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1 Technical Data Sheet EVOQUE 1133 Pre-Composite Polymer Technology 100% Acrylic, Low VOC Capable Pre-Composite Polymer Technology for Interior/Exterior Flat to Semigloss Architectural Coatings (formerly EXP-4340) Regional Product Availability Description North America EVOQUE 1133 Pre-Composite Polymer is one of several Pre-Composite Polymers which is based on a new and unique technology that offers improvements in TiO hiding efficiency through the development of a polymer-pigment composite. During the paint making process, the pre-composite polymer combines with TiO to form a polymer-pigment composite which improves both the wet and dry hiding efficiency of the pigment. The hiding improvement gives formulators the option of either using less TiO or increasing the hiding in their current formulations at equal TiO levels. In addition, barrier performance properties of the film are maintained or improved. Formulations can be developed which emphasize the performance improvements at similar cost or maintain performance at reduced cost while taking advantage of the increase in TiO hiding efficiency. EVOQUE 1133 Pre-Composite Polymer works with most slurry and dry grades of TiO and is compatible with other acrylic binder technologies. In addition, EVOQUE 1133 works well with ROPAQUE Opaque Polymers, offering an additive effect for improved hiding efficiency and reducing dependence on TiO. Benefits All-acrylic polymer prepared with no APEO-containing surfactants Improves both the dry and wet hiding efficiency of TiO Compatible with most common dry and slurry grades of TiO in North America Excellent exterior durability Formulation latitude from flat to semigloss for both interior and exterior use Expanded formulation latitude to address VOC regulations < 50 g/l VOC to 150 g/l VOC Works in tandem with all ROPAQUE Opaque Polymers to offer further TiO reduction Page 1 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

2 Typical Physical Properties TiO Recommendations (These properties are typical but do not constitute specifications). Property Appearance Solids Content 46-47% ph Viscosity, cp 60) <500 Weight per U.S. Gallon, (wet, lb/gal 8.8 Weight per U.S. Gallon,(dry, lb/gal) 9.5 Wet Bulking Value, gal/lb Dry Bulking Value, gal/lb Tg, DSC, onset o C MFFT, o C Typical Values Milky white liquid ~9 o C ~0 o C (Visual) The unique performance features of EVOQUE 1133 Pre-Composite Polymer are due to the interaction of the pre-composite polymer with the surface of the TiO particles. Different grades of TiO will have different surface characteristics, which may affect how EVOQUE 1133 interacts. Most grades of TiO that have been evaluated have shown to be compatible with EVOQUE Below are some of the commercial grades of slurry and dry TiO that have been evaluated in our laboratory. Refer to Form# , TiO Recommendations for EVOQUE Pre-Composite Polymer Technology, for a listing of all EVOQUE Polymers and TiO s evaluated to date. Best Recommended Pairings of Commercial Grades of TiO and EVOQUE 1133 : Ti-Pure R-706 & R-746 (DuPont) Tiona 596i dry and slurry (Cristal) Tioxide TR-90 (Huntsman) Good Pairing that may require additional formulation adjustments to achieve optimal performance with EVOQUE 1133: Tronox CR-86 (Tronox) Kronos 310 (Kronos) Tioxide TR93 (Huntsman) Weaker Composite Formation Pairing which may lead to minimal performance benefits with EVOQUE 1133: Tronox CR-86S (Tronox) Highly Interactive Pairing that may require higher mixing to reduce flocculation or grit with EVOQUE 1133: Kronos 4311 (Kronos) Page of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

3 Handling Dry and Slurry TiO Improvements in TiO efficiency can be obtained when using either dry or slurry grades of titanium dioxide and EVOQUE 1133 Pre-Composite Polymer Technology. Optimal Composite formation is the key to delivering hiding and other performance properties. No special equipment or steps are needed to make paints with EVOQUE 1133, which can be used in a standard paint making protocol; that is, a millbase (grind or dispersion tank) and letdown (mixer tank) with good results. Please refer to Form # , Conventional Paint Making with EVOQUE, for more details. Pease contact your Technical Service Representative if you need further assistance. Formulating Guidelines Extenders One of the other most important, yet sometimes overlooked, ingredients in paint is mineral extenders. Most paint formulations contain TiO for hiding and some combination of pigment extenders to achieve a desired paint PVC (pigment volume concentration). Extenders can either be viewed as a filler, in which case the least expensive mineral is normally chosen, or as value adding materials. Much work has been done in developing starting point formulations looking at various ways to maintain PVC when reducing the level of TiO in paints made with EVOQUE 1133 Pre-Composite Polymer Technology. While our recommendation is to use or increase the level of ROPAQUE Opaque Polymer, other options like increasing extenders would also apply based upon the expected performance properties needed in the final paint. Calcined clays are used extensively to extend TiO in paints and are advertised as promoting both wet and dry hiding properties. Work done in our technical service group has demonstrated that while this class of materials does show improved wet hide in a non-tio containing recipe, in fully formulated paint, the wet hide advantage is minimal or nonexistent. Other extender types, such as Nepheline Syenite and Calcium Carbonate of various particles sizes have also been examined in numerous formulations without any formulation issues. Opaque Polymer ROPAQUE Ultra EF Opaque Polymer is a polymeric pigment which is designed to provide hiding in architectural coatings. ROPAQUE Opaque Polymers enable the formulator to improve properties and realize cost savings. They can be effectively used in various formulations when making composite paints with EVOQUE We have found that higher levels of ROPAQUE Opaque Polymers can be used in conjunction with EVOQUE 1133 when making composite paints as a way to maintain PVC and VS while offering another way to further reduce TiO in a formulation. As with any opaque polymer formulation, the formulator needs to assess the desired gloss and hiding needs to determine the best level of opaque polymer to use. Dispersants The types and levels of pigment dispersants play an important role in attaining a desirable balance of stability, rheology, and gloss in typical paint formulations. In composite paints containing EVOQUE 1133 Pre-Composite Polymer, it is also important to select the right dispersant type and level to make certain that the interaction of the EVOQUE 1133 with the surface of the TiO particles is complete and effective to achieve good hiding. Page 3 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

4 Hydrophobic copolymer dispersants such as TAMOL TM 731A, TAMOL 165A, TAMOL 00, TAMOL 011 and hydrophilic copolymers such as TAMOL 114 work best with EVOQUE 1133 Pre-Composite Polymer. It has been found that dispersant levels of approximately 0.8 % (on total pigment solids) result in a good balance of stability and rheology without affecting the reactivity of EVOQUE Higher levels ( %) may be needed when using TAMOL 00/011 type dispersants. It is best to avoid or minimize the use of strong acid or phosphate types of dispersants as sole dispersants in a formulation, as they may interfere with the interaction of EVOQUE 1133, thus yielding poor hiding in formulated paints. Rheology Modifiers and Thickeners In many composite paints made with EVOQUE 1133 Pre-Composite Polymer, the overall thickener demand may be reduced if the formulator is starting with an existing benchmark formulation. This is due primarily to the TiO -polymer composite formation, which has a higher hydrodynamic volume than the volumes of the individual polymer and pigment particles from which it is made. This interaction typically reduces the level of thickeners needed to achieve the target viscosity profile of the paint. However, it is recommended that the formulator monitor this effect, since ingredients such as letdown binder and thickener type may also have an impact. Non- associative thickeners, i.e. low to mid molecular weight (Mw) cellulosic type thickeners like QP-4000 and QP-15000, work well with EVOQUE 1133, as do most associative thickeners (HASE and HEUR). HASE (Hydrophobically modified Alkali Soluble Emulsion) thickeners like ACRYSOL DR-6600, ACRYSOL RM-7, ACRYSOL TT-935, ACRYSOL TT- 615, and ACRYSOL DR-110 allow the formulator a broad choice of products to be used in a wide formulation and rheology range. Non-solvent containing HEUR (Hydrophobically modified Ethylene Oxide Urethane) thickeners like those listed below, offer the formulator a wide selection of choices to achieve the desired rheology from Pseudoplastic to Newtonian. - ACRYSOL RM-995, RM-44, RM-8W: KU-builders (low shear viscosity) - ACRYSOL RM-3000, RM-5000, RM-00NPR: ICI-builders (high shear viscosity) - ACRYSOL SCT-75: unique KU/ICI balance (product contains solvent) The choice of ACRYSOL Rheology Modifiers has a major impact on paint performance. It facilitates stability during storage, good viscosity for brush, roller or spray applications and enhanced performance and aesthetic appearance for flat to high gloss paints. Listed below are thickener comparisons for two suggested flat formulations (F and F-1133ZnO-) and semigloss formulation (SG ). Comparisons include a benchmark control and its comparable hiding EVOQUE 1133 & ROPAQUE Opaque Polymer counterpart. Paints were formulated to comparable Stormer (KU) and ICI (poise) viscosities. Note, thickener ratios may change and in many cases, KU builder demand is decreased. Page 4 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

5 Flat Control & ROPAQUE Ultra EF Opaque Polymer (F-VSR-50-1) EVOQUE 1133 & ROPAQUE Ultra EF Opaque Polymer (F ) CELLOSIZE QP-4400 (or equivalent).5.5 ACRYSOL RM-00NPR dry lbs/100 gal ACRYSOL TOTAL dry lbs/100 gal Leneta Anti-Sag (4-4 mils) 4 4 Leneta Flow (0-10,best) 5 Flat Control w/zno & ROPAQUE Ultra Opaque Polymer (F-VSR-50-ZnO-) EVOQUE 1133 & ROPAQUE Ultra Opaque Polymer (F-1133ZnO-) CELLOSIZE QP-4400 (or equivalent).5.5 ACRYSOL RM-00NPR dry lbs/100 gal ACRYSOL TOTAL dry lbs/100 gal Leneta Anti-Sag (4-4 mils) 4 4 Leneta Flow (0-10,best) 3 Semigloss Control & ROPAQUE Ultra EF Opaque Polymer (SG-VSR-50-1) EVOQUE 1133 & ROPAQUE Ultra Opaque Polymer (SG ) ACRYSOL 3000 dry lbs/100 gal ACRYSOL 995 dry lbs/100 gal ACRYSOL TOTAL dry lbs/100 gal Leneta Anti-Sag (4-4 mils) Leneta Flow (0-10,best) 9 9 Other Ingredients Attapulgite (i.e. Attagel or Min-U-Gel) is a hydrated magnesium alumino-silicate with a three dimensional chain structure that gives it unique colloidal properties. Their use in coatings offer rapid dispersability and effective thixotropic thickening which aids in viscosity and sag control of paint. Thixotropy with these thickeners is developed by charge attraction on the particle surface, hydrogen bonding, and the entrapment of liquid within a chain-like network. Coatings formulated with these materials tend to form a gel-like structure at rest, yet when sheared, become thin. When formulating paints using EVOQUE Pre-Composite Polymers, the level of attapulgite materials may be reduced due to the hydrodynamic volume of the polymer-pigment composite that not only thickens the composite stage, but also contributes to the overall rheology of the paint. It is recommended that the formulator reduce levels to no more than 3 pounds/100 gallons to maintain a stable viscosity profile. Page 5 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

6 Coalescents While the recommended coalescent level for EVOQUE 1133 Pre-Composite Polymer is approximately -4%, we have found that the level of coalescent in paints formulated with EVOQUE 1133 may also depend upon the letdown binder in the formulation. The 3-5% level recommendation for EVOQUE 1133 facilitates excellent film formation at 40 o F/40% Relative Humidity in the starting point flat formulations. The semigloss starting point formulation, which includes RHOPLEX VSR-015 as the letdown binder and is prepared without solvent, also had excellent film formation without the need for any coalescent. Work has also been done using non-volatile coalescents, like Optifilm 400, to achieve the very low VOC formulating spaces for the various regulations across the country without impacting any performance properties. Please consult your Technical Service Representative for more details. Surfactants In formulating paints with EVOQUE 1133 Pre-Composite Polymer, we typically recommend surfactants with high HLB ( 13) at use levels of > lbs/100 gallons to facilitate good paint making and long term stability. Grind surfactants may be needed to help wet the dry TiO and extenders (if used) to facilitate a good pigment dispersion. ECOSURF LF-30 is an APEO-free surfactant that offers excellent pigment surface wetting with low foam during the dispersion process. Other surfactants such as TRITON CF-10, TRITON X-100 along with Surfynol CT-11 also work well. Surfactants such as TERGITOL 15-S-40, TRITON X-405, and Byk-348 are good to aid in adjusting stability, color acceptance, and substrate wetting in a formulation. Use caution when using phosphate ester surfactants, such as Surfynol and Dextrol products. These anionic surfactants can act as co-dispersants and disrupt the formation of the polymer-tio composite thus lowering the hiding efficiency. Defoamers In making paints with EVOQUE 1133, as seen in the starting point formulations included, it is recommended to add some defoamer to the pre-composite polymer and water before adding TiO or a dispersion containing TiO, to keep foam to a minimum while mixing. It is very important to select the proper defoamer when formulating high gloss systems. Tiny bubbles or craters, which may not be visible in flat paint formulations, can be very noticeable in high gloss formulations. As for defoamer recommendations, polysiloxane (silicone) types work best, like Byk-0, Byk-04, Foamstar A-34, Tego 810, and Tego However, mineral oil types, such as HiMar DFC-38, Rhodoline 643, Foamstar SA-3, and Drewplus 475 may also be effective, but typically work at much higher use levels. Of course, VOC contribution, cost, and use level need to be considered also. Page 6 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

7 Preservatives and Mildewcides KATHON LX 1.5% Microbicide is an effective preservative that helps protect paint formulations based on EVOQUE 1133 Pre-Composite Polymer. The recommended use level is approximately 5 ppm per 1,000 pounds of paint. When formulating with EVOQUE 1133, this microbicide should be added to the grind or premixed with water if it is to be added to the letdown. Preservative efficacy should be evaluated once a final formulation has been selected. Formaldehyde or formaldehyde-releasing preservatives may adversely affect the performance of paints based on EVOQUE 1133 Emulsion and are not recommended for use with this polymer. When selecting a preservative, check with the raw material supplier to ensure that formaldehyde or formaldehyde-releasers are not present. For exterior application, the use of an effective paint mildewcide is recommended. IPBC mildewcides, such as BIOBAN IPBC 0 Antimicrobial (ROCIMA 0) and BIOBAN IPBC 40 Antimicrobial ( ROCIMA 40), are recommended for use with EVOQUE 1133 Emulsion at a level of 1.6 lbs IPBC solids per 100 gallons of paint. BIOBAN IPBC 40 LE Antimicrobial is formulated in solution form and contains low to no VOC content to help further reduce VOC of the formulation. ROCIMA 63 is another microbicide that contains three different active ingredients for exceptional performance against a broad range of fungi and algae. Generally, it is recommended to use from 0.5 to.0 Lbs per 100 Lbs. of formulation (.5 to 0 lbs/100 gallons). Page 7 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

8 Recommended Ingredient Summary Dry Grade TiO Slurry Grade TiO Extenders Extenders TYPE RECOMMENDED LEVEL BENEFIT ALTERNATIVES Multipurpose, Rutile Multipurpose, Rutile Nepheline Syenite Hydrous & Calcined Clay Ti-Pure R-706, Tiona 596, Tioxide TR-90 Ti-PureR-746 Tiona 596i Minex 4 Minex 10 ASP-170, Polygloss 90, Icecap K, Optiwhite as specified as specified as needed as needed Good interaction with EVOQUE 1133 Pre- Composite Polymer Good interaction with EVOQUE 1133 Pre- Composite Polymer Good exterior durability Flatting, Extenders Silica Diafil 55 as needed Matting agent Zinc-Oxide Eagle Zinc 417W 5 lbs Mildewstat Opaque Polymer Dispersant Surfactant Surfactant Coalescent Plasticizer Light- Scattering Pigment Hydrophilic Copolymer Pigment wetting aid Surface wetting VOC containing Very low VOC Eagle Zinc 417W 5 lbs Mildewstat TAMOL 114 (Flat) TAMOL 731A(SG) ECOSURF LF-30 TERGITOL 15-S-40 ByK-348 UCAR IBT Optifilm 400 Film Enhancer Neutralizer Amine AMP-95 Defoamer Rheology Modifier Polysiloxane (preferred) Associative Byk -0, Byk-04 Tego Foamex 810 (SG) a) ACRYSOL RM-3000 b) ACRYSOL RM-995 ~ 0.8 % solids on pigment lbs per 100 gallons lbs per 100 gallons 3-5 % on binder solids (flats) 3-5 % on binder solids as needed to adjust final ph to lbs per 100 gallons Broad formulating latitude APEO-free; low-foam facilitates adequate film formation at 40 o F/40% RH facilitates adequate film formation at 35 o F/50% RH lower odor, codispersant Excellent flow; noncontributors to VOC Tronox CR-86, Kronos 310, Tioxide TR-93 Calcium Carbonate (Duramite, Omyacarb UF) TAMOL 165A, TAMOL 011 Tamol 851 (ZnO Rx) TRITON CF-10 Surfynol CT-11 TRITON Surfactants Texanol DOWANOL Coalescents Ammonia See paragraph above ICI-builder: ACRYSOL 00NPR; QP-4400, QP ( see Paragraph above) Page 8 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

9 Starting-Point Flat Formulations include: Two Benchmark High Quality Exterior Flat Controls based on RHOPLEX VSR-50 Binder with ROPAQUE Ultra or Ultra EF Opaque Polymer (F- VSR-50-1 & F-VSR50-ZnO-) Two High Quality Exterior Flat formulations based on RHOPLEX VSR-50, EVOQUE 1133 Pre-Composite Polymer & ROPAQUE Ultra or Ultra EF Opaque Polymer Hiding Matches: (F & F-1133ZnO-) Flat Formulation Profile and Key Property Comparison: RHOPLEX VSR-50 Exterior Flat Control with ROPAQUE Ultra EF (F-VSR-50-1) RHOPLEX VSR-50 Exterior Flat with EVOQUE 1133 & ROPAQUE Ultra EF (F ) PVC (%)/VS (%) 50/35 50/35 VOC (g/l) TiO 1, lbs/gallon as supplied Percent TiO Removed 0 15% RHOPLEX VSR-50 (46.5%), lbs/gallon as supplied ROPAQUE Ultra(30%), lbs/gallon as supplied Minex 4 Extender, lbs/gallon as supplied EVOQUE 1133 (46.5%), lbs/gallon as supplied S/mil * Contrast Ratio, 1.5 mil(wet) Contrast Ratio, 1.5 mil(dry) Sheen 60/85 4/4 4/4 Y-Reflectance Initial Ku/ICI/pH 99/1./ /1./8.7 Equilibrated KU/ICI/pH 103/1./ /1./8.5 Heat Age (delta KU) -5-5 Alkyd Adhesion Excellent Excellent * S/Mil: Scattering Coefficient: Precise measurement of paint s dry and wet hiding power will yield data not only on its aesthetic value but also on its degree of dispersion and film porosity. 1 Ti-Pure R-706 (Du Pont) tinted with 4 ounces/gallon Phthalo blue Page 9 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

10 Flat Formulation Profile and Key Property Comparison (Cont d.): RHOPLEX VSR-50 Exterior Flat Control with ZnO and ROPAQUE Ultra VSR-50 ZnO-) RHOPLEX VSR-50 Exterior Flat with ZnO, EVOQUE 1133 & ROPAQUE Ultra (F-1133 ZnO-) PVC (%)/VS (%) 48.5/ /37 VOC (g/l) TiO 1, lbs/gallon as supplied Percent TiO Removed 0 10% RHOPLEX VSR-50 (46.5%), lbs/gallon as supplied ROPAQUE Ultra (30%), lbs/gallon as supplied Minex 4 Extender, lbs/gallon as supplied EVOQUE 1133 (46.5%), lbs/gallon as supplied S/mil * Contrast Ratio, 1.5 mil (wet) Contrast Ratio, 1.5 mil(dry) Sheen 60/85 3/3 3/3 Y-Reflectance Initial Ku/ICI/pH 11/1./ /1.3/8.7 Equilibrated KU/ICI/pH 111/1.1/ /1.3/8.7 Heat Age (delta KU) Alkyd Adhesion Excellent Excellent * S/Mil: Scattering Coefficient: Precise measurement of paint s dry and wet hiding power will yield data not only on its aesthetic value but also on its degree of dispersion and film porosity. 1 Ti-Pure R-706 (Du Pont) tinted with 4 ounces/gallon Phthalo blue Page 10 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

11 High Quality Exterior Flat Control Formulation based on RHOPLEX VSR-50 Binder with ROPAQUE Ultra EF Opaque Polymer (F-VSR-50-1) Material Name Pounds Gallons Level Grind Water ROCIMA 63 Microbicide TAMOL 114 Dispersant % Disp. ECOSURF LF-30 Surfactant Propylene Glycol. 0.5 Defoamer (1) KATHON LX 1.5% Microbicide CELLOSIZE QP Titanium Dioxide () % PVC Icecap-K % PVC Minex % PVC Attagel % PVC Grind Sub-total % PVC Let Down RHOPLEX VSR-50 (46.5%) ROPAQUE Ultra EF % PVC UCAR Film Former IBT % Coal Propylene Glycol Surfactant (3) AMP-95 Neutralizer Defoamer (4) ACRYSOL RM-00NPR Rheology Modifier Water Totals => % PVC Volume Solids: 35.03% Density : VOC : 44 g/l Weight Solids : 50.11% 1 Byk-0 (ByK Chemie) or alternative Ti-Pure R-706 (Du Pont) or alternative 3 Byk-348 (ByK Chemie) or alternative 4 Byk-04 (ByK Chemie) or alternative Page 11 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

12 High Quality Exterior Flat Formulation based on RHOPLEX VSR-50 Binder with EVOQUE 1133 Pre-Composite Polymer and ROPAQUE Ultra EF Opaque Polymer (F ) Material Name Pounds Gallons Level Grind Water ROCIMA 63 Microbicide TAMOL 114 Dispersant % Disp. ECOSURF LF-30 Surfactant Propylene Glycol. 0.5 Defoamer (1) KATHON LX 1.5% Microbicide CELLOSIZE QP Titanium Dioxide () % PVC Icecap-K % PVC Minex % PVC Attagel % Diafil % PVC Grind Sub-total % PVC Add GRIND to the following PREMIX (with agitation) and MIX for at least 10 minutes Premix EVOQUE 1133 (46.5%) Water Defoamer (3) Pre-Mix Subtotal Let Down RHOPLEX VSR-50 (46.5%) ROPAQUE Ultra EF % PVC UCAR Film Former IBT % Coal Propylene Glycol Surfactant (4) AMP-95 Neutralizer Defoamer (3) ACRYSOL RM-00NPR Water Totals => % PVC Volume Solids: 35.00% Density : VOC : 44 g/l Weight Solids : 49.11% 1 Byk-0 (ByK Chemie) or alternative Ti-Pure R-706 (Du Pont) or alternative 3 Byk-04 (ByK Chemie) or equivalent 4 Byk 348 (ByK Chemie) or equivalent Page 1 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

13 High Quality Exterior Flat Control Formulation based on RHOPLEX VSR-50 Binder with Zinc Oxide and ROPAQUE Ultra Opaque Polymer (F-VSR-50-ZnO-1) Material Name Pounds Gallons Level Grind Cellulosic Thickener (1) (.5%) Water TAMOL 851 Dispersant % Disp. KTPP % Disp. TRITON CF-10 Surfactant. 0.5 Defoamer () Titanium Dioxide (3) % PVC Eagle Zinc 417W % PVC Minex % PVC Icecap-K % PVC Attagel % PVC SKANE M Grind Sub-total % PVC Let Down RHOPLEX VSR-50 (46.5%) ROPAQUE Ultra % PVC UCAR Film Former IBT % Coal Propylene Glycol Defoamer () ACRYSOL RM-00NPR Rheology Modifier Water Totals => % PVC Volume Solids: 37.00% Density : VOC : 49 g/l Weight Solids : 5.49% 1 CELLOSIZE QP-4400 (Dow Chemical) or other low-moderate MW Cellulosic thickener Rhodoline 643 (Rhoddia) or alternative 3 Ti-Pure R-706 (Du Pont) or alternative Page 13 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

14 High Quality Exterior Flat Formulation based on RHOPLEX VSR-50 Binder with Zinc Oxide, EVOQUE 1133 Pre- Composite Polymer and ROPAQUE Ultra Opaque Polymer (F-1133-ZnO-) Material Name Pounds Gallons Level Grind Cellulosic Thickener (1) Water TAMOL 851 Dispersant % Disp. KTPP % Disp. TRITON CF-10 Surfactant. 0.5 Defoamer () Titanium Dioxide (3) % PVC Eagle Zinc 417W % PVC Minex % PVC Icecap-K % PVC Attagel % PVC SKANE M Grind Sub-total % PVC Add GRIND to the following PREMIX (with agitation) and MIX for at least 10 minutes Premix EVOQUE 1133 (46.5%) Water Defoamer () Pre-Mix Subtotal Let Down RHOPLEX VSR-50 (46.5%) ROPAQUE Ultra % PVC UCAR Film Former IBT % Coal Propylene Glycol Defoamer () ACRYSOL RM-00NPR Rheology Modifier Water Totals => % PVC Volume Solids: 36.90% Density : 11.9 VOC : 50 g/l Weight Solids : 5.1% 1 CELLOSIZE QP-4400(Dow Chemical) or other low-moderate MW cellulosic thickener Rhodoline 643(Rhoddia) or alternative 3 Ti-Pure R-706 (DuPont) or alternative Page 14 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

15 Starting-Point High Quality Semigloss Solvent-free Capable Formulations include: Benchmark High Quality Semigloss Control based on RHOPLEX VSR-015 Binder with ROPAQUE Ultra EF Opaque Polymer (SG-VSR-015-1) High Quality Semigloss Formulation based on RHOPLEX VSR-015 with EVOQUE 1133 Pre-Composite Polymer & ROPAQUE Ultra EF hiding match; (SG ) High Quality Solvent-free Capable Semigloss Formulation Profile and Key Property Comparison: RHOPLEX VSR- 015 SG Control with ROPAQUE Ultra EF (SG-VSR015-1) RHOPLEX VSR- 015 SG with EVOQUE 1133 and ROPAQUE Ultra EF (SG ) PVC (%)/VS (%) 6/38 6/38 VOC (g/l) TiO 1, lbs/gallon as supplied Percent TiO Removed 0 15% RHOPLEX VSR-015 (50%), lbs/gallon as supplied ROPAQUE Ultra EF (30%), lbs/gallon as supplied Minex 10 Extender, lbs/gallon as supplied EVOQUE 1133 (46.5%), lbs/gallon as supplied s/mil Contrast Ratio, 1.5 mil (wet) Contrast Ratio, 1.5 mil (dry) Sheen 0/60 8/64 3/764 4 Y-Reflectance Initial KU/ICI/pH 100/1./8.7 99/1.3/8.7 Equilibrated KU/ICI/pH 100/1./8.7 99/1.4/8.7 Heat Age (delta KU) Alkyd Adhesion Very Good Very Good * S/Mil: Scattering Coefficient: Precise measurement of paint s dry and wet hiding power will yield data not only on its aesthetic value but also on its degree of dispersion and film porosity. 1 Ti-Pure R-746 (Du Pont) tinted with 4 ounces/gallon Phthalo blue Page 15 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

16 High Quality Semigloss Solvent-fee Capable Control Formulation based on RHOPLEX VSR-015 Binder with ROPAQUE Ultra EF Opaque Polymer (SG-015-1) Material Name Pounds Gallons Level Grind TAMOL 731A Dispersant % Disp. Surfactant 1) Defoamers () KATHON LX 1.5% Microbicide Titanium Dioxide (3) % PVC Minex % PVC Grind Sub-total % PVC Let Down Water RHOPLEX VSR-015 (50.0%) ROPAQUE Ultra EF % PVC AMP-95 Neutralizer Surfactant (1) Defoamer () ACRYSOL RM-3000 Rheology Modifier ADJUST STORMER VISCOSITY TO ~ 100 WITH THE FOLLOWING: ACRYSOL RM Water Totals => % PVC 1 Byk 348(ByK Chemie) or alternative Tego Foamex 810 (Tego) or alternative 3 DuPont R-746 (DuPont) or alternative Volume Solids: 38.00% Density : VOC : g/l Weight Solids : 48.87% Page 16 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

17 High Quality Semigloss Solvent-fee Capable Control Formulation based on RHOPLEX VSR-015 Binder with EVOQUE 1133 Pre-Composite Polymer and ROPAQUE Ultra EF Opaque Polymer (SG ) Material Name Pounds Gallons Level Grind TAMOL 731A Dispersant % Disp. Surfactant 1) Defoamers () KATHON LX 1.5% Microbicide Titanium Dioxide (3) % PVC Minex % PVC Grind Sub-total % PVC Add GRIND to the following PREMIX (with agitation) and MIX for at least 10 minutes Premix EVOQUE 1133 (46.5%) Water Defoamer () Pre-Mix Sub-total Let Down Water RHOPLEX VSR-015 (50.0%) ROPAQUE Ultra EF % PVC AMP-95 Neutralizer Surfactant (1) Defoamer () ACRYSOL RM-3000 Rheology Modifier ADJUST STORMER VISCOSITY TO ~ 100 WITH THE FOLLOWING: ACRYSOL RM Water Totals => % PVC Volume Solids: 38.00% Density : VOC : ~ g/l Weight Solids : 47.30% 1 Byk 348(ByK Chemie) or alternative Tego Foamex 810 (Tego) or alternative 3 DuPont R-746 (DuPont) or alternative Page 17 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

18 Handling Precautions Storage Disposal Considerations Before using this product, consult the Material Safety Data Sheet (MSDS)/Safety Data Sheet (SDS) for details on product hazards, recommended handling precautions and product storage. Store products in tightly closed original containers at temperatures recommended on the product label. Dispose in accordance with all local, state (provincial) and federal regulations. Empty containers may contain hazardous residues. This material and its container must be disposed in a safe and legal manner. It is the user's responsibility to verify that treatment and disposal procedures comply with local, state (provincial) and federal regulations. Contact your Dow Coating Materials Technical Representative for more information. Chemical Registration Product Stewardship Customer Notice Many countries require the registration of chemicals, either imported or produced locally, prior to their commercial use. Violation of these regulations may lead to substantial penalties imposed upon the user, the importer or manufacturer, and/or cessation of supply. It is in your interests to ensure that all chemicals used by you are registered. Dow does not supply unregistered products unless permitted under limited sampling procedures as a precursor to registration. Dow has a fundamental concern for all who make, distribute, and use its products, and for the environment in which we live. This concern is the basis for our product stewardship philosophy by which we assess the safety, health, and environmental information on our products and then take appropriate steps to protect employee and public health and our environment. The success of our product stewardship program rests with each and every individual involved with Dow products - from the initial concept and research, to manufacture, use, sale, disposal, and recycle of each product. Dow strongly encourages its customers to review both their manufacturing processes and their applications of Dow products from the standpoint of human health and environmental quality to ensure that Dow products are not used in ways for which they are not intended or tested. Dow personnel are available to answer your questions and to provide reasonable technical support. Dow product literature, including safety data sheets, should be consulted prior to use of Dow products. Current safety data sheets are available from Dow. Contact: North America: Latin America: (+55) Europe: (+800) Asia-Pacific: (+800) Notice: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer's use and for ensuring that Customer's workplace and disposal practices are in compliance with applicable laws and other government enactments. The product shown in this literature may not be available for sale and/or available in all geographies where Dow is represented. The claims made may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to Dow or the Company mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. Page 18 of 18 EVOQUE 1133 Pre-Composite Polymer Technology / Dow Coating Materials 01/013, Rev. 1

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