SYSTERM SAFETY DATA SHEET
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1 SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company/undertaking Product name: Name and address of Supplier: Dichloromethane Classic Chemicals Sdn Bhd 19, Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam, Selangor Emergency telephone no.: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories category 2 Hazard statements Carcinogenicity, Signal word Hazard Statements Warning Suspected of causing cancer. Precautionary statements P201 Obtain special instructions before use. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. Labelling according to EC Directives: Hazard symbols: Xn R-phrases R40 Limited evidence of a carcinogenic effect. S-phrases S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves.
2 SAFETY DATA SHEET Product name: Dichloromethane 3. Composition/information on ingredients Product name: Methylene chloride, Dichloromethane CAS-No.: Molar mass: Molecular formula: CH 2 CI 2 EC No.: Index no.: Other means of identification DCM, Methylene chloride, Methylene dichloride 4. First aid measures After inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical attention. After skin contact: Wash off thoroughly with soap and water. Remove contaminated clothing and wash before re-use. In severe cases, obtain medical attention. After eye contact: Irrigate thoroughly with water for at least 10 minutes. If discomfort persists, obtain medical attention. After ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. 5. Fire-fighting measures Suitable extinguishing media: To suit environment. Do not stay in dangerous zone without respiratory protective equipment. Prevent fire fighting water entering watercourses or ground-water. Special risks: Not combustible. May evolve toxic fumes in fire. (phosgene, hydrochloric acid) 6. Accidental release measures Wear appropriate protective clothing. Inform others to keep at a safe distance. Absorb on an inert absorbent, transfer to a suitable container and arrange removal by disposal company. Wash site of spillage thoroughly with water and detergent. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillages. 7. Handling and storage Handling: Under no circumstances eat, drink or smoke while handling this material. Work under fume extractor. Do not inhale substances. Wash hands and face thoroughly after working with material. Contaminated clothing should be removed and washed before re-use. Do not empty into drains. Storage: Store at room temperature (+15 o C to +25 o C recommended). Keep well closed and protected from direct sunlight and moisture.
3 SAFETY DATA SHEET Product name: Dichloromethane 8. Exposure controls/personal protection As appropriate to the situation and the quantity handled. Engineering methods to control or prevent exposure are preferred. Methods could include process enclosure or mechanical ventilation. Respiratory protection: Self-contained breathing apparatus Ventilation: Eye protection: Glove protection: Other Precautions: Fume cupboard Goggles or face-shield Polyvinyl alcohol (Change gloves regularly.), PE/EVAL (Silver Shield) Plastic apron, sleeves, boots if handling large quantities 9. Physical and chemical properties Form: liquid Colour: colourless Odour: characteristic odour ph value at H 2 O (20 C) 7 Melting temperature 95 o C Boiling temperature 40 o C (1013 hpa) Ignition temperature 605 o C (DIN 51794) Flash point not applicable Explosion limits %(V) Vapour pressure (20 o C) 475 hpa Vapour density 2.93 Density (20 o C) 1.33 g/cm 3 Solubility in water (20 o C) 20 g/l Refractive index Stability and reactivity Stable. Unsuitable working materials: various plastics, light metals. Substances to be avoided alkali metals, alkaline earth metals, metals in powder form, nitrogen oxides, alcoholates, alkali amides, perchloric acid, nitric acid, nonmetallic oxides, oxygen, alcohols, aromatic hydrocarbons, water/ potassium permanganate, aromatic hydrocarbons/ acids. Hazardous decomposition products hydrochloric acid, phosgene Stabilizer 2-methyl-2-butene (Amylene)
4 SAFETY DATA SHEET Product name: Dichloromethane 11. Toxicological information After inhalation: mucosal irritations; inebriation, narcosis, unconsciousness. After skin contact: Irritations. Degreasing effect on the skin, possibly followed by secondary inflammation. Danger of skin absorption. After eye contact: Severe irritations. Risk of corneal clouding. After ingestion and inhalation: dizziness, nausea, vomiting. After absorption of large quantities: CNS disorders, drowsiness, dizziness, drop in blood pressure, cardiac dysrhythmia, respiratory paralysis, depressed respiration, inebriation, narcosis. Ingestion may result in damage of the following: liver, kidneys. Further data LD 50 : 2136 mg/kg oral, rat. LC 50 : 88 mg/l inhalation, rat. NOAEL (inhalation, rat): 200 ppm/6h/d (2y) Has bee found to cause cancer in laboratory animals. (Carcinogen, Category 3) May cause adverse mutagenic or teratogenic effects. 12. Ecological information Low bioaccumulation potential. Low aquatic toxicity. 13. Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. 14. Transport information Transport over land ADR/RID ADR/RID class: 6.1 Name of material: DICHLOROMETHANE Sea transport IMDG IMDG class: 6.1 UN-No.: 1593 Packaging group: III Correct technical name: DICHLOROMETHANE Air transport ICAO-TI and IATA-DGR ICAO/IATA class: 6.1 UN/ID-No.: 1593 Packaging group: III Correct technical name: DICHLOROMETHANE
5 SAFETY DATA SHEET Product name: Dichloromethane 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) 2 Chemical Safety Assessment No data available 16. Other information Relevant R-, H- and EUH-phrases (Number and full text) R40 Limited evidence of a carcinogenic effect. Suspected of causing cancer. Revision Date: 01 Jan 2016 The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.
6 LEMBARAN DATA KESELAMATAN 1. Pengenalpastian bahan / sediaan dan syarikat / aku janji Nama produk: Nama dan alamat pembekal: Diklorometan Classic Chemicals Sdn Bhd 19, Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam, Selangor telefon kecemasan no.: Pengenalpastian bahaya Pengelasan bahan atau campuran Pengelasan menurut Peraturan (EC) No 1272/2008 [CLP] kelas bahaya dan kategori bahaya Kekarsinogenan, kategori 2 Pernyataan bahaya Kata isyarat Amaran Penyata bahaya Disyaki menyebabkan kanser. pernyataan langkah P201 Dapatkan arahan khas sebelum menggunakannya. P281 Gunakan peralatan perlindungan diri seperti yang dikehendaki. P308 + P313 JIKA terdedah atau terkena: Dapatkan nasihat / rawatan perubatan. Pelabelan menurut Arahan EC: Simbol Bahaya: Xn Frasa-R R40 S Frasa S23 S24 / 25 S36 / 37 Bukti terhad mengenai kesan karsinogenik. Jangan menyedut gas / wasap / wap / semburan (perkataan yang sesuai yang dinyatakan oleh pengilang). Elakkan daripada bersentuhan dengan kulit dan mata. Pakai pakaian pelindung yang sesuai dan sarung tangan.
7 LEMBARAN DATA KESELAMATAN Nama produk: Diklorometan 3. Komposisi / maklumat mengenai nama bahan-bahan produk: klorida Methylene, Diklorometan CAS-No.: Molar massa: Formula molekul: CH 2 CI 2 EC No.: Indeks no.: cara pengenalan lain DCM, metilena klorida, Methylene dichloride 4. Langkah-langkah pertolongan cemas Jika tersedut: Jauhi dari pendedahan, rehat dan menyimpan panas. Dalam kes-kes yang teruk dapatkan rawatan perubatan. Jika terkena kulit: Basuh sehingga bersih dengan sabun dan air. Tanggalkan pakaian yang tercemar dan basuh sebelum digunakan semula. Dalam kes-kes yang teruk, dapatkan rawatan perubatan. Jika terkena mata: Mengairi sehingga bersih dengan air sekurang-kurangnya 10 minit. Jika ketidakselesaan berterusan, dapatkan rawatan perubatan. Selepas pengambilan: Basuh mulut sehingga bersih dengan air dan beri banyak air untuk minum. Dapatkan rawatan perubatan. 5. Langkah memadam kebakaran media pemadam yang sesuai: Untuk disesuaikan dengan persekitaran. Janganlah tinggal di zon berbahaya tanpa peralatan perlindungan pernafasan. Mencegah kebakaran pertempuran saluran air memasuki air atau tanah air. risiko khas: Tidak mudah terbakar. Boleh berkembang wasap toksik dalam api. (Fosgen, asid hidroklorik) 6. Langkah-langkah pengawalan pelepasan tidak sengaja Pakai pakaian perlindungan yang sesuai. Maklumkan kepada orang lain untuk berada di jarak yang selamat. Menyerap pada penyerap lengai, memindahkan ke dalam bekas yang sesuai dan menguruskan pembuangan oleh syarikat pelupusan. Basuh tapak tumpahan sehingga bersih dengan air dan detergen. Untuk tumpahan besar cecair harus lengkap dengan pasir atau tanah dan kedua-dua cecair dan pepejal dipindahkan untuk menyelamatkan bekas. Apa-apa sisa harus dianggap sebagai untuk tumpahan kecil. 7. Pengendalian dan penyimpanan Pengendalian: Dalam apa keadaan tidak boleh makan, minum atau merokok semasa mengendalikan bahan ini. Bekerja di bawah wasap pemerah. Jangan menyedut bahan. Basuh tangan dan muka sehingga bersih setelah bekerja dengan bahan. Pakaian yang tercemar hendaklah dikeluarkan dan dibasuh sebelum digunakan semula. Jangan buang ke dalam longkang. Penyimpanan: Simpan pada suhu bilik (+ 15 o C ke + 25 o C disyorkan). Pastikan juga ditutup dan dilindungi daripada cahaya matahari langsung dan kelembapan.
8 LEMBARAN DATA KESELAMATAN Nama produk: Diklorometan 8. Kawalan pendedahan / perlindungan diri Sebagaimana yang sesuai dengan keadaan dan kuantiti yang dikendalikan. kaedah kejuruteraan untuk mengawal atau mencegah pendedahan diutamakan. Perlindungan Pernafasan: Alih udara: Perlindungan mata: Sarung tangan perlindungan: Kaedah boleh termasuk proses tertutup atau pengudaraan mekanikal. alat pernafasan serba lengkap Fume almari Goggles atau perisai muka alkohol polyvinyl (Tukar sarung tangan dengan kerap.), PE / EVAL (Silver Shield) Langkah berjaga-jaga lain: apron plastik, lengan, but - jika pengendalian kuantiti yang besar 9. Sifat-sifat fizikal dan kimia Bentuk: cecair Warna: tidak berwarna Bau: ciri nilai ph di H 2 O (20 C) 7 suhu lebur -95 o C suhu didih 40 o C (1013 hpa) Suhu pencucuhan 605 o C (DIN 51794) Takat kilat tidak berkenaan had letupan 13-22% (V) tekanan wap (20 o C) 475 hpa wap ketumpatan 2.93 ketumpatan (20 o C) 1.33 g / cm 3 Keterlarutan dalam air (20 o C) 20 g / l indeks biasan Kestabilan dan kereaktifan Stabil. bahan-bahan yang tidak sesuai kerja: pelbagai plastik, logam ringan. Bahan yang perlu dielakkan logam alkali, logam alkali bumi, logam dalam bentuk serbuk, oksida nitrogen, alcoholates, amides alkali, asid perchloric, asid nitrik, oksida bukan logam, oksigen, alkohol, hidrokarbon aromatik, air / kalium permanganat, hidrokarbon aromatik / asid. Produk penghuraian yang berbahaya asid hidroklorik, fosgen Stabilizer \ 2-metil-2-butena (Amylene)
9 LEMBARAN DATA KESELAMATAN Nama produk: Diklorometan 11. Maklumat toksikologi Jika tersedut: kegatalan mukosa; mabuk, narkosis, tidak sedarkan diri. Jika terkena kulit: kegatalan. Nyahgris kesan pada kulit, mungkin diikuti oleh keradangan menengah. Bahaya penyerapan kulit. Jika terkena mata: kegatalan yang teruk. Risiko kekaburan kornea. Selepas pengambilan dan terhidu: pening, loya, muntah-muntah. Selepas penyerapan kuantiti yang banyak: gangguan CNS, mengantuk, pening, penurunan tekanan darah, gangguan denyutan jantung jantung, lumpuh pernafasan, pernafasan tertekan, mabuk, narkosis. Pengingesan boleh mengakibatkan kerosakan daripada yang berikut: hati, buah pinggang. maklumat lanjut LD 50 : 2136 mg / kg lisan, tikus. LC 50 : 88 mg / l penyedutan, tikus. NOAEL (penyedutan, tikus): 200 ppm / 6h / d (2y) Mempunyai lebah didapati menyebabkan kanser pada haiwan makmal. (Karsinogen, Kategori 3) Boleh menyebabkan kesan mutagen atau teratogenik buruk. 12. Maklumat ekologi potensi bio Rendah. ketoksikan rendah akuatik. 13. Maklumat pelupusan sisa kimia biasanya diklasifikasikan sebagai sisa khas, dan oleh itu adalah dilindungi oleh peraturanperaturan yang mengikut lokasi. Hubungi pihak berkuasa pelupusan sisa tempatan anda untuk mendapatkan nasihat, atau berpindah kepada syarikat pelupusan kimia. Berkumur bekas kosong teliti sebelum kembali untuk dikitar semula. 14. Maklumat pengangkutan Pengangkutan ke atas jalan ADR / RID ADR / RID: 6.1 Nama bahan: Diklorometan Pengangkutan laut kelas IMDG IMDG 6.1 UN.: 1593 Kumpulan pembungkusan: III Nama teknikal Betul: Diklorometan Pengangkutan udara ICAO-TI dan IATA-DGR kelas ICAO / IATA: 6.1 UN / ID-No.: 1593 Kumpulan pembungkusan: III Nama teknikal Betul: Diklorometan
10 LEMBARAN DATA KESELAMATAN Nama produk: Diklorometan 15. Maklumat pengawalan Keselamatan, kesihatan dan peraturan alam sekitar / undang-undang khusus untuk bahan atau campuran Bahaya air kelas (WGK) 2 Data Keselamatan Kimia Penilaian Tiada tersedia 16. Maklumat lain R- berkaitan, H- dan EUH-frasa (Bilangan dan teks penuh) R40 Bukti terhad mengenai kesan karsinogenik. Disyaki menyebabkan kanser. Tarikh Semakan: 1 Januari 2016 Maklumat yang terkandung dalam dokumen ini adalah berdasarkan pada keadaan pengetahuan semasa kami. Ia menyifatkan produk dengan mengambil kira langkah-langkah keselamatan yang sesuai. Ia tidak mewakili jaminan sifat-sifat produk.
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