*** SAFETY DATA SHEET ***

Transcription

1 *** SAFETY DATA SHEET *** 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME Permabond 802 RECOMMENDED USE SUPPLIER Adhesive Permabond Engineering Adhesives Ltd Wessex House Upper Market Street Eastleigh Hampshire SO50 9FD Telephone: +44 (0) Fax: +44 (0) COMPOSITION/INFORMATION ON INGREDIENTS COMPONENT EC NUMBER CONCENTRATION % EC SYMBOL RISK PHRASES Ethyl-2-cyanoacrylate >50 XI R36/37/38 For full text of risk phrases, please refer to Section HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IRRITANT EYE SKIN CONTACT INHALATION INGESTION PHYSICO-CHEMICAL On contact, will bond eyelids together. Vapours are lachrymatory. Will cause eye irritation. On contact, immediate bonding of the skin will occur. Irritating to the skin. Vapour may be irritant to the respiratory tract. On contact, immediate bonding of mouth could occur. No unusual hazards are expected. PAGE 1 OF 6

2 ENVIRONMENTAL Unknown. 4. FIRST-AID MEASURES EYE SKIN CONTACT INHALATION INGESTION Get medical attention immediately. Flush with large amounts of water while holding eyelids open. Cured adhesive will not bond well to surface of the eye, but corneal damage from abrasion may result. Immediate medical attention is not required. No attempt should be made to remove material from skin or to remove contaminated clothing, as the bonded skin can be easily torn. If symptoms develop, obtain medical attention. Immediate medical attention is not required. Remove to fresh air. Get medical attention if irritation persists. Immediate medical attention is not required. Treat symptomatically and supportively. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA CO2; Dry Chemical; Foam SPECIAL FIREFIGHTING PROCEDURES Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. FIRE & EXPLOSION HAZARDS Cloths used to wipe up spill may cause rapid polymerisation that could generate sufficient heat to ignite the cloth. HAZARDOUS COMBUSTION PRODUCTS Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide, and hydrogen cyanide. LOWER EXPLOSION LIMIT (%) UPPER EXPLOSION LIMIT (%) AUTOFLAMMABILITY FLASH POINT > 81 C 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES Small spills: wipe up with cloth. Immediately soak cloth with water to polymerize the adhesive. Caution! Cloth containing adhesive may undergo autoignition if not soaked with water. Large spills: flood area with water. When cured, remove film with a scraper. Wear approved respirator for organic vapours if needed, and protective clothing. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. PAGE 2 OF 6

3 7. HANDLING AND STORAGE STORAGE TEMPERATURE HANDLING/STORAGE SENSITIVE TO STATIC ELECTRICITY SENSITIVITY TO MECHANICAL IMPACT <5 C Store in cool, dry place. No No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENT Ethyl-2-cyanoacrylate EXPOSURE LIMITS UK EH40 OES 15 minute STEL: 0.3 ppm UK EH40 OES 15 minute STEL: 1.5 mg/m 3 OCCUPATIONAL EXPOSURE CONTROLS VENTILATION REQUIREMENTS Normal (mechanical) room ventilation should be adequate for small volumes. For higher volume activities, or if needed for worker comfort, local mechanical exhaust should be provided. EYE PROTECTION Safety glasses, goggles or face shield to protect against splashing. REQUIREMENTS GLOVE REQUIREMENTS Personal eye protection should conform to EN 166. Nitrile rubber or Viton gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. CLOTHING REQUIREMENTS Uniforms, coveralls, or a lab coat should be worn. WASH REQUIREMENTS Wash before eating, drinking, or using toilet facilities. RESPIRATORY REQUIREMENTS None required under normal handling conditions. PAGE 3 OF 6

4 9. PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR PREPARATION Preparation. PHYSICAL FORM Liquid COLOUR Colourless ODOUR Pungent ODOUR THRESHOLD ph AS IS OXIDIZING PROPERTIES BOILING POINT >200 C MELTING/FREEZING POINT SOLUBILITY IN WATER Insoluble PARTITION COEFFICIENT (noctanol/water) VISCOSITY Approximately 2-50 mpa.s RELATIVE DENSITY 1.07 BULK DENSITY EVAPORATION RATE VAPOUR PRESSURE (mmhg) <0.5 VAPOUR DENSITY (air=1) VOLATILES None VOLATILE ORGANIC COMPOUNDS < 5 g/litre AUTOFLAMMABILITY FLASH POINT > 87 C 10. STABILITY AND REACTIVITY STABILITY CONDITIONS TO AVOID MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS Stable Elevated temperatures. Water., Amines., Bases., Peroxides. Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide, and hydrogen cyanide. 11. TOXICOLOGICAL INFORMATION EYE SKIN INHALATION INGESTION EFFECTS OF CHRONIC EXPOSURE On contact, will bond eyelids together. Vapours are lachrymatory. Will cause eye irritation. On contact, immediate bonding of the skin will occur. Irritating to the skin. Vapour may be irritant to the respiratory tract. On contact, immediate bonding of mouth could occur. Under EU legislation the cyanoacrylates do not require classification as sensitisers and the rapid polymerisation caused on contact with moisture makes this unlikely. However the American Conference of Governmental Industrial Hygienists (ACGIH) has reported some limited evidence of skin and respiratory sensitisation. PAGE 4 OF 6

5 TARGET ORGANS RESPIRATORY SENSITIZATION CARDIAC SENSITIZATION POSSIBLE BIRTH DEFECT HAZARD CARCINOGEN SKIN SENSITIZATION Respiratory system, Skin. May cause allergic reaction. No. No. No. May cause allergic reaction. 12. ECOLOGICAL INFORMATION POTENTIAL EFFECT ON Unknown. ENVIRONMENT AQUATIC TOXICITY None Established POTENTIAL TO BIOACCUMULATE Unknown. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS EMPTY CONTAINER WARNINGS Waste disposal should be in accordance with existing Community,National and local regulations. Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) IATA CLASSIFICATION IMDG CLASSIFICATION ADR/RID PROPER SHIPPING NAME Aviation Regulated Liquid n.o.s (only applies to inner containers >1 litre) TECHNICAL NAME Contains Ethyl-2-cyanoacrylate HAZARD CLASS 9 U.N. NUMBER UN3334 PACKAGING GROUP N/A Not classified as dangerous. Not classified as dangerous. PAGE 5 OF 6

6 15. REGULATORY INFORMATION EC INDICATION OF DANGER EC SYMBOL IRRITANT RISK PHRASES SAFETY PHRASES SPECIAL PHRASES EINECS R36/37/38 - Irritating to eyes, respiratory system and skin. S23 - Do not breathe gas/fumes/vapour/spray. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. 16. OTHER INFORMATION REVISION 26/04/2004 REPLACES VERSION DATED ORIGINAL DOCUMENT DATED 26/04/2004 CHANGES SINCE PREVIOUS ISSUE FOR REGULATORY INFORMATION, CONTACT: New MSDS Permabond Engineering Adhesives Ltd Wessex House Upper Market Street Eastleigh Hampshire SO50 9FD Telephone: +44 (0) Fax: +44 (0) help.europe@permabondllc.com FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Ethyl-2-cyanoacrylate R36/37/38 Irritating to eyes, respiratory system and skin. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. PAGE 6 OF 6