This product is classified as a hazardous chemical according to the Model Work Health and Safety Regulations, 2011.

Transcription

1 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document group: Version number: 3.00 Issue Date: 18/11/2016 Supersedes date: 14/11/2016 This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice (Safe Work Australia, December 2011) SECTION 1: Identification 1.1. Product identifier 3M Clean-Trace Surface Protein Instant (formerly Biotrace Check-It ) Product Identification Numbers DH Recommended use and restrictions on use Recommended use Detection of protein on food production surfaces For Industrial or Professional use only Supplier s details Address: 3M Australia - Building A, 1 Rivett Road, North Ryde NSW 2113 Telephone: E Mail: productinfo.au@mmm.com Website: Emergency telephone number EMERGENCY: (Australia only) SECTION 2: Hazard identification This product is classified as a hazardous chemical according to the Model Work Health and Safety Regulations, Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification Classification of the substance or mixture Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category Label elements The label elements below were prepared in accordance with the Code of Practice on Preparation of Safety Data Sheets for Page: 1 of 13

2 Hazardous Chemicals (Safe Work Australia, December 2011). This information may be different from the actual product label. Signal word DANGER! Symbols Flame Exclamation mark Health Hazard Pictograms Hazard statements H225 H319 H336 H373 Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure: liver Precautionary statements Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ventilating/lighting equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280B Wear protective gloves and eye/face protection. P280A Wear eye/face protection. P264 Wash thoroughly after handling. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. P312 Call a POISON CENTRE or doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. Page: 2 of 13

3 P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations Other assigned/identified product hazards None known Other hazards which do not result in None known. SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient CAS Nbr % by Weight Glycerin % in the Water (30-40% in the swab, 5-15% in the Citric acid SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. attention. Remove contact lenses if easy to do. Continue rinsing. Get medical If swallowed Rinse mouth. If you feel unwell, get medical attention Most important symptoms and effects, both acute and delayed See Section Information on toxicological effects Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish Special hazards arising from the substance or mixture Page: 3 of 13

4 Closed containers exposed to heat from fire may build pressure and explode Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Hazchem Code: 3Y SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. WARNING! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An Alcohol Resistant foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical s for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapour accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from acids. Store away from oxidising agents. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient CAS Nbr Agency Limit type Additional comments Glycerin Australia OELs TWA(Inspirable dust)(8 hours):10 mg/m3 Page: 4 of 13

5 swab, Australia OELs TWA(8 hours): % mg/m3(1000 ppm) swab, ACGIH STEL:1000 ppm A3: Confirmed animal -20% carcinogen. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment CMRG : Chemical Manufacturer's Recommended Guidelines TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling Sen: Sensitiser Sk: Absorption through the skin may be a significant source of exposure Exposure controls Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect vented goggles. Select and use eye protection in accordance with AS/NZS Eye protection should comply with the performance specifications of AS/NZS Skin/hand protection No chemical protective gloves are required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. Select and use respirators according to AS/NZS Respirators should comply with AS/NZS 1716 performance specifications. For information about respirators, call 3M on SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid. Appearance/Odour Clear yellow liquid with alcohol odor. Odour threshold ph Not applicable. Melting point/freezing point Not applicable. Boiling point/initial boiling point/boiling range 78.3 ºC [Details:Based on Glycerin] Flash point 21 ºC [Test Method:Closed Cup] [Details:Estimated] Page: 5 of 13

6 Evaporation rate Flammability (solid, gas) Not applicable. Flammable Limits(LEL) Flammable Limits(UEL) Vapour pressure Vapour density Relative density ºC ] [Ref Std:WATER=1] Water solubility Complete Solubility- non-water Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Viscosity Volatile organic compounds (VOC) VOC less H2O & exempt solvents SECTION 10: Stability and reactivity 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section 10.2 Chemical stability Stable Conditions to avoid Sparks and/or flames Possibility of hazardous reactions Hazardous polymerisation will not occur Incompatible materials Strong oxidising agents Hazardous decomposition products Substance Condition Hydrocarbons. Not specified. Carbon monoxide. Not specified. Carbon dioxide. Not specified. Hydrogen gas. Not specified. SECTION 11: Toxicological information The information below may not be consistent with the material in Section 2 if specific ingredient s are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Page: 6 of 13

7 Inhalation Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin contact Contact with the skin during product use is not expected to result in significant irritation. Eye contact Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Liver effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Additional information: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg 20% Dermal Rabbit LD50 > 15,800 mg/kg Inhalation-Vapour (4 Rat LC mg/l 20% hours) 20% Ingestion Rat LD50 17,800 mg/kg Citric acid Dermal LD50 estimated to be 2,000-5,000 mg/kg Citric acid Ingestion Rat LD50 3,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Glycerin Rabbit No significant irritation Page: 7 of 13

8 Rabbit No significant irritation Citric acid Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Glycerin Rabbit No significant irritation Rabbit Moderate irritant Citric acid Rabbit Severe irritant Skin Sensitisation Name Species Value Glycerin Guinea pig Not sensitizing Human Citric acid Human Not sensitizing Respiratory Sensitisation For the component/components, either no data are currently available or the. Germ Cell Mutagenicity Name Route Value In Vitro In vivo Citric acid In Vitro Not mutagenic Citric acid In vivo Not mutagenic Carcinogenicity Name Route Species Value Glycerin Ingestion Mouse data are not 20% Ingestion Multiple animal species data are not Citric acid Ingestion Rat Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test result Exposure Duration Glycerin Ingestion Not toxic to female reproduction Rat NOAEL 2,000 2 generation Glycerin Ingestion Not toxic to male reproduction Glycerin Ingestion Not toxic to development 70% in the 20% in the Inhalation Not toxic to development Rat Rat NOAEL 2,000 NOAEL 2,000 Rat NOAEL 38 mg/l 2 generation 2 generation during gestation 70% in Ingestion Rat NOAEL premating & during Page: 8 of 13

9 the 20% in the developmental data exist, but the data are not Citric acid Ingestion Not toxic to female reproduction Citric acid Ingestion Not toxic to male reproduction Citric acid Ingestion Not toxic to development Target Organ(s) 5,200 Rat NOAEL 600 Rat NOAEL 600 Rat NOAEL 600 gestation 2 generation 2 generation 2 generation Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Inhalation Inhalation Ingestion Ingestion central nervous system depression respiratory irritation central nervous system depression kidney and/or bladder Citric acid Inhalation respiratory irritation Value Species Test result Exposure Duration May cause Human LOAEL 2.6 mg/l 30 minutes drowsiness or dizziness May cause drowsiness or dizziness Human LOAEL 9.4 mg/l not available Multiple animal species NOAEL not available Dog NOAEL 3,000 mg/kg NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test result Exposure Duration Glycerin Inhalation respiratory system Rat NOAEL 3.91 mg/l 14 days Glycerin Inhalation heart liver kidney and/or bladder Glycerin Ingestion endocrine system hematopoietic All data are negative All data are negative Rat NOAEL 3.91 mg/l Rat NOAEL 10, days 2 years Page: 9 of 13

10 system liver kidney and/or bladder Inhalation liver Inhalation hematopoietic system immune system Ingestion liver Ingestion kidney and/or bladder Citric acid Ingestion bone, teeth, nails, and/or hair Citric acid Ingestion endocrine system hematopoietic system Citric acid Ingestion kidney and/or bladder Rabbit LOAEL 124 mg/l 365 days Rat NOAEL 25 mg/l 14 days Rat LOAEL 8,000 Dog NOAEL 3,000 Rat NOAEL 600 Rat NOAEL 4,670 Rat NOAEL 1,300 4 months 7 days 90 days 6 weeks 6 weeks Aspiration Hazard For the component/components, either no data are currently available or the. Exposure Levels Refer Section 8.1 Control Parameters of this Safety Data Sheet. Interactive Effects Not determined. SECTION 12: Ecological information The information below may not be consistent with the material in Section 2 if specific ingredient s are mandated by a competent authority. Additional information leading to material in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. Page: 10 of 13

11 12.1. Toxicity Acute aquatic hazard: GHS Acute 3: Harmful to aquatic life. Chronic aquatic hazard: Not chronically toxic to aquatic life by GHS criteria. No product test data available. Material CAS Number Organism Type Exposure Test endpoint Test result Glycerin Goldfish Experimental 24 hours LC50 >5,000 mg/l Glycerin Water flea Experimental 24 hours EC50 >10,000 mg/l Green algae Experimental 96 hours EC50 1,000 mg/l 20% Rainbow trout Experimental 96 hours LC50 42 mg/l 20% Water flea Experimental 48 hours EC50 5,012 mg/l 20% Green algae Experimental 96 hours NOEC <500 mg/l 20% Water flea Experimental 11 days NOEC 9.6 mg/l 20% Citric acid Water flea Experimental 48 hours EC mg/l Citric acid Bluegill Experimental 96 hours LC50 1,516 mg/l Persistence and degradability Material CAS Number Test type Duration Study Type Test result Protocol Glycerin Experimental Biodegradation 14 days BOD 63 % weight OECD 301C - MITI test (I) 20% Experimental Biodegradation 14 days BOD 89 % weight OECD 301C - MITI test (I) Water (30-40% in the swab, 5-15% Data not available or in N/A N/A N/A N/A Page: 11 of 13

12 Citric acid Experimental Biodegradation 12.3 : Bioaccumulative potential 14 days BOD 77 % weight OECD 301C - MITI test (I) Material CAS Number Test type Duration Study Type Test result Protocol Glycerin Experimental Bioconcentrati on Log Kow Other methods Estimated 28 days Bioaccumulatio 3.16 Estimated: 20% Bioconcentrati on n factor Bioconcentration factor Water (30-40% in the swab, 5-15% Data not available or in Citric acid Experimental Bioconcentrati on Mobility in soil Please contact manufacturer for more details 12.5 Other adverse effects No information available. SECTION 13: Disposal considerations N/A N/A N/A N/A Log Kow -1.7 Other methods Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. SECTION 14: Transport Information Australian Dangerous Goods Code (ADG) - Road/Rail Transport UN No.: UN1993 Proper shipping name: COMBUSTIBLE LIQUID, N.O.S. Class/Division: 3 Sub Risk: Not applicable. Packing Group: III Special Instructions: Not Restricted - Special Provisions 216 fufilled Hazchem Code: 3Y IERG: 14 International Air Transport Association (IATA) - Air Transport UN No.: UN1993 Proper shipping name: COMBUSTIBLE LIQUID, N.O.S. Class/Division: 3 Page: 12 of 13

13 Sub Risk: Not applicable. Packing Group: III Special Instructions: Not Restricted as per Special Provisions A46 International Maritime Dangerous Goods Code (IMDG)- Marine Transport UN No.: UN1993 Proper shipping name: COMBUSTIBLE LIQUID, N.O.S. Class/Division: 3 Sub Risk: Not applicable. Packing Group: III Marine Pollutant: Not applicable. Special Instructions: Not Restricted - Special Provisions 216 fufilled SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory Status: An ingredient(s) in this product is being introduced under the no unreasonable risk non-cosmetic (<100 Kg) exemption provisions specified in Section 21(4) of the Industrial Chemicals (Notification and Assessment) Act 1989 as amended. Poison Schedule:This product has not been assessed for poisons scheduling as the product is intended for industrial and professional use only. SECTION 16: Other information Revision information: Conversion to GHS format SDS. DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. Greenguard is a United States based program. The Low VOC reference related to United States Federal and State regulations exemptions for some solvents. 3M Australia SDSs are available at Page: 13 of 13