside % 30 Peonidin 3-(6"-coumaroyl)glucoside % 31 Malvidin 3-(6"-coumaroyl)glucoside % 1 Only anthocyanins with high enough concentrations of being quantified were presented in this table. 2 Peak numbers correspond to those in Ref FW: fresh weight.
2 Supplemental Table 2. Concentrations of anthocyanins from berries and fruits 1. Apple (Red Delicious) 1 Cyanidin 3-galactoside 10.5 ± % 3 Cyanidin 3-arabinoside 0.5 ± % 4 Peonidin 3-galactoside 0.2 ± % 5 Cyanidin 7-arabinoside 0.6 ± % 6 Cyanidin 3-xyloside 0.5 ± % Apple (Gala) 1 Cyanidin 3-galactoside 2.1 ± % 2 Cyanidin 3-arabinoside 0.2 ± % Apple (Fuji) 1 Cyanidin 3-galactoside 1.2 ± % 2 Cyanidin 3-arabinoside 0.1 ± % Blackberry 1 Cyanidin 3-glucoside ± % 2 Cyanidin 3-arabinoside 25.1 ± % 3 Cyanidin 3-rutinoside 4 Pelargonidin 3-glucoside 0.7 ± % 5 Cyanidin 3-(3"-malonyl)glucoside 0.5 ± % 7 Cyanidin 3-xyloside 13.7 ± % 8 Cyanidin 3-(6"-malonyl)glucoside 5.9 ± % 9 Cyanidin 3-dioxalylglucoside 16.0 ± % Marion Blackberry 1 Cyanidin 3-glucoside % 2 Cyanidin 3-rutinoside % 3 Pelargonidin 3-glucoside % 4 Peonidin 3-rutinoside % 5 Cyanidin 3-xyloside % 6 Cyanidin 3-(6"-malonyl)glucoside % 7 Cyanidin 3-dioxalylglucoside % Blueberry (Cultivated) 1 Delphinidin 3-galactoside 61.1 ± % 2 Delphinidin 3-glucoside 19.6 ± % 3 Cyanidin 3-galactoside 14.9 ± % 4 Delphinidin 3-arabinoside 39.4 ± % 5 Cyanidin 3-glucoside 4.1 ± % 6 Petunidin 3-galactoside 34.5 ± % 7 Cyanidin 3-arabinoside 7.4 ± % 8 Petunidin 3-glucoside 15.2 ± % 9 Peonidin 3-galactoside 5.6 ± % 10 Petunidin 3-arabinoside 19.1 ± % 11 Peonidin 3-glucoside 28.6 ± % 12 Malvidin 3-galactoside 41.8 ± % 13 Malvidin 3-glucoside 34.9 ± % Delphinidin ACN 1.6 ± % 14 Malvidin 3-arabinoside 45.9 ± % 18 Petunidin + pentose 1.9 ± % Penonidin ACN 0.2 ± % 23 Cyanidin 3-(6"-acetyl)glucoside 2.5 ± % 24 Malvidin 3-(6"-acetyl)galactoside 3.3 ± % 25 Petunidin 3-(6"-acetyl)glucoside 2.3 ± % 27 Malvidin 3-(6"-acetyl)glucoside 6.9 ± %
3 Supplemental Table 2. (continued) Peak No. Anthocyanin mg/100g (FW) % of total ACN Cherry (Sweet) 1 Cyanidin 3-glucoside 7.6 ± % 2 Cyanidin 3-rutinoside ± % 4 Pelargonidin 3-rutinoside 1.4 ± % 6 Peonidin 3-rutinoside 7.5 ± % Cranberry 1 Peonidin 3,5-digalactoside % 2 Cyanidin 3-galactoside 39.5 ± % 3 Delphinidin 3-arabinoside % 4 Cyanidin 3-glucoside 0.9 ± % 5 Pelargonidin 3-galactoside 0.7 ± % 7 Cyanidin 3-arabinoside 25.7 ± % 8 Peonidin 3-galactoside 48.6 ± % 9 Pelargonidin 3-arabinoside % 10 Peonidin 3-glucoside 3.5 ± % 12 Peonidin 3-arabinoside 20.0 ± % 13 Malvidin 3-arabinoside 1.3 ± % Grape (Red) 1 Delphinidin 3-glucoside 1.1 ± % 2 Cyanidin 3-glucoside 3.9 ± % 3 Petunidin 3-glucoside 1.0 ± % 4 Peonidin 3-glucoside 10.1 ± % 5 Malvidin 3-glucoside 4.8 ± % 6 Delphinidin 3-(6"-coumaroyl)glucoside Malvidin 3-(6"-acetyl)glucoside Cyanidin 3-(6"-coumaroyl)glucoside Petunidin 3-(6"-coumaroyl)glucoside Peonidin 3-(6"-coumaroyl)glucoside 11 Malvidin 3-(6"-coumaroyl)glucoside 9.3 ± % Nectarine 1 Cyanidin 3-glucoside 6.5 ± % 2 Cyanidin 3-rutinoside 0.2 ± % Peach 1 Cyanidin 3-glucoside 4.8 ± % Plum 1 Cyanidin 3-galactoside 1.9 ± % 2 Cyanidin 3-glucoside 12.5 ± % 3 Cyanidin 3-rutinoside 4.4 ± % 5 Cyanidin 3-(6"-acetyl)glucoside 0.2 ± % Plum (Black) 1 Cyanidin 3-galactoside % 2 Cyanidin 3-glucoside % 3 Cyanidin 3-rutinoside % 5 Cyanidin 3-(maroyl)glucoside % 7 Cyanidin 3-xyloside % 8 Cyanidin 3-(6"-acetyl)glucoside % Raspberry (Black) 1 Cyanidin 3-sambubioside % 2 Cyanidin 3-glucoside % 3 Cyanidin 3-sambubioside-5-rhamnoside % 4 Cyanidin 3-rutinoside % 5 Pelargonidin 3-glucoside % 6 Pelargonidin 3-rutinoside % 7 Peonidin 3-rutinoside %
4 Supplemental Table 2. (contiuned) Peak No. Anthocyanin mg/100g (FW) % of total ACN Raspberry (Red) 1 Cyanidin 3-sophoroside 32.9 ± % 2 Cyanidin 3-sophoroside-5-rhamnoside 24.2 ± % 3 Cyanidin 3-glucoside 19.1 ± % 5 Cyanidin 3-rutinoside 14.0 ± % 6 Pelargonidin 3-glucoside 1.0 ± % 7 Pelargonidin 3-rutinoside 0.9 ± % Strawberry 1 Cyanidin 3-glucoside 1.2 ± % 2 Cyanidin 3-rutinoside % 3 Pelargonidin 3-glucoside 18.2 ± % 4 Pelargonidin 3-rutinoside 1.6 ± % 5 Pelargonidin 3-(malonyl)glucoside 0.4 ± % 6 Pelargonidin 3-(6"-acetyl)glucoside 0.1 ± % Strawberry-OSC 1 Cyanidin 3-sophoroside % 2 Cyanidin 3-glucoside % 3 Cyanidin 3-rutinoside % 4 Pelargonidin 3-glucoside % 5 Petunidin 3-glucoside % 6 Pelargonidin 3-rutinoside % 7 Pelargonidin 3-(malonyl)glucoside % 8 Pelargonidin 3-(6"-acetyl)glucoside % 1 Only anthocyanins with high enough concentrations of being quantified were presented in this table. Data expressed mg of anthocyanin (anthocyanidin glycosides or acylglycosides) and presented as mean ± SD for sample number > 2. 2 Peak numbers correspond to those in Ref FW: fresh weight. 4 Only one or two in multiple samples contained this anthocyanin.
5 Supplemental Table 3. Concentration of anthocyanins in vegetables and nuts 1. Black Bean 4 1 Delphinidin 3,5-diglucoside % 2 Petunidin 3,5-diglucoside % 3 Delphinidin 3-galacoside % 4 Delphinidin 3-glucoside % 5 Malvidin 3,5-diglucoside % 6 Petunidin 3-galactoside % 7 Petunidin 3-glucoside % 8 Malvidin 3-galactoside % 9 Malvidin 3-glucosie % Eggplant 1 Delphinidin 3-rutinoside-5-galacoside % 2 Delphinidin 3-rutinoside-5-glucoside % 3 Delphinidin 3-glucoside % 4 Delphinidin 3-rutinoside % Red Leaf Lettuce 1 Cyanidin 3-glucoside 0.09 ± % 2 Cyanidin 3-(3"-malonyl)glucoside 0.08 ± % 3 Cyanidin 3-(6"-malonyl)glucoside 2.03 ± % 4 Cyanidin 3-(6"-acetyl)glucoside 0.03 ± % Red Onion 1 Cyanidin 3-(6"-malonyl)-glucoside-5-glucoside % 2 Cyanidin 3-glucoside % 3 Cyanidin 3-laminaribioside % 4 Cyanidin 3-(3"-malonylglucoside) % 5 Peonidin 3-glucoside % 6 Cyanidin 3-(3"-acetyl)glucoside % 7 Cyanidin 3-(6"-malonylglucoside) % 8 Cyanidin 3-(6"-malonyl-laminaribioside) % 9 Peonidin 3-(malonyl)glucoside % 10 Cyanidin 3-(malonyl)(acetyl)glucoside % Small Red Bean 1 Cyanidin 3-glucoside % 2 Pelargonidin 3-sambubioside % 3 Pelargonidin 3-glucoside % Pistachio 4 1 Cyanidin 3-galactoside 6.3 ± % 2 Cyanidin 3-glucoside 1.2 ± % 1 Only anthocyanins with concentration above the limits of detection were quantified and presented in this table. Data expressed mg of anthocyanin (anthocyanidin glycosides or acylglycosides) and presented as mean ± SD for sample number > 2. 2 Peak numbers correspond to those in Ref FW: fresh weight. 4 Data expressed as dry weight.
6 Supplemental Table 4. Concentration anthocyanins of red cabbage and red radish 1. Red Cabbage 1 Cyanidin 3-diglucoside-5-glucoside 46.7 ± % 5 Cyanidin 3-(sinapoyl)diglucoside-5-glucoside 19.0 ± % 9 Cyanidin 3-(caffeoyl)(p-coumaroyl)diglucoside-5-glucoside 6.4 ± % 10 Cyanidin 3-(glycopyranosyl-feruloyl)diglucoside-5-glucoside 3.9 ± % 11 Cyanidin 3-(glycopyranosyl-sinapoyl)diglucoside-5-glucoside 7.0 ± % 12 Cyanidin 3-(sinapoyl)diglucoside-5-glucoside 5.8 ± % 13 Cyanidin 3-(sinapoyl)(p-coumaroyl)diglucoside-5-glucoside 6.8 ± % 14 Cyanidin 3-(caffeoyl)diglucoside-5-glucoside 1.0 ± % 16 Cyanidin 3-(p-coumaroyl)diglucoside-5-glucoside 23.0 ± % 17 Cyanidin 3-(sinapoyl)diglucoside-5-glucoside 84.9 ± % 19 Cyanidin 3-(feruloyl)(feruloyl)diglucoside-5-glucoside 21.6 ± % 20 Cyanidin 3-(sinapoyl)(feruloyl)diglucoside-5-glucoside 18.7 ± % 21 Cyanidin 3-(sinapoyl)(sinapoyl)diglucoside-5-glucoside 76.9 ± % Red Radish 10 pelargonidin-3-(feruloyl)diglucoside-5-(malonoyl)glucoside 2.1 ± % 13 pelargonidin-3-(caffeoyl)diglucoside-5-(malonoyl)glucoside 8.3 ± % 18 pelargonidin-3-(p-coumaroyl)diglucoside-5-glucoside 5.7 ± % 19 pelargonidin-3-(feruloyl)diglucoside-5-glucoside 4.3 ± % 25 pelargonidin-3-(p-coumaroyl)diglucoside-5-(malonyl)glucoside 40.8 ± % 26 pelargonidin-3-(feruloyl)diglucoside-5-(malonyl)glucoside 33.1 ± % 28 pelargonidin-3-(feruloyl)(caffeoyl)diglucoside-5-(malonoyl)glucoside 2.7 ± % 31 pelargonidin-3-(feruloyl)diglucoside 0.4 ± % 32 pelargonidin-3-(feruloyl)(feruloyl)diglucoside-5-(malonyl)glucoside 1.3 ± % 33 pelargonidin-3-(p-coumaroyl)(p-coumaroyl)diglucoside-5-(malonoyl)glucoside 1.2 ± % 34 pelargonidin-3-(p-coumaroyl)(feruloyl)diglucoside-5-(malonoyl)glucoside % Only anthocyanins with concentrations above the limits of detection were quantified and presented in this table. Data expressed mg of anthocyanin (anthocyanidin glycosides or acylglycosides) and presented as mean ± SD for sample number > 2. 1 Peak numbers correspond to those in Ref. 25. FW: fresh weight. Only one or two in multiple samples contained this anthocyanin
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