1/9 Hitachi Industrial Equipment Systems Co., Ltd JP-Y118, 1118Y Version 7.00 Issue revision SAFETY DATA SHEET

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1 1/9 1 IDENTIFICATION SAFETY DATA SHEET Product name : JP-Y118, 1118Y Name of company : Hitachi Industrial Equipment Systems Co., Ltd Labor Systems Division Address : 1-1 Higashitaga-cho 1 chome, Hitachi-shi, Ibaraki-ken, Japan Tel : FAX : Recommended use of the chemical and restrictions on use : Printing ink for industrial ink jet printers 2 HAZARDS IDENTIFICATION GHS classification Physico-chemical endpoints : Flammable liquid Category 2 Acute toxicity - oral Acute toxicity - dermal Acute toxicity - inhalation (air) : Not identified Acute toxicity - inhalation (vapour) : Category 4 Acute toxicity - inhalation (dust) : Not identified Acute toxicity - inhalation (mist) Skin corrosion/irritation : Category 2 Eye damage/irritation : Category 2B Sensitization - respiratory Sensitization - skin Germ cell mutagenicity Carcinogenicity Toxic to reproduction : Category 1B Specific target organ/systemic toxicity (Single exposure) : Category 1 Central nervous system Category 2 Sensory system Category 2 Kidney Category 2 Systematic toxicity Category 3 Respiratory tract irritation Specific target organ/systemic toxicity (Repeated exposure) : Category 1 Central nervous system Category 1 Peripheral nervous system Category 2 Sensory system Aspiration toxicity Hazardous to the aquatic environment -Acute hazard -Chronic hazard

2 2/9 GHS label elements Hazard Symbols: Signal word: Danger Hazard statements and precautionary statement: H315+H320 Causes skin and eye irritation H225 Highly flammable liquid and vapor H332 Harmful if inhaled H335 May cause respiratory irritation H360 May damage fertility or the unborn child H370 Causes damage to central nervous system H371 May cause damage to sensory system, kidney and systematic toxicity H372 Causes damage to central nervous system and peripheral nervous system through prolonged or repeated exposure H373 May cause damage to sensory system through prolonged or repeated exposure Precautionary statements: Keep away from ignition sources such as heat/sparks/open flame/high temperature. Take precautionary measures against static discharge or sparks. Wear appropriate protective gloves and eye/face protection/cap/protective clothing etc., and avoid adhesion to the body and inhaling the vapour. Use only outdoors or in a well-ventilated area. In case of fire, use dry chemical, CO2, or form for extinction. Do not eat, drink or smoke when using this product. Avoid contact during pregnancy/while nursing. Wash face and hands, and gargle thoroughly after handling. IF SWALLOWED: Do not induce vomiting. Call a doctor/physician immediately. IF ON SKIN: Gently wash with plenty of soap and water. Wash/Decontaminate removed clothing before reuse. If skin irritation or rash occurs, seek medical advice/attention. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Use only outdoors or in a well-ventilated area. Call a doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a doctor/physician. Store locked up. Store in cool/well-ventilated place. Keep out of reach of children. Call a doctor/physician if exposed or in case of possibility of exposure. Collect spillage.

3 3/9 3 Composition/information on ingredients Substance or mixture: mixture Composition: Chemical name Concentration (%) CAS No 75-less than First-aid measures Inhalation: In case of inhalation of large quantities of vapour or gas, remove the victim from the contamination immediately to fresh air. Keep the victim warm and quiet. Use a mechanical ventilator if breathing is irregular or stops. Try to prevent victim from swallowing their vomit. Call a doctor/physician immediately. Skin contact: Quickly wipe off substance with a cloth. Wash the affected area thoroughly with plenty of water and soap or detergent for the skin. Do not use solvents or thinners. If there is any change in appearance or pain, arrange for examination and treatment by a doctor/physician. Eye contact: Gently rinse the affected eyes with plenty of clean running water for at least 15 minutes. Wash completely, including the backs of the eyelids. Get medical assistance as soon as possible. Ingestion: If accidentally swallowed, keep the victim quiet and seek immediate medical attention. Try to prevent victim from swallowing their vomit. 5 Fire-fighting measures Suitable extinguishing media: Use dry chemical, CO2, water splay (fog) or form. Fire fighting procedures; Use water spray to cool fire-exposed surface and to protectpersonal. Shut off "fuel" to fire. If a leak or spill has not ignited, use water spray to disperse the vapours. Avoid spraying water directly into storage containers due to danger of boil over. Unusual fire/explosion hazard; Flammable liquid, can release vapours that form flammable mixtures at temperatures at or above the flashpoint. Special protective equipment and precautions for fire fighters: Wear appropriate protective gear (heat-resistant clothing, and respiratory protection (supplied-air respirator, etc.)). 6 Accidental release measures Shut off all sources of ignition; No smoking or flames in area. Absorb apill with inert material (e.g., dry sand or earth), then place in closed containers using non-sparking tools. Flush residual spill (area) with copious amounts of water.

4 4/9 7 Handling and storage Handling: Use only in the well-ventilated areas. Make available in the work area emergency shower and eyes wash. Avoid contact with skin or eyes. Storage: Close up the container and keep it in dark cool(0-20 ) place. Keep away from combustible materials and sources of ignition. 8 Exposure controls/personal protections Exposure guidelines: ACGIH TLV-TWA (ppm) : 200 : 200 (Skin) ACGIH STEL (ppm) : 300 : 250 (Skin) 9 Physical and chemical properties Appearance Physical state : Liquid Color : Yellow Odor : Solvent odor Boiling point 2) : 80 (as ) Flash point : -7.7 Upper/lower flammability or explosive limits 2) : Lower limit 1.8 vol%, upper limit 11.5 vol% (as ) Vapour pressure 2) : 10.5kPa (20 ) (as ) Relative vapour density (Air=1) 2) : 2.41 (as ) Relative density : 0.86 (20 ) Solubility (Water) : 29g/100mL (20 ) (as ) Partition coefficient: n-octanol/water 2) : 0.29(as ) Auto-ignition temperature 2) : 505 (as ) Decomposition temperature : 10 Stability and reactivity Stability: The product is stable. Conditions and materials to avoid : Not available Hazardous decomposition products : These products are carbon oxides 11 Toxicological information Acute toxicity oral: Rat oral LD50 value = 5520mg / kg (EHC 143 (1992), ACGIH (7th, 2001), PATTY (4th, 1994), IRIS

5 5/9 (2003), ATSDR (1992)), 2737mg / kg (PATTY (4th, 1994), IRIS (2003), ATSDR (1992)), 2483mg / kg (PATTY (4th, 1994)) and 2884mg / kg (PATTY (4th, 1994)) The calculated values were applied based on these data, but because the calculated values were less than the minimum values, the minimum value were used, and the substance was classified as Category 5. It was designated as based on rat LD50 values of 6200 mg/kg [EHC 196 (1997)] and 9100 mg/kg [EHC 196 (1997)], but because the toxicity of methanol is described as manifesting more strongly in primates than in rodents [EHC 196 (1997)], and because the dose at which mortality is observed in about half of humans is 1400 mg/kg [DFGOT vol. 16 (2001)], the substance was classified as Category 4. Acute toxicity dermal: Based on rabbit dermal LD50 > 5000 mg/kg (PATTY (4th, 1994)),> 8000 mg/kg (EHC 143 (1992), DFGOT vol.12 (1999), PATTY (4th, 1994), ATSDR (1992)) and mg/kg (PATTY (4th, 1994)), it was designated as. Designated as, based on a rabbit LD50 value of mg/kg DFGOT vol. 16 (2001). Acute toxicity - inhalation (air): GHS defined liquid. This is a GHS defined liquid. Acute toxicity - inhalation (vapour): Based on vapour pressure = 10.5kPa (20 C), saturated vapour pressure concentration = ppm, and LC50 (4H) = ppm (NITE) < ppm X 0.90, it is thought that there is almost no mist mixed in with the vapour, and in compliance with a ppm concentration standard of LC50 = ppm (2500 ppm < Category ppm), the substance is classified as Category 4. From a rat LC50 value > ppm (4 hour time equivalent: ppm), the substance was designated as [DFGOT vol.16 (2001)]. It should be noted that because the saturated vapor pressure concentration level was ppmv, the substance was classified using the reference value for gases. Acute toxicity - inhalation (dust): Acute toxicity - inhalation (mist): Skin corrosion/irritation: No irritation was seen in human skin when exposed (EHC 143 (1992), DFGOT vol. 12 (1999),

6 6/9 PATTY (4th, 1994) and ATSDR (1992)), but skin application studies in rabbits showed mild or moderate irritation (EHC 143 (1992), DFGOT vol.12 (1999), PATTY (4th, 1994) and ATSDR (1992)). Because of this the substance was classified as Category 2. Although some unpublished data of a report that irritation was not observed in a 20 hours closed application study on rabbits [DFGOT vol.16 (2001)], the substance could not be classified due to lack of skin irritation test data. It should be noted that, there was also a report of moderate irritation after 24 hours of closed application in rabbits, but it was estimated to be due to the degreasing effect of methanol [DFGOT vol. 16 (2001)]. Eye damage/irritation: Description of eye irritation were observed in examples of vapour exposure in humans (ACGIH (7th, 2001), DFGOT vol.12 (1999), PATTY (4th, 1994) and IRIS (2003)), and in eye irritation studies using rabbits the average score for corneal opacity after 24 hours was 2. 5, although there was level 2 conjunctival redness, because subjects had almost completely recovered within 7 days (ECETOC TR48 (1992)), the substance was classified as Category 2B. In a Draize test using rabbits, at 24, 48, 72 hours after application the average conjunctivitis score (2.1) was 2 or more, and conjunctival edema were observed for up to 4 hours (score 2.00) but had improved significantly by 72 hours (score 0.50) (EHC 196 (1997)). However, because it is unknown whether they recovered within 7 days, the substance was classified as Category 2 without subdivision. Respiratory or skin sensitization: Respiratory: Skin: Although there was a description of one case of contact dermatitis in the same original literature (EHC 143 (1992), DFGOT vol. 12 (1999), PATTY (4th, 1994) and ATSDR (1992)), there were no other case reports, and since there was a negative result from the Mouse Ear Swelling Test (DFGOT vol.12 (1999) and PATTY (4th, 1994)), the substance was classified as Not identified due to insufficient data. Sensitization - respiratory:. Skin sensitization: Based on reports that sensitization was not observed in skin sensitization studies using guinea pigs (Magnusson-Kligman maximization test) [EHC 196 (1997)], the substance was designated as. Furthermore, although there were some reports of a slight positive reaction in human patch tests, there is also the possibility of cross-reaction with other alcohols, or skin reactions such as erythema after drinking alcohol, so it could not be concluded that methanol causes sensitization ((DFGOT vol.16 (2001))). Germ cell mutagenicity: Because it was classified as I (Inadequate) by the EPA, it was designated. Because in the in-vivo micronucleus test using mouse red blood cells (somatic cell in-vivo mutagenicity test), the results for both inhalation exposure [EHC 196 (1997)] and intraperitoneal administration were negative [DFGOT vol.16 (2001), PATTY (5th, 2001)], the substance was designated as. It should be noted that only the metabolic activation of the mouse lymphoma assay (S9 +) yielded positive results [EHC 196 (1997), DFGOT vol. 16 (2001)], whereas the in vitro mutagenicity tests such as the Ames test [EHC 196 (1997), DFGOT vol. 16 (2001), PATTY (5th, 2001)] the mouse lymphoma assay [EHC 196 (1997), DFGOT vol. 16 (2001)], and the chromosome aberration test using CHO cells [DFGOT vol.16 (2001)], yielded negative results.

7 7/9 Carcinogenicity: Because it was classified as I (Inadequate) by the EPA, it was designated. In an unpublished report by the New Energy and Industrial Technology Development Organization (NEDO), it was reported that there were no carcinogenic effects in studies using rats, mice, and monkeys [EHC 196 (1997)]. Also, in a study using rats in which the substance was administered in drinking water from 8 weeks of age until natural death, it has been reported that the occurrence of cancer in the head and neck in both sexes, and blood lymphoreticular tumors in females, increased significantly in a dose-dependent manner (ACGIH (2009)). However, unlike determination of tumors using standard methods, because it is not performed after the natural death of the animal, evaluation or comparison are considered to be difficult. Not identified due to the conflicting information above. Toxic to reproduction: Observation of malformations in the fetus in inhalation exposure teratogenicity studies in rats were described in (EHC 143 (1992), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)). However, although delayed ossification and bone mutations were seen in the re-test, no deformities were observed (EHC 143 (1992), ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994 ), IRIS (2003) and ATSDR (1992)). Furthermore, although mutation and low bodyweight were observed in young mice in teratogenicity studies using inhalation exposure in mice, no defects were observed (EHC 143 ( 1992), ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)). From this it was determined that all effects were minimal, and the substance designated. Fetal resorption, exencephaly, etc. were observed in studies using inhalation exposure during the organ formation phase of pregnant mice, [PATTY (5th, 2001)], and similar results, including cleft palate, were obtained from yet other studies using inhalation or oral exposure [EHC 196 (1997), DFGOT vol. 16 (2001)]. With respect to the reproductive effects of methanol, it has been scientifically determined to be a health hazard based on the weight of available evidence. And although human data is lacking, because there is a clear evidence of the influence on animals, it has been concluded that with sufficient exposure methanol has an adverse effect on development in humans [NTP-CERHR Monograph (2003)]. Based on the above, the substance is suspected of developmental toxicity in humans, and was classified as Category 1B. STOST-single exposure: In studies by inhalation exposure in humans no effect on the central nervous system was observed (EHC 143 (1992), DFGOT vol. 12 (1999), IRIS (2003) and ATSDR (1992)). And the results of the time estimation test show that there was no statistically significant difference from the control group (EHC 143 (1992) and PATTY (4th, 1994)). On the other hand, in inhalation exposure studies in rats and mice, effects on the central nervous system were observed at relatively low concentrations (EHC 143 (1992), PATTY (4th, 1994) and IRIS (2003)). From this fact the target organ was determined to be the central nervous system, and the substance was classified as Category 1. In addition, because effects on the kidneys were observed after oral administration of moderate doses in rats (DFGOT vol. 12 (1999), IRIS (2003) and ATSDR (1992)), the kidney is also determined to be a target organ, and the substance classified as Category 2. Furthermore, because respiratory tract irritation was observed in examples of human inhalation exposure (ACGIH (7th, 2001), DFGOT vol. 12 (1999), PATTY (4th, 1994), IRIS (2003) and ATSDR (1992)), the substance was classified as Category 3.

8 8/9 Symptoms of acute poisoning in humans manifest as suppression of the central nervous system leading to metabolic acidosis due to the accumulation of formic acid in the blood. Also there are symptoms such as visual impairment, blindness, headaches, dizziness, nausea, vomiting, tachypnea, and coma, which are described as leading to death at times (DFGOT vol. 16 (2001), EHC 196 (1997)). In addition, there are descriptions of disorders of the central nervous system, in particular symptoms like shaking palsy of the extrapyramidal system (DFGOT vol. 16 (2001)), and necrosis of the white matter of the brain has also been reported as a morphological change (DFGOT vol. 16 (2001)). Based on this information concerning humans, the substance was classified as Category 1 (central nervous system). Furthermore, because eye damage is characteristic, the visual organs were determined to be the target organ, and because headache, nausea, vomiting, tachypnea, coma, etc. were also described as symptoms underpinning metabolic acidosis, systemic toxicity was adopted for each. On the other hand, because "anesthesia" is described among the finding from inhalation exposure studies in mice and rats (EHC 196 (1997), PATTY (5th, 2001)), and anesthetic action due to suppression of the central nervous system is described among the findings related to acute intoxication of humans (PATTY (5th, 2001)), the substance was classified as Category 3 (anesthetic actions). STOST-repeated exposure: Numbness of the hands and arms was seen in examples of occupational exposure in humans (EHC 143 (1992), DFGOT vol. 12 (1999) and IRIS (2003)), indications of central nervous system disorders in examples of occupational exposure were described in (DFGOT vol. 12 (1999) and IRIS (2003)), and effects on the central nervous system were observed in 3 cases described in (IRIS (2003)). Because of this, the target organs were determined to be the central nervous system and peripheral nervous system, and both were classified as Category 1. With a wide range of eye damage described as the prominent symptom of long-term exposure to low concentrations of methanol in humans [EHC 196 (1997)], and blindness observed as a chronic toxic effect of occupational exposure to methanol [ACGIH (7th, 2001)], the substance was classified as Category 1 (visual organs). Also, because repeated exposure to methanol vapors was described as causing headache, dizziness, insomnia, and stomach disorders as symptoms of chronic toxicity [ACGIH (7th, 2001)], the substance was classified as Category 1 (central nervous system). In addition, liver weight changes and liver cell hypertrophy have been reported in oral administration studies in rats [PATTY (5th, 2001), IRIS (2005)], but these were thought to be adaptive changes, and so were not utilized. Aspiration toxicity: Because it is a normal class 1 alcohol consisting of 3 or more, but not exceeding 13 carbon atoms, corresponding to isobutyl alcohols and ketones composed of not more than 13 carbon atoms, it was classified as Category Ecological information Environmental Behavior:

9 9/9 Ecotoxicity 1) : Persistence and degradability: Ecological bioaccumulation: Mobility in soil: 13 Disposal considerations Scrap materials may be disposed by licensed contractor or burned in an approved incinerator. Do no dump into sewer, on the ground or into any body of water. Follow national and local regulations. 14 Transport information Follow all regulations in your country. UN Number : 1210 UN Proper Shipping Name : Printing ink related material Transport hazard class : Class 3 (Flammable liquid) Packing Group : II Environmental hazards :No 15 Regulatory information Follow all regulations in your country. Content of RoHS Directive materials Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm 16 References Cited Literature: 1) Results of Eco-toxicity tests of chemicals conducted by Ministry of the Environment in Japan 2) International Chemical Safety Cards

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