MATERIAL SAFETY DATA SHEET. 1. Product and Company Identification

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1 MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name CAS # Product use Manufacturer Supplier LEGEND HMIS/NFPA Severe Serious 4 Moderate 2 Slight 1 Minimal 0 Toilet Seat Cleaner - (Refill) Mixture Cleaner Technical Concepts Bentfield BV Ampèrestraat HB Hillegom, Netherlands Phone: + 1 (0) Kruger Products LP Minnesota Court Mississauga, Ontario L5N 5R5, Canada Phone: Fax: Emergency Phone: Health * 2 Flammability Physical Hazard 0 Personal Protection X 2 Hazards Identification 2 0 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects DANGER Flammable liquid - may release vapors that form flammable mixtures at or above the flash point EYE IRRITANT Skin irritation possible with prolonged exposure Eye, Skin contact, Skin absorption, Inhalation, Ingestion Causes irritation, redness and tearing May cause irritation Harmful if inhaled Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness) Harmful or fatal if swallowed May cause stomach distress, nausea or vomiting Blood Eyes Liver Respiratory system Skin Prolonged or repeated exposure can cause drying, defatting and dermatitis Symptoms are prostration, gasping, pallor, and uncoordinated movements Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Components of this product have been identified as having potential environmental concerns Composition / Information on Ingredients Ingredient(s) CAS # Percent Ethanol First aid procedures Eye contact 4 First Aid Measures If in contact with eyes, immediately flush with water Obtain medical attention if irritation persists #2050 Page 1 of 6 Issue date 1-Jan-2011

2 Skin contact Inhalation Ingestion Notes to physician General advice Flammable properties Immediately flush with water Wash with soap and water Obtain medical attention if irritation persists If inhaled, move person to fresh air If symptoms persist, obtain medical attention If ingested, do not induce vomiting Obtain medical attention immediately Symptoms may be delayed Keep away from sources of ignition No smoking Avoid contact with eyes Wear suitable protective clothing Keep out of reach of children Immediate medical attention is required Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance If you feel unwell, seek medical advice (show the label where possible) 5 Fire Fighting Measures Flammable by WHMIS/OSHA criteria Vapors may travel to a source of ignition and flash back Containers may explode when heated Extinguishing media Suitable extinguishing media Carbon dioxide Water spray Dry chemical Foam Water Fog Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Stop leak if you can do so without risk Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use Handling Storage 7 Handling and Storage For external use only When using, do not eat, drink or smoke Keep away from heat, sparks and open flame DO NOT get in eyes Use good industrial hygiene practices in handling this material Do not get this material in your eyes, on your skin, or on your clothing Do not ingest Wash hands before breaks and immediately after handling the product Keep out of reach of children Do not store at temperatures above 120 F (49 C) Store in a closed container away from incompatible materials Keep away from heat, open flames or other sources of ignition #2050 Page 2 of 6 Issue date 1-Jan-2011

3 Exposure limits Ingredient(s) 8 Exposure Controls / Personal Protection Exposure Limits Ethanol Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection Provide adequate ventilation ACGIH-TLV TWA: 1000 ppm STEL: 1000 ppm OSHA-PEL TWA: 1000 ppm Avoid contact with eyes Wear safety glasses with side shields Avoid contact with the skin Rubber gloves Confirm with a reputable supplier first As required by employer code Not normally required if good ventilation is maintained and exposure guidelines are not exceeded Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact 9 Physical and Chemical Properties Appearance Clear Color Colorless Form aqueous solution Odor Alcohol Odor threshold Physical state Liquid ph 6-8 Melting point Freezing point Boiling point > F (> 78 C) Pour point Evaporation rate Flash point 7520 F (24 C) Tag Closed Cup Auto-ignition temperature > F (> 70 C) Flammability limits in air, lower, % (ethanol) by volume Flammability limits in air, upper, % 19 (ethanol) by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Solubility (H2O) Percent volatile Complete Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid 10 Stability and Reactivity This product may react with strong acids Hazardous polymerization does not occur Stable under recommended storage conditions Avoid high temperatures Do not mix with other chemicals #2050 Page of 6 Issue date 1-Jan-2011

4 Incompatible materials Acids Oxidizers Caustics Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Ethanol Component analysis - Oral LD50 Ingredient(s) 162 ppm rat LD50 Ethanol Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Causes irritation, redness and tearing May cause irritation 450 mg/kg mouse; 7060 mg/kg rat Harmful if inhaled Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness) Harmful or fatal if swallowed May cause stomach distress, nausea or vomiting The finished product is not expected to have chronic health effects The finished product is not expected to have chronic health effects See below ACGIH - Threshold Limit Values - Carcinogens Ethanol A - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC - Group 1 (Carcinogenic to Humans) Ethanol Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [in preparation] (in alcoholic beverages) Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Fish - Acute Toxicity Data Ethanol Hr LC50 Oncorhynchus mykiss: ml/l [static]; 96 Hr LC50 Pimephales promelas: >100 mg/l [static]; 96 Hr LC50 Pimephales promelas: mg/l [flow-through] Ecotoxicity - Water Flea - Acute Toxicity Data Ethanol Hr LC50 Daphnia magna: mg/l; 24 Hr EC50 Daphnia magna: mg/l; 48 Hr EC50 Daphnia magna: 2 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects 1 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations #2050 Page 4 of 6 Issue date 1-Jan-2011

5 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Ethanol, solution Hazard class UN number Packing group Additional information: Special provisions Packaging exceptions ERG number UN1170 III 24, IB2, T4, TP Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name ETHANOL more than 24 per cent ethanol, by volume Hazard class UN number Packing group UN1170 III 15 Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - WHMIS - Ingredient Disclosure List Ethanol % WHMIS status Controlled WHMIS classification Class B - Division 2 - Flammable Liquid, Class D - Division 2B WHMIS labeling Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US Federal regulations Yes CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 02 extremely hazardous substance This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No No #2050 Page 5 of 6 Issue date 1-Jan-2011

6 Section 11 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) State regulations See below US - California - 8 CCR Section 9 - Director's List of Hazardous Substances Ethanol Present (refers to solutions greater than or equal to 25% which are not beverage alcohols) US - California - Proposition 65 - Developmental Toxicity Ethanol developmental toxicity, initial date 10/1/87 (when in alcoholic beverages) US - Massachusetts - Right To Know List Ethanol Teratogen US - Minnesota - Hazardous Substance List Ethanol Present US - New Jersey - Right to Know Hazardous Substance List Ethanol sn 0844 US - Pennsylvania - RTK (Right to Know) List Ethanol Present US - Rhode Island - Hazardous Substance List Ethanol Toxic; Flammable Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) No Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory Yes Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 1-Jan-2011 Issue date Effective date 01-Jan-2011 Expiry date 01-Jan-2014 Prepared by Dell Tech Laboratories Ltd (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document #2050 Page 6 of 6 Issue date 1-Jan-2011