Pico ZnO253DM. Self-Dispersible Coated Zinc Oxide

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1 Pico ZnO253DM Self-Dispersible Coated Zinc Oxide Made By Sales Team Published date : January, 2017

2 Ultra Violet UV-Filter Pico ZnO253DM Effect Dispersion Ability Transparent High UVA Block Effect Good texture Stability Guide Formula Summary

3 Ultra Violet UVA Damage: Tanning Reaction UVB Damage: Erythema

4 UV-Filter UVB UVA TiO2 OMC OS HMS MBC IPMC. ZnO MBBT BEMT BMDM AP DHHB Inorganic Organic Inorganic Organic 나노징크옥사이드의유해성논란 DNA 손상, 잠재적인피부침투력우려 EU 의견 : 100nm 이하의물질을함유하는모든화장품은나노라벨을부탁해야하며, 해당원료및제품에대한안전성자료를확보해야함. FDA 의견 : EU 에서제기되고있는 Sun Screen 에사용되는나노크기의원료들이인체에유해한영향을끼쳤다는증거를찾지못했다고발표. 미국에서는아무런제약없이 Nano Material 을화장품및의약품에사용가능

5 Property Trade Name : Pico ZnO253DM Com. ZnO 97% Hydrogen Dimethicone 3% Pure ZnO 97% Appearance : White Powder Odor : Slightly Odor Purity of ZnO : 97% Water Contents : 1% Loss on Drying(1g, 105, 3hr) : 2% Residue on Ignition(1g, 800 ) : 5% As : 10ppm Pb : 20ppm Primary Particle Size : 25~30nm Secondary Particle Size : 2 μm Packing : 20KG

6 Benefits 1 Excellent Dispersion Ability Without any special milling process, it can be used to the formulation directly. 2 No white Effect It does not have a white effect when it is applied to skin because it is uniform in globular shape. 3 Good Texture It has an excellent soft texture when it is applied to skin because it is uniform in globular shape. 4 High UVA Block Effect It has a high UVA block effect in UVA spectrum.

7 Manufacture Plant Continuous Auto-Synthesis System

8 Dispersion Ability Put Pico ZnO253DM directly Put Nano ZnO dispersed solution Put Pico ZnO253DM directly Put Nano ZnO dispersed solution P. Water To 100 Glycerin 5.0 SF-0005Z 30.0 ZnO253DM 5.0 KF S-Ben(W) 0.5 Phenonip 0.1 All contents are equal P. Water To 100 Glycerin 5.0 SF-0005Z 26.0 SolutionSC 10.0 KF S-Ben(W) 0.5 Phenonip 0.1 Olympus BX41, phase-contrast mode, Ph2, X400 Without a dispersed solution, put the powder directly.

9 Dispersion Ability The test for sedimentation rate (ZnO Powder 5% + D5 95%, (Disper Mixer 4000RPM, 1HR) Pico ZnO253DM S 社 ZnO T 社 ZnO D 社 ZnO After 30 min. After 1 hrs After 2 hrs

10 Dispersion Ability The test for sedimentation rate (ZnO Powder 5% + D5 95% (Disper Mixer 4000RPM, 1HR)) cm Measuring the height from the surface to the bottom after dispersion. ZnO PicoZnO 253DM 253DM 2 Sunzin S 社 ZnO 1.5 NCO 1 MZY T 社 ZnO S 0 Start After 30 min. 1 시간후 2 시간후 DaitoZnO D 社 350 침강속도 : S 社 ZnO < PicoZnO 253DM < D 社 ZnO < T 社 ZnO

11 Transparent Dispersion Sample Pico ZnO253DM S 社 ZnO T 社 ZnO D 社 ZnO After 1 hr After 2 hr Composition : Coated Nano ZnO 50% + Cyclopentasiloxane 50% Pico ZnO253DM shows the best transparency.

12 Transparent Formulated Sample Put Pico ZnO253DM directly Put Nano ZnO dispersed solution P. Water To 100 Glycerin 5.0 SF-0005Z 30.0 ZnO253DM 5.0 KF S-Ben(W) 0.5 Phenonip 0.1 All contents are equal P. Water To 100 Glycerin 5.0 SF-0005Z 26.0 Sunclear Z KF S-Ben(W) 0.5 Phenonip 0.1 When it is applied to the formulation, it shows less white-effect than putting ZnO dispersed solution.

13 Coating Stability (Photosynthesis) Pico ZnO253DM Initial D 社 Coated Nano ZnO Initial An excellent coating(photo) safety against UV. After 8hr After 8hr No risk for discoloration by a change with the passage of time.

14 Primary Particle Size & Shape FIB-SEM measurement result T 社 Coated ZnO D 社 Coated ZnO Pico ZnO 253DM S 社 Coated ZnO It is uniform in almost perfect globular shape. The size is 25~30nm

15 SEM Photo S 社 Nano ZnO Pico ZnO 253DM D 社 Nano ZnO T 社 Nano ZnO

16 SEM Photo Pico ZnO 253 (Non-Coating) Pico ZnO 253DM (Coated Silicone) Pico ZnO 253 (Non-Coating) Pico ZnO 253DM (Coated Silicone)

17 Secondary Particle Size Secondary Particle Size: 2 μm / It is not detected below 100nm.

18 Purity FE-SEM EDS measurement result T 社 Coated ZnO Elements analysis result D 社 Coated ZnO The elements detected in silicone coated nano-sized ZnO are C, O, Si, Zn

19 Purity FE-SEM EDS measurement result Pico ZnO 253DM Elements analysis result S 社 Coated ZnO Chloride impurity is detected. It is because the starting material is ZnCl2..

20 Purity S 社 Nano ZnO Before ignition Pico ZnO 253DM After ignition 600, 40 분강열 Because of remaining Chloride.. S 社 Nano ZnO Before ignition Pico ZnO 253DM After ignition Discoloring to Green.

21 High UVA Block Effect in-vitro Test Result OMC 7% T 社 Coated Nano ZnO SPF 30, PFA 14 TiO2 3.4% ZnO 5.8% Pico ZnO253DM SPF 32, PFA 17 Equipment: Optometrics SPF-290S Analyzer <Formula> Water To 100% + Glycerin 5% + Cyclopentasiloxane 25% + PEG-10 Dimethicone 5% + OMC 7% + TTO-S4 5% + ZnO Part 6% + Bentonite 0.5% + Phenonip 0.5%

22 High UVA Block Effect Put Pico ZnO253DM directly Put Nano ZnO dispersed solution ( S corp.) Result SPF : 58 PFA : 31 Formulation SPF, PFA in-vitro test <<Analysis request : Korea Testing&Research Institute> Result SPF : 41 PFA : 19 Formulation P. Water To 100 Glycerin 5 SF-0005Z 25 ZnO253DM 5 KF OMC 7 Parsol S-Ben(W) 0.5 Phenonip 0.1 P. Water To 100 Glycerin 5 SF-0005Z 21 S 社 ZnO 50% solution 10 KF OMC 7 Parsol S-Ben(W) 0.5 Phenonip 0.1

23 Good Texture Softness Smoothness Whitening Effect Sense of Difference Transparency <Volunteer 10 persons> It has an excellent soft texture because it is uniform in globular shape.

24 Guide Formula Sun Cream SPF35, PA++ Ingredients Contents(%) Process A Ozokerite Wax 1.00 Sorbitan Olivate Cetyl PEG/PPG-10/1 Dimethicone 0.50 PEG-10 Dimethicone 5.00 NF-HPIB Isoamyl p-methoxycinnamate 5.00 Ethylhexyl methoxycinnamate 7.50 Cyclopentasiloxane Titanium Dioxide, Stearic acid, Aluminium 4.00 Pico ZnO253DM 5.00 Bentonite 0.60 B P. Water To 100 NaCl C Preservatives

25 Summary Pico ZnO 253DM, it is an essential choice for good touch, stability, UVA block effect of Sun-screens, BB creams, Make-up bases, foundations, etc. High UVA block effect Excellent dispersion ability Excellent Soft texture Good transp arency Advantages of Pico ZnO253 Dispersion Ability No White Effect Good Texture High UVA Block Effect Feel the coated zinc oxide of sphere type!!

26 Commercial Products MISSHA : All-Around Safe Block Water proof sun milk Manufacturer : Cosmecca Package : 40ml ($14) Launched in 2012 (Renewal) Pico ZnO254DM (Dimethicone/Met hicone Copolymer 4% 코팅 ) 적용

27 Commercial Products Hanskin : Super Light Touch BB ( 한스킨수퍼라이트터치 BB) Manufacturer : Cosmecca Package : 30ml ($25) Launched in 2012 (Renewal) Pico ZnO254DM (Dimethicone/Met hicone Copolymer 4% 코팅 ) 적용

28 THANK YOU Main Office : Getbulro 145 gil 15-6, Yeonsu-gu, Incheon Cuty Contact Number : Tel (82) / Fax (82) Contact Person : Mr. Eric / Ms. Grace of Sales Department nfc_song@naver.com / nfc_kang@naver.com Homepage :

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