HENKEL LOCTITE CORPORATION 1001 TROUT BROOK CROSSING 02/26/03 ROCKY HILL, CONNECTICUT EMERGENCY PHONE: (860)
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1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Type: Surface Treating 2. COMPOSITION, INFORMATION ON INGREDIENTS MATERIAL SAFETY DATA SHEET Page 01 of 05 Ingredients CAS No. % TOLUENE* METHYL ETHYL KETONE* Hydrotreated heavy naphtha Phenolic resin Proprietary 1-5 CARBON BLACK Aluminum salt XYLENES* * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) TOLUENE 50 ppm skin 100 ppm None 188 mg/m3 skin 375mg/M3 METHYL ETHYL KETONE 200 ppm TWA 200 ppm TWA None 590 mg/m3 590 mg/m3 Hydrotreated heavy naphtha None None 300 ppm Phenolic resin 10 mg/m3 10 mg/m3 None CARBON BLACK 3.5 mg/m3 TWA 3.5 mg/m3 TWA 5ppm Aluminum salt 10mg/m3 (As Al) 15mg/m3Total Al None 5 mg/m3resp(al) XYLENES 100 ppm TWA 100 ppm TWA None 434 mg/m3 435 mg/m3 Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) TOLUENE None 150 ppm 560mg/M3 METHYL ETHYL KETONE 300 ppm 300 ppm 885 mg/m3 885 mg/m3 XYLENES 150 ppm 150 ppm 651 mg/m3 655 mg/m3
2 3. HAZARDS IDENTIFICATION MATERIAL SAFETY DATA SHEET Page 02 of 05 Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Eye and skin irritant. Moderately toxic by ingestion. Estimated dermal LD50 more than 2000 mg/kg. Inhalation, absorbtion, ingestion, contact. Nausea, headache, loss of coordination. Toluene: Eye, liver, skin, respiratory and central nervous system diseases; alcoholism. Methyl ethyl ketone: Eye problems, skin and respiratory disorders. Carbon black: Respiratory disorders. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA TOLUENE BEH CAR CNS DEV EAR IRR NO NO NO METHYL ETHYL KETONE CNS IRR NO N/A NO Hydrotreated heavy naphtha NTO NO NO NO Phenolic resin No Data NO NO NO CARBON BLACK RES NO 2B NO Aluminum salt No Data NO NO NO XYLENES CAR CNS IRR KID LIV NO NO NO Abbreviations N/A Not Applicable BEH Behavioral CNS Central nervous system EAR Ear KID Kidney NTO No Target Organs 2B Possibly carcinogenic to humans CAR Cardiac DEV Developmental IRR Irritant LIV Liver RES Respiratory 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: Induce vomiting. Keep individual calm. Obtain Remove to fresh air. If symptoms persist, obtain Wash with soap and water. Flush at least 15 minutes with water. Obtain
3 5. FIRE FIGHTING MEASURES MATERIAL SAFETY DATA SHEET Page 03 of 05 Flash Point: 30 F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Special Firefighting Procedures: Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)lower 1 % Xylene 2.0% Methyl ethyl Ketone 1.4% Toluene 0.9% Naphtha (% by volume in air)upper 7% Xylene 11.4% Methyl ethyl ketone 7.6% Toluene 6% Naphtha 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Maintain adequate ventilation. Soak up with an inert absorbent. Store in a closed container away from sources of ignition until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100 F. (Contact Loctite Customer Service for shelf life information) Handling: Keep away from eyes. Avoid prolonged breathing of vapor. Avoid prolonged skin contact. Avoid sources of ignition. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Safety glasses or goggles. Rubber or plastic gloves. Provide adequate local ventilation to maintain vapor concentration below TLV. See Section 2 for Exposure Limits.
4 9. PHYSICAL AND CHEMICAL PROPERTIES MATERIAL SAFETY DATA SHEET Page 04 of 05 Appearance: Black liquid Odor: Sweet Boiling Point: Approximately 190 F ph: Does not apply Solubility in Water: Slight Specific Gravity 0.85 at 80 F Volatile Organic Compound (EPA Method 24) 83.8%; 712 grams per liter Vapor Pressure: Vapor Density: Evaporation Rate (Ether = 1) STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents, strong acids Conditions to Avoid: Hazardous Decomposition Products (non-thermal): Hydrogen chloride, carbonyl chloride 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS See Section 3. No data available Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number D001 - Hazardous waste per 40CFR TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Hazard Class or Division: Consumer Commodity (Not more than one liter); Flammable liquids, n.o.s., (Contains toluene and ethyl methyl ketone) (More than one liter) ORM-D (Not more than one liter); Class 3, Packing Group II (More than one liter)
5 MATERIAL SAFETY DATA SHEET Page 05 of TRANSPORTATION INFORMATION (continued) Identification Number: None (Not more than one liter); UN 1993 (More than one liter) Marine Pollutant: None IATA Proper Shipping Name: Flammable liquid, n.o.s. (Contains toluene and ethyl methyl ketone) Class or Division: Class 3, Packing Group II UN or ID Number: UN REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Toluene, Carbon Black 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 3 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 3 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto / Rajal Dhruva Title: Research Chemist, Environmental Health & Safety Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: February 26, 2003 Revision: 0034
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