1/7 Hitachi Industrial Equipment Systems Co., Ltd JP-Y108, 1108Y Ver.7.00 Issue 9/6/2013 Revision date 11/18/2016 SAFETY DATA SHEET

Transcription

1 1/7 1 IDENTIFICATION SAFETY DATA SHEET Product name Name of company Address Tel : FAX : Recommended use of the chemical and restrictions on use 2 HAZARDS IDENTIFICATION : JP-Y108, 1108Y : Hitachi Industrial Equipment Systems Co., Ltd : 1-1 Higashitaga-cho 1 chome, Hitachi-shi, Ibaraki-ken, Japan : Printing ink for industrial ink jet printers GHS classification Physico-chemical endpoints : Flammable liquid Category 2 Acute toxicity - oral : Acute toxicity - dermal Acute toxicity - inhalation (air) Acute toxicity - inhalation (vapor) : Category 4 Acute toxicity - inhalation (dust) Acute toxicity - inhalation (mist) Skin corrosion/irritation : Category 2 Eye damage/irritation : Category 2 Sensitization - respiratory Sensitization - skin Germ cell mutagenicity Carcinogenicity Toxic to reproduction Specific target organ/systemic toxicity (Single exposure) : Category 1 Category 2 Category 3 Specific target organ/systemic toxicity (Repeated exposure) : Category 1 Aspiration toxicity Hazardous to the aquatic environment -Acute hazard -Chronic hazard

2 2/7 GHS label elements Hazard Symbols: Signal word: Danger Hazard statements and precautionary statement: Causes skin irritation Causes serious eye irritation Highly flammable liquid and vapor Harmful if inhaled May cause respiratory irritation Causes central nervous system damage May cause damage to kidneys Causes damage to central nervous system and peripheral nervous system through prolonged or repeated exposure Precautionary statements: Keep away from ignition sources such as heat/sparks/open flame/high temperature. Take precautionary measures against static discharge or sparks. Wear appropriate protective gloves and eye/face protection/cap/protective clothing etc., and avoid adhesion to the body and inhaling the vapor. Use only outdoors or in a well-ventilated area. In case of fire, use dry chemical, CO2, or form for extinction. Do not eat, drink or smoke when using this product. Avoid contact during pregnancy/while nursing. Wash face and hands, and gargle thoroughly after handling. IF SWALLOWED: Do not induce vomiting. Call a doctor/physician immediately. IF ON SKIN: Gently wash with plenty of soap and water. Wash/Decontaminate removed clothing before reuse. If skin irritation or rash occurs, seek medical advice/attention. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Use only outdoors or in a well-ventilated area. Call a doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a doctor/physician. Store locked up. Store in cool/well-ventilated place. Keep out of reach of children. Call a doctor/physician if exposed or in case of possibility of exposure. Collect spillage.

3 3/7 3 Composition/information on ingredients Substance or mixture: mixture Composition: Chemical name Concentration (%) CAS No First-aid measures Inhalation: In case of inhalation of large quantities of vapor or gas, remove the victim from the contamination immediately to fresh air. Keep the victim warm and quiet. Use a mechanical ventilator if breathing is irregular or stops. Try to prevent victim from swallowing their vomit. Call a doctor/physician immediately. Skin contact: Quickly wipe off substance with a cloth. Wash the affected area thoroughly with plenty of water and soap or detergent for the skin. Do not use solvents or thinners. If there is any change in appearance or pain, arrange for examination and treatment by a doctor/physician. Eye contact: Gently rinse the affected eyes with plenty of clean running water for at least 15 minutes. Wash completely, including the backs of the eyelids. Get medical assistance as soon as possible. Ingestion: If accidentally swallowed, keep the victim quiet and seek immediate medical attention. Try to prevent victim from swallowing their vomit. 5 Fire-fighting measures Suitable extinguishing media: Use dry chemical, CO2, water splay (fog) or form. Fire fighting procedures; Use water spray to cool fire-exposed surface and to protectpersonal. Shut off "fuel" to fire. If a leak or spill has not ignited, use water spray to disperse the vapors. Avoid spraying water directly into storage containers due to danger of boil over. Unusual fire/explosion hazard; Flammable liquid, can release vapors that form flammable mixtures at temperatures at or above the flashpoint. Special protective equipment and precautions for fire fighters: Wear appropriate protective gear (heat-resistant clothing, and respiratory protection (supplied-air respirator, etc.)). 6 Accidental release measures Shut off all sources of ignition; No smoking or flames in area. Absorb apill with inert material (e.g., dry sand or earth), then place in closed containers using non-sparking tools. Flush residual spill (area) with copious amounts of water. 7 Handling and storage Handling: Use only in the well-ventilated areas. Make available in the work area emergency shower and eyes wash.

4 4/7 Avoid contact with skin or eyes. Storage: Close up the container and keep it in dark cool(0-20 ) place. Keep away from combustible materials and sources of ignition. 8 Exposure controls/personal protections Exposure guidelines: ACGIH TLV-TWA (ppm) : 200 ACGIH STEL (ppm) : Physical and chemical properties Appearance Physical state : Liquid Color : Yellow Odor : Solvent odor Boiling point 2) : 80 (as ) Flash point : -6.5 Upper/lower flammability or explosive limits 2) : Lower limit 1.8 vol%, upper limit 11.5 vol% (as ) Vapor pressure 2) : 10.5kPa (20 ) (as ) Relative vapor density (Air=1) 2) : 2.41 (as ) Relative density : 0.86 (20 ) Solubility (Water) : 29g/100mL (20 ) (as ) Partition coefficient: n-octanol/water 2) : 0.26 Auto-ignition temperature 2) : 470 Decomposition temperature : No data 10 Stability and reactivity Stability: The product is stable. Conditions and materials to avoid : Not available Hazardous decomposition products : These products are carbon oxides 11 Toxicological information Acute toxicity oral: Rat oral LD50 value = 5520mg / kg (EHC 143 (1992), ACGIH (7th, 2001), PATTY (4th, 1994), IRIS (2003), ATSDR (1992)), 2737mg / kg (PATTY (4th, 1994), IRIS (2003), ATSDR (1992)), 2483mg / kg (PATTY (4th, 1994)) and 2884mg / kg (PATTY (4th, 1994)) The calculated values were applied based on these data, but because the calculated values were less than the minimum values, the minimum value were used, and the substance was classified as Category 5. Acute toxicity dermal: Based on rabbit dermal LD50 > 5000 mg/kg (PATTY (4th, 1994)),> 8000 mg/kg (EHC 143 (1992),

5 5/7 DFGOT vol.12 (1999), PATTY (4th, 1994), ATSDR (1992)) and mg/kg (PATTY (4th, 1994)), it was designated as. Acute toxicity - inhalation (air): GHS defined liquid. Acute toxicity - inhalation (vapor): Based on vapor pressure = 10.5kPa (20 C), saturated vapor pressure concentration = ppm, and LC50 (4H) = ppm (NITE) < ppm X 0.90, it is thought that there is almost no mist mixed in with the vapor, and in compliance with a ppm concentration standard of LC50 = ppm (2500 ppm < Category ppm), the substance is classified as Category 4. Acute toxicity - inhalation (dust): No data Acute toxicity - inhalation (mist): No data Skin corrosion/irritation: No irritation was seen in human skin when exposed (EHC 143 (1992), DFGOT vol. 12 (1999), PATTY (4th, 1994) and ATSDR (1992)), but skin application studies in rabbits showed mild or moderate irritation (EHC 143 (1992), DFGOT vol.12 (1999), PATTY (4th, 1994) and ATSDR (1992)). Because of this the substance was classified as Category 2. Eye damage/irritation: Description of eye irritation were observed in examples of vapor exposure in humans (ACGIH (7th, 2001), DFGOT vol.12 (1999), PATTY (4th, 1994) and IRIS (2003)),and in eye irritation studies using rabbits the average score for corneal opacity after 24 hours was 2. 5, although there was level 2 conjunctival redness, because subjects had almost completely recovered within 7 days (ECETOC TR48 (1992)), the substance was classified as Category 2B. Respiratory or skin sensitization: Respiratory: No data Skin: Although there was a description of one case of contact dermatitis in the same original literature (EHC 143 (1992), DFGOT vol. 12 (1999), PATTY (4th, 1994) and ATSDR (1992)), there were no other case reports, and since there was a negative result from the Mouse Ear Swelling Test (DFGOT vol.12 (1999) and PATTY (4th, 1994)), the substance was classified as Not identified due to insufficient data. Germ cell mutagenicity: Because there were negative results on the micronucleus test using mammalian red blood cells (EHC 143 (1992), DFGOT vol.12 (1999), PATTY (4th, 1994), IRIS (2003), ATSDR (1992)) the substance was designated.

6 6/7 Carcinogenicity: Because it was classified as I (Inadequate) by the EPA, it was designated. Toxic to reproduction: Observation of malformations in the fetus in inhalation exposure teratogenicity studies in rats were described in (EHC 143 (1992), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)). However, although delayed ossification and bone mutations were seen in the re-test, no deformities were observed (EHC 143 (1992), ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994 ), IRIS (2003) and ATSDR (1992)). Furthermore, although mutation and low bodyweight were observed in young mice in teratogenicity studies using inhalation exposure in mice, no defects were observed (EHC 143 ( 1992), ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)). From this it was determined that all effects were minimal, and the substance designated. STOST-single exposure: In studies by inhalation exposure in humans no effect on the central nervous system was observed (EHC 143 (1992), DFGOT vol. 12 (1999), IRIS (2003) and ATSDR (1992)). And the results of the time estimation test show that there was no statistically significant difference from the control group (EHC 143 (1992) and PATTY (4th, 1994)). On the other hand, in inhalation exposure studies in rats and mice, effects on the central nervous system were observed at relatively low concentrations (EHC 143 (1992), PATTY (4th, 1994) and IRIS (2003)). From this fact the target organ was determined to be the central nervous system, and the substance was classified as Category 1. In addition, because effects on the kidneys were observed after oral administration of moderate doses in rats (DFGOT vol. 12 (1999), IRIS (2003) and ATSDR (1992)), the kidney is also determined to be a target organ, and the substance classified as Category 2. Furthermore, because respiratory tract irritation was observed in examples of human inhalation exposure (ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)), the substance was classified as Category 3. STOST-repeated exposure: Numbness of the hands and arms was seen in examples of occupational exposure in humans (EHC 143 (1992), DFGOT vol. 12 (1999) and IRIS (2003)), indications of central nervous system disorders in examples of occupational exposure were described in (DFGOT vol. 12 (1999) and IRIS (2003)), and effects on the central nervous system were observed in 3 cases described in (IRIS (2003)). Because of this, the target organs were determined to be the central nervous system and peripheral nervous system, and both were classified as Category 1. Aspiration toxicity: Because it is a normal class 1 alcohol consisting of 3 or more, but not exceeding 13 carbon atoms, corresponding to isobutyl alcohols and ketones composed of not more than 13 carbon atoms, it was classified as Category Ecological information Environmental Behavior:

7 7/7 Ecotoxicity 1) : Persistence and degradability: Ecological bioaccumulation: Mobility in soil: 13 Disposal considerations Scrap materials may be disposed by licensed contractor or burned in an approved incinerator. Do no dump into sewer, on the ground or into any body of water. Follow national and local regulations. 14 Transport information Follow all regulations in your country. UN Number : 1210 UN Proper Shipping Name : Printing ink, flammable Transport hazard class : Class 3 (Flammable liquid) Packing Group : II Environmental hazards : No 15 Regulatory information Follow all regulations in your country. Content of RoHS Directive materials Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm 16 References Cited Literature: 1) Results of Eco-toxicity tests of chemicals conducted by Ministry of the Environment in Japan 2) International Chemical Safety Cards