Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Date: 08/16/2005 Issue date: 08/16/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product type: Sealant Region: United States Company address: Contact Information: Henkel Corporation Telephone: Trout Brook Crossing Emergency telephone: Rocky Hill, Connecticut Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER mg/m³ TWA respirable fraction, particulate matter containing no asbestos and < 1% crystalline silica 15 mg/m³ TWA total dust 5 mg/m³ TWA respirable fraction ppm TWA 400 ppm STEL 400 ppm TWA 980 mg/m³ TWA mg/m³ TWA respirable fraction, particulate matter containing no asbestos and < 1% crystalline silica = 20 mppcf TWA 50 ppm mg/m³ TWA 3.5 mg/m³ TWA mg/m³ TWA respirable fraction 0.1mg/m³ TWA (respirable) 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Viscous liquid HEALTH: 2* Color: Dark brown FLAMMABILITY: 3 Odor: Alcoholic PHYSICAL HAZARD: 0 Personal Protection: See Section 8 WARNING: HMIS: FLAMMABLE LIQUID AND VAPOR. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact Potential Health Effects Inhalation: Skin contact: Vapors and mists will irritate the respiratory tract and nasal passages. May cause allergic skin reaction. May cause skin irritation. Burning sensation. Redness. 1 of 5

2 Eye contact: Contact with eyes will cause irritation. Redness. Swelling. Stinging. Ingestion: Not expected to be harmful by ingestion. Existing conditions aggravated by exposure: Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If discomfort persists seek medical attention. Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and shoes. Get medical attention if symptoms develop and persist. Wash clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: 24.4 C (76 F) Tagliabue closed cup Autoignition temperature: C (750 F) Flammable/Explosive limits-lower %: 2.3 % Flammable/Explosive limits-upper %: 12.7 % Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Aldehydes. Carboxylic acids. Irritating organic vapors. Oxides of carbon. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Remove all ignition sources. Maintain good ventilation for large spills. Soak up with inert absorbent. Scrape up spilled material and place in sealed container for disposal. 7. HANDLING AND STORAGE Handling: Storage: Incompatible products: Use only with adequate ventilation. Keep away from heat, spark and flame. Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Store away from heat, sparks, flames, or other sources of ignition. Store in original container until ready to use. Oxidizing and spontaneously flammable products. For information on product shelf life contact Henkel Customer Service at (800) of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Provide adequate ventilation. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use impermeable gloves and protective clothing as necessary to prevent skin contact. Chemical splash goggles or safety glasses with side shields. See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Viscous liquid Color: Dark brown Odor: Alcoholic Vapor pressure: 33 C (68 F) ph: Not applicable Boiling point/range: Boiling point/range: 82.2 C (180 F) Melting point/range: Specific gravity: 1.37 Vapor density: Heavier than air Evaporation rate: Solubility in water: Partial Partition coefficient (n-octanol/water): Not determined VOC content: 15.2% (EPA Method 24) 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable. Will not occur. Oxides of carbon. Aldehydes. Strong oxidizing agents. Flammable materials. Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen No Group 2B Yes Known Carcinogen Group 1 Yes Literature Referenced Target Organ & Other Health Effects 3 of 5

4 Hazardous components Health Effects/Target Organs Nuisance dust No data Respiratory, Irritant, Allergen Allergen, Blood, Central nervous system, Irritant, Kidney, Liver, Brain, Spleen Some evidence of carcinogenicity, Lung, Irritant Respiratory, Some evidence of carcinogenicity Some evidence of carcinogenicity, Lung, Immune system 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of in accordance with Federal, State and local regulations. D001: Ignitable. 14. TRANSPORT INFORMATION The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Hazard class or division: 3 Identification number: UN 1866 Exceptions: (Not more than 5L) Consumer Commodity ORM-D International Air Transportation (ICAO/IATA): Hazard class or division: 3 Identification number: UN1866 Exceptions: (Not more than 500 ml) Consumer Commodity ORM-D, ID8000 WaterTransportation (IMO/IMDG): Hazard class or division: 3.2 Identification number: UN of 5

5 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory... Immediate Health Hazard, Delayed Health Hazard, Fire. This product contains a chemical known to the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: Contains one or more components listed on the Non-Domestic Substances list. B.2, D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 16 Prepared by: Kyra Kozak Woods, Product Safety and Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. 5 of 5